National Taipei University of Technology, Institute of Environmental Engineering and

Management

99 academic year first semester course and management of renewable resources

Lecture 2
Waste glass - recycling and management

Instructor: Professor Zhang Tianjin

98 10 13
 Presentation Outline

Waste glass Overview

Waste glass and regulations

Waste glass recycling technology

Resource re-use of waste glass

2/93
1. Waste glass
Overview

3/93
 Media propaganda information reported
Newspapers, periodicals Title Date

Independence Evening Post Glass recycling, sparkling future 89105

Min Sheng Daily Glass asphalt road, paved a successful test 89927
United Daily News Waste glass has a way out, but when the asphalt paving 89927
The Liberty Times Recycling glass, paving the way for beautifully 89927
China Times Waste glass paving at night sparkling 89926
EPA's press release New way to waste glass, glass to light the way asphalt 89926
King reported Waste glass and a road use, the first one born in Yunlin 89923
Township, Yunlin County, the potential environmental paved
China Times
road, the domestic first test
89916
United Daily News Asphalt paving really green glass 89916
Min Sheng Daily Tires and glass, the road will be paved 8946
Min Sheng Daily China Glass Street will be paved, the road first Douliou Taipei 89316
Glass World Recycling of waste glass bottles and glass concrete pavement 881210
Business Times Re-use of waste glass - sparkling future 881121
4/70
4/93
Media propaganda information reported

5/93
Media propaganda information reported

6/93
 Waste glass recycling to high-profile of the reason

International concern and become one of the indicators

of national competitiveness assessment
Waste disposal area of pressure, glass is not burning,
and long-perishable and not buried
"Earth's environment symbiosis" consciousness rise, the
increasing shortage of resources, waste glass recycling
therefore abandoned the trend of sustainable
development

7/93
 Waste glass recycling

Waste glass recycling:

"Recyclable" = food containers, general medical waste, no
injection of liquid crystal glass substrate, CRT panel glass,
fluorescent tubes, glass fiber
"Not recycling" = has been injected into the LCD glass
substrate, CRT tube glass cone
Waste glass recycling including notice and not notice the
container glass, automotive glass, the glass face plate, cone
glass, lighting glass and flat glass, container glass waste and
waste generally two main types of flat glass and other items,
because these two have Health effects of volume exclusion

8/93
 Overview of waste glass container (1 / 8)

Republic of China in 92 years to 97 years for the total

amount of waste 3,183 tons, while the glass container
class six years a total of 1.02 million tons of glass
containers recycled waste, average recovery of about
17.2 million tonnes

Dark brown Green Transparent

Colored glass containers 9/93

 Waste glass containers Overview (2 / 8)

92 93 94 95 96 97
Sales
volume 234,689 245,637 245,719 233,005 235,551 218,145
(tons )
Recovered
161,106 158,076 147,805 166,249 197,839 194,694
(tons)

Recovery
68.65 64.35 60.15 71.35 83.99 89.25
(%)

10/93
 Waste glass containers profile (3 / 8)

The flow of waste glass

TGI
Classification
- Separation Large
share
China
Dichroic glass is not classified
Classification of mottled glass broken after
separation
Other waste glass
11/93
 Overview of waste glass containers (4 / 8)

Waste glass on the impact of incinerators and landfills

Temperatures above 1,000 glass

need only Glassy heavy, can not break down
Completely melted, such as liquid-like naturally, occupy landfill space,
viscosity reducing the useful life of landfill
Attached to the incinerator body, will
hurt
Furnace, resulting in downtime

12/93
 13/93

Finished
Recycled materials
Re-use of waste glass manufacturing process (1 / 4)
Waste glass containers Overview (5 / 8)

Vibrating sieve
Winnowing
Magnetic separation
Fine crushing to acute
Thick broken
- Magnetic separation
Recovery of waste glass
 Overview of waste glass container (6 / 8)

Renewable resources into Dumped into the feed reservoir

the plant carrying Weighing storage

Hopper into the crushing

Be crushing waste glass
machine
Transport

Re-use of waste glass manufacturing process (2 / 4)

14/93
 Waste glass container profiles (7 / 8)

Shock screening
Crusher Crushing waste glass has been
machine

Sand and gravel batching

system
Mixing machine Forming

Re-use of waste glass manufacturing process (3 / 4)

15/93
 Overview of waste glass containers (8 / 8)

Semi-finished products transported

Stripping to the aircraft maintenance
Curing

QC Clip brick Package

Re-use of waste glass manufacturing process (4 / 4)
16/93
2. Management
and regulatory
waste glass

