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Name__________________________________Period:______Date:____________
Number of Valence
Group Electrons
1
2
13
14
15
16
17
18
1
Electron Configuration of oxygen:
5) In the Lewis electron-dot formulas for atoms of main group elements, valence
electrons are represented by _________that surround an elements symbol.
6) Examples of Lewis electron-dot formulas for atoms of the main group elements:
2
DETERMINING BOND TYPE
1) __________________= a chemical bond resulting from
________________________________between positive and negative ions
a) In a purely ionic bond, one or more electrons are transferred from one atom to
another
+ -
3) Chemical bonds between two unlike atoms are NEVER
completely ionic and RARELY completely covalent. Bonds
can be anywhere in the range between these two extremes, depending upon how
strongly the bonded atoms attract electrons.
3
4) _______________________= a measure of the ability of an atom in a
chemical compound to attract electrons
6) The electronegativity difference of two atoms can be used to determine the ionic
character of a bond.
7) The scale below can be used to classify the probable bond type between two atoms.
b) Shared electrons spend MORE of their time near the atom with the
_____________________ electronegativity.
c) __________________________ (+ or -) result.
4
9) Determine the electronegativity difference and probable bond type with respect to
bonds formed between the following pairs of atoms. Assign partial charges if the
probable bond type is polar-covalent.
S and H
S and Cs
I and I
Cl and Br
S and Cl
Br and F
e) The chemical formula for an ionic compound represents a formula unit, NOT
a____________________________.
5
3) ____________________= a compound of positive and negative ions (anions and
cations) that are combined so that the numbers of positive and negative charges are
equal
4) The chemical formula of an ionic compound shows the _______of ions present in a
sample of any size.
5) The chemical formula for an ionic compound represents a formula unit, NOT a
molecule.
6
b) Use electron-dot formulas to illustrate the formation of ionic bonds involving Ca
and F.
Ionic Formula = ________________
c) Use electron-dot formulas to illustrate the formation of ionic bonds involving K and
O.
Ionic Formula = ________________
7) Certain elements occur naturally as diatomic molecules (you need to know these
elements!!)
b) The example below shows two HCl molecules. The force of attraction that exists
between the two molecules is an intermolecular force.
8
o Ex: ____________________compounds
Ex: O2
9
d) In general, _________________are _________________and ____________than
single bonds.
d) Add electron pairs around the _____________________to satisfy the octet rule
for the terminal atoms. THERE ARE EXCEPTIONS TO THE OCTET RULE! (see
below)
g) If the central atom has LESS than an octet of electrons, then move one or
more lone pairs from the _________________atoms to form multiple bonds
(double and triple bonds).
oxygen, nitrogen and carbon CAN form ___________________.
h) DO THE FOLLOWING FINAL CHECKS:
Check that the total number of valence electrons in the molecule is correct.
Check that the octet rule is satisfied for all atoms. DONT FORGET ABOUT
THE EXCEPTIONS.
5) EXCEPTIONS to the octet rule:
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b) ________________and _______________are SOMETIMES exceptions to the
octet rule. These atoms sometimes contain less than eight electrons in their
outermost occupied main energy level. Remembering that these atoms DO NOT
form double and triple bonds will be helpful when determining if they break the
octet rule.
6) Guide for Writing Lewis Structural Formulas for Molecules and Polyatomic
Ions:
a) Follow all guides from above except write a __________to indicate every bond
pair.
O= _______________
H3 = _____________
o Ex: NH4 +1
_____________
_____________
____________
_____________
11
A NEGATIVE CHARGE indicates you have to _________electron(s)
o Ex: CO3-2 has _____valence electrons
C= ________________________
O3 = ________________________
12
Lone
Atoms
Pairs
Bonded
Around Predicted
Molecular to
the Bond Example
Geometry Central
Central Angles
Atom
Atom
BeF2
2 0
BeF3
3 0
NH3
3 1
SnCl2
2 1
H 2O
2 2
CH4
4 0
13
e) Notice the bond angle distortion for molecules with a molecular geometry of
_____________________and ___________(with_____________________).
Ex: O3 is considered bent with a predicted bond angle of 120 since there is
only 1 lone pair of electrons
Ex: H2O is considered bent with a predicted bond angle of 105 since there is
2 lone pairs of electrons
When writing dot formulas and structural formulas you still will have to
account for lone pair(s) of electrons since models do not account for lone
pair(s)
YES
NO
2. Is the electronegativity of all terminal atoms the same?
NO YES
The molecule is NONPOLAR
The molecule is POLAR
15
16
# of Predicted
Molecular Polar or
Formula Valence Lewis Electron-Dot Formula Lewis Structural Formula Bond
Geometry Nonpolar?
Electrons Angles
ICl
NA
Complete the following tables on pg 16-18 as a class.
CH3I
BeF2
BF3
17
# of Predicted
Molecular Polar or
Formula Valence Lewis Electron-Dot Formula Lewis Structural Formula Bond
Geometry Nonpolar?
