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Standardized determination of
the oxidation stability of biodiesel and
biodiesel blends as per EN 14 112
Subject to modifications
8.873.6003 2007-02
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The 873 Biodiesel Rancimat is a modern, PC-controlled instrument for the convenient determination
of the oxidation stability of biodiesel and biodiesel blends (mixtures of biodiesel and conventional
diesel fuel) as per EN 14 112. The software of the third Rancimat generation comprises automatic
data acquisition and evaluation as well as a database and permits the easy management of large
amounts of data.
Disposable reaction vessels minimize cleaning requirements. This saves both time and money. The
accuracy and reproducibility of the measurements are also significantly improved. The GLP Set with
certified temperature sensor allows to set the temperature very accurately and reproducibly, which
in turn improves the precision of the results.
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The use of alternative fuels from renewable plant sources has become increasingly widespread
in recent years and will continue to increase considerably in the future. There are several reasons
for this, among them the following:
Fossil fuel deposits are limited, which makes economic use of these resources imperative
biodiesel is obtained from renewable raw materials.
The combustion of biogenic fuels is CO2-neutral. The carbon dioxide released from them has
previously been assimilated from the atmosphere during the growth phase of the plants. In
contrast to CO2 from fossil fuels, it makes no contribution to the enrichment of carbon dioxide
in the atmosphere and the resulting atmospheric warming.
Alternative fuels can often be produced locally and this reduces dependence on imported raw
materials.
Alternative fuels are usually very easily biodegradable and therefore cause less environmental
damage, particularly when used in ecologically sensitive areas.
In addition to other alternative fuels such as ethanol, methanol or biogas (methane), fatty acid
methyl esters are increasingly found on the market; these are then known as biodiesel, RME
(rapeseed oil methyl esters) or FAME (fatty acid methyl esters). Fatty acid methyl esters are usually
obtained from oil seeds and are mainly used in their pure form or mixed with conventional diesel
fuel in the transport sector.
Biodiesel is usually produced from vegetable oils, but animal fats can also be used. The vegetable
oil is transesterified with methanol. This produces the methyl esters of the fatty acids present in
the oil together with glycerol as a byproduct. Fatty acid methyl esters are relatively unstable on
storage, as like all natural oils and fats they are slowly oxidized by atmospheric oxygen. The
substances produced in this way could cause motor damage. This is why
the oxidation stability is an important quality criterion for biodiesel;
it is regularly determined during the production process. With the
873 Biodiesel Rancimat this determination can be carried out quickly
and simply. The oxidation process can be delayed by the addition
of antioxidants. The 873 Biodiesel Rancimat can also be used to
determine the effectiveness of antioxidants. This opens up a
further field of application for the instrument.
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During the measurement a stream of air is passed through the fatty acid methyl ester sample con-
tained in a sealed and heated reaction vessel. This treatment results in oxidation of the fatty acid
methyl ester molecules in the sample, with peroxides initially being formed as the primary oxidation
products. After some time the fatty acid methyl esters disintegrate completely; the secondary oxi-
dation products formed include low-molecular organic acids in addition to other volatile organic
compounds. These are transported in the stream of air to a second vessel containing distilled water.
The conductivity in this vessel is recorded continuously. The organic acids can be detected by the
increase in conductivity. The time that elapses until these secondary reaction products appear is
known as induction time or induction period.
The oxidation stability of fatty acid methyl esters is already included in various standards as a para-
meter for defining the minimum quality requirements of commercial biodiesel used as vehicle fuel
or heating oil:
ASTM D 6751 (ASTM American Society for Testing and Materials) Standard specification for
biodiesel fuel blend stock (B100) for middle distillate fuels
EN 14 214 Automotive fuels Fatty acid methyl esters (FAME) for diesel engines Requirements
and test methods
EN 14 213 Heating fuels Fatty acid methyl esters (FAME) Requirements and test methods
EN 14 112 Fat and oil derivatives Fatty
acid methyl esters (FAME) Determining the
oxidation stability (accelerated oxidation test)
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Measuring vessels
Robust glass beakers are used for automatic con-
ductivity measurement.
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Software functions
All functions of the 873 Biodiesel Rancimat are controlled by the Rancimat software, which excels
by its user-friendliness. All the functions are clearly arranged in just a few windows, the operation
is intuitive.
