HELIOS EDUCORE 1

TEST SERIES JEE-2018

JEE-MAIN
Topic : Stoichiometry & Atomic Structure

Time : 90 Min Max. Mark : 60

* +3 for correct and –1 for incorrect. BEST OF LUCK

1. Select the correct statement

(a) Radial part is dependent on r and angular part is dependent on q and f
(b) Angular wave function ‘qf’ depends only on l and m1 independent on n for
a given type of orbital
(c) Both (a) and (b) are correct
(d) None of the above is correct

2. Select the correct alternate

(a) Radial probability function gives the probability of finding the electron at
a distance r from the nucleus
(b) The maximum in the curve corresponds to the distance at which the
probability of finding the electron is maximum
(c) This distance is called the radius of maximum probability (52.9 pm for
hydrogen)
(d) All the above statements are correct statements

3. Atomic emission spectra of an element cannot be used to

(a) identify the element
(b) determine the mass number of the nucleus of the atom
(c) measure the difference in energy between pairs of stationary states of the
atom
(d) calculate the ionisation energy of the atom
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4. Consider the following observations

He2+ + 2e– → He; DH° = –79.0 eV

He+ + e– → He; DH° = x eV

He2+ + e– → He; DH° = –54.4 eV

Select the correct statements

(A) First ionisation energy of He+ is 54.5 eV
(B) First ionisation energy of He is 24.6 eV
(C) Second ionisation energy of He is 54.4 eV
a-particle gains two electrons by losing energy of 79.0 eV
(D)
(a) A, B, C, D (b) A, B, D (c) A, C, D (d) B, C, D

5. One mole of N2H4 loses ten moles of electrons to form a new compound y. Assuming
that all the nitrogen appears in the new compound. What is the oxidation state of
nitrogen in y. There is no change in the oxidation state of hydrogen:
(a) –1 (b) –3 (c) +3 (d) +5

6. 150 mL M/10 Ba(MnO4)2 in acidic medium can oxidize completely

(A) 150 mL 1 M Fe2+ (B) 50 mL 1 M FeCrO4
(C) 75 mL 1 M C2O42– ions (D) 25 mL 1 M K2Cr2O7 solution
(a) A, B, C, D (b) A, B, D (c) A, C, D (d) B, C, D
7. Which one is not correct about the reaction : FeS2 → Fe2O3 + SO2.
(1) Eq. weight of FeS2 is M/11
(2) Eq. wt. of SO2 = M/5
(3) 1 mole of FeS2 requires 7/4 mole of O2
(4) S has –2 oxidation sate in FeS2
Option
(a) 1, 2 & 3 (b) 1 & 2 (c) 1, 2, 3 & 4 (d) 2 & 3
8. 100 ml of mixture of CO and CO2 is mixed with 30 ml of oxygen and sparked in a
eudiometer tube. The residual gas after treatment with aqueous KOH has a volume
of 10 ml which remains unchanged when treated with alkaline pyrogallol. If all the
volumes are under the same conditions, point out the correct options.
(A) The volume of CO that reacts, is 60 ml
(B) The volume of CO that remains unreacted, is 10 ml
(C) The volume of O2 that remains unreacted, is 10 ml
(D) The volume of CO2 that gets absorbed by aqueous KOH, is 90 ml.
(a) A, B, C, D (b) A, B, D (c) A, C, D (d) B, C, D
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9. Which of the following statements is/are correct?

(A) A photon is positively charged nuclear particle.
(B) A photon is a particle of light energy
(C) A photon is a quantum of light
(D) A photon is a bundle of energy of definite magnitude but not necessarily
light energy
(a) A, C, D (b) B, C (c) A, D (d) A, B

10. Which of the following is/are correct?

(A) the energy of an electron depends only on the principal quantum numbers
not on the other quantum numbers
(B) the energy of an electron depends only on the principal quantum number
in case of hydrogen and hydrogen like atoms.
(C) The difference in potential energies of any two energy level is always more
than the difference in kinetic energies of these two levels.
(D) An electron in ground state can emit a photon
(a) A, C, D (b) B, C (c) A, D (d) A, B

11. In Bohr series of lines of hydrogen spectrum, third line from the red end corresponds
to which one of the following inner orbit jumps of electron for Bohr’s orbit in
atom of hydrogen
(a) 4 → 1 (b) 2 → 5 (c) 3 → 2 (d) 5 → 2

12. The wavelength of a spectral line for an electronic transition is inversely related
to :
(a) The number of electrons undergoing the transition
(b) The nuclear charge of the atom
(c) The difference in the energy of the energy levels involved in the transition
(d) The velocity of the electron undergoing the transition

13. If 0.80 mole of MnO2 and 146 g of HCl react

MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O
then
(A) 0.80 mole of Cl2 is formed (B) 0.80 mole of HCl remains unreacted
(C) MnO2 is completely reacts (D) MnO2 is the limiting reactant
(a) A, C, D (b) B, C (c) A, D (d) A, B, C

14. Equivalent weights of KMnO4 in acidic medium, concentrated alkaline medium,

and dilute basic medium respectively are M/5, M/1, M/3. Reduced products can
be :
(a) MnO2, MnO42–, Mn2+ (b) MnO2, Mn2+, MnO42–
(c) Mn2+, MnO42–, MnO2 (d) Mn2+, MnO2, MnO42–
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15. 1 mole of FeC2O4 is oxidised by x moles of Cr2O72– in acidic medium, x is :

(a) 3 (b) 1.5 (c) 0.5 (d) 1.0

16. In the following reaction,

VO32– + MnO4– → Mn2+ + VO43–
1 mole of VO32– is oxidised by MnO4– using
(a) 0.2 mol (b) 0.4 mol (c) 0.8 mol (d) 1.0 mol

17. 1 g of X% H2O2 required x mL of KMnO4 solution in acidic medium. Thus,

molarity of KMnO4 solution is
(a) 0.12 M (b) 0.60 M (c) 0.024 M (d) None of correct

18. A mixture of Na2C2O4(A) and KHC2O4.H2C2O4(B) required equal volumes of

0.1 M KMnO4 and 0.1 M NaOH separated. Molar ratio of A and B in the mixture
is
(a) 1 : 1 (b) 1 : 5.5 (c) 5.5 : 1 (d) 3.1 : 1

19. 25 mL of a solution containing 6.1 g L–1 of an oxalate of formula KxHy (C2O4)z.

nH2O required. 18 mL of 0.1 N NaOH in titration I and 24 mL of 0.1 N KMnO4
in acidic medium in titration II.
What is the value of (x + y) ?
(a) 2 (b) 3
(c) 4 (d) cannot be determined

20. Find ratio of time period of electron in 4th and 2nd orbit of He+.
(a) 8 : 1 (b) 4 : 1 (c) 2 : 1 (d) None of these