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SULFATE-FREE
SURFACTANT
SOLUTIONS
Innovative Chemical Solutions for a Cleaner, Healthier, More Energy Efficient World
STEPAN SULFATE-FREE
SURFACTANT SOLUTIONS
The sulfate-free trend has emerged from beauty salons into the
mainstream. Originally meant to convey resistance to color-fading
on dyed hair, the sulfate-free concept has grown to include low
skin irritation claims in body washes and other cleansing
products.
SHAMPOO
Economy Sulfate-Free Shampoo (No. 1112)
High-Foaming, Premium Sulfate -Free Shampoo (No. 1158)
Naturally-Derived, Color Care, Sulfate-Free Shampoo (No. 1189) NEW!
Pearlescent, Sulfate-Free, Conditioning Shampoo (No. 1111)
BODY WASH
Naturally-Derived, 1,4-Dioxane Free, Mild Baby Wash (No. 1164)
Naturally - Derived, Sulfate-Free, Moisturizing Shampoo and Body
Wash (No. 1119)
Scrubbing Shower Gel (No. 1012)
HAND SOAP
Sulfate- Free Hand Wash (No. 1065)
Sulfate-Free, Moisturizing, Gentle Foaming Hand Soap (No. 1179)
FACIAL CLEANSER
Clear Face Wash with 2% Salicylic Acid (No. 1072)
Sulfate- Free Facial Cleanser (No. 1190) NEW!
Additional formulations are available from Stepan Company. Please contact Stepans U.S.
Technical Service or visit Stepans website at www.stepan.com. Formulation numbers can be
used to reference the formulation on Stepans website or when contacting Stepans U.S.
Technical Service at techserv@stepan.com or 1-800-745-7837.
ECONOMY SULFATE-FREE SHAMPOO
(No. 1112)
Total 100.0
Procedure: In a suitable container, add Deionized water and turn on the agitator. Add
ALPHA-STEP PC - 48 and AMPHOSOL CDB Special and mix until homogeneous.
Add Sodium chloride to adjust viscosity. Add fragrance and dye while mixing. Adjust pH
with Citric acid or Sodium hydroxide. Add Methylchloroisothiazolinone (and)
Methylisothiazolinone.
Typical Properties:
Appearance at 25C Clear viscous liquid
pH, as is 5.0 -5.5
Viscosity at 25C, cps 3,500 - 6,200
Total 100.0
Procedure: In a suitable vessel equipped with heating and agitation capabilities, charge
Deionized water. While agitating, heat Deionized water to 55C - 60C then add
STEPAN-MILD LSB and LATHANOL LAL Powder. Mix well until solubilized. Cool
down to 40C - 45C. Add ALPHA-STEP PC- 48 and AMPHOSOL HCG, while
continuing agitation. Add STEPAN-MILD GCC. Mix well. Cool batch to 25C. Adjust pH
with Citric acid. Add fragrance, dye, and preservative. Adjust viscosity with Sodium
chloride, if necessary.
Typical Properties:
Appearance at 25C Clear liquid
pH, as is 5.5- 5.8
Viscosity at 25C, cps 4,100- 4,500
Total
100.0
Procedure: In a suitable vessel equipped with heating and agitation capabilities, add
Deionized water and heat to 60C - 65C. Add LATHANOL LAL Powder, and mix until
completely dissolved. Cool to 42C - 45C. Add AMPHOSOL HCG, AMPHOSOL
2CSF, and ALPHA-STEP PC-48. Mix until homogeneous. Add STEPAN-MILD GCC
and mix until clear. Adjust pH with Citric acid, if necessary. Add fragrance, dye and,
preservative while mixing.
