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C. MELTING POINTS OF POLYMERS

In the following table of melting points, entries are
alphabetical according to the basic structure of the polymer,
ignoring substituents. Substituted polymers are listed
alphabetically (according to the substituent) under the
entry for the unsubstituted polymer. The molecular
weight is that of the chemical repeat (the constitutional
base unit) in the polymer. Melting points (in 0C) are taken
from the reference cited. Melting points are presented in
this table only for those polymers without (as yet) available
crystallographic data: an asterisk (*) in the reference
column signifies that the relevant melting point data is
contained within the "Crystallographic Data" table of
Section B.

Molecular Melting
Polymer weight point Refs.

Cellulose, see Poly (1,4-P-D-glucose) *

Poly(acetaldehyde)
-, 2,2,2-trichloro- *
Poly(acrylamide) 71.08
-, JV-docosyl- 379.67 68 1906
- , N-dodecyl- 239.40 -8 1906
- , N-hexadecyl- 295.51 45 1906
- , N-isopropyl- *
- , W-octadecyl- 323.56 68 1906
- , N-tetradecyl- 267.46 18 1906
Poly(acrylic acid) 72.06
- , allyl ester *
-,butyl ester 128.17 47 401
- , sec-butyl ester *
-, tert-butyl ester *
- , decyl ester 212.33
-, - 1,1-dihydroperfluoro- 554.15 100 1898
-, docosyl ester 380.66 72 1906
-, dodecyl ester 240.39 12 1906
-, hexadecyl ester 296.50 43 1906
-, isobutyl ester *
- , isopropyl ester *
- , octadecyl ester 324.55 56 1906
- , octyl ester 184.28
- , - , 1,1-dihydroperfluoro- 454.14 35 1898
- , tetradecyl ester 268.44 32 1906
Poly(acrylonitrile) *
- , a-ethyl- 81.12 200 436
- , a-isopropyl- 95.14 310 436
- , a-propyl- 95.14 210 436
Poly(2,2/-adipamidodibenzoic isophthalic anhydride) 514.49 225 1871
Poly (4,4'-adipamidodibenzoic isophthalic anhydride) 514.49 273 1871
Poly(2,2/-adipamidodibenzoic terephthalic anhydride) 514.49 235 1871
Poly(4,4/-adipamidodibenzoic terephthalic anhydride) 514.49 285 1871
Poly(adipic anhydride) 128.13 85 1840
98 1841
77 1564
Poly(adipoyl dithionisophthaloyldihydrazide) 336.43 280 1889
Poly(adipoyl ethylenediurea) 256.26 241 402
Poly(adipoyl octamethylenediurea) 340.42 290 402
Poly(adipoyl pentamethylenediurea) 298.34 222 402
Poly((3-alanine), see poly(3-aminopropionic acid) *
Poly(allene) *
- , tetrafluoro- *
Poly(allylbenzene), see Poly(propene), 3-phenyl- *
Poly(2-aminoacetic acid), see Poly(glycine) *
Poly(m-aminobenzoic acid) 119.12 425 735
Poly(p-aminobenzoic acid) *
Poly(3-aminobutyric acid) *
Poly(4-aminobutyric acid) *
PoIy(10-aminocapric acid) *
Poly(6-aminocaproic acid) [caprolactam] *
- , D-(-)-3-methyl- *
- , 6-methyl- 127.19 185 402

References page VI-159

 Molecular Melting
Polymer weight point Refs.

Poly(6-aminocaproic acid-a/Ml-aminoundecanoic acid) *

Poly(8-aminocaprylic acid) *
Poly(3-aminocyclobutylene)-propionic acid) 125.17
- , 2,2-dimethyl- 153.22 358 1816
Poly(4-aminocyclohexyleneacetic acid) 139.20 400 402
Poly(aminodihexamethylene suberamide) 353.55 160 402
Poly(aminoditrimethylene oxamide 185.23
-, N-methyl 199.25 202 291
Poly(22-aminodocosanoic acid) 337.59 145 177
Poly(7-aminoenanthic acid) *
-, (/0-3-methyl-
-, (S)-4-methyl-
-, (/?)-5-methyl-
-, (/?)-6-methyl-
- , Af-methyl- 141.21 65 1828
Poly[p-(aminoethylene)-phenyleneacetic acid] 161.20 283 402
Poly[/?-(aminoethylene)-phenylenebutyric acid] 189.26 224 402
Poly[p-(aminoethylene)-phenylenepropionic acid] 175.23 382 402
Poly[p-(aminoethylene)-phenylenevaleric acid] 203.28 275 402
Poly(2-aminoethylenesulfonic acid) 107.13 275 1938
Poly(17-aminoheptadecanoic acid) 267.46 150 292
Poly(aminoformic acid) 43.02
- , N- butyl-
- , - , 2-methyl- 113.16 220 1909
- , N-phenyl- 119.12 275 528
Poly(/7-aminohydrocinnamic acid) 147.18 310 402
360 1911
PoIy(12-aminolauric acid) *
-,TV-methyl- 211.35 52 1929
Poly[(3-aminomethylene)-cyclohexyleneacetic acid] 153.22
- , 1,3-dimethyl- 181.28 297 1816
Poly[/7-(aminomethylene)-phenyleneacetic acid] 147.18 355 402
Poly[p-(aminomethylene)-phenylenebutyric acid] 175.23 267 402
Poly[p-(aminomethylene)-phenylenepropionic acid] 161.20 300 402
Poly[p-(aminomethylene)-phenylenevaleric acid] 189.26 233 402
Poly(6-amino-4-oxacaproic acid) 115.13
- , 3,5-dimethyl- 143.19 210 1902
Poly(5-amino-3-oxavaleric acid) 101.10 148 402
Poly(9-aminopelargonic acid) *
Poly(3-aminopropionic acid) [p-alanine] *
- , 2-butyl-2-methyl- *
- , 2,2-dimethyl
- , 2,3-dimethyl- 99.13
erythro 405 503
threo 355 503
- , 3,3-dimethyl- 99.13 296 503
- , 2-ethyl-2-methyl- *
- , N-isopropyl- 113.16 130 1869
- , Ar-methyl- 85.11 225 1863
202 1869
-, 3-methyl-, see Poly(3-aminobutyric acid) *
- , 2-methyl-2-propyl- *
- , N-phenyl- 147.18 205 1869
PoIy(18-aminostearic acid) *
Poly(2-aminotetrahydropyran-6-carboxylic acid) *
Poly(13-amino-ll-thiatridecanoic acid) 229.38 150 402
PoIy(13-amino-12-thiatridecanoic acid) 229.38 150 402
Poly(6-aminothiocaproic acid) 129.22 120 402
Poly(7-aminothioenanthic acid) 143.25 235 402
Poly(a-aminotoluic acid) 133.15 300 444
PoIy(13-aminotridecanoic acid) 211.35 183 177
Poly(3-aminotrimethylenesulfonic acid) 107.15 260 1932
PoIy(11-aminoundecanoic acid) *
-,tf-allyl- 223.36 350 402
-, /V-ethyl- 212.36 -30 402
 Molecular Melting
Polymer weight point Refs.

- , 2-methyl- 197.32 130 402

- , TV-methyl- 197.32 80 402
- , N-phenyl- 259.39 -30 402
- , iV-piperazinyl- 267.42 142 402
Poly(5-aminovaleric acid) *
Poly(L-aspartic acid) 115.09
- , oc-isobutyl ester *
Poly(azelaic anhydride) 170.21 54 1823
Poly(azelaoyl oxalodihydrazide) 270.29 260 402
Poly (benzaldehyde-a/f-dimethylketene) 176.22 290 1817
-,p-chloro- 210.66 260 1817
- , p-methoxy- 206.24 240 1817
- , m-nitro- 221.21 240 1817
Poly(benzylidenethiodecamethylene sulfide) 294.52 135 1923
Poly(benzylidenethiohexamethylene sulfide) 238.42 115 1923
-,p-methoxy- 268.44 130 1923
Poly(benzylvinyl ether) *
Poly(4,4'-biphenyldicarboxaldehyde) 210.23 250 1801
Poly(4,4/-biphenylene adipamide) 294.35 400 402
Poly(4,4/-biphenylene adipate) 296.32 300 1901
Poly(4,4'-biphenylene carbodiimine) 192.22 >300 1907
- , 3,3'-dimethoxy- 220.27 190 1907
Poly (4,4 '-biphenylene-4",4 "'-dibenzylidenimino adipate) 502.57
- , 3",3'"-dimethoxy- 562.62 220 1893
Poly(4,4'-biphenylene-4",4'''-dibenzylidenimino sebacate) 558.68
- , 3",3'"-dimethoxy 618.73 230 1893
Poly[4,4/-(4,4/-biphenylenedioxy)-diphenylene carbonate] 396.40 250 1915
Poly(4,4/-biphenylenedioxy 4,4'-diphenylene ketone) *
Poly(4,4'-biphenylene disiloxanylenedipropionamide) 370.56
- , tetramethyl- (Si) 426.66 300 402
Poly [4,4 '-(2,2 '-2,2 /-biphenylenedithiazole)-oxy-/?-phenylene] 486.61 240 1810
Poly [4,4 '-(2,2 '-2,2 '-biphenylenedithiazole)-/?-phenylene] 394.51 250 1810
Poly(4,4/-biphenylene dithiolisophthalate) 348.44 340 1922
Poly(4,4/-biphenylene dithiolterephthalate) 348.44 >460 1922
Poly (4,4 '-biphenylenegermylene) 224.79 295 1777
Poly(biphenylene 3,3/,4,4/-oxydiphenylenetetracarboximide) *
Poly (4,4'-biphenylene pyromellitimide) *
Poly(4,4'-biphenylene sebacamide) 350.46 435 402
Poly(4,4 '-biphenylene terephthalamide) 314.34 500 402
- , 3,3'-dimethyl- 342.40 440 402
- , - , AW-diethyl- 398.51 254 1870
- , - , JV,AT'-diethyl- 370.45 316 1870
Poly(4,4'-biphenylene terephthalate) *
- , 2,2'-dipropyl- 400.47 350 1901
Poly[4,4'-biphenylene 4",4'"-(thiodiphenylene)-dioxy-3,3 ',4,4'-diphenylenetetracarboximide] 658.68 483 1771
PoIy(1,3-butadiene), 1,2- *
PoIy(1,3-butadiene), 1,4-
- , 2-tert-butyl *
- , 2-chloro- [chloroprene] *
- , 2,3-dimethyl-
- , 1-methoxy- 84.12
trans- 118 1803
- , 2-methyl- [isoprene] *
- , - , hydrochlorinated *
- , 2-methylacetoxy- *
- , 2-propyl- *
Poly( 1,3-butadiene( 1,4-)-a/Mnethacrylonitrile] 121.18
- , 1,1,4,4-tetradeutero- 125.22 75 1825
Poly[l,3-butadiene(l,4-)-a/Mnethyl methacrylate] 154.21 56 1849
Poly(butadiene oxide) 70.09 74 1809
Poly(butenamer) 54.09
I. 210 1864
II. 150 1864
PoIy(I-butene)
- , 4-cyclohexyl- 138.25 170 282
138 328
References page VI-159
 Molecular Melting
Polymer weight point Refs.