Electrons Angles
CO2
H2CO
NH3
H2O
18
# of Predicted
Molecular Polar or
Formula Valence Lewis Electron-Dot Formula Lewis Structural Formula Bond
Geometry Nonpolar?
Electrons Angles
SO2
SO42
NA
NH4+
NA
N2
NA
Valence Electrons & Lewis Electron-Dot Notation Worksheet
3) Determine the number of valence electrons in one atom of each of the following
elements. Then write the electron-dot notation for each element.
a) Na
b) F
c) Rb
d) Ba
e) I
f) Se
g) Al
h) C
i) Mg
j) He
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Electronegativity & Probable Bond Type Worksheet
1) When predicting probable bond types, list the ranges for the following:
3) What is the difference between polar-covalent and non-polar covalent bond types?
5) Determine the electronegativity difference and probable bond type with respect to bonds
formed between the following pairs of atoms. Assign partial charges if the probable bond
type is polar-covalent.
Pair of Probable Bond Partial Charges (if
Electronegativity Difference
Atoms Type polar-covalent)
H and H
S and O
H and I
K and Br
Si and Cl
H and F
Se and S
C and H
Na and Cl
O and H
N and N
I and Cl
20
Ionic Bonding & Ionic Compounds Worksheet
1) Ionic compounds usually have what type of elements present?
21
9) Use electron-dot formulas to illustrate the formation of ionic bonds involving
Al and I.
Ionic Formula = ________________
10) Use electron-dot formulas to illustrate the formation of ionic bonds involving
Ca and O.
Ionic Formula = ________________
11) Use electron-dot formulas to illustrate the formation of ionic bonds involving
Na and S.
Ionic Formula = ________________
12) Use electron-dot formulas to illustrate the formation of ionic bonds involving
Al and S.
Ionic Formula = ________________
22
23
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
NO2+
NA
O3
Complete the following table.
BF4
NA
H2BF
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Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
BeCl2
CH4
NO2 NA
HCl
NA
25
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
Cl2CO
CHCl3
NF3
CCl4
26
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
H2
NA
CHI3
H2Te
SiO2
27
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
H2S
HCN
ClO
NA NA
PH3
28
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
ClO2
NA
HClO
PCl3
OF2
29
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
H 3 O+
NA
I2
NA
CF4
SCl2
30
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
NCl3
Cl2O
NH2Cl
SiCl3Br
31
Number
Predicted
of Molecular Polar or
Formula Lewis Electron-Dot Formula Lewis Structural Formula Bond
Valence Geometry Nonpolar?
Angles
Electrons
ONCl
NO3
NA
SO42
NA
SCN
NA
32
Ionic Compounds vs. Molecular Compounds
IONIC COMPOUNDS MOLECULAR COMPOUNDS
1. What type(s) of elements are
usually contained in this type of
compound?
2. Under ordinary conditions, in
what state of matter would you
find this compound?
3. This type of compound can be
described as a collection of
________?
4. What type of bond is holding
the atoms together? Explain
how atoms are held together by
this type of bonding?
5. Describe the melting points
and boiling points.
6. Describe the IM forces.
Bonding Basics Worksheet
Vocabulary: Use your notes to help you identify the following vocabulary.
3) _________________________ is a chemical bond resulting from electrostatic attraction between positive &
negative ions
4) A _________________ is a neutral group of atoms held to together by covalent bonds
5) __________________________ is a chemical bond resulting from the sharing of electrons between two
atoms
15) _____________________________ is the outermost electrons available to be lost, gained, or shared in the
formation of chemical bonds
16) __________________________________________ is an electron pair NOT involved in bonding
17) ___________________________________ is a covalent bond in which the bonding electrons are shared
equally by the bonded atoms
18) ____________________________________________ are forces of attraction between adjacent particles
(molecules, atoms, or ions)
33
Concepts: Answer the following questions.
1. When predicting probable bond types, list the ranges for the following:
e. Polar-covalent = __________________________________
f. Ionic = __________________________________________
2. Which atom is assigned the partial negative charge when a polar covalent bond is established?
4. What phase(s) of matter would you most likely find ionic compounds? _______________________
6. What phase(s) of matter would you most likely find molecular compounds? _____________________
________________________________________________________________
8. In terms of IM forces, describe melting points and boiling points of ionic and molecular compounds?
9. Use electron dot formulas to illustrate the formation of ionic bonds involving Li and N.
10. Use electron dot formulas to illustrate the formation of ionic bonds involving Na and O.
34
Dot & Structural Formulas: For each of the following formulas determine the number of valence electrons and draw the
electron dot formula and structural formula.
Number
of Lewis Electron Dot Lewis Structural
Formula Valence Formula Formula
Electrons
CO
SeF2
NCl3
BeCl2
HCN
35
Dot & Structural Formulas: For each of the following formulas determine the number of valence electrons and draw the
electron dot formula and structural formula.
