15-16 - Test 2

ALL INDIA INTERNAL TEST SERIES
CHEMISTRY, MATHEMATICS & PHYSICS

SET – A
APT - 2 080109.1 Ai2TS -2
Time Allotted : 3 Hours Maximum Marks: 201

INSTRUCTIONS
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
 Attempt ALL the questions. Answers have to be marked on the OMR sheets.
 This question paper contains Three Sections.
 Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
 Each Section is further divided into two Parts: Part – A &Part – B.
 Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
 Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet

CLASS XI
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Parts.
(i) PART-A(01 – 06) contains 6 Multiple Choice Questions which have Only One Correct answer. Each
question carries +3 marks for correct answer and –1 mark for wrong answer.
PART-A (07 – 09) contains 3 Assertion-Reasoning Questions (MCQs) which have Only One Correct answer.
Each question carries +3 marks for correct answer and – 1 mark for wrong answer.
PART-A (10 – 15) contains 2 Paragraphs. Based upon each paragraph, 3 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +4 marks for the correct answer and
–1 mark for a wrong answer.
(ii) PART-B(01 – 02) contains 2 Matrix Match Type Questions which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +8 marks for all correct answer however for
each correct row +2 marks will be awarded and –1 mark for each row matched incorrectly.
Name of Candidate :
Batch ID : Date of Examination : / / 2 0 1
Enrolment Number :
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, SarvapriyaVihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
Website: www.fiitjee.com, Mail :aiits@fiitjee.com
2
Ai TS – 2 ( XI ) | SET – A | APT – 2 | Page |1
S
SEEC
CTTIIO
ONN–– 1
1:: C
CHHE
EMMIIS
STTR
RYY
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
1. n+l=5
m = 0, 1 ,+2
s = ½
Maximum number of electrons of an atom of copper that will have the above set of combination of quantum
number in ground state is __
(a) 5 (b) 13 (c) 8 (d) 3
2. A box of washing soda is dispatched off by FIITJEE SOUTH DELHI to FIITJEE BHOPAL containing 1.50 kg
of Na2CO3.10H2O (molar mass = 286). A.O.department complains because it finds that the box appears partly
empty and weighs only 1.34 kg. An independent analyst made by FIITJEE PUNJABI BAGHsays that the box
contains the correct mass of sodium carbonate, but that it has lost water of crystallization. What is the
composition of washing soda received at FIITJEE BHOPAL?
(a) Na2CO3.1.3 H2O (b) Na2CO3 .1.7 H2O (c) Na2CO3 . 8.3 H2O (d) Na2CO2 . 8.9 H2O
3. Incorrect statement is…


(a) CO  CO  e H  ve (b) O
2
 O  e H  ve
2   
(c) O  O  2e H  ve (d) O O  e H  ve
4. A mixture of two gases A and B in the mole ratio 2 : 3 is kept in a 2 litre vessel. A second 3 litre vessel has the
same two gases in the mole ratio 3 : 5. Both gas mixtures have the same temperature and same total
pressure. They are allowed to intermix and the final temperature and total pressure are the same as the initial
values, the final volume being 5 litres. Given that the molar masses are M A and MB . What is the mean molar
mass of the final mixture ?
77MA  123MB 123MA  77MB 77MA  123MB 123MA  77MB
(a) (b) (c) (d)
200 200 250 250
5. Minimum number of Hydrogen atoms required to produce radiation of all possible wavelength when electrons
th
fall from 5 orbit is
(a) 5 (b) 10 (c) 20 (d) 6
6. Clay found in upper lake at Bhopal contains 15% by mass moisture and rest are CaCO 3 and non volatile
SiO2. This on heating loses part of its moisture, but CaCO 3 is completely converted into CaO. The partially
dried sample now contains 7.35% moisture and 51.5% SiO 2. The mass percentage of CaCO3 in the original
sample of clay is approximately:
(a) 41.9% (b) 62.2% (c) 50% (d) 31.4%
PART – A
Assertion – Reason Type
This section contains 3 questions numbered 7 to 9. Each question contains STATEMENT-1 (Assertion) and
STATEMENT – 2 (Reason). Each question has 4 choices (a), (b), (c) and (d) out of which ONLY ONE is
correct.