- , 4-n-tt-diisopropylamino- 155.28 315 191

- , 3,3-dimethyl- 84.16 260 282
- , 3-methyl-
- , 3-methyl- (1,3-via hydride shift) *
- , 3-phenyl- 132.21 360 90
- , 4-phenyl- *
- , 4-o-tolyl- 146.23 239 187
- , 4-/?-tolyl- 146.23 196 187
_, 4,4,4-trifluoro- 110.08 263 1813
- , 3-trifluoromethyl- 124.11 300 1813
- , 4-trimethylsilyl- *
Poly(2-butene-«/r-ethylene) *
Poly(2-butene 4-octenediamide) 222.29
trans-, trans- 301 657
Poly(2-butene oxide) *
-,2-methyl- 86.13 196 1879
Poly(2-butene sulfide) 88.17
cis- 156 548
trans- 192 548
Poly(2-butenylene hexamethylenediurethane) 256.30
cis- 136 402
trans- 111 402
Poly (4,4'-butylidenediphenylene carbonate) 268.31 170 438
Poly[4,4'-(2,2-butylidene)-diphenylene carbonate] 268.31 222 438
Poly(butylvinyl ether) *
- , 2-methyl-
Poly(sec-butylvinyl ether), see Poly(propylvinyl ether), methyl- *
Poly(te7t-butylvinyl ether) *
Poly(butyraldehyde) *
Poly(caprolactam), see Poly(6-aminocaproic acid) *
Poly(caprylaldehyde) 128.22 35 329
Poly(carbon monoxide-a/f-ethylene) [ketone] *

Poly[m-(carboxyphenoxy)-acetic anhydride] 178.14 134 1565

Poly[/7-(carboxyphenoxy)-acetic anhydride] 178.14
- , 3-bromo- 257.04 179 1565
Poly(chloroprene), see PoIy(1,3-butadiene), chloro- *
Poly(chlorotrifluoroethylene-tf/?-ethylene) *
Poly (1,3-cyclobutylene) 54.09
- , 1-cyano- *
Poly( 1,3-cyclobutylene carbonate) 114.10
- , 2,2,4,4-tetramethyl-
Poly( 1,3-cyclobutyleneoxymethylene oxide) 110.12
- , 2,2,4,4-tetramethyl-
PoIy (1,2-cycloheptylene-0//-ethylene) *
Poly (1,4-poly-1,3-cy clohexadiene) 80.13
trans- 380 221
Poly(cyclohexene oxide) 98.14 126 527
PoIy(1,3-cyclohexylene adipamide) 224.30
cw- 170 402
trans- 300 402
Poly(l,4-cyclohexylene adipamide) 224.30 400 402
PoIy(1,4-cyclohexylene adipate) *
PoIy(1,3-cyclohexylene azelamide) 266.38
cis- 125 402
trans- 300 402
PoIy(1,4-cyclohexylene 3,3/-dibenzamide) 320.39 390 402
PoIy(1,3-cyclohexylenedimethylene adipamide) *
PoIy(1,4-cyclohexylenedimethylene adipamide) 252.36
cis- 246 385
225 1878
trans- 345 385
342 1806
347 1878
PoIy(1,4-cyclohexylenedimethylene adipate) *
 Molecular Melting
Polymer weight point Refs.

PoIy(1,4-cyclohexylenedimethylene azelamide) 294.44

cis- 195 385
trans- 275 385
PoIy(1,4-cyclohexylenedimethylene azelate) 296.41
cis- 41 547
trans- 50 547
Poly( 1,4-cyclohexylenedimethylene
1,4-cyclohexylenedicarboxylate) 280.36
cis-, trans- 205 547
trans-, trans- 246 547
Poly(1,4-cyclohexylenedimethylene dithiol-1,4-cyclohexylenedicarboxylate) 312.49
trans-, trans- 310 1922
PoIy(1,4-cyclohexylenedimethylene dodecanediamide) 336.52
cis- 215 385
190 1878
trans- 278 385
280 1878
PoIy(1,4-cyclohexylenedimethylene dodecanedioate) 338.49
cis- 46 547
trans- 85 547
Poly[ 1,4-cyclohexylenedimethylene (ethylenedithio)-diethylenediurethane] 376.53
trans- 121 1897
Poly(1,4-cyclohexylenedimethylene glutaramide) 238.33
cis- 167 385
trans- 290 385
PoIy(1,4-cyclohexylenedimethylene glutarate) 240.30
trans- 50 547
Poly[ 1,4-cyclohexylenedimethylene (hexamethylenedithio)-diethylenediurethane] 432.64
trans- 124 1897
PoIy(1,4-cyclohexylenedimethylene isophthalamide) 272.35
trans- 310 385
Poly(1,4-cyclohexylenedimethylene isophthalate) 274.32
trans- 197 547
PoIy(1,4-cyclohexylenedimethylene 2,6-naphthalate) 324.38
cw- 287 547
trans- 341 547
Poly( 1,4-cyclohexylenedimethylene octamethylenediurethane) 340.46
trans- 160 402
160 291
PoIy(1,4-cyclohexylenedimethylene oxalate) 198.22
trans- 215 547
PoIy(1,4-cyclohexylenedimethylene)-oxymethylene oxide) 156.22
trans- 78 369
86 1945
Poly[l,4-cylohexylenedimethylene (pentamethylenedithio)-diethylenediurethane] 418.61
trans- 102 1897
PoIy(1,4-cyclohexylenedimethylene /?-phenylenediacetate) 302.37
CW- 55 547
Poly(1,4-cyclohexylenedimethylene pimelamide) 266.3 8
cis- 191 385
trans- 293 385
PoIy(1,4-cyclohexylenedimethylene pimelate) 268.35
trans- 42 547
Poly(1,4-cyclohexylenedimethylene sebacamide) 308.47
cis- 208 385
200 1878
trans- 300 385
296 1878
292 1769
Poly(1,4-cyclohexylenedimethylene sebacate) 310.43
cis- 50 547
trans- 78 547
PoIy(1,4-cyclohexylenedimethylene suberamide) 280.41
cis- 215 385
trans- 311 385

References page VI-159

 Molecular Melting
Polymer weight point Refs.

Poly(l,4-cyclohexylenedimethylene suberate) 282.38

cis- 50 547
trans- 96 547
PoIy(1,4-cyclohexylenedimethylene succinate) *
PoIy(1,4-cyclohexylenedimethylene terephthalate) *
Poly[ 1,4-cyclohexylenedimethylene (tetramethylenedithio)-diethylenediurethane] 404.58
trans- 129 1897
Poly[ 1,4-cyclohexylenedimethylene (trimethylenedithio)-diethylenediurethane] 390.56
trans- 105 1897
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene adipamide] 340.46 196 402
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4/-(ethylenedioxy)-dibenzamide] 496.60 250 402
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4'-(hexamethylenedioxy)-dibenzamide] 552.71 215 402
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene oxamide] 284.36 246 402
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4/-(oxydiethylenedioxy)-dibenzamide] 540.66 125 402
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene (/?-phenylenedioxy)-diacetamide] 420.51 160 402
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene terephthalamide 360.45 384 402
Poly[(l,4-cyclohexylenedioxy)-ditrimethylene 4,4/-(tetramethylenedioxy)-dibenzamide] 524.66 224 402
PoIy(1,4-cyclohexylene dithiolsuccinate) 230.35
trans- 302 1922
Poly[ 1,4-cyclohexylene (ethylenedithio)-diethylenediurethane] 348.48
trans- 214 1897
Poly[ 1,4-cyclohexylene (hexamethylenedithio)-diethylene-diurethane] 404.58
trans- 204 1897
PoIy(1,4-cyclohexylene 3,3'-methylenedibenzamide) 334.42 174 402
PoIy(1,4-cyclohexylene octamethylenediurethane) 312.41
trans- 255 633
255 402
221 291
Poly(l,4-cyclohexyleneoxymethylene oxide) 128.17
trans- 209 369
Poly[ 1,4-cyclohexylene (pentamethylenedithio)-diethylene-diurethane] 390.56
trans- 189 1897
Poly(l,3-cyclohexylene sebacamide) 280.41
cis- 120 402
trans- 290 402
PoIy(1,4-cyclohexylene sebacate) *
PoIy(1,4-cyclohexylene suberate) 254.33
trans- 181 1174
PoIy(1,2-cyclohexylene sulfide) 114.21 130 1917
PoIy(1,3-cyclohexylene sulfide) 114.21 139 1917
PoIy(1,2-cyclohexylene sulfone) 146.21 284 1917
Poly(l,3-cyclohexylene sulfone) 146.21 309 1917
Poly[ 1,4-cyclohexylene (tetramethylenedithio)-diethylene-diurethane] 376.53
trans- 214 1897
Poly[ 1,4-cyclohexylene (trimethylenedithio)-diethylene-diurethane] 362.50
trans- 202 1897
Poly(l,4-cylclohexylene urethane) 141.17 >355 444
Poly(cyclohexylidenedimethylene oxide) 126.20 152 1935
- , 3,4-dihydro- 124.18 102 1935
- , - , 4-methyl- 138.21 155 1935
- , 4-methyl- 140.23 165 1935
Poly(4,4/cyclohexylidenediphenylene carbonate) 294.35 260 438
- , 2,2'-dimethyl- 322.40 200 1915
- , 3,3/,5,5'-tetrachloro- 427.09 270 540
Poly(cyclohexylidenethiohexamethylene sulfide) 230.44 75 1923
PoIy(1,2-cyclopentylene-a/f-ethylene) *
PoIy(1,3-cyclopentylene-tf/Mnethylene) [1,5-hexadiene] *
Poly(4,4'-cyclopentylidenediphenylene carbonate) 280.32 250 438
Poly(cyclopropylene cyclopropylenedicarboxamide) 166.18 285 1865
Poly[cyclopropylene (cyclopropylenedicarboxoyl)-diurethane] 254.20
trans-, trans- 245 1865
Poly(cyclopropylenedimethylene cyclopropylenedicarboxamide) 194.23 220 1865
Poly(cyclopropylenedimethylene cyclopropylenediurethane) 226.23
cis- 175 1865
trans- 210 1865
 Molecular Melting
Polymer weight point Refs.

