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XI (F.Sc.) CHEMISTRY CHAPTER # 1

02-10-2013 10 10 MINUTES

Q.No.1 Choose the best option. 10

(i) All are molecular ions except:
(a) CH 4 (b) CH 3 (c) NH 3 (d) O22
(ii) In one kilogram, there are present __________a.m.u.
(a) 1.66 x 10-27 (b) 1.66 x 10+27 (c) 0.6 x 10-27 (d) 0.6 x 10+27
(iii) Efficiency of a reaction can be determined by:
(a) isotropy (b) mass spectrometer(c) isotropy (d) percentage yield
(iv) The volume occupied by 0.14g of N2 at STP is:
(a) 2.24dm3 (b) 22.4dm3 (c) 1.12dm3 (d) 0.112dm3
(v) A limiting reactant is the reactant which controls quantity of:
(a) reactants (b) product (c) equilibrium constant (d) reaction mixture
(vi) The mass of one mole of electrons is:
(a) 1.008mg (b) 0.55mg (c) 0.184mg (d) 1.673mg
(vii) How much mass of HCl is required to produce 12g of hydrogen gas when HCl is
reacted with Mg metal?
(a) 485g (b) 438mg (c) 438g (d) 438kg
(viii) 27g of Al will react completely with how much mass of O2 to produce Al2O3:
(a) 8g (b) 16g (c) 32g (d) 24g
(ix) When 9.8g of H2SO4 is dissolved in one liter of water, it produces 0.2moles of H+
and 0.1 mole of sulphate ions then select the correct statement:
(a) it will produce 2NA of H+ ions (b) it will produce 2 x NA of negative
charge
(c) it will produce 9.6g of SO42 (d) complete ionization never happens as H2SO4 is
a weak acid
(x) CH2O could be the empirical formula of which compound:
(a) glucose (b) acetic acid (c) ethanol (d) both a & b

XI (F.Sc.) 30 50 MINUTES

Q.No.2 Give short answers to the following questions. 10x2=20

(i) The atomic masses may be in fraction. Justify?
(ii) Give two assumptions of stoichiometry.
(iii) Explain why the concept of limiting reactant is not applicable to the reversible reactions.
(iv) What is the function of electrometer in mass spectrometer?
(v) Formation of dinegative ion is endothermic. Justify?
(vi) Justify that N2 and CO have same number of electrons, protons and neutrons.
(vii) Explain molar volume with two examples.
(viii) How the limiting reactant is identified?
(ix) How many carbon atoms are there in 18g of carbon?
(x) Calculate formula units in 100g of KClO3?
Q.No.3 (A) What is yield? Give its types. How the efficiency is related with %age yield? 05
(B) Calculate the number of grams of Al2S3 which can be prepared by the reaction
of 20g of Al and 30g of S. How much the non-limiting reaction is in excess? 05