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Steady flow energy equation in boiler leading to the concept of enthalpy-typical.

Typically, a substance entering a process has a potential energy(PE), kinetic energy(KE),


internal energy (U) and flow work(Wf). Although negligible, let me explain that Potential
energy is dependent on the substance mass and its elevation; kinetic is dependent on the
substance mass and velocity; internal energy, which is dependent on the temperature and the
mass of the substance, and its flow work, which is the reason why that substance is entering
the process and is dependent on its pressure and volume. Bear in mind that flow work is not
the same with work steady flow :) Moving on, we assume that the substance receives heat (Q)
and does work steady flow (Wsf) during the process. Thus, it changes its state at its final
position. We then formulate an equation based on the Law of Conservation of Energy, energy
in = energy out:

PE1 + KE1 + U1 +Wf1 + Q = PE2 + KE2 + U2 +Wf2 +Wsf : this is the steady flow energy
equation

notice that Q is on the left side because it is added in the process as what we have assumed
earlier. Wsf, on the other hand, is at the right side because we said work is "done" and
therefore leaves the process. Here we place your assumption that changes in kinetic and
potential are negligible, making:

PE1= PE2
KE1=KE2

and thereby cancelling each other out leaving us with the equation:

U1 + Wf1 + Q = U2 + Wf2 +Wsf : this is the simplified steady flow equation neglecting PE and
KE changes

enthalpy(H) is the available energy of the substance which is also equal to the sum of the flow
work and internal energy that is why we have the equation: H1 (enthalpy before); H2
(enthalpy after, i.e., after heat)

H1+ Q = H2 + Wsf

transposing the initial state to the right side and subtracting it from the final state indicates a
change:

Q = (H2-H1) + Wsf

the process in a boiler is isobaric, isobaric processes when used in open flow system does not
produce work. In simple sense, you dont use a boiler to extract work from it, you need it to
boil the water in it. Thus we need a value for Q and leaving the Wsf = 0;

Q = H2 - H1
here we see that for you to change the initial enthalpy (H1) to the final enthalpy (H2) you need
to add heat (Q) so your final state will have a higher enthalpy than your initial.

Hope you understand

From Wikipedia:

Principle

A boiler explosion is a kind of boiling liquid expanding vapor explosion (BLEVE).

Boiler explosions are particularly devastating because of the huge amount of energy
stored in the heated liquid water. A basic fire-tube boiler operating at 50 psi (340 kPa)
contains water at a temperature of roughly 150 C (300 F). Checking against a steam
table, we see the water (??) (or steam!) will release 2.74 MJ/kg as it flashes to steam and
condenses again. This is 66% of the energy per kilogram which TNT releases when
detonated. A typical locomotive boiler holds over 10,000 liters of pressurized water
under these conditions. Based on the data above, if such a boiler were to
catastrophically fail, it would release approximately 1.6 times the energy of a RAF
Blockbuster bomb (*) - the largest conventional munition used during World War II.

In the case of a firebox explosion, these typically occur after a burner flameout. Oil
fumes, natural gas, propane, coal, or any other fuel can build up inside the combustion
chamber. This is especially of concern when the vessel is hot; the fuels will rapidly
volatize due to the temperature. Once the lower explosive limit (LEL) is reached, any
source of ignition will cause an explosion of the vapors.

A fuel explosion within the confines of the firebox may damage the pressurized boiler
tubes and interior shell, potentially triggering structural failure, steam or water leakage,
and/or a secondary boiler shell failure and steam explosion.

(*) The term Blockbuster was originally a name coined by the press and referred to a
bomb which had enough explosive power to destroy an entire city block

Texto do NBIC

A Boiler: The Explosive Potential of a Bomb

This article by the late William Axtman was originally published in the winter 1996
National Board BULLETIN. Some code requirements may have changed because of
advances in material technology and/or actual experience. The reader is cautioned to
refer to the latest edition and addenda of the National Board Inspection Code for
current requirements.
Over the years, various estimates of the potential energy of a boiler or pressure-vessel
explosion have been presented, with the intent of demonstrating the danger of this
equipment if not properly maintained.

Consider this: if you could capture all the energy released when a 30-gallon home hot-
water tank flashes into explosive failure at 332F, you would have enough force to send
the average car (weighing 2,500 pounds) to a height of nearly 125 feet or more than
the height of a 14-story apartment building starting with a lift-off velocity of 85 miles
per hour!

When this amount of explosive force is unleashed in a basement or utility closet, the
shock wave created by the explosion carries dirt, debris, ceiling, pipe, darkness, and
burning temperatures in all directions with tremendous force. The result is devastating
damage to anything in the vicinity. Whole houses can be leveled. Nearby cars can be
tossed around like playthings. Furniture, even several rooms from the point of the
explosion, will become airborne. People in the same building or on a nearby sidewalk or
parking lot can be injured or killed. All of this is due to the power unleashed in a shock
wave of energy as the pressure vessel explodes. In a fraction of a second, as hot water
snaps to steam, everything turns to darkness and destruction.

Standard physics laws of temperature and pressure are used to measure the explosive
potential of boilers and pressure vessels. New calculations show, for instance, that if
liberated in a rupture, a 30-gallon hot-water tank at 90 psig (or 104.7 psia) has
approximately 314,095 foot-pounds of energy to flash its water into steam at 332F.
Translate that force potential into real-world terms and you have the example of the car
being rocketed into the air as noted above. Another way to look at this 300,000 foot-
pound figure is that it equals the explosive force of 0.16 pounds of nitroglycerin.