Poly(cyclopropylenedimethylene hexamethylenediurethane) 270.33

cis- 120 1860
trans- 165 1860
Poly(cyclopropylenedimethylene isophthalamide) 230.27 220 1865
Poly(cyclopropylenedimethylene isophthalate) 232.24 100 1860
Poly[cyclopropylenedimethylene 4,4 /-(methylenediphenylene)-diurethane] 352.39
cis- 230 1860
trans- 290 1860
Poly(cyclopropylenedimethylene piperazinediurethane) 240.26
cis- 70 1860
trans- 100 1860
Poly (cyclopropylenedimethylene sebacamide) 266.38 223 1865
Poly(cyclopropylenedimethylene terephthalate) 232.24 130 1860
Poly(cyclopropylenedimethylene toluylenediurethane) 276.29
cis- 170 1860
trans- 200 1860
Poly(cyclopropylene hexamethylenediurea) 240.31 180 1865
Poly(cyclopropylene isophthalamide) 202.21 250 1865
Poly(cyclopropylene piperazinediurea) 210.24 260 1865
Poly(cyclopropylene sebacamide) 238.33 220 1865
Poly(cyclopropylidenedimethylene oxide) 84.12 45 1935
Poly(decamethylene) 140.27
-, 1,2-dichloro- 209.16
trans- 47 1925
Poly(decamethylene adipamide) *
Poly(decamethylene adipate) *
- , 3-methyl-(diacid) 298.42 -2 1796
Poly[decamethylene WV-adipolyldi(6-aminocaproate)] 510.72 137 1792
Poly(decamethylene adipoyldiurethane) 370.45 164 402
Poly(decamethyleneaminohexamethylene amine) 254.46 102 1829
Poly(decamethylene azelamide) *
Poly(decamethylene azelate) *
Poly(decamethylene 4,4 '-biphenylenediurethane) 410.51
-, 3,3'-dimethyl- (diisocyanate) 438.57 219 633
Poly (decamethylene carbonate) 200.28 55 1820
Poly(decamethylene m-carboxycarbanilate) 319.40 127 1891
Poly(decamethylene p-carboxycarbanilate) 319.40 158 1891
Poly[decamethylene (decamethylenedisulfonyl)-dicaproamide] 634.98 207 402
Poly(decamethylene decamethylenediurethane) 398.59 145 291
142 634
Poly (decamethylene 2,2'-dibenzoate) 380.48 -3 1552
Poly(decamethylene 3,3'-dibenzoate) 380.48 90 1552
Poly(decamethylene 4,4'-dibenzoate) 380.48 132 1552
Poly[(decamethylenedioxy)-dihexamethylene oxide] 356.59 68 542
Poly[4,4'"-(4'A//-(decamethylenedioxy)-diphenylenedioxy)-diphenylene terephthalate] 672.78 242 1773
Poly[4,4/-(decamethylenedioxy)-diphenyleneoxy-p-xylylene oxide] 460.62 211 1789
Poly[3,3/-(decamethylenedioxy)-diphenylene terephthalate] 488.58 108 1773
Poly[4,4'-(decamethylenedioxy)-diphenylene terephthalate] 488.58 259 1773
- , dichloro-(diol) 557.47 160 1773
Poly(4,4/-decamethylenediphenylene carbonate) 352.47 110 1915
150 1174
Poly(4,4/-decamethylenedipiperazine sebacamide) *
Poly(decamethylene disiloxanylenedipropionamide) 358.63
- , tetramethyl- (silicone) 414.74 50 402
Poly (decamethylene disulfide) 204.39 45 1868
65 725
Poly(decamethylenedithioethylene disulfide) 296.56 80 1837
Poly(decamethylenedithiohexamethylene disulfide) 352.67 46 1784
Poly(decamethylene dithioladipate) 316.53 75 1922
Poly(decamethylene dithiolsebacate) 372.63 103 1922
Poly(decamethylene dithiolterephthalate) 336.52 201 1922
Poly(decamethylenedithiotetramethylene disulfide) 324.62 56 1837
58 1784
Poly(decamethylene docosanediamide) 506.86 169 454
Poly (decamethylene dodecamethylenediurea) 424.67 190 634

References page VI-159

 Molecular Melting
Polymer weight point Refs.

Poly(decamethylene phosphinylidenedipropionamide) 330.41

-, methyl- (P)
Poly(decamethylene phthalamide) 302.42 115 1868
Poly(decamethylene pimelate) 298.42 66 764
Poly(decamethylene dodecanediamide) 366.59 191 244
192 454
Poly[decamethylene ^,A^'-dodecanedioyldiQ^-aminobenzoate)] 606.80 171 1792
Poly(decamethylene eicosanediamide) 478.80 171 244
Poly[decamethylene 4,4/-(ethylenedioxy)-dibenzoate] 440.54 135 290
Poly[decamethylene 4,4/-(ethylenediphenylene)-dioxydiacetamide] 466.62 220 402
Poly(decamethylene WV-ethylenediterephthalamate) 494.59 277 781
Poly(decamethylene 4,4/-ethylidenedibenzamide) 406.57 150 402
Poly(decamethylene fumaramide) 252.36 50 402
- , 2,3-dimethyl- (diacid) 280.41
trans- 267 1931
-, methyl- (diacid) 266.38 166 1931
Poly(decamethylene 2,5-furandicarboxamide) 292.38 130 1905
Poly(decamethylene 2,5-furandipropionamide) 348.49 140 402
Poly(decamethylene glutaramide) 268.40
- , 3-carboxyl- (diacid) 312.41 70 402
Poly(decamethylene glutarate) *
Poly[decamethylene (hexamethylenedisulfonyl)-dicapromide] 578.87 218 402
Poly(decamethylene WV'-hexamethylenediterephthalamate) 550.70 235 781
Poly(decamethylene hexamethylenediurea) 340.51 210 402
216 634
Poly(decamethylene hexamethylenediurethane) *
Poly(decamethylene 3-hexenedioate) *
Poly(decamethylene isophthalamide) 302.42 186 1868
Poly(decamethylene isophthalate) 304.39 36 1794
Poly[decamethylene 4,4/-(isopropylidenediphenylene)-dioxy-diacetamide] 480.65 105 402
Poly(decamethylene malonamide) 240.35
-, dodecyl-(diacid) 408.67 123 1774
Poly(decamethylene malonate) 242.32 34 764
Poly(decamethylene 3,3'-methylenedibeiizamide) 392.54 65 402
Poly(decamethylene 4,4'-methylenedibenzamide) 392.54 100 402
Poly(decamethylene 4,4/-methylenediphenylenediurea) 422.57 246 634
Poly(decamethylene 4,4'-methylenediphenylenediurethane) *
Poly[decamethylene (methylene-2,5-furan)-dicarboxamide] 306.41 111 402
Poly[decamethylene (methylene-2,5-tetrahydrofuran)-dicarboxamide] 310.44 85 402
Poly[decamethylene octadecamethylenediurea) 508.84 172 634
Poly(decamethylene ocatadecanediamide) 450.75 170 454
Poly[decamethylene octadecanedioate) *
Poly[decamethylene octamethylenediurea) 368.57 201 634
Poly[decamethylene octamethylenediurethane) 370.53 146 402
Poly(decamethylene 4-octenediamide) *
Poly(decamethylene 4-octenedioate) *
Poly(2,5-decamethylene-l,3,4-oxadiazole) 208.30 100 1921
Poly(decamethylene oxalate) *
Poly(decamethylene oxamide) 226.32 229 291
252 743
290 402
Poly(decamethylene oxamide-a/f-decamethylene sebacamide) 564.86 231 1781
Poly(decamethylene oxide) *
Poly(decamethylene oxydiacetate) 272.34 64 1798
Poly(decamethyleneoxymethylene oxide) 186.30 57 695
Poly(decamethyleneoxy-/7-phenylene oxide) 248.37 < 100 1868
Poly[decamethylene (pentamethylenedisulfonyl)-dicaproamide] 564.84 223 402
Poly(decamethylene A^N'-pentamethylenediterephthalamate) 536.67 205 781
Poly(decamethylene /?-phenylenediacetamide) 330.47 242 291
265 454
Poly[decamethylene (p-phenylenedioxy)-diacetamide] 362.47 188 402
Poly(decamethylene /?-phenylenedipropionamide) 358.53 265 402
271 454
Poly(decamethylene S^'-phosphinylidenedibenzamide) 426.50
-, methyl- (P) 440.52 155 402
 Molecular Melting
Polymer weight point Refs.

