SULIT*

SMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYOGPENGSMKYONG
PENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSM
962/2 STPM 2017(P2)
KYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGP
CHEMISRY
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PRA-PENTAKSIRAN STPM 2017(P2)
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PRE-ASSESSMENT
ONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPEN
( 1 JAM 30 MINIT)
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NGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENG
(1 HOUR 30 MINUTES)
SMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENGSMKYONGPENG

SIJIL TINGGI PERSEKOLAHAN MALAYSIA

(MALAYSIA HIGHER SCHOOL CERTIFICATE)

Instructions to candidates:
DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO.
Answer all questions in Section A. Indicate the correct answer on the Multiple-choice Answer Sheet
provided.
Answer all questions in Section B. Write your answers in the spaces provided.
Answer two questions only in Section C. All essential working should be shown. For numerical
answers, unit should be quoted wherever appropriate. Begin each answer on a fresh sheet of paper
and arrange your answers in numerical order.
Values of constants are provided in this question paper.
Arahan kepada calon:
JANGAN BUKA BUKU SOALAN INI SEHINGGA ANDA DIBENARKAN BERBUAT
DEMIKIAN.
Jawab semua soalan dalam Bahagian A. Tandakan jawapan yang betul pada Borang Jawapan
Aneka Pilihan yang dibekalkan.
Jawab semua soalan dalam Bahagian B. Tulis jawapan anda dalam ruangan kosong yang
disediakan.
Jawab dua soalan sahaja dalam Bahagian C. Semua langkah kerja penting mestilah ditunjukkan.
Bagi jawapan yang berangka, unit seharusnya dinyatakan jika sesuai. Mula setiap jawapan pada
kertas jawapan baru and menyusun jawapan mengikut turutan.
Nilai-nilai pemalar ada disediakan dalam kertas soalan ini.

Disediakan oleh Disahkan oleh

______________ ________________
Earliany binti Mohd Shahri
Guru Kimia Pra-U
Kertas soalan ini terdiri daripada 8 halaman bercetak .
(This question paper consists of 8 printed pages)
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SECTION A
(15 MARKS)
Answer all questions in this section.

1. The proton number of ion Y is 16, its nucleon number is 33 and it has the same number of electrons and
neurons. What is the charge of ion Y?
A. +1 B. -1 C. +2 D. -2

2. Boron has two isotopes with relative isotopic masses of 10 and 11. When 1.00 g of boron reacts
completely with hydrogen, 1.278 g of boron hydride, B2H6 is produced. Which graph shows the mass
spectrum of boron?

3. Transition of electrons between energy levels in an atom will cause an absorption or emission of light.
Which energy level diagram shows the transition of electrons that emits light with the shortest wavelength?
SULIT*

4. An atom of element Z has nucleon number 55 and thirty fundamental uncharged particles in its nucleus.
What is the electronic configuration of a Z2+?

A. 1s22s22p63s23p63d5 C. 1s22s22p63s23p63d34s2
B. 1s22s22p63s23p63d44s1 D. 1s22s22p63s23p63d104s2

5. Polyatomic molecules and ions have varied geometries. Which species and geometry correspond
correctly?
Species Geometry
A NH2- Linear
+
B H3O Trigonal planar
C SiCl4 Square planar
D ICl3 T-shaped

6. Which ionic compound has the highest covalent characteristic?

A. MgO B. Al2O3 C. MgF2 D. AlF3

7. The boiling points of CH3OH and CH3SH are 64.5 C and 5.8 C respectively. What is the cause of the
difference in the boiling points?

A. The O-H bond is stronger than the S-H bond

B. Hydrogen bonds exist between CH3OH molecules
C. CH3SH molecule is bigger than CH3OH molecule
D. The electronegativity of oxygen is higher than that of sulphur.

8. A manometer is a device for measuring gas pressures. A sample of nitrogen gas is placed in a close-end
manometer at 25C until there is an increase of 0.100 g in its mass. The diagram below shows the heights of
mercury in the manometer.