Rancimat control
This is where the measuring parameters can be called up and edited. From here the instrument
functions are controlled directly, the measurements started and the actual measuring values shown
in the live display field. The arrangement of this window corresponds to a view of the instrument
from above. This means that the assignment of sample information and measuring position is
perfectly clear. The timer function can be used to automatically switch on the heating blocks in
advance, so that it is no longer necessary to wait while they warm up.
Rancimat results
At the end of each determination the measuring data is stored in a database and can be viewed
by the user in the results window. Sample information and results are shown in tabular form and
can be exported in various formats. The measured curves can be shown individually or in groups.
It is also possible to edit the automatic evaluation and recalculate the results. You can, of course,
sort or filter all the displayed data and adapt the display to meet your requirements.
Overview table
Curve display: individual or multiple plots
Re-evaluation: induction time, stability time
and manual tangent method
Report printout
Database functions: filtering, sorting
Data export
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GLP functions
By using the built-in monitoring of the validation intervals, nothing can go wrong with your quality
management procedure. The software prompts you to carry out the validation in good time. The
wizards for temperature and conductivity validation help you to do this.
User administration
The software includes flexible and comfortable user administration with login function; this can be
used to define detailed access rights for groups of users and individuals.
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Technical specifications
Heating blocks
2 aluminum heating blocks; electrically heated; can be set to different temperatures
Number of samples
8 samples (4 measuring positions per heating block)
Air throughput
Pump Diaphragm pump
Output range 7...25 L/h
Conductivity measurement
Measuring range 0...400 S/cm
Electrodes 6.0913.130 conductivity cell with double steel-pin electrode built into vessel
cover
Ambient temperature
Nominal working range +5...+40 C (at 20...80% relative humidity)
Storage -20...+70 C
Transport -40...+70 C
Line power
Voltage 2.873.0014: 230 V (220...240 V 10%)
2.873.0015: 115 V (100...120 V 10%)
Frequency 50...60 Hz
Power consumption <450 VA (depending on heating power)
Dimensions
Width 405 mm
Height 268 mm without accessories, 353 mm with accessories
Depth 466 mm
Weight
27.6 kg (with accessories)
PC requirements
Processor Pentium III with 700 MHz or higher
Operating system Windows NT, Windows 2000 or Windows XP
Memory 20 MB for program files, 200 MB recommended for measuring data storage
RAM working memory 128 MB, recommended 256 MB or higher (particularly for Windows XP)
Graphics resolution Min. 800 x 600, recommended 1024 x 768 or higher
Interface 1 free RS-232C interface (COM)
Printer All printers supported by Windows
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Ordering information
Options
6.2059.000 Turntable for 873 Biodiesel Rancimat
6.2757.000 Exhaust collection tube for 873 Biodiesel Rancimat (with 8 stoppers)
6.1839.000 Iso-Versinic tubing for biodiesel measurements, 6 mm i.d., 9 mm o.d.;
length 22 cm (8 pieces are required)
6.5616.000 GLP Test Set
6.1111.010 Pt-100 temperature sensor 16 cm
6.1253.000 Measuring insert for heating block
6.2109.030 Test plug 10 kOhm
6.2301.060 KCl conductivity standard c(KCl) = 0.1 mol/L, 250 mL
6.1429.050 Reaction vessel long (length 250 mm) for measurements involving volatile oils,
hput. mineral oils and biodiesel blends
6.2418.130 Air inlet tube long (length 248 mm) for measurements involving volatile oils,
mineral oils and biodiesel blends
Consumables
6.1429.040 Reaction vessels for 873 Biodiesel Rancimat (117 pcs.)
6.2418.100 Air inlet tubes for oil measurements (117 pcs.)
essel 6.1428.030 Conductivity measuring vessel, glass, for 873 Biodiesel Rancimat
6.1839.000 Iso-Versinic tubing for biodiesel measurements, 6 mm i.d., 9 mm o.d.;
length 22 cm
6.2724.010 Dust filter
6.2753.100 Reaction vessel cover
6.2811.000 Molecular sieve, 250 g
rage
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I o n a n a l y s i s
Metrohm Ltd.
CH-9101 Herisau/Switzerland
Phone +41 71 353 85 85
Fax +41 71 353 89 01
www.metrohm.com
info@metrohm.com
8.873.6003 2007-02