DSP: Seminar 2, Binary distillation, McCabe-Thiele method, column with one

MH2O 18 kg/kmol Maa 60.5 kg/kmol vhsteam at 0.4 Mpa 2133.9

Solution:
, column with one and multiple feeds

kJkg-1
 DSP: Seminar 2, Binary distillation, McCabe-Thiele method, column with one fee
Data to Picture
Equlibrium 0 0
0.0055 0.0112 nF= 100 kmol/h nD= 77.77778
0.053 0.133 xF= 0.75 nW= 22.22222
0.125 0.24 q= 1
0.206 0.338 xD/Rmin+1 0.355
0.297 0.437 Rmin= 1.676056
0.51 0.63 R= 3.352113
0.649 0.751
0.803 0.866 xD= 0.95 xD/R+1= 0.218285
0.9594 0.9725 xw= 0.05 Steps 13.5
1 1 P= 101.325 kPa NTS 12.50

45 o line
1
0 0
1 1 0.9
q-line
0.8
0.75 0.75
0.75 0.83 0.7

0.6

0.5
y

Operating line in rectifying section

0.95 0.95 0.4
0 0.218285 0.3
F
0.75 0 0.2
0.75 0.75 0.1
D
0.95 0 0
0.95 0.95 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
W x
0.05 0
0.05 0.05
umn with one feed

vhwater= 2214 kJkg-1K-1 MH2O 18 Kg/kmol

vhaa= 390 kJkg-1K-1 Maa 60.05 Kg/kmol
Psteam 0.4 Mpa
vhsteam 2133.9 kJkg-1 nvm 338.4977

yw 0.13
v h v 25555.73 kJ/kmol/K
msteam 4053.87 kg/h

cpwater 4.18 kJ/kg/K

v h D 39030.38 kJ/kmol/K
dtH2O 20 K
mH2O 158034.6 kg/h

0.6 0.7 0.8 0.9 1

 DSP: Seminar 2, Binary distillation, McCabe-Thiele method, column with multiple
Data to Picture
Equlibrium 0 0
0.0055 0.0112 nF1= 100 kmol/h nD=nF1*xF1+nF2*xF2-(nF1+nF2)*
0.053 0.133 xF1= 0.75 nW= nF1+nF2-nD=
0.125 0.24 q1= 1 nL1= 344.5227
0.206 0.338 nF2= 50 kmol/h nV1= 447.3005
0.297 0.437 xF2= 0.5 nL2= 444.5227
0.51 0.63 q2= 0.5 nV2= 447.3005
0.649 0.751 nL3= 469.5227
0.803 0.866 xD= 0.95 nV3= 422.3005
0.9594 0.9725 xw= 0.05
1 1 P= 101.325 kPa
steps 14.3
45 o
line xD/Rmin+1 0.355 N 13.3
0 0 Rmin= 1.676056
1 1 R= 3.352113
q1-line
0.75 0.75 xD/R+1= 0.218285
0.75 0.83
q2-line
0.5 0.5
0.2 0.8
Operating line in section1
0.95 0.95
0 0.218285
F1 F2
0.75 0 0.5 0
0.75 0.75 0.5 0.5
D
0.95 0
0.95 0.95
Operating line in section 3 Operaiting line in section 2
0.05 0.05
0.5 0.55032
W
0.05 0
0.05 0.05
umn with multiple feeds

F1+nF2*xF2-(nF1+nF2)*xW/(xD-xW)= 102.7778
nF1+nF2-nD= 47.22222
kmol/h

Optimal Feed stage 1 6

Optimal Feed stage 2 10
0 0.0055 0.053 0.125 0.206 0.297 0.51 0.649 0.803 0.9594
0 0.0112 0.133 0.24 0.338 0.437 0.63 0.751 0.866 0.9725

x-y diagram, Water-Acetic Acid

1

0.9

0.8

0.7

0.6

0.5
y

xd/Rmin+1 0.35
Rmin 0.4
1.714286 x'
R= 3.428571

xd/R+1 0.30.214516

0.2

0.1
x
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

1.2

0.8

0.6
y
 1

0.8

0.6
y

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1
x
 1
1

0 0
1 1

Acid
0.75 0
0.75 0.75

0.95 0
0.95 0.95

0.05 0
0.05 0.05

x'

0.8 0.9 1
1 1.2