1994. SAT CHEMISTRY SUBJECT TEST For alt question involving solutions andor chemical equations, sssume thatthe sytem isin pure water unless ‘srwive sated. Part A rs ‘Each st of letered choices below refers the numbered questions or statements immediatly folowing Disssions: pesStect the one lettered choice that best answers each question or best its each statement, and then fill nthe corre ‘ponding ovel onthe answer sheet. A choice may be used once, more than once, or not aan ach set Questions 1-4 XY @®) xY Om Oxy; © xy Which ofthe above represents the formula forthe mos common compound of X and ¥, where X and Y repre= Sent piven pais of elements as indicated below? ny LoMe a creor aN OW ao Questions 59 (a) cr07" @ Ht © on- @) ce Bet? Which of the above isthe appropriate ion foreach ‘lank in the following series of reactions? oF +), —— co + Bact (yellow pes |e rods) Se ne + CHOP + 140 iitte) 8 $040.1" 80,4) +9) + HOQuestions 10-12 (A) ses bonds (®) s-p bonds © pep bonds (©) spp bonds (8) sp*ap* bonds (0, esribes the bonding in He 1, Desertes she bonding in HF 2, Describes the bonding in Fs Questions 13:15 rete 0 che following elements (A) Liaiom (B) Sedium (©) Powessium (B) Rubicam (8) Cesium 1, Which forms the smallest ofthe +1 fons? 14 Which has the Largest atomic radius? 15, Which has the smales rt ionization energy? Questions 16:18 (A) Element with atomic number 2 (8) Bement with stomic number 7 (C) Element with stomic number 19 {D) Element wth tome number 35 {E)_ Element with atone number 74 16 An element that reacts vigorously with water 17, A transition element 18. An element whese chemical properties are similar to those ofehiorne 19, An element tat forms diatomic molecules that have triple bonds Questions 20-22 refer to the Following processes, (A) Precipitation {) Oxidation-reduction (©) Disilation | (D) Hyération (8) Condensation 20, Electrolysis of water v form hydrogen and oxygen nes 21, Reaction of silver fon with chloride ion in water solution 22, Reaction of iron flings with powered sulfur Questions 23-25 wy @ x oy m © 3 ¢ x 2, Could bea plot of he presue ofa as (») again the volume (a) for one mols an lal ost ed temperature 24, Could bes plot ofthe pressure ofa gas (y') against the absolute venperature (%) Tor one mole of an ideal gas in fixed volume 25, Could be the plot of the average molecular kinetic ‘energy of molecules (3) spainst te absolute - perature (x) for one oe of an eal gasCHEMISTRY TEST—Continued PLEASE GO TO THE SPECIAL SECTION AT THE LOWER LEFT-HAND CORNER OF paGE2 OF YOUR ANSWER SHEET LABELED CHEMISTRY AND ANSWER QUESTIONS [ol-I3 ACCORDING TO THE FOLLOWING DIRECTIONS. Par B EN _________ Diazaung: Each question below consists of two satements nthe left-hand column and Tin the right-band alum, For each question, determine whether statement Iis true or false and whether statement I is tue oF {Sse and fill nthe eoresponding T or F ovals on your answer sheet, Ellin oval CE only {statement His tomee explanation of statement [ EXAMpLes: EX 1, H,SO.isastrong acid. BECAUSE _H,80, contains sulfur. EX2. Anotomofonygenis BECAUSE sn oxygen atom contains an equal, sletrialy neutral umber of protons and electrons ca SAMPLE ANSWERS saeo 2 alee y a (ol, Teesapect a waermukeuleis near BECAUSE — the bond ina water mole are nonpi 102, Some sinha pasties shot ata thin meal fol BECAUSE alpha particles shot at thin meta fol some fre reflected back toward the source imes approach the nucle of the metal atoms head-on and are thus repelled. 