Tugas 1

Putra Maulana
5213415062
Rombel RABU
10.2 assuming raoult's law to be valid, prepare a P-x-y diagram for a temperature of 363,15 K (90 C)
and a t-x-y diagram for a preasure of 90 kPa for one of the following systems:
(a) benzene (1)/ ethylbenzene (2); (b) 1-Chlorobutane(1)/chlorobenzene(2).

penyelesaian
T 363.15
p 90
asumsi x=0,6

Ln Psat/kPa= A-B/T+C
A B C Ln Psat/kPa
Benzene 13.8594 2773.78 -53.08 4.9137425678
ethlybenzene 14.0045 3279.47 -59.95 3.1883060686

1-Chlorobutane 13.9600 2826.26 -49.05 4.9620375677

chlorobenzene 13.9926 3295.12 -55.6 3.2785047309

Tabel A asumsi x
x1 y1 P/kPa bubble p
0 0 24.24731934 dew P
0.2 0.583982123 46.62745652 y1
0.4 0.7891769467 69.007593699 x1
0.6 0.8938705706 91.387730879
0.8 0.9573740464 113.76786806
1 1 136.14800524

Tabel B asumsi x
x1 y1 P/kPa bubble p
0 0 26.536064464 dew p
0.2 0.5737673008 49.805778892 y1
0.4 0.7821206816 73.075493321 x1
0.6 0.8898292294 96.345207749
0.8 0.9556308461 119.61492218
1 1 142.88463661

diagram T,x,y p 90 kPa

Tabel A
x1 y1 T P1sat P2sat
 0.8385992355 0.8385995506 349.437 90.0000338095 14.5260404495
0.8203226125 0.8350111699 350 91.6115247073 14.8489947131
0.5503449271 0.7595046953 360 124.2046927611 21.6445774204
0.3584206339 0.6578613277 370 165.190041795 30.7924805099
0.2183776105 0.5238642931 380 215.900275956 42.852213624
0.1135904369 0.3505257255 390 277.7286199616 58.4526847067
0.0332566589 0.1301125322 400 352.1137807445 78.2898721053
1.07629418533421E-07 4.716065376E-07 404.987 394.3586146459 89.9999575554

diagram T,x,y p 90 kPa

Tabel A
x1 y1 T P1sat P2sat
0.9999990282 0.9999998368 347.803 90.0000727705 15.116429086
0.9195508494 0.9853013949 350 96.4352603141 16.443610076
0.6209744385 0.8999743324 360 130.4364316815 23.7511951545
0.4045659654 0.7782791049 370 173.1364608798 33.5131675364
0.243322178 0.6107800284 380 225.9152988191 46.2942039884
0.1198908959 0.3866053927 390 290.2179108366 62.7257625243
0.0228722698 0.0934050688 400 367.53921953 83.5034574149
-2.51702725426218E-07 -1.0935271E-06 402.7182 391.0066476913 90.0000757642
 160
grafik p,x,y
140
benzene dan ethylbenzene
120

100

80 liquid
vapour
60
Pi sat P y1
40
136.148005 91.38773 0.893871
24.2473193 20

0
142.884637 96.34521 0.889829 0 0.2 0.4 0.6 0.8 1 1.2
26.5360645

0.6
91.3877309
grafik p,x,y
25.5673328 1-chlorobutane dan chlorobenzene
0.89387057
0.1678606
160
1.06173117
140 liquid
120 vapour
100
80
60
0.6 40
96.3452077 20
28.0100414 0
0.88982923 0 0.2 0.4 0.6 0.8 1 1.2
0.1744355

grafik T,x,y
benzene dan ethylbenzene
 grafik T,x,y
benzene dan ethylbenzene

410
400
liquid
390
vapour
380
370
360
350
340
330
320
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

grafik T,x,y
1-chlorobutane dan chlorobenzene

410
400
liquid
390
vapour
380
370
360
350
340
330
320
-0.2 0 0.2 0.4 0.6 0.8 1 1.2
nzene

liquid
vapour

1.2

obenzene

liquid
vapour

1.2
10.3
T 298.15 K
H1 200 bar
P2sat 0.1 bar

dicari x1 dan y1....!!!

Penyelesaian

y1.P=x1.H1
y2.P=x2.P2sat
P=x1.H1+x2.P2sat

Asumsi Liquid nilai

x1 0.03 x1 0.00015
P 6.097 y1 0.983601
x2 0.99985
y2 0.016399

x1 0.045 x1 0.000225 Pnya sudah mendekati 1 maka

P 9.0955 y1 0.989008 x1
x2 0.999775 y1
y2 0.010992

x1 0.0046 x1 0.005098
P 1.01954 y1 0.902417
x2 0.994902
y2 0.097583
Pnya sudah mendekati 1 maka
0.0055098
0.902417