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Fourier's law
The law of heat conduction, also known as Fourier's law, states that the
time rate of heat transfer through a materialis proportional to the
negative gradient in the temperature and to the area, at right angles to
that gradient, through which the heat flows.
Newton's law of cooling states that the rate of heat loss of a body is
proportional to the difference intemperatures between the body and its
surroundings while under the effects of a breeze.
Fick's first law relates the diffusive flux to the concentration under the
assumption of steady state. It postulates that
the flux goes from regions of high concentration to regions of low
concentration, with a magnitude that is
proportional to the concentration gradient (spatial derivative), or in
simplistic terms the concept that a solute will
move from a region of high concentration to a region of low
concentration across a concentration gradient.
Positive deviation
When the cohesive forces between like moleculesare greater than the
adhesive forces betweendissimilar molecules, the dissimilarities of
polarityleads both components to escape solution more easily. Therefore,
the vapor pressure is greater than expected fromthe Raoult's law,
showing positive deviation. If the deviation is large, then the vapor
pressure curve shows amaximum at a particular composition and form a
positive azeotrope. Some mixtures in which this happens are (1)benzene
and methanol, (2) carbon disulfide and acetone, and (3) chloroform and
ethanol.
Conductance
For general scientific use, thermal conductance is the quantity of heat
that passes in unit time through a plate of
particular area and thickness when its opposite faces differ in
temperature by one kelvin. For a plate of thermal
conductivity k, area A and thickness L, the conductance calculated is
kA/L, measured in WK1 (equivalent to: W/
C).