Tutorial 7 - Equilibrium

9.28 Write the equilibrium constant expression for each of the following reactions in terms of molar
concentrations.

(a) 2PCl3(g) + O2(g) 2POCl3(g)

(b) 2SO3(g) 2SO2(g) + O2(g)

(c) N2H4(g) + 2O2(g) 2NO(g) + 2H2O(g)

(d) N2H4(g) + 6H2O2(g) 2NO2(g) + 8H2O(g)

(e) SOCl2(g) + H2O(g) SO2(g) + 2HCl(g)

(f) 3Cl2(g) + NH3(g) NCl3(g) + 3HCl(g)

(g) PCl3(g) + PBr3(g) PCl2Br(g) + PClBr2(g)

(h) NO(g) + NO2(g) + H2O(g) 2HNO2(g)

(i) H2O(g) + Cl2O(g) 2HOCl(g)

(j) Br2(g) + 5F2(g) 2BrF5(g)

9.20 How will the equilibrium:

be affected by the following?

(a) addition of CH4(g)
(b) addition of H2(g)
(c) removal of CS2(g)
(d) decreasing the volume of the container
(e) increasing the temperature (the forward reaction is endothermic)

9.32 Use the following equilibria:

to calculate Kc for the reaction:

9.47 The heterogeneous reaction:

has Kc = 1.6 10-34 at 25 C. Suppose 0.100 mol each of HCl and solid I2 are placed in a 1.00 L
container. Calculate the equilibrium concentrations of HI and Cl2 in the container.

9.50
The reaction NO2(g) + NO(g) N2O(g) + O2(g) has . A 1.00
L reaction vessel at 1273 K contains 0.0200 mol NO2, 0.040 mol NO, 0.015 mol N2O and
0.0350 mol O2. Is the reaction mixture at equilibrium? If not, in which direction will
spontaneous change occur to reach equilibrium?

9.67 At 25 C, 0.0560 mol O2 and 0.020 mol N2O were placed in a 1.00 L container where the
following equilibrium was then established:

2N2O (g) +3O2(g) 4NO2(g)

At equilibrium, the NO2 concentration was 0.020 M. What is the value of Kc for this reaction?

9.76 At 500 C, the decomposition of water into hydrogen and oxygen:

has Kc = 6.0 10-28. What amounts of H2 and O2 are present at equilibrium in a 5.00 L reaction
vessel at this temperature if the container originally held 0.015 mol H2O?

10.55 The molar solubility of Ba3(PO4)2 in water at 25 C is 1.4 10-8 mol L-1. What is the value of
Ksp for this salt?

10.70 Does a precipitate of PbCl2 form when 0.0150 mol of Pb(NO3)2 and 0.0120 mol of NaCl is
dissolved in 1.00 L of solution at 25 C? (Ksp PbCl2 = 1.7x10-5)