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Journal of Earth Science, Vol. 21, No. 4, p. 392401, August 2010 ISSN 1674-487X
Printed in China
DOI: 10.1007/s12583-010-0102-4
ABSTRACT: The ages for porphyry Mo deposits in south segment of Da Hinggan Mountains, North-
east China, are not well known. Five molybdenite samples from the Aolunhua () porphyry Mo
deposit, five molybdenite samples from the Yangchang () porphyry-quartz vein Mo deposit and
two molybdenite samples from the Banlashan () porphyry Mo deposit were selected for Re-Os
dating. Three deposits are spatial-temporally associated with the granite porphyry stock. Re-Os
isochron age of 131.21.9 Ma was obtained for the Aolunhua porphyry Mo deposit. The Yangchang Mo
deposit provides isochron age of 138.54.5 Ma for two groups of molybdenite (within porphyry ore and
within quartz vein). The Banlashan porphyry Mo deposit provides model ages of 140.52.4 and 1432.2
Ma. All of these Re-Os ages are consistent presumed Yanshanian ages for granite intrusions, formed in
crust thinning setting in Cretaceous in North China.
KEY WORDS: molybdenite, Re-Os dating, south segment of Da Hinggan Mountains, Northeast China.
INTRODUCTION Barra et al., 2003; Selby et al., 2003; Mao et al., 2002,
Dating sulfide mineralization is of critical im- 1999; Selby and Creaser, 2001; Stein et al., 2001,
portance in establishing the age and duration of eco- 1998, 1997; Watanabe and Stein, 2000; Markey et al.,
nomic mineralization in ore deposits and metallogenic 1998; Suzuki et al., 1996).
provinces (Stein et al., 1998, 1997). In recent years, The Aolunhua porphyry Mo deposit, Banlashan
the precise and accurate age determinations of sulfide porphyry Mo deposit, and Yangchang porphyry-quartz
mineralization have been made in molybdenite. Re-Os vein Mo deposit occur at the Hercynian fold belt of
dating of molybdenite is a well-established method for south segment of Da Hinggan Mountains, Northeast
obtaining ages for intrusion-associated mineralization China (Fig. 1). The deposits have been explored and
(e.g., Valencia et al., 2006; Masterman et al., 2004; mined in recent years: the Aolunhua deposit and the
Yangchang deposit were discovered in 2005, and the
This study was supported by the National Natural Science Banashan deposit was discovered in 2006. Their met-
Foundation of China (No. 40972065). allogenic ages are not well known, but have been in-
*Corresponding author: zengqingdong@mail.igcas.ac.cn ferred as Yanshanian (Zeng et al., 2009a, b). We have
China University of Geosciences and Springer-Verlag Berlin sampled molybdenite from the Aolunhua porphyry Mo
Heidelberg 2010 deposit, the Banlashan porphyry Mo deposit and the
Yangchang porphyry-quartz vein Mo deposit for
Manuscript received January 22, 2010. Re-Os dating in order to determine the age of miner-
Manuscript accepted April 15, 2010. alization.
Re-Os Geochronology of Porphyry Molybdenum Deposit in South Segment of Da Hinggan Mountains, Northeast China 393
Figure 3. Ore photos of the Mo deposits in the south segment of Da Hinggan Mountains. (a), (b) Veinlet ores
(Aolunhua deposit); (c) breccia ore; (d) veinlet ore (Banlashan deposit); (e) breccia; (f) veined ore (Yang-
chang deposit). Mo. molybdenite; Py. pyrite; Cp. chalcopyrite; Qv. quartz vein; Pgp. plagioclase granite
porphyry; Gp. granite porphyry; Gr. granite.
appears at depth of 2040 m. The host rocks are samples of molybdenite for Re-Os dating.
strongly altered; the alteration includes silicification,
sericitiztion and chloritization. Yangchang Mo Porphyry-Quartz Vein Deposit
Fine-grained and crystal-powder molybdenite The Yangchang deposit is located at the south-
commonly occurs as cements of the breccia in the ores west Banlashan deposit (Fig. 1). It is discovered in
(Figs. 3c, 3d). Both molybdenite and pyrite are con- 2005 and being explored. Mo mineralization occurs
centrated in the cements of the breccia. We chose two within the quartz veins and cryptoexplosive breccia
396 Zeng Qingdong, Liu Jianming and Zhang Zuolun
RESULTS
The Re-Os analytical results of 12 molybdenite
samples from the Aolunhua porphyry Mo deposit,
Banlashan porphyry Mo deposit and the Yangchang
porphyry-quartz vein Mo deposit are listed in Table 1.
Five samples from the Aolunhua porphyry Mo deposit
defined an isochron age of 131.21.9 Ma with an ini-
tial 187Os of 0.130.46 ng/g (MSWD=1.6) (Fig. 6a).