2py 
2

MO configuration of CO is 1s ,  1s , 2s ,  2s , 2p , 
2 * 2 2 * 2 2
7. STATEMENT 1:  x
2pz 

2

Because
+
STATEMENT 2: bond length of CO is more than CO .
(a) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(b) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True.
2
8. STATEMENT 1: In the reaction : As2S3  HNO3  H2O  H3 AsO4  H2SO4  NO

If X equivalents of HNO3 are reacted then X equivalents of H3AsO4 and X
equivalents of H2SO4 are formed.
Because
STATEMENT 2: In a simple redox reaction number of equivalents of compounds participating in redox
on both sides of reaction are same.
9. STATEMENT 1 : Root mean square speed(vrms) of CH4contained in 10 litre container with 10 atm
pressure is more than that of CH4contained in 2 litre container with 2 atm pressure
both at same temperature 400 K.
Because
3PV
STATEMENT 2: for one mole of gas root mean square speed (vrms) is given by
M
(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions have to be answered.
Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Question no. 10 to 12
The process of eudiometry is used to calculate the volume of the various reacting gases present together in a
closed vessel, it is done by sparking the content and noting the volume change or pressure change depending
upon the conditions mentioned.
 a
The Vander Waal’s equation for 1 mole real gas is P  2  (v  b)  RT . The Virial equation for 1 mole real
 v 
PV x y z
gas is Z   1   2  3  ...... to higher power of n where x, y and z are constants which are known
RT V V V
as second, third and fourth Virial coefficients respectively. x and y are related with a and b as
a
x b andy  b2
RT
Critical temperature (Tc )is the maximum temperature at which a real gas can be liquefied and above this
temperature gas cannot be liquefied.
10. A 2.0 mole mixture of H2(g), O2(g) and He(g) are placed together in a closed container at pressure equal to 50
atm. An electric spark is passed and pressure is noted as 12.5 atm after cooling the content to original temp.
(Room temp). Oxygen gas is introduced for pressure to change to 25 atm, keeping volume and temp
constant. Again electrical spark is passed and pressure drops to 10 atm under original temperature
conditions. The moles of He(g) present in the mixture sample is
(a) 0.2 (b) 0.1 (c) 0.5 (d) 1.4

-2 2
11. The third virial coefficient of He gas is 9 × 10 (L/mol) then what will be volume of 3 mole of He gas at STP.
(a) 66.3 (b) 67.2 (c) 68.1 (d) 22.4
12.
For two gases A and B, P v/s V isotherms are drawn at T K as
shown. TA& TB are critical temperatures of A & B respectively.
Which of following is true?
(A) TA< T < TB (B) TA> T > TB

(C) TA >TB> T (D) T > TA> TB
2

o A titration is a technique where a solution of known concentration is used to determine the concentration of an
unknown solution.
o Back Titration:Determining the concentration of an analyte by reacting it with a known number of moles of
excess reagent. The excess reagent is then titrated with a second reagent. The concentration of the analyte in
the original solution is then related to the amount ofreagent consumed.
o Oleum can be described by the formula H2SO4.xSO3 where x is now defined as the molar free sulfur trioxide
content. Oleum is generally assayed according to the free SO 3 content by weight. It can also be expressed as a
percentage of sulfuric acid strength; for oleum concentrations, that would be over 100%.
13. Stone found in Idgah-Hills at Bhopal contains CrI3 a black solid that is used to prepare other chromium
compounds. A sample of CrI3is treated with excess of Cl2 in basic medium. Produced periodate is treated with
KI in acidic medium to produce I2. Which is then titrated with HYPO solution in strong basic medium.
Reactions involved are:
CrI3  KOH  Cl2 
 K 2Cr2O7  KIO4  KCl  H2O
KIO4  KI  H2SO4 I2  K 2SO4  H2O
I2  Na2S2O3  NaOH NaI  Na2SO4  H2O
If for titration 1.5 milimol of HYPO is used then the milimol of CrI3 present in sample is:
4 1
(a) 1.5 milimol (b) 0.5 milimol (c) milimol (d) milimol
9 18
14. 50 gm of sample of Ca(OH)2 is dissolved in 50 ml of 0.5 N HCl solution. The excess of HCl was titrated with
0.25 N – NaOH. The volume of NaOH used was 20cc. Calculate % purity of Ca(OH) 2.
(a) 14.06% (b) 2.96% (c) 1.48% (d) 1.85%
15. 5 gm of oleum (fuming H2SO4) is diluted with water. The solution requires 533.16 ml of 0.1 M Ba(OH)2 solution
for complete neutralization. Incorrect option in the following is:
(a) Oleum strength is 104.5%
(b) percentage of free SO3 in the sample of oleum is 20%
(c) Same solution will require 533.16 ml of 0.2 M of NaOH solution for complete neutralization
(d) 8 gm of NaOH is required to complete reaction with5 gm of given oleum
PART - B
Matrix-Match Type
This section contains 2 questions. Each question contains statements given in two columns which have to be
matched. Statements (a, b, c, d) in Column I have to be matched with statements (p, q, r, s) in Column II.
The answer to these questions have to be appropriately bubbled as illustrated in the following example.If the
correct matches are a-p, a-s, b-q, b-r, c-p, c-q and d-s, then the correctly bubbled 4 × 4 matrix should be as
follows :
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
Match the conditions/expressions in Column I with statements in Column II and indicate your answer by
darkening the appropriate bubbles in the 4 × 4 matrix given in OMR
1. Match the compounds mentioned in Column – I with their properties mentioned in Column – II
Column – I Column – IColumn – II
2
(A) P(CF3)2(CH3)3 (P) contains SP hybrid non terminal atom
At least 2 H atoms and 2 F atoms lie in same
(B) P(CF3)3(CH3)2 (Q)
vertical plane
(C) SOF2(CH3)2 (R) Polar molecule
(D) CH2SF4 (S) Contains  - bond
2
3
(T) Contains SP hybrid non terminal atom
2.
Column – I Column – II
(A) B2(if 2s, 2p mixing is not allowed) (P) Paramagnetic
(B) N2 (Q) Diamagnetic
(C) O2 (R) Stability more than O2 (thermodynamic stability)
(D) C2(if 2s, 2p mixing is not allowed) (S) Bond order < 2
(T) Contain two  bonds
2
S
SEEC
CTTIIO
ONN–– 2
2:: M
MAAT
THHS
S
PART – A
sin 2 y 1  cos y sin y