Yet another approach to examine the potential explosive force is the flashpoint
conversion factor for water to steam. Here the increase in volume is a factor of
approximately 1,600 to 1. So when water or a similar dense liquid that normally needs
one cubic foot for containment suddenly needs 1,600 cubic feet, explosion occurs.
Thats like taking the volume of an S-gallon bathroom trash can and causing it to fill a
12- by 11-foot living room with an 8-foot ceiling in a split second. Such a dose of
explosive power propagates the shock wave that inevitably does most of the damage to
property and humans.

Several operational situations can bring on the violent, deafening blasts that result when
a buildup of pressure is suddenly released. A common cause of explosion is the
runaway firing condition that takes place when the boilers burner does not shut off. In
this case, when the hot-water heater is connected to the city water supply on one side
and the building hot-water service on the other, the check valve will shut off and no
back pressure will go into the city side. Instead, the tank will take the pressure. As a
result, the temperature in the tank will rise. And this temperature rise will compromise
the tank structure, weakening the metal around the bottom of the tank and causing a
sudden failure.

Of course, a properly functioning pressure and temperature relief valve would prevent
such a failure. But a properly installed and maintained safety valve is not a universal
feature of pressurized vessels.
Another type of explosion is caused by superheated liquid. Here the resulting vapor
explosion occurs when a liquid transforms quickly into a gas, causing a rapid pressure
increase. Actually, a typical malfunction can result when normally benign, saturated
steam is forced out of its temperature/pressure equilibrium by a combination of valves
shutting and extra energy being introduced into the system. These conditions disrupt the
temperature/pressure balance, causing the fluid (steam) system to seek out a new
equilibrium.

When this occurs in a closed vessel, as the liquid accidentally heats above its boiling
point, the frantic and almost instantaneous physics of the system trying to re-establish
equilibrium can result in explosion. Often, part of the vessel breaks away because the
liquid is vaporizing to gas so rapidly. The rarefaction wave moves within the vessel and
the resulting compression wave violently forces the liquid particles out through the
vessel breach. This sequence of events spells split-second disaster.

Firefighters and other well-trained emergency personnel follow important protocols for
identifying flows of superheated material. They are trained to assume a mine-field-type
situation exists if they hear a leak. Everyone stops moving immediately. Someone at a
safe peripheral location at the incident scene cautiously holds up a broom handle or 2-
by 4-inch board and waves it across the breach where the invisible but searing steam
might be. If present, the steam will literally cut the wood. If a human hand were to reach
up unsuspectingly, trying to detect the steam, it too, could be cut by superheated steam!
Instead, the length of wood indicates the area of the leak or, preferably, the clear path
around the leak and the personnel can be shown a path to safety.

Preventing catastrophic failure of any boiler or pressure vessel has always been a
concern of the National Board. Boilers in dry cleaning operations, pressurized steam
cleaners in jewelry shops, air compressors used by painters, pressurized air systems
used with power hydraulic lifts in auto repair shops, even instrument sterilizers in
dentists offices all are capable of causing injury due to explosion. On one hand, they
rarely are inspected for proper mechanical performance and structural integrity. On the
other hand, their operators are occasionally guilty of rigging the wiring or controls
intended to prevent potentially explosive operational problems. And as a complicating
factor, each state or province has its own inspection rules, and most apply only to
commercial operations of a certain size or to water heaters or steam heat systems in
dwellings that hold four or more housing units.

The National Board is conspicuously aware of the explosion hazard of boilers and
pressure vessels. For most of this century, the public, law enforcement agencies,
emergency response teams, and industry standards groups have looked to the National
Board for assistance in setting guidelines for boiler safety. One of those areas of
concern is the actual force generated by explosive failure and how best to increase
public awareness and safety practices to control this.

Quantidade de flash formado a partir da despressurizao:


Quantidade de flash formado a partir da despressurizao:

Exemplo de clculo: seja pV = 6 bar (absoluto) e qmV = 1000 kg/h.

Conforme Tabela de vapor saturado - Referncia de presso, hfV = 670,7 kJ/kg.

V (condensado ou gua antes de flashear) = Cond (condensado aps flash ocorrer) + Flash

hfV a entalpia do condensado ou (gua) antes da despressurizao (ou flasheamento)!

Para presso atmosfrica, patm 1 bar absoluto, segundo mesma tabela,

hfCond = 417,5 kJ/kg (coluna hf da tabela). (entalpia do condensado aps despressurizao)

hgFlash = 2675,2 kJ/kg (coluna hg da tabela). (entalpia do flash aps despressurizao)

Segundo a conservao da massa,

qmV = qmCond + qmFlash

1000 = qmCond + qmFlash.

Pela conservao da energia, a entalpia deve ser mantida:

hfV x qmV = hfCond qmCond + hgFlash qmFlash

670,7 x1000 = 417,5 qmCond + 2675,2 qmFlash = 417,5 qmCond + 2675,2 (1000 qmCond).

qmCond = 670,7 1000 2675,2 1000 / (417,5 2675,2) 888 kg/h.


qmFlash = 1000 qmCond 112 kg/h.

As equaes acima formam um sistema que permite a determinao das duas incgnitas
qmCond e qmFlash.

evidente que, nos aspectos da eficincia energtica e do consumo de gua, a


contribuio do vapor de flash negativa. Algumas instalaes enviam o condensado
para um reservatrio especial, formando uma espcie de gerador de vapor de baixa
presso, que pode ser utilizado por alguns tipos de equipamentos.