Figure 6. Re-Os isochron plot for molybdenite
Model ages for ore samples range from 130133 Ma
samples from the Aolunhua porphyry Mo deposit
(Table 1). Five molybdenites from the Yangchang
(a) and Yangchang porphyry-quartz vein Mo de-
porphyry-quartz vein type Mo deposit yielded an
posit (b) in the southern segment of Da Hinggan
isochron age of 134.85.1 Ma with an initial 187Os of
Mountains.
0.270.58 ng/g (MSWD= 4.7) (Fig. 6b). Model ages
range from 134140 Ma (Table 1). The model ages of
to I type and to S type granite-related deposits. Stein
two molybdenites from the Banlashan porphyry Mo
et al. (2001) also suggested that deposits with a mantle
deposit are 140.52.4 Ma and 143.02.2 Ma, respec-
component to their derivation could have significantly
tively (Table 1).
higher Re contents than those deposits that are derived
from the crust. The Re data of the molybdenites from
DISCUSSION
the Aolunhua porphyry Mo deposit, Banlashan por-
Rhenium Concentrations in Molybdenite
phyry Mo deposit and the Yangchang porphyry-quartz
The Re content in molybdenite from the Aolun-
type Mo deposit (Table 1) suggest that these Mo de-
hua, Banlashan and Yangchang Mo deposits is consis-
posits could have a crustal origin.
tent with many other deposits discovered in China and
elsewhere in the world (Table 2). Rhenium contents in
Age of Mineralization and Its Geological Signifi-
molybdenites vary greatly (Terada et al., 1971;
cance
Fleischer, 1960). Mao et al. (1999) suggested that the
The Re-Os geochronometer of molybdenite has
Re contents of molybdenite could reflect the source of
been demonstrated to be remarkably effective, even in
the deposits with Re content decreasing from mantle
situations where metamorphism and deformation
398 Zeng Qingdong, Liu Jianming and Zhang Zuolun
Table 1 Re-Os isotope data for molybdenite samples from the porphyry Mo deposits in
southern segment of Da Hinggan Mountains
Re 187 187
Model age
Sample Weight (g) Brief sample description Re (g/g) Os (ng/g)
(g/g) (Ma)
Aolunhua Con. Un. Con. Un.
ZA-1 0.050 14 Single disseminated Mo grain 21.97 13.81 0.11 30.21 0.24 131.2 (1.8)
ZA-2 0.050 48 MoPy+Qz vein, V2 ore body 79.81 50.16 0.40 109.5 0.9 130.9 (1.8)
ZA-3 0.050 78 Single disseminated Mo grain, V2 19.77 12.43 0.12 27.23 0.23 131.4 (2.0)
ore body
ZA-4 0.050 22 Single disseminated Mo grain, V1 19.52 12.27 0.09 26.88 0.21 131.4 (1.8)
ore body
ZA-5 0.051 78 Single disseminated Mo grain, V1 29.67 18.65 0.16 41.38 0.34 133.1 (1.9)
ore body
Yangchang
Y-1 0.052 62 V2 quartz ore body 4.108 2.582 0.022 5.978 0.051 138.8 (2.0)
Y-2 0.050 46 V1 quartz ore body 11.12 6.989 0.062 16.05 0.13 137.7 (2.0)
Y-3 0.050 28 V1 quartz ore body 11.86 7.455 0.075 17.11 0.14 137.6 (2.1)
Y-4 0.050 60 V1 quartz ore body 10.85 6.819 0.058 15.93 0.13 140.0 (2.0)
Y-5 0.050 88 Breccia ore 20.24 12.72 0.11 28.54 0.24 134.5 (2.2)
Banlashan
ZB-1 0.050 36 Breccia ore (Mo) 1.054 0.663 0.008 1.553 0.015 140.5 (2.4)
ZB-2 0.050 05 Breccia ore (Mo) 1.291 0.811 0.008 1.935 0.016 143.0 (2.2)
Enriched 190Os and 185Re were obtained from the Oak Ridge National Laboratory. Decay constant: 187Re=1.66610-11 a-1 (Smoliar et
al., 1996). The uncertainty of the contents of Re and Os includes weighing error of sample and diluent, calibration error of diluent,
fractionation correction error of mass spectrum measurement and isotopic ratio measurement error of awaiting test sample. The con-
fidence level is 95%, uncertainty of the model age includes the uncertainty (1.02%) of the decay constant in confidence level (95%).
The concentrations of common Os in molybdenite were determined as lower than 0.02 ng/g and can be ignored. Model ages for the
187
deposit were calculated by assuming that the initial abundance of Os is zero. The numbers within the brackets in the table are
measurement errors, and correspond to the last digit of analytical data in front of the brackets. Con. concentration; Un. uncertainty.
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