Typical Properties:
Appearance at 25C Clear viscous liquid
pH, as is, 5.8-6.0
Viscosity at 25C, cps 12,000
Procedure: In a suitable vessel equipped with heating and agitation capabilities, charge
Deionized water and begin heating. Add ALPHA-STEP PC -48, AMPHOSOL CDB Special,
STEPAN-MILD L3, STEPAN SLL-FB, and Glycol monostearate using moderate agitation. Heat
to 60C-65C. Mix for at least 30 minutes until all materials dissolve. Begin cooling. At 40C, add
Polyquaternium-7, Hydrolyzed collagen, Linium usitatissium extract, and Panthenol with continued
mixing. Cool batch to 25C. Adjust pH with Citric acid or Sodium hydroxide. Add fragrance, dye,
and Methylchloroisothiazolinone (and) Methylisothiazolinone, as desired.
Typical Properties:
Appearance at 25C Pearlescent viscous liquid
pH, as is 5.5-6.5
Viscosity at 25C, cps 5,500-6,000
Total 100.0
Procedure: In a suitable vessel equipped with heating and agitation capabilities, charge
Deionized water. While agitating, heat to 55C-60C. Add ALPHA-STEP PC-48 and
LATHANOL LAL Powder. Mix well until solubilized. Cool to 40C-45C. Add AMPHOSOL
HCG, while continuing agitation. Add STEPAN-MILD GCC. Mix well. Cool batch to 25C.
Adjust pH with Citric acid. Add fragrance, dye, and preservative with mixing. Adjust viscosity with
Sodium chloride, if necessary.
Typical Properties:
Appearance at 25C Clear liquid
pH, as is 5.5-5.8
Viscosity at 25C, cps 4,500-4,800
Total 100.0
Procedure: In a suitable vessel equipped with heating and agitation capabilities, charge
Deionized water. Start heating water to 40C-45C. Add STEPAN-MILD LSB, AMPHOSOL
CS-50, STEPAN-MILD GCC, and STEPAN-MILD L3 using moderate agitation. Mix for at
least 30 minutes until everything is completely dissolved. Add Panthenol with continued mixing.
Cool the batch to 25C. Adjust pH with Citric acid or Sodium hydroxide, if necessary. Adjust
viscosity with Sodium chloride, if necessary. Add fragrance, dye, and preservative, as desired.
Typical Properties:
Appearance at 25C Clear viscous liquid
pH, as is, 5.0-5.5
Viscosity at 25C, cps 3,000 -7,000
Total 100.0
Procedure: Charge vessel with Deionized water. Start agitation. Slowly sprinkle in Xantham gum.
Mix until completely dispersed. Add Glycerin, STEPAN-MILD PCL, AMPHOSOL HCG,
Crushed apricot seed and Walnut shell powder. Mix until homogeneous. Adjust pH with Citric acid
or Sodium hydroxide. Add fragrance, dye, and preservative.
Typical Properties:
Appearance at 25C Translucent viscous liquid
pH, as is 5.0-6.0
Viscosity at 25C, cps 10,000 -12,000
Total 100.0
Procedure: Into a suitable vessel equipped with mixing capabilities, combine Deionized water
and ALPHA-STEP HWC, fragrance, dye, and preservative. Mix until homogeneous. Adjust to
desired pH with Citric acid or Sodium hydroxide. Adjust viscosity with Sodium chloride, if desired.
Typical Properties:
Appearance at 25C Clear liquid
pH, as is, 5.0-6.0
Viscosity at 25C, cps Water thin
Total 100.0
Procedure: In a suitable vessel equipped with heating and agitation capabilities, charge
Deionized water and begin mixing. Sprinkle in Hydroxypropyl methylcellulose. Mix until dispersed.
Add Glycerin, ALPHA-STEP PC-48, and AMPHOSOL HCG. Mix well. Start heating to
45C. Add STEPAN-MILD L3. Mix until clear. Add fragrance. Mix until clear. Cool to 25C.
Adjust pH with Citric acid. Add Methylchloroisothiazolinone (and) Methylisothiazolinone.
Typical Properties:
Appearance at 25C Clear liquid
pH, as is 5.0-6.0
Viscosity at 25C, cps Water thin
Total 100.0
Procedure: In a suitable vessel equipped with heating and agitation capabilities, charge
Deionized water, Propylene glycol, and BIO-TERGE AS-40 CG-K. Start heating to 45C-50C
with mixing. Add STEPAN-MILD L3 with agitation. Continue heating to 45C -50C; mix until
clear. Add Salicylic acid with agitation; mix until clear. Add PEG-150 distearate with agitation; mix
until clear. Begin cooling to room temperature with agitation. Adjust pH with Sodium hydroxide.
