the temperaturenin a CO shift reactor can be moderated by injection of excess steam.

Assuming
a feed of 30% CO, 20% H2, and 50% H2O at 6000F and assuming 90% of the CO will be converted,
determine the additional 5500F steam required (permol of feed) to maintain the reactor outlet
temperature below 8500F. the reaction stoichiometry is.
CO(g) + H2O(g) CO2(g) + H2(g)

3. A catalytic reactor is charge with a feed consisting of 5 mol H2 to 1 mol CO2 at 4000C and 5
bar. In the reactor, the reaction
CO(g) + 3H2(g) CH4(g) + H2O(g)
CO2(g) + H2(g) CO(g) + H2O(g)
Take place with 90% conversion of CO2. If the reactor operates adibatically and the exit stream
is at 4000C, calculated the composition of exit stream.

H2 = 5 mol H2=5mol
Dq/dt
CO2=1 mol CO2=1mol

CO=-r1+r2

CH4=r1

H2O=r1+r2

Konversi CO2 = 90% Tr = 250C = 2980K

0.9 = r2/1mol

r2 = 0.9 mol

dq/dt = r1 [(4000+273) r2 +2(4000+273)]+0

400
0 = r1[ (250C) + 25 ( 4 + 2 3. 2)] + [2(250C) +
400
25 ( + 2 2 2)]

a bT cT2 dT3 eT4

CH4 3.838 . 10-1 -7.366 . 10-2 2.9098 . 10-4 -2.638 . 10-7 8.0067 . 10-11
H2O 3.4047 . 10-1 -9.650 . 10-3 3.2998 . 10-5 -2.0446 . 10-8 4.30228 . 10-12
CO 2.90063 . 104 2.4923 . 10-3 -1.8544 . 10-5 4.789 . 10-8 -2.67260 . 10-11
3H2 1.7638 . 10 9 6.70055 . 10-2 -1.3148 . 10-4 1.05883 . 10-7 -2.9180 . 10-11
15.43473 . 101 0.1201982 6.99874 . 10-4 -2.8424 . 10-7 1.45182 . 10-10