Documente Academic
Documente Profesional
Documente Cultură
Outline
3.1 Air Pollutants Measurement
3.2 Ambient Oriented Measurement
3.3 Source Oriented Measurement
3.4 Emission Factor
3.0 RECAP
Recaps: Emissions, Transport & Receptors
Atmosphere
Transport
Dilution
Modification
Receptor
Emission Sink
Effects on:
Sources Pollutant removed
Human Health
Measurement without harmful
Materials
Control effect to others
Global Climate
3.1 Air Pollution Measurement
SOURCE
Pollutants emitted AMBIENT
must follow the set Within the
STANDARD breathable limit
to ensure minimal set by regulatory
6 PRINCIPAL POLLUTANTS (EQA)
impact to recipient. Carbon Monoxide (CO) bodies
Nitrogen Oxides (NOx)
Sulphur Dioxide (SO2)
Ozone (O3)
Particulate Matter (PM10 / PM2.5)
Heavy Metals
Emission Receptor
3.1 Air Pollution Measurement
Emission Receptor
3.1 Air Pollution Measurement
1
Average concentration cavg
t cdt
3.1.1 Concentration Determination
Particulate Matter, TSP, PM10, & PM2.5
Ozone (O3)
The air is mixed with ethylene, which reacts with ozone in a light emitting
(chemiluminescent) reaction. The light intensity is measured with a
photomultiplier tube
Concentration =Light
3.1.1 Concentration Determination
Heavy Metals
The mass flow rate of pollutant is the product of the concentration in the
gas and the molar or mass flow rate of the gas
3.1.2 Determining Pollutant Flow Rates
Example The SO2 train sampling indicates that the concentration of SO2
in a stack is 600 ppm (mole). The Pitot tube and manometer in the same
figure indicate that the flow velocity is 40 ft/s. The stack diameter is 5ft.
The stack gas temperature and pressure are 450oF and 1 atm. What is
the SO2 flow rate? Given molar density at 0.001503 lbmole/ft3.
3.1.2 Determining Pollutant Flow Rates
Example The SO2 train sampling indicates that the concentration of SO2
in a stack is 600 ppm (mole). The Pitot tube and manometer in the same
figure indicate that the flow velocity is 40 ft/s. The stack diameter is 5ft.
The stack gas temperature and pressure are 450oF and 1 atm. What is
the SO2 flow rate? Given molar density at 0.001503 lbmole/ft3.
Solution
Determine the gas molar flowrate (velocity x area x density)
40 ft/s x (5/2)2 x 0.001503 lbmole/ft3 = 1.18 lbmol/s
? Where to measure?
For the following diagram, deduce the possibility of placing the air sampler for air
quality monitoring CO measurement (EPA): Issue in choosing a sampler site.
Where to measure?
Generally the ambient air sampler should be located at the place to which the
public has free access where the pollutant concentration is highest.
This means that all indoor spaces, which the public has no access are excluded.
Parking
lot
Government
building
3.2 Ambient Oriented Measurement
Where to measure?
Parking
lot
Government
building
3.2 Ambient Oriented Measurement
Where to measure?
Parking
lot
Government
building
3.2 Ambient Oriented Measurement
Where to measure?
Parking
lot
Government
building
3.2 Ambient Oriented Measurement
Where to measure?
Air monitoring
CO concentration station
exceed standard Downtown air-
monitoring station
Parking
lot
Government
building
3.2 Ambient Oriented Measurement
Where to measure?
Estimate the suitable locations for air quality monitoring equipment
to be placed. Justify your answer accordingly.
3.3 Source Oriented Measurement
? Where to measure?
Point A Point B
A
B
3.3 Source Oriented Measurement
Average Concentration
Point A Point B
A
B
3.3 Source Oriented Measurement
Average Concentration
Point A Point B
Gas Velocity (m/s) A Gas Velocity (m/s)
c avg
Total mass
V Ac Vc
Total volume V A V
for equal areas
Instead of measuring
How can we estimate the
concentration of pollutants
released?
3.4 Emission Factor
Emission rate of bituminous and subbituminous coal combustion without control equipment
Emission Factors (lb/ton) of coal burned a
Furnace type
All particle PM10 SOx NOx CO
* PC =pulverized coal
a The emission factor is expressed by lb/ton. To obtain emission factors in kg/MT, divide the value by 2
* The value of A represent the weight percentage and S represent the sulfur content of the respective
pollutant depending on type of fuel
3.4 Emission Factor
Common solid fuels used for electricity generation and their analysis
Bituminous coal 75.8 5.0 7.4 1.5 1.6 8.7 13,600 11,964
Using the tables, estimate the emissions (tonne/hr) from a 500-MW power
plant at full load, from the combustion of bituminous coal if no control devices
are used. The thermal efficiency is 35 percent. The power plants boiler is
assumed to be of the PC, wall-fired, dry bottom type.
Solution
???
Heating value of bituminous coal
Therefore;
???