What is the volume of the nitrogen gas in the manometer?

[Relative atomic mass: N = 14.0; molar gas constant = 8.31 JK-1 mol -1 ; 760 mm Hg = 101 kPa]
A. 95 cm3 B. 111 cm3 C. 133 cm3 D. 266 cm3

9. Fullerene , C60 is one of carbon allotropes which is used as the base study of carbon nanotube and its
technology. Which statement about fullerene is not true?
A. Its density is higher than diamond
B. It contain delocalised electrons
C. The bonding angle of fullerene is 120C
D. All of its carbon atoms are sp2 hybridised
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10. The initial rate of reaction between P and Q at different concentration is given in the table below.
[P] / mol dm-3 [Q] / mol dm-3 Initial rate of reaction / mol dm-3 s-1
x y r
4x y 2r
16x 2y 8r

What is the initial rate of reaction in terms of r if the concentration of Pand Q is 4x and 3y respectively?
A. 2r B. 6r C. 12r D. 48r

11. A mixture of 0.60 mol of carboxylic acid X, 0.5 mol of alcohol Y, 0.60 mol of ester Z and 0.40 mol of water
of total volume V dm3 is refluxed in the presence of hydrochloric acid. At equilibrium, only 0.40 mol of X
remains. What is the numerical value of KC for the reaction

X (aq) + Y (aq) Z (aq) + H2O (l) ?

A. 0.25 B. 4.0 C. 6.7 D. 40.0

12. An equilibrium system is subjected to the following changes separately:

(i) Decreasing pressure at a constant temperature

(ii) Increasing temperature at a constant pressure

The equilibrium system whose reaction product will increase in quantity when subjected to the above
changes is

A. 2SO2 (g) + O2 (g) 2SO3 (g) H = negative

B. N2 (g) + 3H2(g) 2NH3 (g) H = negative
C. H2 (g) + I2 (g) 2HI (g) H = positive
D. CaCO3 (s) CaO (s) + CO2 (g) H = positive

13. The graph below shows the variation in pH against the volume of sodium hydroxide added when a
sample of acid, HA is titrated with sodium hydroxide.

Which of the following statements is not true?

A. HA is a weak acid
B. The pKa for HA is around 4.5
C. The concentration of NaOH used is 0.050 mol dm-3
D. Phenolphthalein will be a suitable indicator for this titration
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14. An equal number of moles of two solutions are mixed together. Which pair of solutions will yield a buffer
solution?
A. CH3COOH (aq) and CH3COONa (aq) C. NaOH (aq) and CH3COONa (aq)
B. CH3COOH (aq) and NaOH (aq) D. H2SO4 (aq) and NaHSO4(aq)

15. The boiling point composition diagram for a mixture of two miscible liquids, P and Q is shown below

Based on the diagram above, we can conclude that

I pure P and pure Q cannot be obtained from fractional distillation of mixture X.
II fractional distillation of mixture Y produces pure P.
III the mixture of P and Q shows positive deviation from Raoults law.
IV vapour pressure of the azeotropic mixture is lower than pure P and pure Q

A. I, II and III only correct C. I, III and IV only correct

B. I, II and IV only correct D. II, III and IV only correct

ANSWER

1 6 11

2 7 12

3 8 13

4 9 14

5 10 15
SULIT*

SECTION B
(15 MARKS)
Answer all questions in this section

16. (a) Element R consists of two isotopes 35R and 37R. Part of the mass spectrum of R is shown below.

9.0
6.0
1.0

70 72 74 m/e

(i) Define isotopes [1 mark]

(ii) Calculate the relative abundance of 35R : 37R [4 marks]

(b) Relative molecular mass of S is 28.0. Calculate the density of gas S in g dm-3 at 107C and 200.0 kPa.
[2 marks]

17. benzoic acid C6H5COOH and citric acid C5H7O4COOH with Ka 6.3 x10-5 mol dm-3 and 7.0 x 10-4 mol dm-3.
(a) Write the expression of K a for each acids. [2 marks]
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(b) Using given Ka value, compare the acidity of two acid. Explain your answer. [2 marks]

..

