Documente Academic
Documente Profesional
Documente Cultură
Edition: 2012-01
CONTENT
n Plants worldwide
06 Keltan® Global Grade Portfolio / characteristics
07 Keltan® Global Grade Portfolio / packaging 17 4 production locations
LANXESS is a leading specialty chemicals company with sales of EUR 7.1 LANXESS is a major global supplier of Ethylene-Propylene Rubbers with
billion in 2010 and currently around 15,800 employees in 30 countries. The over 45 years of production, sales, technical, research & development, and
company is at present represented with 46 production sites worldwide. The marketing experience.
core business of LANXESS is the development, manufacturing and marke- The business Unit TRP - Technical Rubber Products - offers all EP(D)M grades
ting of plastics, rubber, intermediates and specialty chemicals. LANXESS is under the brand name Keltan®.
a member of the leading sustainable indices Dow Jones Sustainability Index
(DJSI) World and FTSE4Good. We know our customer requirements:
n consistent quality
Our global LANXESS website: www.lanxess.com n supply reliability
n expert technical support
LANXESS has a streamlined organizational structure to make it flexible and n broad product portfolio
dynamic. Our structure and business activities are geared to market needs, n global production and sales presence
ensuring that we have the speed and flexibility to continue offering customers n state-of-art laboratory equipment
top-quality products supported by excellent service. n continous product innovation
n standard industry bale size
n pelletized grades
and we strive to deliver accordingly.
For further information, please contact our local experts. You find their
addresses at the end of this brochure.
For information on applications, please contact the Health, Safety, Environ-
ment and Quality Department of LANXESS Germany or, for business in the
USA, the LANXESS Product Safety and Regulatory Affairs Department in
Pittsburgh, PA at 1-800-LANXESS.
Please note:
The information contained in this publication is current as of January,
2012. Please contact www.keltan.com or LANXESS Elastomers B.V., The
Netherlands or LANXESS Corporation to determine if this publication has
been revised.
Page 3 of 20: This document contains important information and must be read in its entirety. 3
THE VERSATILE ELASTOMER
Overall product description The properties of the raw rubber and the corresponding vulcanizates are
directly influenced by the rubber polymer structure:
The general term ethylene-propylene rubber refers to two different kinds of n molecular weight
polymers: n molecular weight distribution
n EPM represents a copolymer from ethylene and propylene monomers; n composition
EPM is entirely saturated and normally vulcanized by means of organic n crystallinity
peroxides. Sometimes also radiation cure is applied. n distribution of monomer units within a chain
n EPDM denotes a terpolymer based on three monomers: ethylene, n the extent of long-chain branching
propylene and a non-conjugated diene; EPDM grades have a residual
unsaturation in the side chains and can therefore be cured with sulfur These properties are directly related to the polymerization conditions and
and accelerators. Its aging resistance is distinctly better than that of catalyst system used in the EP rubber manufacturing process. By varying the
Natural Rubber, SBR and Butadiene Rubber. reaction parameters, one can obtain a wide range of properties, suitable for a
large number of applications. The production of a broad range of high quality
The molecules of both EPM and EPDM have a completely saturated hydro- synthetic rubber grades of this type is made possible by a thorough under-
carbon backbone, through which excellent ozone resistance and very good standing of the relationship between the process variables and the resulting
resistance to aging and weathering are achieved. product properties.
Key properties of ethylene-propylene elastomers: Main criteria for the design of EP(D)M rubbers are:
n The lowest density (0.86 g/cm3) of all the n Mooney viscosity
commercially available rubbers n Ethylene/propylene ratio
n Very good resistance to heat and oxidation n Diene content
n Very good resistance to ozone and weathering n Oil content and oil type
n Good chemical resistance
n Good low temperature flexibility (depending on ethylene content)
n Good electrical insulation properties
n Good vulcanizate physical properties (stress-strain behavior,
compression set)
n Can be molded, extruded, or calendered
n Fast and efficient mixing with additives
n Ability to accept higher filler loadings than other elastomers
n An example of the wide range of successful applications: LANXESS EP(D)M helps that modern constructions do not only look spectacular, but remain
permanently operational. Thanks to excellent ozone and weather resistance.