17/93
 The status of China's waste glass recycling

Waste glass recycling-related laws

Environmental Protection in the Republic of 17 August 1982,
"Waste Disposal Act," Article X of the second
Notice for the easy removal of waste glass containers, easy to
handle and with a long decay component of the general waste,
designated type of business in the manufacturing sector,
importer, importer of goods and merchandise vendors
Early announcement to 87 waste glass containers for the waste
glass only recycling projects, and the value of recycled glass
with a notice is still being assessed

Waste code Name of waste Remarks

Industrial waste code

Notice can be directly re-use, waste glass generated institutions

(bottles, scrap, CRT panel glass, glass fiber, glass is not injected into
Waste the liquid crystal panel) (Ministry of Economic Affairs) business
R-0401
glass generated waste glass debris (Interior) business generated waste glass
(dropping bottle, bottles, beverage cans, canned food cans)
(Department of Health)

Waste glass
R-0407 Notice should be recycling waste
containers

18/93
 Framework for waste glass recycling related laws
Waste recycling industry to be
responsible management practices
Waste container recycling clearance and
disposal methods and facilities for the
storage standard
Recycling of waste recycling industry
Waste Disposal Act
should management approach
Recycling Waste Disposal should be
subsidy application process management
approach
EPA recycling rate review committee to
set methods
Recycling Management Fund, custodian
and trust fund payments using some
methods
Auditing and certification of waste should
be recycled Regulations
Responsibility should be recycling waste
management practices related to the book industry
announcements table
Recycling logo, marking provisions relevant to the
content
To the competent authority for registration and
declaration of recovery, capacity and related
operating conditions of the recycling industry and
recyclable waste processing industry, the scale of
the
Recycling rate of clearance and disposal subsidies
Recycling rate of clearance and disposal fee
Notice specified financial institution, account
General waste scrap metal containers, scrap
container, paper container, scrap aluminum foil,
glass containers of waste pesticide containers
special containers and environmental sanitation
agent waste clearance and disposal of waste
batteries recycling various auditing Certification
Manual
19/93
 Background information and description of the
current situation
Recycling of waste glass regulatory, economic, technological and educational noodle market bottleneck
analysis

1 chemical waste container resource requirements and related

specifications for the use of glass and equipment specifications
shall be kiln, so will limit the waste glass recycling container glass
Re manufacturing processing pipeline only, and ignore the
gu Government importance of dealing with agencies.
Waste glass recycling market analysis

lat Act (2) Waste Disposal Act, the waste is divided into two general
io categories of waste and industrial waste, but waste is only one
clear law Article X specification for general waste, will result in
ns different types of waste material recycling processing market
fa crowding out effect occurs .
ce
Product Use of secondary raw materials of glass products lack
regulations Construction & Engineering manual or technical specifications.

For clean team and the community to actively participate in

Eco
The price recycling work, but only recycled glass processing pipeline
mechanism manufacturers, so the secondary raw materials will lead to
no
mic imbalance between supply and demand and cost-effective low.
sid
e
Equipment, lack of investment incentives or subsidies and the lack of
Incentives
secondary raw materials and recycled products, offer rewards.

20/93
 Background information and description of the current
situation

Recycling of waste glass regulatory, economic, technological and educational noodle market bottleneck analysis

As the public's ideas and habits of poor color separation, and

recycling waste glass pipes and facilities unsatisfactory, so the
Secondary
raw materials high cost of processing, the production of secondary raw materials
Tec and because of the high quality than good quality processing
hnic equipment and technology be costly.
al
Waste glass recycling market analysis

Recycled As the poor quality of secondary raw materials and supply

products instability and lack of consumer acceptance.

On product quality, safety and other aspects of the market

In implementation assessment to replace part of cement raw materials, waste glass
containers should be feasible

21/93
 And re-use of waste glass to the Investigation and Analysis

Recycling of the technical feasibility assessment

Assessment of Public Works

Four considerations

1
Engineering
Feature
3
Economy

2
Security
4
Recovery of

22/93
 And re-use of waste glass to the Investigation and Analysis

Recycling purposes
Shards of glass recycling and re-use resources and technology assessment

Classification Technology Economy Re-use potential

Can be used as coarse aggregate replaced with fine aggregate or
Concrete
Reduce the use of silica sand
materials The consumption of large waste glass, with development potential

As fine aggregates in concrete instead of asphalt

Asphalt surface of the slip the more general results and better
Glass
drainage capacity
asphalt
Waste glass containers