..

(c)Calculate the pH of a 0.25 mol dm-3 citric acid solution [2 marks]

(d) Calculate the pH of an aqueous solution containing 0.25 mol dm-3 of citric acid and 0.3 mol dm-3 of
sodium citrate. [2 marks]

SECTION C
(30 MARKS)

Answer any two questions in this section.

18. Period 3 elements can form different fluoride based compound for example MgF2, AlF3 and PF3.
(a) Melting point of MgF2, AlF3 and PF3 are described in the table below.

Compound Melting point / C

Magnesium fluoride 1264
Aluminium fluoride 1040
Nitrogen trifluoride -22

Explain melting point of these fluorides [4 marks]

(b) Sulphur can also react with fluorine to form sulphur fluoride at different oxidation states, namely sulphur
difluoride (SF2), sulphur tetrafluoride (SF4) and sulphur hexafluoride (SF6)

(i) Explain what is meant by valence-shell electron-pair repulsion theory. [2 marks]

(ii) Draw the Lewis structures of SF2, SF4 and SF6. Using valence-shell electron-pair repulsion theory, deduce
the shape of these molecules. [6 marks]

(c) Sulphur trioxide formed is very hygroscopic , where SO3 has a high ability of a substance to attract and
hold water molecules from the surrounding environment. Using suitable bonding concept, explain this
phenomenon. [3 marks]
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19. Variation of the rate constant with temperature for the reaction
A 2B + C
is given in the table below.

Temperature /K Rate constants / s

298 1.74 x 10
308 6.61 x10
318 2.51 x 10
328 7.59 x 10
338 2.40 x 10

(a) (i) What is meant by rate constant [1 mark]

(ii) What is the order of this reaction? Justify your answer [2 marks]

(b) (i) By plotting a graph of ln k against 1/T, determine the activation energy for the reaction above.
[8 marks]

(ii) Based on the graph which you have plotted, calculate the half-life of the above reaction at 300 K.
[4 marks]

20. (a) Pure Bromic acid, HBrO is a colourless liquid which forms an azeotropic mixture with water, aqueous
bromic acid shows deviation from Raoults law.

(i) Explain the type of deviation in aqueous bromic acid. [2 marks]

(ii) Sketch a boiling-composition diagram for aqueous hydrochloric acid given that pure bromic acid boils
at 48.0C and an azeotrope mixture containing 49.2% of bromic acid by mass boils at 122C and
101KPa. [4 marks]

(iii) State the charges which occur in the composition of the residual liquid and the distillate when a
solution containing 80.0% of bromic acid is continuously distilled [3 marks]

(b) (i) A mixture containing hydrogen and nitrogen in the ratio of 3:1 (by volume) is allowed to come to
equilibrium at 20 atm pressure and T C. Under these conditions the equilibrium mixture contains
40% by volume of ammonia.

N2 (g) + 3H2(g) 2NH3(g)

Calculate Kp for the reaction. [3 marks]

(ii) Calculate the equibrium constant Kc at 100C for the system below
N2 (g) + 3H2(g) 2NH3(g) H: -92.2 kJ

[Kc = 6 x 105 dm6 mol-2 at 25C] [3 marks]

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Answer
1 B 6 B 11 B
2 A 7 B 12 D
3 C 8 C 13 C
4 A 9 A 14 A
5 D 10 B 15 B

16. (a) (i) same proton number but different number of neutron / nucleon number. [1 mark]
(ii) Mr of R2 = ( 70x9) + (72x6) + (74x1) [1 mark]
9+6+1
= 71.0 [1 mark]

Ar of R = x 71.0
= 35.5

35 + 37(1 ) = 35.5 [1 mark]

= 0.75

35
R : 37R = 0.75: 025
= 3: 1 [1 mark]
(b). PV=nRT
m/V = PMr / RT
= 200 x 28.0 [1 mark]
8.31 x (273 + 107)

= 1.77 g dm-3 [1 mark]