4 Page 4 of 20: This document contains important information and must be read in its entirety.
Structure of EP(D)M
EP(D)M
ENB unit
Keltan® copolymers are produced by copolymerization of ethylene and To produce a sulfur-curable rubber, a non-conjugated diene is introduced as
propylene. the third monomer during polymerization. Appropriate third monomers con-
tain one double bond which takes part in the polymerization and one which
Distribution of the co-monomer propylene can vary from random to alterna- does not. This results in pendant unsaturation which serves as crosslinking
ting. The function of propylene is to disrupt long sequences of ethylene and sites without affecting the saturated main chain. Terpolymers from LANXESS
prevent them from crystallizing. use ethylidene norbornene (ENB) or dicyclopentadiene (DCPD) as the third
n At high propylene levels (above 50 percent), only short ethylene monomer.
sequences exist in the polymer chain so crystallinity is absent
n At low propylene levels (e.g. below 40 percent), a small amount
of crystallinity is present which provides the EPM with green strength
Peroxide curing of EPM is more efficient at high ethylene content due to‚
reduced chain scission which occurs at the tertiary carbon atoms of the
propylene units.
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Product range and packaging
6 Page 6 of 20: This document contains important information and must be read in its entirety.
Keltan® Global Grade Portfolio
Wrapping foil Bale Box
New grade name Former grade name type color thickness weight form number weight supported material
microns kg of bales kg packaging
Suffix
C = ACETM grade
Q = Slurry grade
D = DCPD grade
L = Low Mooney
P = Pellets
R = Reactive Extrusion
Page 7 of 20: This document contains important information and must be read in its entirety. 7
NOMENCLATURE
Keltan® 5469Q
Ethylene content Suffix
weight % C = ACETM grade
5 = ≤ 55 Oil content parts Q = Slurry grade
6 = 56 - 65 hundred rubber D = DCPD grade
7 = ≥ 66 9 = 90 - 100 L = Low Mooney
P = Pellets
Keltan® 2708R is the first grade of a new product line of functionalized Some of the main application areas of Keltan® 2708R:
EP(P)M grades. The product is grafted with maleic anhydride by a so called n impact modifier for engineering plastics such as polyamide
reactive extrusion process (REX). Keltan® 2708R is available as free flowing (eg PA6, PA66)
pellets, delivered in 1000 kg big bags. n compatibilizer for wood-plastic composites
n compatibilizer for fiber reinforcement in EP(D)M compounds,
like for industrial and coolant hoses
Remark:
Grades with the suffix R, Keltan® 0500R and Keltan® 1500R are downsheared grades. (R stands for reactive extrusion.) Keltan® 2708R is the first product that
contains MAH (maleic anhydride): The last two digits of the nomenclature indicate the MAH grafting level (08=0.8 wt. %).
8 Page 8 of 20: This document contains important information and must be read in its entirety.
Grades positioning
5531A
T5459 4551A
G5567
T6465
7341A
viscosity
G5455 6251A
↑Oil extended 6531A
G3963
100 –
–
T9650
Mooney
– 8642A 8340A
G8450
–
4703
740 G6850
–
Polymer
G6170P T6470
T6250 G6470P/5508
50 –
G5440
–
T3950
– 3200A G3440 G3850
G2070P G2470 2340A
– PA1305 G2470LM
1200A
–
RED = Former grade name Keltan® BLACK = Former grade name Buna® EP
5469
5469Q
4869
4577
5465Q
4455 7752
viscosity
6471 6951
↑Oil extended 3973
100 –
–
9650Q
Mooney
8550
– 8570
7450
–
6160D 6950
– 5470Q 6750
Polymer
5170P
5260Q 5470P/5470
50 –
4450
–
3960Q
– 3050 2450 2750
2070P 2470 2650
– 1500R 2470L
0500R
–
Page 9 of 20: This document contains important information and must be read in its entirety. 9
Sustainable EP(D)M
10 Page 10 of 20: This document contains important information and must be read in its entirety.
World premiere: Bio based EP(D)M - Keltan® Eco LANXESS TRP has done this to test firstly the market’s response to the
need for bio-polymers and secondly to pioneer the reduction in fossil fuel
Keltan® Eco is the worlds first commercial EP(D)M that has been produced dependence. From a process point of view we have also crossed the
using an organically derived feedstock. The ethylene used in this process is threshold of proving that this translation from fossil to bio-sourced is feasible
derived from ethanol produced from sugar cane. As a consequence of the and achievable.
source and process substantial reduction in the amount of CO2 generated is
possible. This product delivers the benefits of regular EP(D)M in addition to it As of October 2011our production of Keltan® Eco is a fact.
being a unique bio-based Elastomer.