1 The value of the expression1 – + – is equal to
1  cos y sin y 1  cos y
(A) 0 (B) 1 (C) sin y (D) cos y
2 3 4 8  8 
2 Let x1 = 97, x2 = , x3 = , x4 = , ……., x8 = then log3   x i  60 =
2  
x1 x2 x3 x7  i 1 
3 5
(A) (B) 4 (C) 6 (D)
2 2
3. In the ABC, the coordinates of B are (0, 0) AB = 2, ABC = /3 and the middle point of BC has the
coordinates (2, 0). The centroid of the triangle is –
1 3 5 1   4  3 1
(A)  ,  (B)  ,  (C)  , 
(D) none of these
2 2 
  3 3  3 3
4. The straight line y = x – 2 rotates about a point where it cuts x-axis and becomes perpendicular on the straight
line ax + by + c = 0 then its equation is -
(A) ax + by + 2a = 0 (B) ay – bx + 2b = 0 (C) ax + by + 2b = 0 (D) none of these
2 2
5. C has two values C1 and C2 for which y = 2x + C touches a circle x + y – 4x –4y – 5 = 0 then
C1 + C2 is equal to-
(A) 2 65 (B) 4 (C) – 4 (D) – 2 65
2 2
6. For the circle x + y – 2x – 6y + 1 = 0 the chord of minimum length and passing through (1, 2) is of length-
(A) 2 2 (B) 4 2 (C) 6 2 (D) 8 2
PART – A
correct.
7. Assertion (A) : If a line L = 0 is tangent to the circle S = 0, then it will also be a tangent to the circle
S + L = 0.
Reason (R) : If a line touches a circle, then perpendicular distance of the line from the centre of the circle is
equal to the radius of the circle.
8. Assertion (A) : Each point on the line y – x + 12 = 0 is at same distance from the lines 3x + 4y – 12 = 0 and
4x + 3y – 12 = 0.
Reason (R) : Locus of points which is at equal distance from the two given lines is the angle bisectors of the
two lines.
2
9. Assertion (A) :The equation(log x)2 – log x3 + 2 = 0 has only one solution.
Reason (R) : log x2 = 2 log x if x > 0.
(Paragraph Type)

2 2
A line 2x + y = 3 intersects circle x + y – 4x – 6y + 4 = 0 at A and B. Tangents at A and B are drawn which
meets at P. M is the mid point of AB
On the basis of above passage, answer the following questions :
10. Length of chord AB is equal to-

