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m' 33 g
Cu
nm = = = 0.519 mol
Cu A Cu 63.55 g / mol
Likewise, for Zn
47 g
nm = = 0.719 mol
Zn 65.39 g / mol
nm
' Cu
C Cu = x 100
nm nm
Cu Zn
0.519 mol
= x 100 = 41.9 at%
0.519 mol 0.719 mol
Also, 4.10 The concentration of an element in an alloy, in atom percent, may be computed
using Equation (4.5). With this problem, it first becomes necessary to compute the number
of moles of both Cu and Zn, for which Equation (4.4) is employed. Thus, the number of
moles of Cu is just
m' 33 g
Cu
nm = = = 0.519 mol
Cu A Cu 63.55 g / mol
Likewise, for Zn
47 g
nm = = 0.719 mol
Zn 65.39 g / mol
NA Al
N =
A
Al
3
The density of Al (from the table inside of the front cover) is 2.71 g/cm , while its atomic
weight is 26.98 g/mol. Thus,
N =
6.023 x 10 23 atoms/ mol 2.71 g / cm 3
26 .98 g / mol
22 3 28 3
= 6.05 x 10 atoms/cm = 6.05 x 10 atoms/m
3
4.15 In order to compute the concentration in kg/m of Si in a 0.25 wt% Si-99.75 wt% Fe alloy
we must employ Equation (4.9) as
CSi
''
CSi = x 103
CSi CFe
Si Fe
3
From inside the front cover, densities for silicon and iron are 2.33 and 7.87 g/cm ,
respectively; and, therefore
'' 0.25 3
CSi = x 10
0.25 99 .75
2.33 g / cm3 7.87 g / cm3
3
= 19.6 kg/m
4.18 This problem asks us to determine the number of molybdenum atoms per cubic centimeter
for a 16.4 wt% Mo-83.6 wt% W solid solution. To solve this problem, employment of
Equation (4.17) is necessary, using the following values:
C =C = 16.4 wt%
1 Mo
3
= = 10.22 g/cm
1 Mo
3
= = 19.3 g/cm
2 W
A =A = 95.94 g/mol
1 Mo
Thus
NA CMo
NMo =
CMo A Mo
100
A Mo
CMo
Mo W
=
6.023 x 10 23 atoms/ mol (16.4)
(16.4)(95.94 g / mol) 95.94 g / mol
100 16.4
(10.22 g / cm 3 ) 19.3 g / cm 3
22 3
= 1.73 x 10 atoms/cm
4.22 This problem asks us to determine the weight percent of Ge that must be added to Si such
21
that the resultant alloy will contain 2.43 x10 Ge atoms per cubic centimeter. To solve this
problem, employment of Equation (4.18) is necessary, using the following values:
21 3
N =N = 2.43 x 10 atoms/cm
1 Ge
3
= = 5.32 g/cm
1 Ge
3
= = 2.33 g/cm
2 Si
A =A = 72.59 g/mol
1 Ge
A = A = 28.09 g/mol
2 Si
Thus
100
C Ge =
N A Si Si
1
N GeA Ge Ge
100
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= 11.7 wt%
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