Poly(decamethylene 4,4/-phosphinylidenedibenzamide) 426.50

- , methyl- (P) 440.52 186 402
- , phenyl-(P) 502.59 192 402
Poly(decamethylene 2,4-pyridinedicarboxamide) 303.41 190 1905
Poly(decamethylene 2,5-pyridinedicarboxamide) 303.41 232 1905
Poly(decamethylene 2,6-pyridinedicarboxamide) 303.41 200 1905
- , l,4-dihydro-4-0jco- 319.41 137 1905
Poly(decamethylene 3,5-pyridinedicarboxamide) 303.41 210 1905
Poly(decamethylene pyromelltimide) *
-, 3-bromo- (imide) 433.30 291 1267
Poly(decamethylene sebacamide) *
Poly(decamethylene sebacate) *
Poly(decamethylene sebacoyldiurethane) 426.55 153 402
Poly(decamethylene suberamide) 310.48 217 244
208 291
Poly(decamethylene suberate) *
Poly(decamethylene succinamide) *
Poly(decamethylene succinate) *
- , D-l,2-dihydroxy- (diacid) 288.34 66 609
Poly(decamethylene sulfide) 172.33 78 1819
91 181
Poly(decamethylene sulfonyldivalerate) 404.56 101 1797
Poly(decamethylene terephthalamide) 302.42 276 1868
Poly(decamethylene terephthalate) *
Poly[decamethylene N,Af'-terephthaloyldi(6-aminocaproate)] 530.71 166 1792
Poly(decamethylene tetradecamethylenediurea) 452.73 180 634
Poly(decamethylene tetradecanediamide) 394.64 189 2
Poly(decamethylene 2,5-tetrahydrofurandipropionamide) 352.52 178 402
Poly[decamethylene (tetramethylenedisulfonyl)-dicaproamide] 550.81 236 402
Poly(decamethylene AW'-tetramethylenediterephthalamate) 522.64 261 781
Poly(decamethylene tetramethylenediurethane) 314.43 171 633
Poly(decamethylene thiodivalerate) 372.56 57 767
Poly(decamethylenethiohexamethylene sulfide) 288.55 78 1819
Poly(decamethylene 2,5-thiophenedicarboxamide) 308.44 250 1905
Poly(2,5-decamethylene-l,3,4-triazole) 207.32
- , 1-amino- (triazole) 222.34 242 610
Poly(decamethylenetridecanediamide) 380.62 175 339
Poly(decamethylene AW'-trimethylenediterephthalamate) 508.61 222 781
Poly(decamethylene urea) 198.31 200 402
197 634
210 291
Poly(decamethylene /7-xylylenediurea) 360.50 260 634
Poly(decamethylene /?-xylylenediurethane) 362.47 147 634
Poly(decenamer) *
PoIy(I-decene)
Poly(decylvinyl ether) 184.32 7 1900
Poly [2,7-( 1,6-diazanthrylene)-4,4 '-biphenylene] 330.39
- , 4,9-diphenyl- 482.58 498 1778
Poly [2,8-( 1,9-diazanthrylene)-4,4 '-biphenylene] 330.39
- 4,6-diphenyl 482.52 513 1778
Poly [2,7-( 1,6-diazanthrylene)-4,4 '-oxydiphenylene] 346.39
-,4,9-diphenyl- 498.58 490 1778
Poly [2,8-( 1,9-diazanthrylene)-4,4 '-oxydiphenylene] 346.39
-,4,6-diphenyl- 498.58 502 1778
Poly(dimethyl ketene) *
Poly(di-l,4-naphthyleneoxyethylene oxide) 312.37 291 1787
Poly(di-l,4-naphthyleneoxyheptamethylene oxide) 382.50 239 1787
Poly(di-l,4-naphthyleneoxyhexamethylene oxide) 368.48 280 1787
Poly(di-l,4-naphthyleneoxypentamethylene oxide) 354.45 196 1787
Poly(di-l,4-naphthyleneoxytetramethylene oxide) 340.42 324 1787
Poly(di-l,4-naphthyleneoxytrimethylene oxide) 326.40 278 1787
PoIy(1,4-dioxanylene-2,5-dimethylene adipamide) 256.30
trans- 291 1769
PoIy(1,4-dioxanylene-2,5-dimethylene sebacamide) 312.41
trans- 262 1769

References page VI-159

 Molecular Melting
Polymer weight point Refs.

PoIy(I, 3-dioxolane), see Poly(ethyleneoxymethylene oxide) *

PoIy(1,3-dioxopane), see Poly(methyleneoxytetramethylene oxide) *
Poly(dithiodiethylene sebacamide) 318.49 155 402
Poly(4,4/-dithiodiphenylene hexamethylenediurea) 416.56 262 402
Poly(divinylbenzal) 176.22 100 1830
- , 2-methyl- 190.24 95 1830
- , 4-methyl- 190.24 115 1830
Poly(divinylfurfural) 166.18 145 1830
PoIy(I-docosene) *
Poly(dodecamethylene) 168.32
-, 1,2-dichloro- 237.21
trans- 40 1925
- , 1-methyl- 182.35 30 1926
Poly(dodecamethylene adipamide) 310.48 210 339
230 544
Poly(dodecamethylene adipate) *
Poly[dodecamethylene AW-adipoyldi(6-aminocaproate)] 538.77 134 1792
Poly(dodecamethylene 4,4'-biphenylenediurethane) 438.57
- , 3,3'-dimethyl- (diisocyanate) 466.62 219 402
Poly(dodecamethylene decamethylenediurethane) 426.64 133 634
Poly[4,4;-(dodecamethylenedioxy)-diphenyleneoxy-/7-xylylene oxide] 488.67 207 1789
Poly(dodecamethylene docosanediamide) 534.92 164 454
Poly(dodecamethylene A^AT'-dodecamethylenediterephthalamate) *
Poly(dodecamethylene dodecamethylenediurethane) 454.70 128 633
Poly(dodecamethylene dodecanediamide) 394.64 183 454
Poly[dodecamethylene AW'-dodecanedioyldi(p-aminobenzoate)] 634.86 167 1792
Poly(dodecamethylene AW-ethylenediterephthalamate) 522.64 264 781
Poly(dodecamethylene AW-hexamethylenediterephthalamate) 578.75 231 781
Poly(dodecamethylene hexamethylenediurea) 368.57 205 634
238 1892
Poly(dodecamethylene hexamethylenediurethane) 370.53 139 634
Poly(dodecamethylene 3-hexenedioate) *
Poly(dodecamethylene 4,4/-methylenediphenylenediurea) 450.63 240 634
Poly(dodecamethylene 4,4'-methylenediphenylenediurethane) 452.59 164 634
Poly(dodecamethylene 1,4,5,8-naphthalenetetracarboximide) *
Poly(dodecamethylene octadecanediamide) 478.80 167 454
Poly(dodecamethylene 4-octenedioate) *
Poly(dodecamethylene oxamide) *
Poly(dodecamethylene oxamide-a/f-dodecamethylene sebacamide) 620.96 217 1781
Poly(dodecamethylene AW-pentamethylenediterephthalamate) 564.72 206 781
Poly(dodecamethylene p-phenylenediacetamide) 358.53 256 454
Poly(dodecamethylene/?-phenylenedipropionamide) 386.58 263 454
Poly(dodecamethylene phosphinylidenedipropionamide) 358.46
-, methyl- (P)
Poly(dodecamethylene pyromellitimide) *
- , 3-bromo-(imide) 461.36 238 1267
Poly(dodecamethylene sebacamide) *
Poly(dodecamethylene suberate) *
Poly(dodecamethylene succinamide) *
Poly(dodecamethylene terephthalamide) 330.47 296 454
301 544
Poly[dodecamethylene AW'-terephthaloyldi(6-aminocaproate)] 558.76 163 1792
Poly(dodecamethylene AW-tetramethylenediterephthalamate) 550.70 258 781
Poly(dodecamethylene AW-trimethylenediterephthalamate) 536.67 216 781
Poly(dodecamethylene p-xylylenediurea) 388.56 258 634
Poly(dodecamethylene p-xylylenediurethane) 390.52 178 634
Poly(dodecanedioic anhydride) 212.29 87 1823
Poly(dodecenamer) *
PoIy(I-dodecene) *
Poly(dodecylvinyl ether) 212.38 30 1900
Poly(eicosamethylene adipate) 424.67 87 1790
- , 3-methyl-(diacid) 438.69 60 1796
Poly(eicosamethylene azelate) 466.75 87 1790
Poly(eicosamethylene 3,3'-dibenzoate) 520.76 91 1552
Poly(eicosamethylene 4,4 '-dibenzoate) 520.76 115 1552
 Molecular Melting
Polymer weight point Refs.

Poly(eicosamethylene glutarate) 410.64 80 1790

- , 3-(p-nitrophenyl)- (diacid) 531.74 46 1796
Poly(eicosamethylene isophthalate) 444.66 49 1794
Poly(eicosamethylene malonate) 382.58 69 1868
69 1790
Poly(eicosamethylene oxalate) 368.56 90 1790
Poly(eicosamethylene oxydiacetate) 412.61 89 1798
Poly(eicosamethylene phthalate) 444.66 52 1794
Poly(eicosamethylene pimelate) 438.69 84 1790
Poly(eicosamethylene sebacate) 480.78 92 1790
Poly(eicosamethylene suberate) 452.72 88 1790
Poly(eicosamethylene succinate) 396.61 89 1790
Poly(eicosamethylene sulfonyldivalerate) 544.83 117 1797
Poly(eicosamethylene terephthalate) 444.66 113 1794
Poly(eicosamethylene thiodivalerate) 512.84 79 767
Poly(enanthaldehyde, see Poly(heptaldehyde) *
Poly(epichlorohydrin), see Poly(ethylene oxide), chloromethyl- *
Poly(ethylene)
- , chlorotrifluoro- *
-, l-butoxy-2-methyl- 114.19
cis- (erythro-di-isotactic) 100 1880
trans- (threo-di-isotactic) 100 1880
-, l-tert-butoxy-2-methyl- 114.19
cis- (erythro-di-isotactic) >250 1880
- , l-ethoxy-2-methoxy- 102.13
trans- 217 141
-, l-ethoxy-2-methyl- 86.13
cis- (erythro-di-isotactic) 191 1880
trans- (threo-di-isotactic) 207 1880
230 1804
243 141
-, isobutoxy-2-methyl- *
-, l-isopropoxy-2-methyl- 100.16
cis- (erythro-di-isotactic) 204 1880
trans- (threo-di-isotactic) 211 1880
- , l-methoxy-2-methyl- 72.11
cis- or trans- (threo-di-isotactic) 230 1880
287 1804
210 141
- , l-methyl-2-propoxy- 100.16
trans- 168 1804
- , tetrafluoro- *
- , trifluoro- *
Polyethylene adipamide) 170.21 310 402
Polyethylene adipamide-a/f-ethylene oxamide) 284.32 D359 1781
Poly(ethylene adipate) *
- , methyl-(diol) 186.21 -20 765
Polyethylene A^V'-adipoyldi(6-aminocaproate)] 398.50 163 1792
Polyethylene adipoyldiurethane) 258.23 210 402
Poly(ethylene amine) *
-, AT-acetyl- 85.11 200 747
-, Af-benzoyl- *
- , - , /7-chloro- *
-, Af-butyryl- *
-, - , 4-(4-methylthiophenyoxy)- *
-, N-cyclohexanecarbonyl- 153.22 285 747
-, N-dodecanoyl- 225.38 155 747
-, Af-heptanoyl- *
- , Af-hexanoyl- *
- , Af-isobutyryl- *
-, Af-isovaleryl- *
- , JV-2-naphthoyl- 197.24 258 747
- , Af-octadecanoyl- 309.54 145 747
- , iV-octanoyl- *
- , A^-perfluorooctanoyl- 439.12 245 747

References page VI-159

 Molecular Melting
Polymer weight point Refs.