With reflective properties, increase nighttime visibility

Waste glass and the consumption of large

Production of cement clinker as raw material

Cement Reduce the use of silica sand

Pre-treatment only coarse glass sand, cost reduction

Reduce the use of clay brick-making raw materials in the amount of

Tile

Reduce the sintering temperature, reduce energy consumption

materials Part of the nature of the product is still better than not added glass

products

Manmade Aggregates as raised beaches

beach Place long-term consumption of waste glass

Note: there are still doubts still re-evaluation of feasible

23/93
 And re-use of waste glass to the Investigation and Analysis
assessment
Shards of glass recycling and re-use resources and technology

Recycling purposes
Technolog
Classification Economy Re-use potential
y
After treatment, may contain harmful mercury
and phosphor powder material composition, re-
Waste fluorescent use when there are concerns

tubes The future may be sent to recycling plants, as
the new system or fluorescent tube glass
recycling materials
Special and Waste containing harmful ingredients for glass cone,
Harmful so the development is more important to re-use
glass
pipeline
Abolition of the TV
CRT glass as a new system usually has one of the
screen,
limitations of raw materials, so the rest of the face
TV monitor waste
plate glass and cone glass recycling can be put into

other channels who wish to apply to domestic,

domestic-related testing is still needed

Note: there are still doubts still re-evaluation of feasible 24/93

 And re-use of waste glass to the Investigation and Analysis

The whole of the glass to the plight of domestic solutions Overview of the difficulties to

Economic Asia Labor costs

Recessio Financial The
Storm
n increase

Hsinchu glass industry sales declining

Collapse of the original manufacturers shut plants

Transfer of funds to China, Vietnam Other

Countries with low labor costs
25
25/93
 And re-use of waste glass to the Investigation and Analysis

The whole of the glass to the plight of domestic solutions Overview of the difficulties to

Regeneration process for the market to
increase market demand

Expand the market demand Zero Waste


Zero waste
Source reduction





Recycling

Green production 26/93

 And re-use of waste glass to the Investigation and Analysis

The whole of the glass to the plight of domestic solutions Overview of the difficulties to

Government Act:
Not renewable resources (including hazardous waste glass containers and
Regulations face

special glass) related management practices

Mark in the product areas:
- For the CNS (National Standards) currently does not provide specifications
for recycled glass
- Green Mark
- Secondary raw materials for re-use of waste glass related products, lack of
manual or technical specifications of its

The price mechanism

Economic side

Recycling of waste glass pipe saturation makes price Drop-Low cost

Incentives
- Equipment, lack of investment incentives or subsidies
-Lack of secondary raw materials and recycled products offer reward

12 27/93
 And re-use of waste glass to the Investigation and Analysis

Overview of the difficulties to

The whole of the glass to the plight of domestic solutions

Secondary raw materials

- Recovery of waste glass and taxonomic status of the separation
Technical

to be improved
-High quality processing equipment and technology is expensive
Recycled products
- Poor quality of secondary raw materials, and the amount of
instability for
- Lack of consumer acceptance and market acceptance of poor
Education face

Lack of environmental awareness

The lack of green ideas

28/93
 And re-use of waste glass to the Investigation and Analysis

The whole of the glass to the plight of domestic solutions Solution to the dilemma of

The first stage The second stage The third stage

That set out some of the public training regulations and

Create a City Field norms
Continued subsidies and subsidies to fee rate review
New demands The establishment of treatment plants
Promote green ideas
Strengthen advocacy

To improve
secondary Strengthen the garbage
Quality of raw Improve the recycling system
materials Promoting technology research

Amend the relevant laws

Assist in handling Regulations to promote the product
Institutions to Flow of market information
Control of the market changes
establish
29/93
 And re-use of waste glass to the Investigation and Analysis

The whole of the glass to the plight of domestic solutions Solution to the dilemma of

The first stage The second stage The third stage

Encourage the
Department Reason Processing facilities for the processing technology to improve the
investment and financial subsidies or other incentives given to
Institutions to May be required for the purchase of additional new equipment, low
establish rate loans give
Special glass recycling technology of harmful subsidies.

