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Ethanoyl chloride reacts instantly with cold ethanol. There is a very exothermic reaction in which a steamy acidic
gas is given off (hydrogen chloride). Ethyl ethanoate (an ester) is formed.
4. A tank is half filled with water, if N2= 1.02 moles and H2O= 1.02moles. what happens to the N2 when dissolved
in water? ( increase, decrease, remains the same, none of these)
5. Given 1mol of gas A at 1 bar and 1mol of gas B at 2bar. If the membrane separating the two gases mixtures is
removed, find the entropy change
6. Given 1 mol of glacial acetic acid freeze in an ice bath. If Hf acid= 11.2 kJ/mol and Hf ice= 6.02kJ/mol, calculate
the entropy change of the acid, change in enthalpy in ice bath total change in entropy if Hf=237lJ/mol and 532
kj/mol for methane ang propane
7. Which has the ff higher heat of combustion on a gram per gram basis
8. Freezing point depression
9. Boiling point elevation
10. Center of an atom
11. Evaluate the given structural formulas(paraffin)
12. Given density of sulfuric acid determine its molarity
13. Given NH4OH solution initially at 30mL diluted to 400mL then titrated with HCl. Compute pH
At the start
At the equiv point
After addition of 40m HCl
14. What is the pressure generated by placing 0.6kg of chlorine gas in a 15Lvessel at 23C?
15. Carnot efficiency
16. BOD calculation
17. Gibbs-helmholtz relationship
18. Growth rate of bacteria in a vessel
19. Nuclear chemistry calculations
20. Given lead metal, melting point, cp, Hv, and mass of metal. Find the heat needed to melt all metal
21. Reaction of N2O4 to 2NO2. MW is 61.22. find E and K
22. mL volume of 1mol ethanol
23. convert 98F to K
24. heat reaction
25. proton and electron, coulombs law
26. some molecule to another molecule formed by fischer projection,what are the reactants and products
27. titration of Fe to MnO4,C2O4 and AsO3
28. buffer solution of chloroacetic acid: acid is 0.43 M, base is 1.3M in 218.2mL,and addition of 50.1mL of 0.21M
NaOH
29. pond of 20,000m3, 25,000mg/m3 and diluted to 500 mg/m3, how much water must be added?
30. First order kinetics 16mg/L at the start, after 3 days
31. pH of rainwater given ammonia, HCl, sulfuric acid, and nitric acid concentration
32. SO2 emission calculation
33. Power output of a dam
34. Bioaccumulation factor calculation
35. Peptide bonds
36. The concentration of ketone bodies in the blood of a healthy humans is approximately 0.01mM/L. however, in
diabetic patients, this concentration increases to as much as 500 times. In the case when the ketone
concentration is increased a hundred fold, determine what basic chemical reaction occurs.
37. Otto Cycle: Find thermal efficiency, MEP. Substance is Air.
38. Given Fe3+, find the pH.
39. Delta H vaporization problem.
40. Vanadium Oxide problem, find the mass formed
41. Given %Sn and %), find the empirical formula. Ans: SnO2
42. What can you sacrifice to protect iron from corrosion? (Possible answers derived from activity series)
43. H2SO4 + Fe2SO4 + KMNO4 -> (predict the reactions and balance; answers were the coefficients)
44. What is Arrhenius base and acid equilibrium?
- 0.01 M with pK 1.8
- 0.1 M of weak acid and 0.01 M of the same acid
- D) 0.1 M of acid and 0.1 M of base
149. Determine the value of the rate constant at 410K for a reaction with a rate constant of 3.101x10^1sec^-
1 at 430K and an activation energy of 86.52kJ/mol
10.31x10^-1
9.54x10^0
8.65x10^-2
8.33x10^-3
150. Balancing: C6H12O6 + O2 = CO2 + H2O
3,6,12,6
1,6,6,6
2,12,6,2
1,12,6,2
151. 1 min disintegration of Radon-226, half-life is 1400 years
152. What is the most polar of the ff functional groups (R-OH, R-NH3, R-COOH, C triple bond C and C-C)
153. What happen to the enthalpy of the real gases when it is throttled at constant temperature
154. Heat of reaction when ethyne is hydrogenated to ethane
155. Balancing: Ca(OH)2 + HCl = CaCl2 + H2O
156. What is the danger in using pure methane as a household fuel for heating and cooking?
157. Determine the equilibrium concentration of iron ion in water if [OH]^-= 1^-1x10^-7 M at 25C and the
equilibrium constant for the solubility reaction of iron hydroxide is 2x10^-39 at 25C?
158. If the cosmic radiation discovered by two Nobel Prize winners in 1965 has a perfect black body spectrum
with a temperature of 3.01K, at what wavelength is the most intense radiation? in what range of
electromagnetic radiation does this wavelength fall?
159.