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Cabangal, Erwin Cayl P.

Cabungcal, Cesarah Justine

Experiment no. 4 : Heat of Combustion: The Bomb Calorimeter


Treatment of Results

Weight of Benzoic Acid : 1.0043 g


Initial Fuse Length: 10 cm
Final Fuse length : 3.2 cm
Initial Fuse weight: 0.0161 g
Final fuse weight: 0.0051 g

Time (s) Temperature (o C) Temperature v


0 26.4 29

30 26.4 28.5
60 26.4
28
90 26.4

Temperature (oC)
120 26.4 27.5
150 26.4
27
180 26.4
210 26.4 26.5
240 26.4 26
270 26.4
25.5
300 26.4
310 26.6 25
0 100 200
320 27
330 27.1 Ti
340 27.5
350 27.6
360 27.7
370 27.9
380 27.9
390 28
400 28
410 28.1
420 28.2
430 28.2
440 28.3
450 28.3
460 28.3
470 28.4
480 28.4
490 28.4
500 28.4
510 28.4
520 28.5
530 28.5
540 28.5
550 28.5
560 28.5
570 28.5

Ignition
Initial Temperature 26.4
Final Temperature 28.5
Change in Temperature: 2. 1
Temperature vs. time Graph

0 100 200 300 400 500 600


Time (s)
Cabangal, Erwin Cayl P.
Cabungcal, Cesarah Justine

Experiment no. 4 : Heat of Combustion: The Bomb Calorimeter


Treatment of Results

Weight of Benzoic Acid : 1.0043 g


Initial Fuse Length: 10 cm
Final Fuse length : 3.2 cm
Initial Fuse weight: 0.0161 g
Final fuse weight: 0.0051 g

Time (s) Temperature (o C)


0 25.9 Temperature vs time
30 25.9 30
60 25.9
29
90 25.9
120 25.9

Temperature( oC)
28
150 25.9
27
180 25.9
210 25.9 26
240 25.9
270 25.9 25
300 25.9 24
310 25.9 0 100 200 300 400
320 26.1 Time (s)
330 26.7
340 26.3
350 26.9
360 27
370 27.4
380 27.7
390 28
400 28.3
410 28.4
420 28.6
430 28.8
440 28.9
450 29
460 29.1
470 29.1
480 29.2
490 29.2
500 29.2
510 29.3
520 29.3
530 29.3
540 29.3
550 29.3
560 29.4
570 29.4
580 29.5
590 29.5
600 29.5
610 29.5
620 29.5
630 29.5
640 29.5
650 29.5

Ignition
Initial Temperature 25.9
Final Temperature 29.5
Change in Temperature: 3.6
Temperature vs time Graph

100 200 300 400 500 600 700


Time (s)
A. Heat Capacity of the Bomb Calorimeter
Benzoic Acid
Weight 1.0043 g
Molar mass 122.13 g/mol Q = 26.5363 kJ
Change in Temperature 2.1 K dT = 2.1 K
Enthalpy 3227 kJ/mol
Heat Capacity of Bomb Cal. 12.6363 kJ/o C

B. Heat of combustion of Naphthalene


Weight 1.0306g C = 12.6363kJ/oC
Molar Mass 128.17 g.mol n= 8.0409 x10-3
Change in Temperature 3.6 K dT= 3.6 K
Heat of Combustion -5657.4115

Theoretical Value -5156.3


Actual Value -5657.41

% Error: 9.72%