- , N-perfluoropropionyl- 189.08 216 747

- , JV-pivaloyl- 127.19 320 747
- , iV-P-toluoyl- *
- , Af-valeryl- *
Poly(ethylene azelamide-tf/f-ethylene oxamide) 326.40 343 1781
Poly(ethylene azelate) *
- , methyl- (diol) 228.29 -38 765
Poly(4,4 '-ethylenebiphenylene) 180.25 > 550 1187
Polyethylene p-(carboxyphenoxy)-acetate] 222.20 140 290
Polyethylene /?-(carboxyphenoxy)-butyrate] 250.25 85 290
Polyethylene /?-(carboxyphenoxy)-caproate] 278.30 45 290
Polyethylene p-(carboxyphenoxy)-heptanoate] 292.33 55 290
Polyethylene p-(carboxyphenoxy)-undecanoate] 348.44 65 290
Polyethylene /?-(carboxyphenoxy)-valerate] 264.28 55 290
Polyethylene p-(carboxyphenylene)-acetamide] 204.23 221 1904
Poly(ethylene 1,4-cyclohexylenedicarboxylate) 198.22
cis- <30 1912
trans- 120 1912
Poly(ethylene cyclopropylenedicarboxamide) 154.17
trans- 350 1860
Poly(ethylene decamethylenediurethane) *
Polyethylene 2,2'-dibenzoate) 268.27 130 1654
- , methyl-(diol) 282.30 55 1552
Polyethylene 3,3 '-dibenzoate) 268.27 122 1552
- , methyl-(diol) 282.30 97 1552
Polyethylene 4,4'-dibenzoate) *
-, methyl- (diol) 282.30 140 1552
Poly(4,4'-ethylenedibenzoic anhydride) 252.27 340 1854
Poly(4,4'-ethylenedicyclohexylene dodecanediamide) 418.66 316 1926
Poly(4,4/-ethylenedicyclohexylene sebacamide) 390.61 333 1926
Poly[3,3/-(ethylenedioxy)-dibenzoic anhydride] 284.27 237 1854
Poly[4,4'-(ethylenedioxy)-dibenzoic anhydride] 284.27 208 1854
215 1565
222 1872
- , 3,3/-dimethoxy- 344.32 220 1855
Poly[4,4/-(ethylenedioxy)-dibenzoic isophthalic anhydride] 432.38 140 1871
Poly[4,4/-(ethylenedioxy)-dibenzoic phthalic anhydride] 432.38 185 1872
Poly[4,4'-(ethylenedioxy)-dibenzoic terephthalic anhydride] 432.38 209 1871
Poly[(ethylenedioxy)-diethylene adipamide] 258.32 160 291
190 402
Poly[(ethylenedioxy)-diethylene adipate] 260.29 - 30 765
Poly[(ethylenedioxy)-diethylene azelate] 302.37 - 40 765
Poly[(ethylenedioxy)-diethylene 2,2'-dibenzoate] 356.37 41 1552
Poly[(ethylenedioxy)-diethylene 3,3'-dibenzoate] 356.37 46 1552
Poly[(ethylenedioxy)-diethylene 4,4'-dibenzoate] 356.37 93 1552
Poly [4,4'-(ethylenedioxydiethylenedioxy)-diphenylene 3,3',4,4'-(carbonyldiphenylene)tetracarboximide] 616.58 405 1808
Poly[3,4 /-(ethylenedioxydiethylenedioxy)-diphenylene 3,3 ',4,4/-(oxydiphenylene)tetracarboximide] *
Poly[(ethylenedioxy)-diethylene glutarate] 246.26 - 28 765
Poly[(ethylenedioxy)-diethylene isophthalate] 280.28 65 1794
Poly[(ethylenedioxy)-diethylene malonate] 218.21 -28 765
Poly[(ethylenedioxy)-diethylene oxalate] 204.18 -10 765
Poly[(ethylenedioxy)-diethylene pimelate] 274.32 - 37 765
Poly[(ethylenedioxy)-diethylene 1,4-piperazinediacetamide] 314.39 115 291
Poly[(ethylenedioxy)-diethylene sebacate] 316.39 29 696
35 767
Poly[(ethylenedioxy)-diethylene suberate] 288.34 - 36 765
Poly[(ethylenedioxy)-diethylene succinate] 232.23 -18 765
Poly[(ethylenedioxy)-diethylene sulfonyldivalerate 348.39 27 1797
Poly[(ethylenedioxy)-diethylene terephthalate] 280.28 65 1794
Poly[(ethylenedioxy)-diethylene thiodivalerate] 348.46 - 37 767
Poly[(ethylenedioxy)-diethylene undecanediamide] 328.45
- , 6-hydroxy-(diacid) 344.45 156 402
Poly[4,4/-(ethylenedioxy)-diphenylene 3,3',4,4'-(carbonyl-diphenylene)-tetracarboximide] 528.48 470 1808
Poly[3,4/-(ethylenedioxy)-diphenylene 3,3 /,4,4/-(oxy-diphenylene)-tetracarboximide] *
Poly[(ethylenedioxy)-ditrimethylene adipamide] 286.37 180 1791
 Molecular Melting
Polymer weight point Refs.

Poly[(ethylenedioxy)-ditrimethylene azelamide] 328.45 130 1791

Poly[(ethylenedioxy)-ditrimethylene sebacamide] 342.48 160 1791
Poly[(ethylenedioxy)-ditrimethylene terephthalamide] 306.36 240 1791
Poly (4,4'-ethylenediphenylene adipamide) 322.41 400 402
Poly(4,4/-ethylenediphenylene carbonate) 240.26 300 438
Poly(4,4/-(ethylenediphenylene)-methylene] 194.28 255 1187
Poly(4,4/-ethylenediphenylene sebacamide) 378.52 360 402
Poly(ethylene disiloxanylenedipropionamide) 246.42
- , tetramethyl- (silicone) 302.52 55 402
Polyethylene disulfide)
Poiy[(ethylenedisulfonyl)-diacetic anhydride] 256.24 185 1856
Poly[(ethylenedisulfonyl)-dipropionic anhydride] 284.30 255 1856
Poly [4,4 '-(2,2 '-ethylenedithiazole)-/?-phenylene] 270.37 265 1810
Poly[(ethylenedithio)-diacetic anhydride] 192.25 83 1565
Poly[(ethylenedithio)-dipropionic anhydride] 220.30 75 1565
Poly(ethylenedithiohexamethylene disulfide) 240.56 102 1837
107 1784
Polyethylene dithioladipate) 204.31 125 1922
Polyethylene dithiolisophthalate) 224.30 185 1922
Polyethylene dithiol-2,5-pyridinedicarboxylate) 252.29 280 1922
Polyethylene dithiolterephthalate) 224.29 340 1922
Polyethylene dithionisophthalate) 224.29 80 1889
Polyethylene dithiotetramethylene disulfide) 212.40 96 1837
88 1784
Polyethylene MA^-dodecamethylenediterephthalamate) *
Polyethylene dodecanediamide) 254.37 261 244
Polyethylene WV'-dodecanedioyldi(p-aminobenzoate)] 494.59 242 1792
Poly[ethylene (ethylenediamino)-dipropionamide] 228.30
- , WV'-diisopropyl-, A^V'-dimethyl- 340.51 102 1875
Poly(ethylene 4,4/-ethylenedibenzoate) 296.32 212 1566
>320 1654
Polyethylene ethylenedioxy)-diacetamide] 202.21 168 1894
Polyethylene 3,3 /-(ethylenedioxy)-dibenzoate] 328.32 141 111
Poly[ethylene 4,4'-(ethylenedioxy)-dibenzoate] *
- , 3,3'-dimethoxy- 388.37 210 1914
Polyethylene 4,4/-(ethylenedioxydimethylene)-dibenzoate] 356.38 135 1174
Poly[ethylene 4,4/-(ethylenediphenylene)-diurethane] *
Poly[ethylene 4,4/-(ethylenedithio)-dibenzoate] 360.44 190 291
Polyethylene (ethylenedithio)-diethylenediurethane] 294.38 168 1897
Polyethylene fumaramide) 140.14 50 402
Polyethylene ghitarate) 158.15
- , methyl-(diol) 172.18 -18 765
- , 3-(p-nitro)- 279.25 76 1796
Polyethylene 2,4-hexadienediamide) 166.18 61 402
Poly(ethylene 4,4'-hexamethylenedibenzoate) 352.43 160 1174
Poly[ethylene (hexamethylenedithio)-diethylene-diurethane] 350.49 130 1897
Poly(ethylene hexamethylenediurea) 228.30 293 1892
240 1768
Polyethylene hexamethylenediurethane) *
Polyethylene isophthalate) *
- , methyl- (diol) 206.20 87 1794
Polyethylene WV'-lysyldiurea) 258.28
- , methyl ester 272.30 160 1768
Polyethylene 4,4'-methylenedibenzoate) 282.30 220 291
>320 1654
Poly[ethylene 4,4/-(methylenediphenylene)-diurethane] *
Polyethylene 1,5-naphthalate) 242.23 230 291
Polyethylene 2,6-naphthalate)
Polyethylene 2,7-naphthalate) 242.23 270 1911
Poly(ethylene nonamethylenediurethane) *
Poly(ethylene oxalate) *
Polyethylene oxamide-a/f-ethylene sebacamide) 340.42 323 1781
Polyethylene oxamide-aft-ethylene suberamide) 312.37 348 1781
Poly(ethylene oxide) *
- , 1,1-bischloromethyl- 141.00 180 1816

References page VI-159

 Molecular Melting
Polymer weight point Refs.