29 29 2 29 29
(A) (B) 2 (C) (D)
5 5 5 5
11. Co-ordinate of M is-

 2 11  1 13  3 9
(A)  ,  (B)  ,  (C)  ,  (D) None of these
5 5  5 5  5 5
12. Equation of circum circle of triangle PAB is-
2 2 2 2
(A) 4x + 4y + 4x – 15y – 11 = 0 (B) 4x + 4y + 2x – 15y – 11 = 0
2 2 2 2
(C) 4x + 4y – 2x – 15y – 11 = 0 (D) 4x + 4y – 4x – 15y – 11 = 0

Let B1 3x + 4y – 10 = 0 and B2 4x – 3y – 5 = 0 are the bisectors of angle between lines L1 = 0and L2 = 0. If L1
2
passes through origin and L2 = 0 meets the curve y = 4ax at A and B and P is the point of intersection of L 1 = 0
and L2 = 0 then
On the basis of above passage, answer the following questions :
13. Equation of line L2 = 0 is-

(A) 11x + 2y = 24 (B) 11x – 2y = 20 (C) 5x + 3y = 13 (D) None of these
14. If AB subtends 90º angle at origin, then a is equal to-

4 3 5
(A) (B) (C) (D) None of these
11 11 11
15. Co-ordinates of point P is
(A) (1, 2) (B) (2, 1) (C) (4 , 2) (D) (2, 4)
PART - B
Matrix-Match Type
The answer to these questions have to be appropriately bubbled as illustrated in the following example.If the
correct matches are a-p, a-s, b-q, b-r, c-p, c-q and d-s, then the correctly bubbled 4 × 4 matrix should be as
follows :
2
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
1. Column-1 Column-2
(A) Number of common tangents of (P) 1
2 2
the circles x + y – 2x = 0 and
2 2
x + y + 6x – 6y + 2 = 0 is
(B) Number of indirect common (Q) 2
tangents of the circles
2 2
x + y –10y – 4x + 4 = 0
2 2
& x + y – 6x – 12y –55 = 0 is
(C) Number of common tangents of (R) 3
2 2
the circles x + y – 2x – 4y = 0
2 2
& x + y – 8y – 4 =0 is
(D) Number of direct common tangents (S) 0
2 2
of the circles x +y +2x–8y + 13 = 0
2 2
& x + y – 6x – 2y + 6 = 0 is
2. The equation of the line through the intersection of the line 2x – 3y = 0 and 4x – 5y = 2 and
Column-I Column-II
(A) Through the point (2, 1) (P) 2x – y = 4
(B)  to line x+ 2y + 1 = 0 (Q) x + y– 5 = 0,x – y – 1 = 0
(C) || to line3x – 4y + 5 = 0 (R) x – y – 1 = 0
(D) Equally inclined to axes (S) 3x – 4y – 1 = 0
2
S
SEEC
CTTIIO
ONN–– 3
3:: P
PHHY
YSSIIC
CSS
PART – A
th
1. For the given figure find power of friction force at 4
second.
(a) 0 watt (b) 100 watt (c) 50 watt (d) 25 watt

 
2. Magnitude of component of A  4iˆ  2jˆ  kˆ along B  2iˆ  ˆj  2kˆ is
3 4 5 2
(a) (b) (c) (d)
4 3 3 3
3. Velocity as a function of position is given as v = 2x. Find v at t = 2 sec if it is given that x = 2 at t = 0

4 4
(a) 4e (b) 2 Ln 4 (c) 6 m/s (d) 2e
4. Acceleration position graph of given velocity position

graph can be given as
(a) (b) (c) (d)
5. A stone falls freely from rest and total distance covered by it in last second of its motion equals the distance
covered by it in the first three seconds of its motion. Then stone remained in air for
(a) 6 Sec (b) 5 sec (c) 7 sec (d) 4 sec
6. Distance travelled by block until its velocity becomes 0 for

st
1 time is
(a) 4m (b) 5m
(c) 6m (d) 3 m
PART – A
correct.
7. STATEMENT 1 : If the sum of two unit vector’s is a unit vector then there difference is also a unit
vector.
Because
STATEMENT 2 : To find resultant of two vectors we use triangle law of vector addition.
(e) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(f) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for Statement-1
(g) Statement-1 is True, Statement-2 is False
(h) Statement-1 is False, Statement-2 is True.
2
8. STATEMENT 1 : Work done by gravitational force in bringing a body from the top to the bottom of a
smooth inclined plane is same as in bringing it from identically but rough inclined
plane.
Because
STATEMENT 2 : Work done by conservative force is path independent
(i) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(j) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for Statement-1
(k) Statement-1 is True, Statement-2 is False
(l) Statement-1 is False, Statement-2 is True.
9. STATEMENT 1 : A body can not have mechanical energy without having momentum.
Because
STATEMENT 2 : Kinetic energy E and momentum P are related as P  2mE
(Paragraph Type)
A point mass m suspended about O by a string of length  is given

v  8 m/ s at its lowest position. It can move in vertical plane. Now answer
2
the following questions. [take g = 10 m/s , l = 20 cm]
10. Tension in the string when point mass is at P is