17. (a) Ka = [H+][C6H5COO-] Ka = [C5H7O4COO-][ H+] [2 marks]

[C5H6COOH] [C5H7O4COO H]

(b) - citric acid are more acidic than than benzoic acid [1 mark]
- pKa lower more acidic [1 mark]

(c) [H+] = Ka x c
= (7.0 x 10-4) (0.25)
= 0.0132 [1 mark]
+
- log [H ] = -log (0.0132)
pH = 1.88 [1 mark]

(d) pH = pKa log [C5H7O4COOH]

[C5H7O4COONa]

= -log (7.0 x 10-4) log [0.25] [1 mark]

[0.30]
pH = 3.24 [1 mark]

18.(a) - MgF2 and AlF3 are hold by ionic crystal lattice [1 mark]
- NF3 is simple covalent molecule hold by weak van Der Waals forces [1 mark]
- Al3+ in AlF3 has higher charge than Mg2+ in MgF2 [1 mark]
- Al3+ has higher polarising power/covalency [1 mark]
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(b)(i) valence-shell electron-pair repulsion theory

- The electron-pairs around the central atom repel each other [1 mark]
- The electron-pairs (bonding pairs and lone pairs) arrange themselves to be as
far apart as possible to minimise the force of repulsion [1 mark]

(ii)

[3 marks]

[3 marks]

(c) - Sulphur trioxide dissolved in water to form sulphuric acid [1 mark]

- SO3 + H2O H2SO4 [1 mark]
- O from SO3 form hydrogen bond with H from H2O [1 mark]

19. (a) (i) The rate constant is the proportionality constant in a rate equation. [1 mark]
Rate = k[ concentration]
(ii) first order [1 mark]
- Because the unit for rate constant is time [1 mark]

(b) (i) ln k = ln A - E
RT
The gradient of graph ln k against 1/T would give the gradient = E /R [1 mark]

Correct all 1/T [1 mark]

Correct all ln k [1 mark]

All points correct transfer [2 marks]]

Line [1 mark]
SULIT*

Gradient = - (100 -65) x 10

(32.8 -30.0) x10
= -1.25 x10K [1 mark]

-1.25 x10k =- E / 8.31

E = 103.9 kJ mol [1 mark]

(ii) At 300K, 1/T = 33.3 x10 K

From graph, ln k = - 106.0 x10 [1 mark]
K = 2.49 x10 s [1 mark]

T = ln 2 / k [1 mark]
= 0. 693 / 2.49x10 s
= 2.7813 x10 s [1 mark]

20. (a) (i) negative deviation [1 mark]

- since electrostatic attraction forces between H3O+ and Br- is stronger than
weak intermolecular forces between H2O and HBrO [1 mark]

(ii)

(iii) vapourisation and condensation process occur [1 mark]

- Bromic acid HBrO is first distillate [1 mark]
- Residue is azeotropic mixture [1 mark]

(b) (i) % of NH3 = 40% Mole fraction = 0.4

% of N2 = x 60 = 15% Mole fraction = 0.15
% of H2 = x 60 = 45 % Mole fraction = 0.45 [1 mark]

PNH3 = 20 x 0.4 = 8.0 atm

PN2 = 20 x 0.15 = 3.0 atm
PH2 = 20 x 0.45 = 9.0 atm [1 mark]

N2 (g) + 3H2(g) 2NH3(g)

Kp = (PNH3)2 = 82
(PN2) x (PH2)3 3x 93

= 0.029 atm-2 [1 mark]

SULIT*

(ii) ln K2 (100 C) = H ( 1 - 1) [1 mark]

K1 (25 C) R T 1 T2

ln K2 = -92.2 x 103 ( 1 - 1 ) = -7.49 [1 mark]

5
6 x 10 8.31 298 373

ln K2 = 5.59 x10-4
5
6 x 10

K2 = 3.35 x 102 dm6 mol-2 [1 mark]