-, bromomethyl-[epibromohydrin] 136.98 112 1809

-, tert-butyl- *
-, chloromethyl- [epichlorohydrin] *
-, 1,2-dichloromethyl- 141.00
cis- 235 1779
trans- 145 1779
-, fluoromethyl-[epifluorohydrin] 76.07 68 119
- , isopropyl- *
- , neopentyl- 114.19 82 527
- , p-nitrophenol complex *
- , resorcinol complex *
- , tetrafluoro- 116.02 42 1858
-, tetramethyl- 100.16 300 664
- , urea complex *
Poly(ethylene-p-oxybenzoate) *
- , m-chloro- 198.61 285 1174
- , o-chloro- 198.61 153 1174
- , m-mehthyl- 178.19 292 1174
-, 0-methyl- 178.19 157 1174
Polyethylene oxydiacetate) 160.13 20 1798
- , methyl-(diol) 174.15 21 1798
Polyethylene 4,4/-oxydibenzoate) 284.27 152 291
134 1939
Poly[ethylene 4,4/-(oxydiethylene)-dioxydibenzoate] 372.37
-, 3,3/-dimethoxy- 432.42 118 1914
Polyethylene 4,4/-oxydimethylene)-di-2-(l,3-dioxolane)-caprylate] 500.63 19 797
Poly(ethyleneoxymethylene oxide) [1,3-dioxolane] *
Polyethylene p-oxyphenyleneacetate) 178.19 172 1841
Poly(ethyleneoxy-/?-phenylene oxide) 136.15 270 1868
Polyethylene 4,4'-(pentamethylenedioxy)-dibenzoate] 370.40 150 1912
Polyethylene (pentamethylenedithio)-diethylenediurethane] 336.46 126 1897
Polyethylene /?-phenylenediacetate) 220.22 107 325
137 341
Polyethylene m-phenylenedisulfonamide) 262.30 182 1384
Polyethylene phthalamide) 190.20 250 1833
Polyethylene phthalate) 192.17 104 1654
-, methyl-(diol) 206.20 50 1794
Polyethylene pimelate) *
-, methyl- (diol) 200.24 -30 765
Polyethylene 1,4-piperazinedicarboxylate) *
Polyethylene 1,4-piperazinedipropionamide) 254.33 D231 1875
- , A^V'-diisopropyl- 338.50 210 1875
Polyethylene 1,4-piperazinedipropionate) 256.30 93 1875
Polyethylene sebacamide) 226.32 276 244
254 291
280 402
Polyethylene sebacate) *
- , methyl (diol) 242.32 - 26 765
Polyethylene sebacoyldiurea) 312.37 228 402
Polyethylene sebacoyldiurethane) 314.34 198 402
Polyethylene suberate) *
- , methyl-(diol) 214.26 -34 765
Poly(ethylene succinate) *
- , methyl- (diol) 158.15 0 765
Poly(ethylene sulfide) *
-, terf-butyl- *
Polyethylene 4,4/-sulfonyldibenzamide) 330.36 380 1835
Polyethylene sulfonyldivalerate) 292.35 86 1797
- , methyl- (diol) 306.38 68 1797
Polyethylene L-tartaramide) 174.16
- , di-O-methyl- *
Polyethylene terephthalamide) 190.20 455 829
- , AW-dimethyl- 218.26 379 829
Polyethylene terephthalate)
- , chloro- (diacid) 226.62 92 1913
 Molecular Melting
Polymer weight point Refs.

- , 2,5-dichloro- 261.06 165 1913

- , 2,5-dimethyl- 220.22 180 1913
-, methyl- (diacid) 206.20 70 1913
- , methyl-(diol) 206.20 111 1794
Polyethylene MA^/-terephthaloyldi(6-aminocaproate)] 418.49 204 1792
Polyethylene 2,5-tetrahydrofurandipropionamide) 240.30 218 402
Polyethylene 4,4/-tetramethylenedibenzoate) 324.38 170 291
Poly[ethylene 3,3'-(tetramethylenedioxy)-dibenzoate] 356.37 100 111
Polyethylene 4,4/-(tetramethylenedioxy)-dibenzoate] 356.37 252 1841
-, 3,3/-dimethoxy- 416.43 117 1914
Polyethylene 4,4/-(tetramethylenediphenylene)-diurethane] 354.41 274 414
Poly[ethylene (tetramethylenedithio)-diethylene-diurethane] 322.44 126 1897
Polyethylene 2,4,8,10-tetraoxa-3,9-spiro(5.5)hendecane-dicaprylate] 470.60 85 797
Polyethylene 4,4'-AiOdIbCnZOaIe) 300.33 200 291
Polyethylene thiodienanthamide) 314.49 210 402
Polyethylene thiodivaleramide) 258.38 220 402
Polyethylene thiodivalerate) 260.35 28 1797
- , methyl- (diol) 274.38 - 34 767
Poly(ethylenethiohexamethylene sulfide) 176.34 86 1819
Poly(ethylenethiotetramethylene sulfide) 148.29 89 181
Poly(2,5-ethylene-1,3,4-triazole) 95.10
- , 1 -amino- (triazole) 110.12 360 610
Polyethylene 4,4/-(trimethylenedioxy)-dibenzoate] 342.35 190 1912
- , 3,3'-dimethoxy- 403.00 105 1914
Polyethylene 4,4/-(trimethylenediphenylene)-diurethane] 340.38 207 414
Polyethylene WV'-trimethylenediterephthalamate) 396.40 205 781
Polyethylene urea) 86.09 400 402
Poly(ethylidene)
Poly(4,4/-ethylidenediphenylene carbonate) 240.26 195 438
-, phenyl- 316.36 230 438
Polyethylidene p-phenylene) 104.15 205 1876
Poly(ethylvinyl ether) 72.11 86 114
-, 2-chloro- 106.55 150 114
- , 2-methoxy- 102.13 73 114
-, 2,2,2-trifluoro- 126.08 128 114
Poly(formaldehyde), see Poly(oxymethylene) *
Poly(2,5-furandipropionic anhydride) 194.19 67 1565
Poly(furfural-«/r-dimethylketene) 166.18 180 1817
Poly(l,4-P-D-glucose) [cellulose] 162.14
- , triacetate *
- , tributyrate *
- , tricaprate 624.90 88 144
- , tricaproate 456.58 94 144
- , tricaprylate *
- , triheptylate 498.66 88 144
- , trilaurate 709.06 91 144
- , trimyristate 793.22 106 144
- , trinitrate *
- , tripalmitate 877.38 105 144
-, tripropionate *
-, trivalerate 414.50 122 144
- , 2.44-nitrate *
Poly(glycine) *
Poly(glycolic acid), see Poly(2-hydroxyacetic acid) *
Poly(glycyl-12-aminododecanoic acid) *
Poly(l,3-heptadiene), 1,4-
- , 5-methyl- 110.20
trans-
isotactic 180 1896
- , 6-methyl- *
Poly(heptaldehyde)
Poly(heptamethylene) 98.19
- , 1,2-dichloro- 167.08
trans- 53 1925
Poly(heptamethylene adipamide) *

References page VI-159

 Molecular Melting
Polymer weight point Refs.

Poly(heptamethylene azelamide) *
Poly[4,4/-(heptamethylenedioxy)-diphenyleneoxy-/7-xylylene oxide] 418.54 207 1789
Poly(heptamethylene disulfide) 162.31 130 1868
Poly(heptamethylene AyV'-ethylenediterephthalamate) 452.51 275 781
Poly(heptamethylene A^N'-hexamethylenediterephthalamate) 508.61 227 781
Poly(heptamethylene hexamethylenediurea) 298.43 243 1892
Poly(heptamethylene malonamide) 198.26
- , dodecyl-(diacid) 366.59 147 1774
Poly[heptamethylene 4,4/-(methylenediphenylene)diurethane] *
Poly(heptamethylene 4-octenediamide) 266.38
trans-I. 261 657
IL 249 657
Poly(heptamethylene oxamide-«/?-heptamethylene sebacamide) 480.69 248 1781
Poly(heptamethylene A^AT'-pentamethylenediterephthalamate) 494.59 199 781
Poly(heptamethylene p-phenylenediacetamide) 288.39 234 402
Poly(heptamethylene pimelamide) *
Poly(heptamethylene sebacamide) *
Poly(heptamethylene sebacate) *
Poly(heptamethylene suberamide) *
Poly(heptamethylene 4,4/-sulfonyldibenzamide) 400.49
- , 4,4-dimethyl- 428.55 268 1835
Poly(heptamethylene terephthalamide) 260.34 328 1775
330 828
341 829
Poly(heptamethylene terephthalate) *
Poly(heptamethylene 2,5-tetrahydrofurandipropionamide) 310.44 148 402
Poly(heptamethylene AW'-tetramethylenediterephthalamate) 480.56 269 781
Poly(2,5-heptamethylene-l,3,4-triazole) 165.24
-, 1-amino- 180.26 237 610
Poly(heptamethylene MN'-trimethylenediterephthalamate) 466.53 222 781
Poly(heptametylene undecanediamide) 310.48 195 2
Poly(heptenamer) *
PoIy(I -heptene)
- , 6,6-dimethyl- 126.24 104 282
-, 5-methyl- *
Poly[4,4/-heptylidene)-diphenylene carbonate] 310.39 200 438
Poly(hexadecamethylene adipate) *
Poly(hexadecamethylene decamethylenediurethane) 482.75 128 634
Poly(hexadecamethylene hexamethylenediurethane) 426.64 134 634
Poly(hexadecamethylene 3-hexenedioate) *
Poly(hexadecamethylene 4,4/-(methylenediphenylene)-diurethane] 508.70 152 634
Poly(hexadecamethylene 4-octenedioate) *
Poly(hexadecamethylene suberate) *
Poly(hexadecamethylene/?-xylylenediurethane) 446.63 168 634
PoIy(I-hexadecene) *
PoIy(1,5-hexadiene), see Poly(cyclopentylene-a/Mnethylene) *
PoIy(1,3-hexadiene), 1,4-
-, 5-methyl-
Poly(2,4-hexadiene), 2,5-
- , 2,5-dimethyl-
Poly(2,4-hexadienedioic acid), 2,5- 142.11
- , diisopropyl ester *
Poly(2,4-hexadienoic acid), 2,5- 112.13
-, 6-amino- *
Poly(2,4-hexadiyne adipate) 220.22 130 1782
Poly(2,4-hexadiynediol), 2,5- 110.11
- , l,6-bis(/7-methoxyphenylsulfonyl)- *
Poly(2,4-hexadiyne hexamethylenediurethane) 278.31 149 1782
Poly[2,4-hexadiyne (4,4/-methylenediphenylene)-diurethane] 360.37 150 1782
Poly(hexafluoroisobutylene-tf/?-vinylidene fluoride) *
Poly(hexamethylene adipamide) *
- , 2,5-dihydroxy- (diacid) 258.32 163 402
- , WV'-dimethyl- 254.37 75 402
- , 3-methyl- (diacid) 240.35 216 291
230 1859
 Molecular Melting
Polymer weight point Refs.