Adjust viscosity with Sodium chloride. Add fragrance, dye, and preservative, if needed.
Typical Properties:
Appearance at 25C Clear viscous liquid
pH, as is 4.3-4.6
Viscosity at 25C, cps 13,400
Procedure: Into a suitable vessel equipped with mixing capabilities, combine Deionized water,
STEPAN-MILD LSB, AMPHOSOL CG-UN and Hypoallergenic perfume. Mix until
homogeneous. Adjust pH with Citric acid. Add Potassium(E-E)-hexa-2.4 dienoate and Sodium
benzoate. Add STEPAN-MILD GCC and stir until clear.
Typical Properties:
Appearance at 25C Clear liquid
pH, as is 5.0-5.5
Viscosity at 25C, cps Water thin
NATURALLY-DERIVED:
Stepan defines as derived from biorenewable resource originating from animal,
plant or marine feedstock. All Stepan surfactants used in formulations labeled as
naturally-derived have a minimum of 50% biorenewable carbon content (based on
Stepans BCI calculation). Other ingredients were not evaluated.
SULFATE-FREE:
There is no industry cosmetic guideline or regulatory definition for "sulfate-free.
Stepan defines a product to be sulfate free if it does not contain Alcohol sulfate
or Alcohol ether sulfate as per INCI nomenclature. This definition does not include
the inorganic sulfates, e.g. Sodium sulfates, used as processing aids or formed as
a residual impurity or by-product.
ZEIN SCORE:
The amount of Zein protein solubilized by a given surfactant compared to the
amount solubilized by Sodium lauryl sulfate (SLS), a surfactant used in Personal
Care products (the Zein Score for SLS is 100%). The less protein solubilized, the
milder the surfactant.
STEPANS SULFATE-FREE SURFACTANTS
SHAKE FOAM SHAKE FOAM SURFACE
STEPAN TRADE NAME INCI NAME ACTIVES, % FORM AT ZEIN WITHOUT OIL, WITH OIL, BCI CMC TENSION
25C SCORE (ml) (ml) (mg/L) (mN/m)
Anionic
ALPHA-STEP PC-48 Sodium methyl 2-sulfolaurate (and) Disodium 39 Liquid 68 275 250 94 177 26
2-sulfolaurate
BIO-TERGE AS-40 Sodium C14-16 olefin sulfonate 39 Liquid 75 500 350 0 301 31
LATHANOL LAL Powder Sodium lauryl sulfoacetate 65 Powder 55 375 343 86 131 23
STEPAN-MILD LSB Sodium lauryl sulfoacetate (and) Disodium 25 Liquid 42 413 373 64 105 23
laureth sulfosuccinate
STEPAN-MILD PCL Sodium methyl 2-sulfolaurate (and) Disodium 23 Liquid 61 448 430 90 65 25
2-sulfolaurate (and) Sodium lauryl sulfoacetate
STEPAN SLL-FB Sodium lauroyl lactylate 100 Solid 51 370 335 100 143 35
Amphoteric
50
AMPHOSOL CS-50 Cocamidopropyl hydroxysultaine Liquid 22 320 150 59 30 32
(solids)
Nonionic
STEPAN-MILD GCC Glyceryl caprylate/caprate 100 Liquid to soft N/A N/A N/A 100 152 28
paste
STEPAN-MILD L3 Lauryl lactyl lactate 100 Liquid N/A N/A N/A 100 N/A N/A
STEPAN 745 GC PEG/PPG-6/2 glyceryl cocoate 100 Liquid N/A N/A N/A 67 31 36
Blend
ALPHA-STEP HWC See Formulation No. 1065 34 Liquid 30 345* 210* 78 N/A N/A
Innovative Chemical Solutions for a Cleaner, Healthier, More Energy Efficient World