Sugarcane
100% 50-70% 15-20%
organic organic organic
Ethanol
Ethylene
EP(D)M
0% 0%
organic organic
Crude oil
Raw materials End products
Page 11 of 20: This document contains important information and must be read in its entirety. 11
Tailored solutions
This is by far the largest application segment, ranging from solid and sponge Since the 1980s, EP(D)M has shown a spectacular growth pattern in the
automotive body sealing to „under the hood“ applications like coolant hoses, field of single ply roofing sheets, particularly in the USA. The use of a thin
airco hoses, brake parts, belts or engine mounts and some others like wind- flexible membrane to replace traditional asphalt materials represents a con-
shield wipers. siderable technological advance, and improves long term performance. Due
to their superior water, ozone and weathering resistance, such membranes
The majority of the extruded profiles are made by pressure-less continuous have proven longevity, and are endorsed by a track record over 35 years.
cure. For these products the emphasis is on requirements such as low com-
pression set and good retention of heat-aged physical properties. Based on Since vulcanization for building profiles takes place in pressureless contin-
the need for higher end product reliability and extended service life, there is a uous curing equipment, high molecular weight EP(D)M provides good
growing demand for better surface finish. collapse or distortion resistance during the curing step. Glazing gaskets and
building profiles must retain high elastic sealing forces over a wide tempe-
The product should be free from porosity, fast curing, and should adhere well rature range. To withstand strong wind forces, low compression set require-
to textile flock and metal. High modulus is required for optimum sealing force, ments need to be met.
to prevent leakage through window surrounds and to minimize wind noise
from window seals. Other typical applications include tunnel seals, expansion joints, solar panel
tubing, sound insulation wall panels, bridge bearing pads, railway paths,
The growing demand for nitrosamine-free compounding prompted the artificial grass, sports granulate and rubber tiles for playgrounds.
need for faster curing EP(D)M types that should allow the formulation of cure
systems which are free from bloom and iridescence.
n In effect effectively and efficiently for the installation: coated pipe systems
n Keltan® meets the highest requirements. E.g. for hose assemblies for air n Keltan® for future technologies, e.g. pre-insulated pipes2 in solar systems
conditioners1
1
Foto: Conti 2
Foto: Duosolar by Armacell
12 Page 12 of 20: This document contains important information and must be read in its entirety.
Plastics modification
Special EPM grafted with maleic anhydride products are being used for the
impact modification of Engineered Plastics, such as PA6 and PA66.
Page 13 of 20: This document contains important information and must be read in its entirety. 13
Tailored solutions
Due to the great application versatility of Keltan® EP(D)M grades, a broad Keltan® EP(D)M grades can be especially used in the following wire & cable
spectrum of diverse requirements can be met. The below mentions only a few industry applications:
technical goods applications
n low and medium voltage cables and
n washing machine gaskets (bull-eyes) n transmission and distribution, like
n potable & waste water seals n connectors
n valve and tank linings n arrestors
n roll coverings n relays
n hoses and tubes
n conveyors belts
n floor tiles
n windmill applications, like seals, cables, hoses
14 Page 14 of 20: This document contains important information and must be read in its entirety.
n Offset printing unit: different rolls with different coverings1
1
3-D-Object: Westland Gummiwerke
Page 15 of 20: This document contains important information and must be read in its entirety. 15
The versatility of our Keltan®
elastomer, high product quality,
high supply reliability and high
service level - this unique com-
bination enables high performance
for our customers, products and
industrial solutions.
PLANTS WORLDWIDE
Page 17 of 20: This document contains important information and must be read in its entirety. 17
IMPORTANT NOTES
As with any product, use of the products mentioned in this publication Regulatory compliance information
in a given application must be tested (including field testing, etc.) by user in Some of the end uses of the products described in this publication must
advance to determine suitability. comply with applicable regulations, such as the FDA, BfR, NSF, USDA, and
CPSC. If you have any questions on the regulatory status of these products,
Product safety contact your LANXESS Corporation representative, the LANXESS Regu-
Relevant safety data and references as well as the possibly necessary warning latory Affairs Manager in Pittsburgh, PA or the Health, Safety, Environment
labels are to be found in the corresponding safety data sheets. and Quality Department (HSEQ) of LANXESS Germany.