- , 3-methyl-(diamine) 240.35 180 291

-,/!-methyl- 240.35 145 291
Poly(hexamethylene adipamide-a/f-hexamethylene oxamide) 396.53 268 1781
Poly(hexamethylene adipate) *
Poly[hexamethylene Af,7V'-adipoyldi(6-aminocaproate)] 454.61 147 1792
Poly(hexamethylene adipoyldiurethane) 314.34 206 402
Poly(hexamethylene azelamide) *
Poly(hexamethylene azelamide-a/f-hexamethylene oxamide) 438.61 254 1781
Poly(hexamethylene azelate) 270.37 53 539
55 764
Poly(hexamethylene carbonate) 144.17 60 1820
Poly(hexamethylene m-carboxycarbanilate) 263.29 96 1891
Poly[hexamethylene/?-(carboxyphenoxy)-acetate] 278.30 50 290
Poly[hexamethylene /?-(carboxyphenoxy)-caproate] 334.41 60 290
Poly[hexamethylene/?-(carboxyphenoxy)-undecanoate] 404.55 72 290
Poly[hexamethylene p-(carboxyphenoxy)-valerate] 320.38 60 290
Poly[hexamethylene p-(carboxyphenylene)-acetamide] 260.34 227 1904
Poly(hexamethylene 1,2-cyclohexylenediacetamide) 280.41 255 402
Poly(hexamethylene 1,2-cyclohexylenedicarboxamide) 252.36
trans- 242 402
Poly(hexamethylene 1,3-cyclohexylenedicarboxamide) 252.36
trans- 312 402
Poly(hexamethylene 1,4-cyclohexylenedicarboxamide) 252.36
trans- 360 402
Poly(hexamethylene 1,4-cyclohexylenedicarboxylate) 254.33
trans- 120 1174
Poly(hexamethylene cyclopropylenedicarboxamide) 210.28
cis- 180 1860
-, - , AUV'-dibutyl 432.45 20 402
-, - , JV,iV'-diethyl- 376.34 5 402
- , - , WV'-diisopropyl- 404.40 20 402
- , - , AW-dimethyl- 348.29 30 402
Poly(hexamethylene glutarate) 214.26 34 764
Poly [hexamethy lene (hexamethylenedioxy)-dipropionamide] 342.48 105 402
Poly[hexamethylene 4,4'-(hexamethylenedisulfonyl)-dibenzoate] 536.66 186 1174
Poly[hexamethylene (hexamethylenedisulfonyl)-dicaproamide] 522.76 222 402
Poly(hexamethylene Af,Af'-hexamethylenediterephthalamate) *
Poly [hexamethy lene (hexamethylenedithio)-diethylene-diurethane] 406.60 106 1897
Poly(hexamethylene hexamethylenediurethane) *
Poly(hexamethylene 3-hexenedioate) *
Poly(hexamethylene isophthalamide) 246.31 220 402
200 828
- , 5-terf-butyl- (diacid) 302.42 210 402
Poly(hexamethylene isophthalate) 248.28 140 111
80 1794
Poly(hexamethylene 4,4/-isopropylidenedibenzamide) 364.49 180 402
Poly(hexamethylene 4,4'-ketodibenzamide) 350.42 350 402
Poly(hexamethylene ketodipropionamide) 254.33 180 402
Poly(hexamethylene N,Ar'-rysyldiurea) 314.38
- , methyl ester 328.41 180 1768
Poly(hexamethylene malonamide) *
- , butyl- (diacid) 240.35 161 1783
160 1774
- , decyl- (diacid) 324.51 133 1783
134 1774
-, dimethyl-(diacid) 212.19 117 402
-, dodecyl- (diacid) 352.56 134 1783
132 1774
-, heptadecyl- (diacid) 422.70 166 1774
-, heptyl-(diacid) 282.43 135 1774
-, hexadecyl-(diacid) 408.67 164 1783
160 1774
-, hexyl-(diacid) 268.40 145 1783
144 1774
-, nonyl- (diacid) 310.48 137 1774

References page VI-159

 Molecular Melting
Polymer weight point Refs.

- , octadecyl- (diacid) 436.72 167 1783

163 1774
-, octyl-(diacid) 296.45 133 1783
131 1774
-, pentadecyl- (diacid) 394.64 164 1774
-, pentyl- (diacid) 254.37 151 1774
-, propyl- (diacid) 226.32 163 1774
-, tetradecyl- (diacid) 380.62 152 1783
148 1774
- , tridecyl- (diacid) 366.59 133 1774
-, undecyl-(diacid) 338.54 133 1774
Poly(hexamethylene 3,3 '-methylenedibenzamide) 336.44 113 402
Poly(hexamethylene 4,4/-methylenediphenylene) 336.44 132 402
Poly[hexamethylene 4,4/-(methylenediphenylene)-dioxy-diacetamide] 396.49 174 402
Poly[hexamethylene 4,4/-(methylenediphenylene)-diurea] 366.46 250 402
-, 3,3'-dimethyl- 394.52 290 402
-, - , AW'-diethyl- 450.63 120 402
- , - , WV'-dipropyl- 478.68 90 402
Poly[hexamethylene 4,4/-(methylenediphenylene)-diurethane] *
Poly[hexamethylene (methylene-2,5-furan)-dicarboxamide] 250.30 115 402
Poly[hexamethylene (p-methylenephenoxy)-diacetamide] 304.39 220 402
226 1202
Poly[hexamethylene (p-methylenephenylene)-diacetamide] 283.39 204 1202
Poly[hexamethylene (methylene-2,5-tetrahydrofuran)-dicarboxamide] 254.33 78 402
Poly(hexamethylene naphthalenedicarboxamide) 298.39 200 402
Poly(hexamethylene nonamethylenediurea) 326.48 243 1892
Poly(hexamethylene octadecamethylenediurea) 452.73 192 634
Poly(hexamethylene octadecanediamide) 394.64 192 454
-, 9,10-dihydroxy- 426.64 172 402
-, AW-dimethyl- 422.70 52 1877
Poly(hexamethylene octamethylenedithiourea) 344.58 160 402
Poly(hexamethylene octamethylenediurea) 312.46 239 634
253 1892
255 402
Poly(hexamethylene octamethylenediurethane) 342.48 153 633
Poly(hexamethylene 4-octenediamide) *
Poly(hexamethylene 4-octenedioate) *
Poly(hexamethylene 5-oxadodecanediamide) 312.45 149 1847
Poly(hexamethylene 6-oxaheptadecanediamide) 382.59 160 1847
Poly(hexamethylene 5-oxahexadecanediamide) 368.56 159 1847
Poly(hexamethylene oxalate) *
Poly(hexamethylene oxamide) *
- , 3-oxypropyl- 228.29 240 402
Poly(hexamethylene oxamide-tf/f-hexamethylene pimelamide) 410.56 259 1781
Poly(hexamethylene oxamide-<z/£-hexamethylene sebacamide) 452.64 257 1781
Poly(hexamethylene oxamide-a/J-hexamethylene suberamide) 424.58 260 1781
Poly(hexamethylene 6-oxapentadecanediamide) 354.53 154 1847
Poly(hexamethylene 5-oxasebacamide) 284.40 160 1847
Poly(hexamethylene 5-oxatetradecanediamide) 340.51 155 1847
Poly(hexamethylene 5-oxaundecanediamide) 298.43 152 1847
Poly(hexamethylene oxide) *
Poly(hexamethylene oxydiacetamide) 214.26 143 402
172 1894
Poly(hexamethylene oxydiacetate) 216.23 51 1798
78 1791
Poly(hexamethylene 4,4'-oxydibenzoate) 340.38 74 1939
Poly(hexamethylene oxydibutyramide) 270.37 187 1847
Poly(hexamethylene oxydicaproamide) 326.48 175 1847
Poly(hexamethylene oxydienanthamide) 354.53 170 1847
Poly[hexamethylene 4,4/-(oxydimethylene)-di-2-(l,3-dioxolane)-caprylamide] 554.77 145 797
Poly(hexamethylene oxydipelarqonamide) 410.64 158 1847
Poly[hexamethylene 4,4'-(oxydiphenylene)-dioxydiacetamide] 398.46 220 402
Poly(hexamethylene 3,3/,4,4/-oxydiphenylenetetracarboximide) *
Poly(hexamethyelene oxydivaleramide) 298.43 180 1847
Poly(hexamethyleneoxymethylene oxide) *
 Molecular Melting
Polymer weight point Refs.