103, Potassium permangonate is a colored BECAUSE both potassium and manganese are metals, compourd Jo A molecue of sion tetrachloride, SICly, is BECAUSE the four bonds in SiCl, ae identical and the sompokit 105, When solid KNO. dissolves in water, BECAUSE solid KNO) dissociates into K* and NO; covalent bonds ae Broken fons in wate. 106. An clement thot as he ekestzon configu: BECAUSE i atoms of transition elements, the ration Ta" 2s2g¢ poh 4 isa 1h, Br 2p, Arand 3p orbitals ar completely (eanstion clement filled in the ground state. 101. The restion of hydrogen with oxygen to BECAUSE water molecules have polar covalent bonds (orm water ian exetRermie rexeton Cetera aesCHEMISTRY TEST—Continued W 108. 4 clement whore atoms have an out BECAUSE metallic elements readily pan elecrons, on configuration. 30! shows metalic Properties 108, H:0 ond HO; hve the same empirical «BECAUSE in H,0 and 1:03, oxygen hs the same Forma oxidation state 140. salt whose water Solotion hasa pH of | BECAUSE a solution having a pH of Shas higher con- hase entation of Hj0" jong than of OH” sons, 111, A bare is normally used in volumes BECAUSE a buretcan accurately measure the values of featione ‘solution delivered 112, The combustion of fuels containing sulfur BECAUSE sulfur oxides form aid solutions in wate, leeds tothe production of acid cain 13, After sastm has reached eberaeal BECAUSE reaetions are mot reversible at equilibrium, ‘lta, there no change i the Concentrations of reactants and products 14, Al the sme temperature and BECAUSE eqasl volumes of deal gases atthe same Ptr of hyéropen gas ao | Iter of neon temperature and pressure contain the sme as have the same nase runber of moles Beller Liquid Water [E ! A — Vscsum Pump A container of water i placed inside a insulated bell ar as shown above. A vacuum pump lowers the pressure 11S. When the pressure drops sufficently, BECAUSE at she boiling point, the vapor pressure the water stars 10 boll ofthe water equals the pressure inside the tel RETURN TO THE SECTION OF YOUR ANSWER SHEET YOU STARTED FOR CHEMISTRY AND’ ANSWER QUESTIONS 26-70, PeaceParc 26 4 esrtain mass of carbon requited 16 grams of copa To Be converted ito sarbon monoride, CO. Tihs sane mass of earn were to be converied ino orbon dioxide, COs, the mass of oxygen ‘oquired would be oe (A) 40 grams (i) 0 grams {Ch (2 grams {D} 32 grams {) ingeterminable for he information given 2 BOW) # He) es HO) BO) ‘When the equation forthe eation represented Shove blind and al eens ae roueed {Slbwest wholesnomor ms. be coin or NCI is : ALB? C3 Ds HE 2. fru tn portant sous oral off lowing EXCEPT. ate A acai us 1B) Stine Stine Facing os Poros Membrane 29, As shown inthe figure above, two compartments ae eporaied by a porous membrane tat i permeable Jonie salts. A sodium chloride solution i placed in one ‘Compartment while dsiled water is placed inthe oer. factors tat ifloenee the initial rate at which the water ‘ifaes int the compartment containing the NaCl Solotion inchude which ofthe following? 1, Concentriton of the som ebloride solution UI, en ofthe porous membrane AML, Temperature ofthe system | (8) Lonly (8) Wenly (©) Land ItLonly (D) Hand tt only (6) 1.1 and it 3. CIO" FF... GO" +. ‘When the equation for she eaction represented ove i balance with coeticiets reduced 0 the ibwest whole namber term, corret sorements include which ofthe following? 1. The coeticent for CI" isa UU, “The coetTicient for ClOs” is 2. ML, The oelisient for CIO” is 3 (A) Lonly (B) Monky {© only 1D) Hand If only ( Llland Ht "Dusan Fash of e ues or incomplete sateneo ew i flowed by ve uggs answers ‘ompletions. Select the one shar is best im each case up then fill inthe corresponding oval on the answer shee 2 2. 