Improve
The Improve the effectiveness of recycling
effectiveness Widespread waste glass recycling bins
of recycling

Promote the Improve the convenience of the public with cost-

glass effective and resource recovery, removal of the
existing implementation of the deviation of the
Comprehensiv
phenomenon.
e recycling 30/93
 And re-use of waste glass to the Investigation and Analysis

Solution to the dilemma of

The whole of the glass to the plight of domestic solutions

The first stage The second stage The third stage

Implementing Environmental protection and sustainable development to

green production internalize external costs

National source reduction, green design, environmental

Promote green management measures related to the feasibility assessment,
prompting consumers to understand the value of recycled products,
consumption products

Counseling glass Implementation of the fee charges directly from

industry the bottle recycling industry

Complete information
exchange and resource Review the operation and related amendments to improve
management center the overall efficiency of resource recovery system

31/93
3. Waste glass recycling
technology

32/93


1 To collect domestic waste container recycling and reuse of technical data access, conduct a
of path
market survey estimated the number of waste containers and to assess the output of industry
conditions and available resources (or re-use)

1.

2.

3.




(
)
33/93
33/78
 Waste glass container recycling technology

Waste glass collection

Transport

Storage Storage containers

Considerations

Boxes of material resources can be

Personal protective equipment Placed outside the glass

Resource material

34/93
 Waste glass container recycling technology

Waste glass recycling Condition

Subject to
Clean Reduce debris
separation

Typical specifications of recycled glass dichroic

Mixture of light (%)

Color
Transparent Brown Green Other
Transparent 97100 03 01 03
Brown 05 95100 05 05
Green 010 015 85100 010
35/93
 Waste glass container recycling technology

Recycled glass

Recovery system processes Crusher

Purity of the
Spiral separator

glass 93%
Dewatering screen

Hopper car

Large iron objects

Overhead magnetic conveyor belt

Foreign body
Rough classification of artificial

Two-plate door shaker
Artificial separation or laser color scanner
(Small pieces)
(Large)
Flint (flint) glass artificial classification
(flint)
Small pieces of artificial classification

(Flint glass)
The impact of broken machines External foreign matter such as ceramic

Foreign body
Screening and inflatable double tilt Marked, aluminum cover, buckles, plastic
Magnetic separator Small iron objects
Quality control
Storage trough 36/93
 Waste glass container recycling technology

Waste glass recycled products

Glass, asphalt and civil engineering materials

Made ground (wall) tiles

Construction with ultra-lightweight aggregate (G-lite)

Glass fiber

Chemical adsorbent
37/93
 Waste glass recycled products

Glass, asphalt and civil engineering materials

Improve road drainage, slip and illumination

Alternative rock bottom or base of a road filled with asphalt
concrete material

Examples of cases

The amount of
Length / area
Location
/
Japan
Okinawa to Hokkaido Average
Asahikawa line between consumption of
T about 17.4 kg m2
20km/
2700 surface

155,000m2 Glass pellets

38/93


15%


()

39/93


4.75mm

1.3~1.4

0.3~0.4%

10~15%
40/93


()

()

6~19mm

1.5~6mm
1.5mm
41/93


(%) 1.5 1
(kg/cm2) 210 200
(g) 0.04 0.04~0.08
(BPN) 77~97 35~60
300 10

0.6 1.1~1.3
3% 3%

2.32 2.2~2.4
42/93


(G-lite)

1. p.c.

2.

3.

4.

5.
43/93


100mesh


44/93


()

()

45/93






1




2




/

3






4

()
198919901997
46/93


1.

2.

3.

4.
47/93


MRT

MRT

48/93


49/93


50/93


(Werec) 0.5%Hg

+



+

12.5%
85%
2.5% 51/93
 (Werec)

85%

14

FeNi


52/93
 (Werec)

53/93
 MRT

HID

54/93


CRT

CRT

55/93
 CRT

56/93
 CRT

57/93
 CRT

CRT CRTBaPb



CRT CRT
CRT

CRT

CRT

58/93


59/93


1.

2.

CRT
1.
CRT


2.


60/93


61/93


ITC

CRT

Panel Funel






Panel
Funnel

62/93
4.

63/93
 (1/8)

97

()




100% 194,693

64/93
 (2/8)

0.6~12 mm 1~3.5 mm

65/93
 (3/8)

2.5~5 mm (1~3.5 mm)

66/93
 (4/8)

67/93
 (5/8)

68/93
 (6/8)

69/93
 (7/8)

70/93
 (8/8)

53

71/93
1-

72/93
73/120


74/120


!!!

75/93


76/93


77/93


78/93


79/93


80/93
2-

81/93


TFT
SEG

82/93


83/93
 /

( )

( )

84/93
/

85/93
 /

50%
500
21201650

1500
:

86/93
 /

87/93


88/93


89/93


- 90/93

-
()
(
-
)
100

4200

15


20
15
1500

50




8500


100
250
50
300
91/93


92/93
93/93