35 25 37
(a) 20 N (b) N (c) N (d) N
2 2 2
11. Height above point of suspension O where tension becomes zero is

40 28 35
(a) cm (b) 10 cm (c) cm (d) cm
3 3 3
12. Maximum height above point O where point mass can reach is ?
420 200 220 460
(a) cm (b) cm (c) cm (d) cm
23 11 13 27
From above figure answer following questions.(All surfaces are smooth)
13. Normal reaction between A & B is

(a) 60 N (b) 100 N (c) 80 N (d) 120 N
2
Ai TS – 2 ( XI ) | SET – A | APT – 2 | P a g e | 10
14. Normal reaction between B and C is

(a) 60 N (b) 100 N (c) 80 N (d) 120 N
15. Distance travelled by C in 2 sec if it starts from rest is

(a) 6m (b) 12 m (c) 10 m (d) 8 m
PART - B
Matrix-Match Type
The answer to these questions have to be appropriately bubbled as illustrated in the following example.
If the correct matches are a-p, a-s, b-q, b-r, c-p, c-q and d-s, then the correctly bubbled 4 × 4 matrix should
be as follows :
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
1. The system shown in figure is in equilibrium. Then [x represent point from which spring is cut]
(a) Just after the spring 2 is cut block D (P) Acceleration up
(b) Just after spring 2 is cut block C (Q) Acceleration down
(c) Just after spring 2 is cut down block A (R) Acceleration is zero (momentry rest)
(d) Just after string connecting A and B is cut block D (S) Moves up with acceleration g
2. From the given figure Match Column-I with Column-II
(a) If F = 12N then (P) There is relative motion between A and B
(b) If F = 15N then (Q) There is relative motion between B and C
(c) If F = 25N then (R) There is motion of C
(d) If F = 40N then (S) There is no relative motion between any two surface in
contact

15-16 - Test 2

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ALL INDIA INTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS

Time Allotted : 3 Hours Maximum Marks: 201

B. Filling of OMR Sheet

C. Marking Scheme For All Parts.

Batch ID : Date of Examination : / / 2 0 1

3. Incorrect statement is…

8. STATEMENT 1: In the reaction : As2S3  HNO3  H2O  H3 AsO4  H2SO4  NO

(a) 0.2 (b) 0.1 (c) 0.5 (d) 1.4

(A) TA< T < TB (B) TA> T > TB

Paragraph for Question no. 13 to 15

(A) B2(if 2s, 2p mixing is not allowed) (P) Paramagnetic

(B) N2 (Q) Diamagnetic

(C) O2 (R) Stability more than O2 (thermodynamic stability)

(T) Contain two  bonds

sin 2 y 1  cos y sin y

Paragraph for Question no. 10 to 12

10. Length of chord AB is equal to-

11. Co-ordinate of M is-

Paragraph for Question no. 13 to 15

13. Equation of line L2 = 0 is-

14. If AB subtends 90º angle at origin, then a is equal to-

(B)  to line x+ 2y + 1 = 0 (Q) x + y– 5 = 0,x – y – 1 = 0

(C) || to line3x – 4y + 5 = 0 (R) x – y – 1 = 0

(D) Equally inclined to axes (S) 3x – 4y – 1 = 0

(a) 0 watt (b) 100 watt (c) 50 watt (d) 25 watt

3. Velocity as a function of position is given as v = 2x. Find v at t = 2 sec if it is given that x = 2 at t = 0

4. Acceleration position graph of given velocity position

(a) (b) (c) (d)

6. Distance travelled by block until its velocity becomes 0 for

Paragraph for Question no. 10 to 12

A point mass m suspended about O by a string of length  is given

10. Tension in the string when point mass is at P is

11. Height above point of suspension O where tension becomes zero is

Paragraph for Question no. 13 to 15

From above figure answer following questions.(All surfaces are smooth)

13. Normal reaction between A & B is

14. Normal reaction between B and C is

15. Distance travelled by C in 2 sec if it starts from rest is

2. From the given figure Match Column-I with Column-II

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