Health and safety information The manner in which you use and the purpose to which you put and utilize
Appropriate literature has been assembled which provides information our products, technical assistance and information (whether verbal, written
concerning the health and safety precautions that must be observed when or by way of production evaluations), including any suggested formulations
handling the LANXESS products mentioned in this publication. For materials and recommendations, are beyond our control. Therefore, it is imperative
mentioned which are not LANXESS products, appropriate industrial hygiene that you test our products, technical assistance and information to deter-
and other safety precautions recommended by their manufacturers should mine to your own satisfaction whether they are suitable for your intended
be followed. Before working with any of these products, you must read and uses and applications. This application-specific analysis must at least include
become familiar with the available information on their hazards, proper use testing to determine suitability from a technical as well as health, safety, and
and handling. This cannot be overemphasized. Information is available in environmental standpoint. Such testing has not necessarily been done
several forms, e.g., material safety data sheets and product labels. Consult by us. Unless we otherwise agree in writing, all products are sold strictly
your LANXESS representative in Germany or contact the Health, Safety, En- pursuant to the terms of our standard conditions of sale. All information and
vironment and Quality Department (HSEQ) of LANXESS Germany or - for technical assistance is given without warranty or guarantee and is subject
business in the USA - the LANXESS Product Safety and Regulatory Affairs to change without notice. It is expressly understood and agreed that you
Department in Pittsburgh, PA. assume and hereby expressly release us from all liability, in tort, contract
or otherwise, incurred in connection with the use of our products, technical
assistance, and information.
Any statement or recommendation not contained herein is unauthorized and
shall not bind us. Nothing herein shall be construed as a recommendation to
use any product in conflict with patents covering any material or its use. No
license is implied or in fact granted under the claims of any patent.
Forward-looking statements
This product information contains forward-looking statements based on cur-
rent assumptions and forecasts made by the LANXESS AG management.
Various known and unknown risks, uncertainties and other factors could
lead to material differences between the actual future consolidated results,
financial situation, development or performance of the company, and the
estimates given here. The company assumes no liability to update such
forward-looking statements or to adapt to future events or development.
18 Page 18 of 20: This document contains important information and must be read in its entirety.
Quality assurance Please direct any questions on Keltan® from LANXESS to one of the follow-
ing adresses, contact your regional sales office or visit our technical online-
Quality is a core value of LANXESS, founded on the global principles of system: www.keltan.com
quality management, product stewardship, and sustainable development.
All of our EP(D)M manufacturing sites worldwide, customer service opera- Sales offices worldwide: www.sales-offices-trp.lanxess.com
tions, and supply chain operations maintain quality systems registered to www.keltan.com
ISO 9001. www.trp.lanxess.com
NAFTA
Make use of our experience
LANXESS Corporation
111 RIDC Park West Drive
Talk to us! Whether it’s technical details or new product ideas you need, Pittsburgh, PA 15275 1112
our experts will be at your side from development right through to full-scale USA
E-mail: chia.chu@lanxess.com
production. From individual recipe recommendations to on-site advice. We
Phone: 001 (412) 809 4759
think of ourselves not just as suppliers, but as an active partner to our custo- www.keltan.com
mers. We’ve been providing this service throughout the world for over 90
LATAM
years. Make use of all this experience in research and practical applications LANXESS Ind. de Prod. Quimicos e Plásticos Ltda.
– get in touch today! Av. Maria Coelho de Aguiar, 215 - Bloco B - 2º andar
05804-902 - São Paulo - SP - Brasil
Marie Rose Damiani
1
”Responsible Care Management System” is an American standard which ensures that E-mail : marie-rose.damiani@lanxess.com
manufacturers have systems in place to ensure the health and safety of LANXESS em- Phone : +55 11 3741 5948
www.keltan.com
ployees, customers and surrounding communities.
Page 19 of 20: This document contains important information and must be read in its entirety. 19
EP(D)M ENERGIZED BY