6 36. {nl he resulting sation is new solution i evaporated to dryness, the substance that fenmans ean be correctly described as whic of the following? A white, erstaline so M.A covalent solid IL, A vatersolable salt (A) Lonty (B) Toaly (©) Ito {D) Land I only 1B) hlleana it ow many milters of ©.200-molar sodium hydroxide most be added toa 100snilliter solution ‘of 0100-molr irc cd to obtain solution with 3 pH of? WW) 00m (B) 2500. (©) 500 mt (0) 100. at (8) 200. mat ihe owing tment tot aa {They irate he vale ofthe cin (0) They reds the amount of rode present ‘equilibrium. . : (©) Tey inrease the concentration of ects {(B) Ty te pean store the reaction woceed (6) Thy eb the action energy of he Complete combustion of ydracarbons produces & CHR 8) HOH,O; (©) Ry + CH,COOH, (©) CO; + 1,0 (E) CHCHACH; + CH, “The ate at which a solid dissolves in waters intense by which ofthe Following? 1 Ireng te sre of he bing he tener of heater, UL, Stirring the Sine (a) Honly (8) Toaly {© Land lt only (0) Hand th only (6) 1. tleand tt46. ”. 3. ». CHEMISTRY TEST—Continued CU) + HS OUR) ~ COX) +. $0444) +... HOC) ‘When the equation for the reaction represented above i balanced and the speicients are reduced tothe lowest whele-number terms the coelisient foe SOx) 1 12 ©3 Ms HS The ground sate eeciton configuration ofthe silicon atom i characteraed by which ofthe following? 1, Paniatly ed 3p orbitals 1 The presence of tap IME. Si valence electrons (A) Fooly (8) only (©) Land th only (©) fand Monly (©) 1.itand tir Which ofthe folowing gates i LEAST dense when allare measured under the sme conditions? (4) CO; (BG; (©) $0, OH, «NO Which ofthe ftlowing best accounts for some ofthe nonideal Behavior observed in ral eased! (A) Some gaseous molecules are not spheric. (B) There are intermolecular attractive forces, (©) The temperature fs not hept constant. (D) Re the gas constant. is not ttre constant (E} Eiperimentlerors sre made i the measure ‘ent of the pressure and the volume,CHEMISTRY TEST—Continued Questions 40 Rae ie experiment. the etiperature was held constant a 2 440 milimeters of He. gue ‘Each Bivision = am Befor injection of isopropanol 40. Acconing to Figure 1 the iil pressure inside the asks 4A) near zor (vacuum) () 27 mmHg (C) Pao mn Hi {D) (760 ~ ZT) om Hg, (&) (790 + 27) mm He 4, According to Figure TL the vapor pressure of iBonvopanol at 25°C was éeermined tobe (Ay 20mm He (B) ISmm HE {C) asm Be (B) 5mm He (E795 mi Hg 5 refer to the experiment shown below in which the vapor pressure of isopropanol was determines dna te atmosphene peesure remsined at ach Division © mm After equilrium i established 42, Which ofthe fllowing i posse source of error in the resus ofthis experimen (A) Inaceurate weighing of the isopropanol (B) ‘The presence of bus of Broken glass inthe Rash {C), Faure to corret for humidity {(D) Misreding of the atmospbecie pressure (©) Leakage around the rubber stopper 43, Which of the fliowing changes nthe experimen would cause the Mig levels ia the Utube to vary from those shown in Figure U2 (A) Replacing the Mask with one hat has a round ‘ottom (B) Doubling the volume of guid injcted into the Mask (©) tnereasng the tmperatre ofthe system owe (D) Replacing the ai originally inthe Mask with Tum gas at pressuse of 1€0 mm Hig (8) rereasing the dumeter ofthe Utube eras dens4a, Flation isa technique pareulany suited tothe Separation of Ay two solid wit different densities {B) two igi with different molar asses {EG} two igus with diferent boiling points {D) a sold and aiquid Uo) apesanda kguid 45, {n which of dhe folloning compounds does bromine Hae he hight positive oxdation