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If solute is non volatile solid or liquid the vapour pressure of solution is equal to
partial vapour pressure of solvent in the solution. Latest articles from
If the solute is volatile solid or liquid, then vapour pressure will be equal to the sum Blog
of partial vapour pressure of solute and that of solvent.
Raoult’s Law:
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“The partial vapour pressure of any component in the solution is directly proportional to its
mole fraction”.
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For a binary solution of two components A and to come in JEE 2018
B,
Where
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P A = vapour pressure of component A in pure
state.
Where
?These solutions obey Raoult’s law at all compositions of solute in solvent at all
temperature
Two liquids A and B form and ideal solution when A –A and B–B molecular attractions
will be same and hence A–B molecular attraction will be almost same as A–A and B–B
molecular attraction.
Examples , Ethyl chloride and ethyl bromide, n–hexane and n–heptane , CCl4 and SiCl4
Non-Ideal Solution:
?These solutions deviate from ideal behaviour and do not obey Raoult’s law over
entire range of composition.
1. dHmixing ≠ 0
2. dHmixing ≠ 0
2. dHmix > 0
3. dVmix > 0
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B) Negative Deviation:
2. dHmix < 0
3. dVmix < 0
Colligative Properties
The properties of dilute solutions which depend only on number particles of solute
present in the solution and not on their identity are called colligative
properties (denoting depending upon collection).
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where M1 = molecular weight of solute and w2 and w1 are weights of solute and
solvent
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where M1 = molecular weight of solute and w2 and w1 are weights of solute and
solvent
V = nRT
where
= Osmotic pressure
R = Gas constant
Degree of Association:
The fraction of the total number of molecules which combine to form bigger molecule
Obviously, i < 1
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Degree of Dissociation
The fraction of the total number of molecules which dissociates in the solution, that is,
breaks into simpler molecules or ions.
1-
i = 1+ = 1+ (2–1)
In general, i = 1+ (n–1) ,
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Add a comment...
Malti Kumari
its useful
Like · Reply · 1 · Jan 12, 2017 2:56am
Malti Kumari
it will be helpful for quick revision
Like · Reply · 1 · Jan 12, 2017 2:57am
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