Number
of Lewis Electron Dot Lewis Structural
Formula Valence Formula Formula
Electrons
PH3
SO3
CS2
CH2O
SiCl4
(silicon
tetrachloride)
36
BONDING REVIEW WORKSHEET
1) What are valance electrons?
3) What is the difference between a non-polar covalent bond and a polar-covalent bond?
4) What is electronegativity?
5) When predicting probable bond types, list the ranges for the following:
b. Polar-covalent = __________________________________
c. Ionic = __________________________________________
8) What phase(s) of matter would you most likely find ionic compounds?___________________
11)What phase(s) of matter would you most likely find molecular compounds?
12)What are diatomic molecules? List the naturally occurring diatomic molecules.
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13)What is the difference between lone pair electrons and bond pair electrons?
14)What are the exceptions to the octet rule when constructing electron dot formulas?
15)What needs to be added to the electron dot and structural formulas for polyatomic ions?
__________________________ & ______________________________
16)List the 6 types of molecular geometry that a compound may exhibit and the predicted
bond angle.
17) Use electron dot formulas to illustrate the formation of ionic bonds involving Ca and Cl.
18)Use electron dot formulas to illustrate the formation of ionic bonds involving K and O.
19)What is the difference between the melting and boiling points of ionic and molecular
compounds?
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Unit Learning Map (10 days): Bonding Mrs. Hostetter
Chemical Bonds Bond Types Electron Dot and Structural VSEPR Model
Formulas
Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions:
Why do chemical bonds How do you determine How can molecules and How can the VSEPR model
form? probably bond type? polyatomic ions be be used to predict molecular
represented using electron geometry and bond angles?
dot and structural formulas?
39
Bonding Vocabulary:
1) Chemical bond- an interaction between atoms that holds them together by reducing the potential energy of
their electrons
2) Chemical formula- a shorthand representation of the composition of a substance using atomic symbols and
numeric subscripts (Ex: NaCl, MgCl2, H2O, C6H12O6)
3) Valence electrons- the outermost electrons available to be lost, gained, or shared in the formation of
chemical bonds
4) Ionic bonds- a chemical bond resulting from electrostatic attraction between positive & negative ions
5) Covalent bonds- a chemical bond resulting from the sharing of electrons between two atoms
6) Nonpolar-covalent bond- a covalent bond in which the bonding electrons are shared equally by the bonded
atoms
7) Polar-covalent bond- a covalent bond in which the bonding electrons are shared unequally by the bonded
atoms
8) Electronegativity- a measure of the ability of an atom in a chemical compound to attract electrons
9) Ionic compound- a compound of positive and negative ions (anions and cations) that are combined so that
the numbers of positive and negative charges are equal
10) Formula unit- the simplest collection of ions from which an ionic compounds formula can be established
11) Octet rule- chemical compounds tend to form so that each atom (by gaining, losing, or sharing electrons)
contains eight electrons in its outermost occupied main energy level (valence electrons)
12) Molecular compound- a chemical compound whose simplest units are molecules
13) Molecule- a neutral group of atoms held to together by covalent bonds
14) Molecular formula- a shorthand representation showing the types and numbers of atoms combined in a
single molecule
15) Diatomic molecule- a molecule containing only two atoms (Natural = H2,O2, N2, Cl2, Br2, I2, F2)
16) Intermolecular forces (IM Forces) = forces of attraction between adjacent particles (molecules, atoms, or
ions)
17) Lone pair electrons- an electron pair NOT involved in bonding
18) Bond pair electrons- an electron pair shared between two atoms
19) Single bond- a covalent bond produced by the sharing of one pair of electrons between two atoms
20) Double bond- a covalent bond produced by the sharing of two pairs of electrons between two atoms
21) Triple bond- a covalent bond produced by the sharing of three pairs of electrons between two atoms
22) Central atom- atom in the center of the compound, often carbon
23) Dot formula- when dots are used to show bond pairs and lone pairs
24) VSEPR Model- (Valence Shell Electron Pair Repulsion Model) has proven useful in predicting molecular
geometry and bond angles
25) Molecular geometry- Linear, Trigonal planer, Bent, Tetrahedral, Trigonal pyramidal, and Bent
26) Bond angles- angle at which the bond takes place
27) Linear- 2 atoms bonded to central angle and predicted bond angles is 180
28) Trigonal planar- 3 atoms bonded to central angle and predicted bond angles is 120
29) Bent-2 atoms bonded to central angle,1 lone pair around the central atom;predicted bond angle is 120
30) Bent- 2 atoms bonded to central angle, 2 lone pairs around central atom; predicted bond angle is 105
31) Tetrahedral- 4 atoms bonded to central angle; predicted bond angle is 109.5
32) Trigonal Pyramidal- 3 atoms bonded to central angle, 1 lone pair around central atom; predicted bond
angle is 107
33) Isomer = Compounds that have the same molecular formula, but different structural formula.
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