stats? (a) Hae (8) BFS (C) Bros {D) NaBrO {IE} NaBeO, 46, What i the empisca formula of a compound that serthins 0025 mole of Cd, 1030 moe of C, and 11100 moe of O? (a) Caco (B) CACO, 10) CACO, {B) cac0, (8) CACO, 47, The mass of 602 % 10 molecules ofa gas is GB prams, What volute does 8.00 grams ofthe fis cecopy af standara temperate and pressure? (a) #0 ess 8) 500 hers tC) Nz hers (by 224 hers (2) 640 ers 48, Raising the temperature at wich a chemical reac: tion proceeds may do all ofthe following EXCEPT (A) increase the molecular eolision frequency {B) increase the number of molecules with energy reeter than the activation enesy (©) speedup the forward and reverse reactions ID) decrease the randomness ofthe system (2) change the relative concentrations of products o reactants that are present at equilibrium 49, To determine whether a water solution of Nas6:O3 at room temperate fs supersaturated, one cam (A) heat the sotution to its boiling point {B) add water tothe solution {C) add a crystal of Naj03 tothe solution {D) acidity the solution {8} cool the slution 10 ls eezing point estions 50-52 ‘The following elements ae listed in order of cre eat ae ape in he ero (Ca, Na, Me, Zn, Fe, H.Cu, He, Ag, Au 50. The element that i the best reducing agent is (A) Ca (B) Av (C)H D) Fe (E) Gu 51. OF ihe following, the element that does NOT react. ‘ith hydroenlorc seid 4 produce hydrogen gas (A) Zo (B) Fe (©) He (D) Ca) Me $2. Ine crostini show hove, whe {GetSloing fae sonst hea (a) Go +e 4 Cu" (B) 200) 4205" +20 (©) Za* +20 Zs) (D) Cus) +o +26 (&) Cu? +26 + Cute) 53. Anatom contains 15 protons, 18 eects, and 1S euteons, Which ofthe following combinations of particles isan isotope ofthat ator? Protons Electcons Neu ws 16 7 1s 16 16 © 15 1s 1s ©) is 5 16 @ ou 1 15 54, Wha the pee composton by mas of lumina ins emmpound of saminun and oxen ‘if the mole ratio of AL: is 2:37 ha (A) 37% At B) 47% al (© BAL (©) Gx AL we al 55, At constant temperature the change of state of Substance from lgid to ges alvaye inches which sr eee ealondaegseeeteees eaeacatinnes 1, The breaking of covalent bonds 1. Amincrease nthe randomness of the syste LL, The absorption of energy (A) Lonly ) only (©) Land It only (D) Wand 1 only 1ltvand IMsions 56-57 Nag) +3 Hale) = 2 NEK(g) + 92 hlojoules ‘6. Ammonia is produced from nitrogen and hydrogen inv ie exothermic reaction represented above. When Pines of ammonia tre produced by the action, ‘sho the following occurs? 1A) 46 kilojouies ate absorbed. 1B) 92 klojoules are absorbed {C) 18 kilojoules ate absorbed. {D) 92 klooues ae given off. AE) 184 kilojoukes are piven of. 57, According to the equation above, what mass of figopen gs i requ 0 produce 8 grams of (a) 112 grams (8) 56 grums kc) 4 prams (D) 28 rams te) 1s geams 8. The lection dt srt Fr the Hydronium fm 8 wi @ (e6T © [meal Hl oy HOH i @ [Rory lee 49, Which ofthe following does NOT react with & Gite H.SO, Solution? (Ay NaNO; (8) Nas (©) NanPOe (D) NaxCOs (©) NaOH ©. ANCIag) + NH(ag) 4 HAO Which ofthe following i one ofthe products ‘plained fromthe reaction above? (ay AlN ) Aly Ox 1D) ALNO»)s (2) AKOH); a. 6. A 0.1-oar solution of which ofthe following ‘compounds has the lowest hydrogen ion ‘oncenation?