There are 3 DVDs in each volume case. Each volume has 26 episodes.

I compared each episode to the episode list

on wiki and found that there are 4 episodes missing: Beauty and the Beach, The Legend of Dratini, Cyber Soldier
Porygon, and Holiday Hi-Jynx . I wrote them in the list below so you can see where they fall in the series. There are
some episodes out of order based on air date/Japanese release date. I also listed those episodes with the correct
episode numbers in the list below. However, I found that when I watched these episodes in the order the DVD set
presented them, they did not interfere with the story line as it all happened between cities and were filler episodes.
The episode that people have seen would assume were out of place is Snow Day Out, which is due to a Japanese
error. Both Snow Day Out and Holiday Jinx were postponed in Japan and wasn't shown until the next years holiday
season because of what happened with the Cyber Soldier Porygon episode that delayed the season for the year
before. This had nothing to do with VIZ media. The episodes titles and numbers are not listed on the DVD set so I
ended up finding and adjusting a list online and printing them out and slipping them inside the DVD case as shown.
Otherwise, for the price, I am very grateful to have this piece of childhood in one neat box set. I couldn't be happier.

Volume 1

Disc 1:
1. Pokmon I Choose You!
2. Pokmon Emergency
3. Ash Catches A Pokmon
4. Challenge Of The Samurai
5. Showdown In Pewter City
6. Clefairy And The Moon Stone
7. The Water Flowers Of Cerulean City
8. The Path To The Pokmon League
9. The School Of Hard Knocks

Disc 2:
10. Bulbasaur And The Hidden Village
11. Charmander-The Stray Pokmon
12. Here Comes The Squirtle Squad
13. Mystery At The Lighthouse
14. Electric Shock Showdown
15. Battle Aboard The St. Anne
16. Pokmon Shipwreck
17. Island Of The Giant Pokmon
18. Beauty and the Beach not included
19. Tentacool & Tentacruel

Disc 3:
20. The Ghost Of Maiden's Peak
21. Bye Bye Butterfree
22. Abra And The Psychic Showdown
23. The Tower Of Terror
24. Haunter Versus Kadabra
25. Primeape Goes Bananas
26. Pokemon Scent-Station!
27. Hypno's Naptime
Volume 2

Disc 4:
28. Pokmon Fashion Flash
29. The Punchy Pokmon
30. Sparks Fly For Magnemite
31. Dig Those Diglett!
32. The Ninja Pok-Showdown
33. The Flame Pokmon-athon!
34. The Kangaskhan Kid
35. The Legend of Dratini not included (never aired in US)
36. The Bridge Bike Gang
37. Ditto's Mysterious Mansion
38. Cyber Soldier Porygon not included (never aired in US)

Disc 5:
39. Pikachu's Goodbye
40. The Battling Eevee Brothers
41. Wake Up Snorlax!
42.. Showdown At Dark City
43. The March Of The Exeggutor Squad
44. The Problem With Paras
45. The Song Of Jigglypuff
46. Attack Of The Prehistoric Pokemon
47. A Chansey Operation

Disc 6:
48. Holy Matrimony!
49. So Near, Yet So Farfetch'd
50. Who Gets To Keep Togepi?
51. Bulbasaur's Mysterious Garden
54. The Case Of The K-9 Caper
55. Pokmon Paparazzi
56. The Ultimate Test
57. The Breeding Center Secret
Volume 3

Disc 7:
52. Princess vs. Princess
53. The Purr-fect Hero
58. Riddle Me This
59. Volcanic Panic
60. Beach Blank-out Blastoise
61. The Misty Mermaid
62. Clefairy Tales
63. The Battle Of The Badge
64. It's Mr. Mimie Time

Disc 8:
65. Holiday Hi-Jynx - not included
66. Snow Way Out!
67. Showdown At The Po-k Corrall
68. The Evolution Solution
69. The Pi-kahuna
70. Make Room For Gloom!
71. Lights, Camera, Quack-tion
72. Go West Young Meowth
73. To Master The Onixpected!

Disc 9:
74. The Ancient Puzzle Of Pokemopolis
75. Bad To The Bone
76. All Fired Up!
77. Round One -- Begin!
78. Fire And Ice
79. The Fourth Round Rumble
80. A Friend In Deed
81. Friend And Foe Alike
82. Friends To The End
83. Pallet Party Panic - not included in this set but is in the Adventures on the Orange Islands box set