| (a) Hel (B) AIC, (©) Nalico, (D) NaOH (B) HCHO; (acetic acid) Mitititers of 041M Miliiters 90.1.4 Mixture” PELNOS): Nal 1 2 1 i 3 6 a 4 5 W 5 4 v 6 aI ‘Which of the mintures listed above yields the maxi- mum amount of precipitated Pa” wt On CM OV EY When HS” acts asa Brnsed base, which ofthe following is formed? ws He ons DHS, & Hs 2NO(g) + Hy(g) = NOle) + H:0(e) + 351 Hlojoules the total pressure on the system is increased when the reaction represented above fat equiltium, which ofthe fllowing occurs? (A) The concentration of H,O increases. {B) ‘The conceatration of N3O desreases. (C) The rate of the eeaction decreases, {D) The temperature of the system decreases (E) The Hy gas condenses,CHEMISTRY TEST—Continued earsiaion of $0 ites of 2 anlar NAOH sn ets voto of wh af HE LAL EAT HSOs py ESE CHCOOH iy FAPHCL aor LMENHY LE) MLM ELSOS 4 novo witaoride, BF, 84 omotir cel Boro oni, Ni, pas motel, The spre puis eae te at hal iy BE, as no hydrogen bonding nd NH doe 1a) Be angola planar and NH» pyramiga BE ai emis base and NH isa Lens acid 1) BESS? pond i es pol than the N-H bond 1 is more eleironceative han mHFOREY Late, He sD ced AaB tes equim canst fo the ese Pr ceo above 40. 40% whal A gu const Fr tHE Fee “Apecsened by equa HE? rar ie WE wwe dos 10? edo o 1» 7 aos io ey ao ‘8, A solution is made by adding 3.6 arams of KOM Sauce So pram) to enouch water 1 make (mols ef slucon, What is he approximate PL fhe vesuling solution? wt ® 3 O72 9 oo 6. He) + S(0)== Se) ‘wnt is the mass ation expression cuit Wat Sepresion forthe erm mature of corer nyrogen as, and hysirogsn lie ES ‘ofecened by the equation above? Okan pele © FBS ~ Hh © 8 ta (py x EE OS) aust 5 ro © £8) 1. A ter sample of 0,0L-melar ston Sreachy contains a tora of (A) 004 mote of CaP (8) 0.02 moe of C (©) 001 mole of Cl (0) 001 mole of C (6) 002 mote of STOPPercentage oF Students veetion | correct the Question Number | Answer | right | Wrong | Covet TABLEA ovestion Number Conect newer _| Right Wrong, Answers to the SAT Il: Chemistry Subject Test, Form 3PACT7 reformatted, and, Percentage of Students Answering Each Question Correctly ‘Anemering the Question Conecty™ 8 slagae Rasegaleregaeageg 38 a 56 26 @ 46 a 46 >oloom>olamocolsoroc>mmoolmaomcloamom 36 16 a 8 ea ‘so a ws | tT 30 “6 wr | ow 32 5, woe | ote 4 | 4 too | RF ot | 7 44 |_| oer 60 T 2 at | ance 73 3 12 | Tce 70 | 7m wo | OF es 48 6 | er 22 63 us | tree “ 4 These percentages are based on an analysis ofthe answer sheets for a random sample of 2,282 students who 10k this form ofthe test in May 1994 and Whase mean score was 698. They may be used as an inction of re restive cificulty ofa partetar question. Each percentage may algo be Used fo predict the Hkelhood that a peal SAT ls Chemisty Subject Test cancicate wil answer correty thet question on ths ection of ths tet.How to Score the SAT Il: Chemistry Subject est ‘when you take the Chemsry Subject Tet, your answer shet wi be “ead” BY 8 cao machiae hat wil recoré your response to each Guest. Then 9 com ner wl compare your answers wth he correct answer and produce Your Faw peor, You get ane point french corret answer. For eXCh wrong answer YOU 18 ectourth ots pole, Quetins you omit (and ny for wblch you mask more than eer egnwer are not counted Trav acore ls converted tassel score thet reported to you and to the colleges you spect. STEP Tobe Afon page 302 Sethe correct anseras for af the quatons on the SAT Chemisey Subic Test tats emprocuced in tis Book. + compara your nanare wih those given inthe tale. {ura check nthe slrmn marked “Hight your ananer i corect. 1 pute check in he ctumn marked “Wrong” I your anewer is incorrect 1 anv both column bank you omite he cuosion STEP Count he number fight anewors STEP & Munipy the number of wrong sewers by 258, mer the prodocthete; STEP se Subivet the rent ebtetned in Stop 4 fom te toa you obeined step, STEP Round the nub Enter te ert nee ‘Te number you atin in Sap 6a your raw tort sere, Kt geass sieeaee agg S88 88 8 als #8 % 3 stesgelseessisrezasagé