Poly(hexamethyleneoxy-/?-phenylene oxide) 192.26 170 1868

Poly[hexamethylene (pentamethylenedisulfonyl)-dicaproamide] 508.73 226 402
Poly(hexamethylene N,iV'-pentamethylenediterephthalamate) 480.56 238 781
Poly[hexamethylene (pentamethylenedithio)-diethylene-diurethane] 392.57 98 1897
Poly(hexamethylene pentamethylenediurea) 270.38 251 1892
Poly[hexamethylene (p-phenoxy)-diacetamide] 290.36 86 402
180 1202
Poly(hexamethylene m-phenylenediacetamide) 274.36 182 402
Poly(hexamethylene/7-phenylenediacetamide) 274.36 300 454
Poly(hexamethylene 3,3'-/?-phenylenedibutyramide) 330.47 196 1895
-, 3,3'-dimethyl- (diacid) 358.52 193 1895
Poly[hexamethylene (/?-phenylenedioxy)-diacetamide] 306.36 237 402
239 1202
Poly(hexamethylene/?-phenylenedipropionamide) 302.42 290 291
295 402
298 1202
300 1895
-, 3-methyl- (diacid) 316.44 227 1895
Poly(hexamethylene ra-phenylenedisulfonamide) *
Poly(hexamethylene m-phenylenediurea) 276.34
-, 4-methyl- (diisocyanate) 290.37 235 402
Poly(hexamethylene S^'-phosphinylidenedibenzamide) 370.39
-, methyl- (P) 384.42 172 402
Poly(hexamethylene 4,4/-phosphinylidenedibenzamide) 370.39
- , hydroxy- (P) 386.39 245 402
-,methyl- (P) 384.42 213 402
-, phenyl-(P) 445.48 231 402
Poly(hexamethylene phthalamide) 246.31 150 1833
Poly(hexamethylene phthalate) 248.28 2 1794
Poly(hexamethylene pimelamide) 240.35 228 244
202 339
Poly(hexamethylene pimelate) 242.32 50 539
55 764
Poly(hexamethylene 1,4-piperazinediacetamide) 282.39 168 291
Poly(hexamethylene Af,W-piperazinediterephthalamate) 464.52 255 1174
Poly[hexamethylene (l,4-piperazinedithio)-dicarboxylate] 322.44 144 1934
Poly(hexamethylene piperazinediurea) 254.33 245 402
265 1838
Poly(hexamethylene propylenediurea) 270.33
racemic 230 1768
Poly(hexamethylene 4(H)-pyran-2,6-dicarboxamide) 250.30
- , 4-oxo- (diacid) 264.28 77 1905
Poly(hexamethylene 2,3-pyrazoledicarboxamide) 238.29 140 1905
Poly(hexamethylene 2,4-pyrazoledicarboxamide) 238.29 271 1905
Poly(hexamethylene 2,3-pyridinedicarboxamide) 247.30 103 1905
Poly(hexamethylene 2,4-pyridinedicarboxamide) 247.30 220 1905
Poly(hexamethylene 2,5-pyridinedicarboxamide) 247.30 272 1905
Poly(hexamethylene 2,6-pyridinedicarboxamide) 247.30 220 1905
- , l,4-dihydro-4-oxo- 263.30 178 1905
Poly(hexamethylene 3,4-pyridinedicarboxamide) 247.30 101 1905
Poly(hexamethylene 3,5-pyridinedicarboxamide) 247.30 257 1905
-, 2,6-dimethyl- (diacid) 275.35 140 1905
Poly(hexamethylene pyromellitimide) *
Poly(hexamethylene 2,5-pyrroledipropionamide) 291.40
-, 1-methyl- (diacid) 305.42 180 402
Poly(hexamethylene 2,5-pyrrolidinedipropionamide) 295.43
- , 1-methyl- (diacid) 309.45 200 402
Poly(hexamethylene 5-pyrrolidonylidenedipropionamide) 295.40 250 402
Poly(hexamethylene sebacamide) *
- , 3-methyl- (diamine) 296.46 153 402
Poly(hexamethylene sebacate) *
Poly(hexamethylene sebacoyldiurethane) 370.45 158 402
Poly(hexamethylene 4,4'-silylenedibenzamide) 352.51
- , dimethyl- (Si) 380.56 190 402
Poly(hexamethylene suberamide) *

References page VI-159

 Molecular Melting
Polymer weight point Refs.

Poly(hexamethylene suberate) *
Poly[hexamethylene A^V'-suberoyldi(/?-aminobenzoate)] 494.59 250 1174
Poly(hexamethylene succinamide) *
Poly(hexamethylene succinate) 200.23 57 305
Poly(hexamethylene sulfide) *
Poly(hexamethylene sulfone) *
Poly(hexamethylene 4,4'-sulfonyldibenzamide) 386.46 310 1835
Poly(hexamethylene 4,4'-sulfonyldibenzoate) 388.44 280 1174
Poly[hexamethylene 4,4/-(sulfonyldimethylene)-dibenzoate] 416.49 252 1174
Poly(hexamethylene sulfonyldivaleramide) 346.49 215 402
Poly(hexamethylene sulfonyldivalerate) 348.46 92 1797
Poly(hexamethylenesulfonylpentamethylene sulfone) *
Poly(hexamethylenesulfonyltetramethylene sulfone) *
Poly (hexamethylene L-tartaramide) 230.26
- , di-O-methyl- *
Poly(hexamethylene terephthalamide) *
- , 2,5-dihydroxy- (diacid) 278.31 334 402
- , 2,5-dimethyl- (diacid) 274.36 143 402
- , WV'-dimethyl- 274.36 260 829
- , methyl- (diacid) 260.34 248 402
Poly(hexamethylene terephthalate) *
Poly[hexamethylene N,Ar'-terephthaloyldi(6-aminocaproate)] 474.60 177 1792
Poly(hexamethylene tetradecamethylenediurea) 396.62 198 634
Poly(hexamethylene tetradecanediamide) 338.54 209 2
Poly(hexamethylene 2,5-tetrahydrofurandipropionamide) 296.41 182 402
Poly[hexamethylene (tetramethylenedioxy)-dipropionamide] 314.43 110 402
Poly [hexamethylene (tetramethylenedisulfonyl)-dicaproamide] 494.70 241 402
Poly(hexamethylene MN'-tetramethylenediterephthalamate) 466.53 290 781
Poly [hexamethylene (tetramethylenedithio)-diethylene-diurethane] 378.55 120 1897
Poly(hexamethylene tetramethylenediurea) 256.35 283 1892
Poly[hexamethylene 2,4,8,10-tetraoxa-3,9-spiro(5.5)hendecane-dicaprylamide] 524.74 186 797
Poly(hexamethylene 4,4/-tetrasiloxanylenedibenzamide) 490.81
-, tetramethyl-tetraphenyl- (Si) 847.28 140 402
Poly(hexamethylene thiodibutyramide) 286.43 200 291
Poly (hexamethylene thiodienanthamide) 370.60 170 402
Poly(hexamethylene thiodipropionamide) 258.38 216 1859
219 402
Poly(hexamethylene thiodivaleramide) 314.49 180 402
185 1853
Poly (hexamethylene thiodivalerate) 316.46 46 767
Poly[hexamethylenethio-4,4 /-(methylenediphenylene)-diethylene sulfide] 370.61 88 1819
Poly(hexamethylenethiopentamethylene sulfide) 218.42 65 1819
Poly(hexamethylene 2,5-thiophenediacetamide) 280.39 230 1905
Poly(hexamethylene 2,5-thiophenedicarboxamide) 252.33 315 1905
Poly(hexamethylene 2,5-thiophenedipropionamide) 308.44 232 402
210 1905
Poly(hexamethylenethiotetramethylene sulfide) 204.39 67 1819
75 181
Poly(hexamethylenethioundecamethylene sulfide) 302.59 78 1923
Poly(hexamethylene thiourea) 158.26 160 402
Poly (2,5-hexamethylene-1,3,4-triazole) 151.21
- , 1-amino- (triazole) 166.23 275 610
Poly [hexamethylene 4,4/-(trimethylenediphenylene)-dioxy-diacetamide] 424.54 80 402
Poly[hexamethylene(trimethylenedisulfonyl)-diimino-dicaproamide] 446.59 185 402
Poly(hexamethylene MN'-trimethylenediterephthalamate) 452.51 256 781
Poly(hexamethylene trimethylenediurea) 242.32 266 1892
Poly (hexamethylene undecanediamide) 296.46
- , 6-hydroxy- (diacid) 312.45 165 402
Poly(hexamethylene urea) *
Poly(hexamethylene 4,4/-vinylenedibenzamide) 348.44
-, methyl- (diacid) 362.47 160 402
Poly[hexamethylene 4,4'-(p-xylylenedisulfonyl)-dibutyrate] 488.61 196 1174
Poly[hexamethylene AW-p-xylylenediterephthalamate) 514.58 285 1174
Poly(hexamethylene /7-xylylenediurea) 304.39 306 634
Poly(hexamethylene /?-xylylenediurethane) 306.36 209 634
 Molecular Melting
Polymer weight point Refs.

PoIy(1,3,5-hexatriene), 1,6- 80.13 250 1848

Poly(hexenamer) 82.15 61 439
PoIy(I-hexene) *
- , 4,4-dimethyl- 112.22 350 90
- , 4-ethyl- 112.22 234 632
- , 3-methyl- 98.19 285 441
- , 4-methyl
- , 5-methyl- *
Poly[4,4/-(2,2-hexylidene)-diphenylene carbonate] 296.36 200 438
Poly(hydrazo adipamide) 142.16 320 402
Poly(hydrazo azelamide) 184.24 237 402
Poly(hydrazo docosanediamide) 366.59 210 402
Poly(hydrazo dodecanediamide) 226.32 242 402
Poly(hydrazo glutaramide) 128.13 140 402
Poly(hydrazo pimelamide) 156.18 260 402
Poly(hydrazo sebacamide) 198.27 260 402
Poly(hydrazo suberamide) 170.21 275 402
Poly(hydrazo succinamide) 114.10 360 402
Poly(hydrazo thiodivaleramide) 230.33 180 402
Poly(2-hydroxyacetic acid) [glycolic acid] *
- , diethyl- 114.14 200 1928
-,dimethyl- 86.09 190 1174
- , isopropyl- 100.12 205 1930
Poly(m-hydroxybenzoic acid) 120.11 176 1799
Poly(p-hydroxybenzoic acid) *
- , 3,5-di-tert-butyl- 232.32 480 1814
- , 3-rc-propyl-
PoIy(4,4 '-hydroxybibenzoic acid) *
Poly(3-hydroxy-3-butenoic acid) *
Poly(3-hydroxybutyric acid) *
PoIy(I O-hydroxycapric acid)
Poly(6-hydroxycaproic acid)
Poly[5-hydroxy-2-(l,3-dioxane)-caprylic acid] *
Poly(7-hydroxyenanthic acid) 128.17
- , 4-methyl- (R + ) 142.20 36 1836
Poly[4-hydroxymethylene-2-(l,3-dioxolane)-caprylic acid] *
Poly[5-hydroxymethylene-5-methyl-2-(l,3-dioxane)-caprylic acid] 256.34 81 797
Poly(5-hydroxy-3-oxavaleric acid) 102.09 89 305
Poly[(p-hydroxyphenylene)-acetic acid] 134.13 280 1174
Poly[3-(/?-hydroxyphenylene)-propenoic acid] 146.14
trans- 313 1943
Poly(2-hydroxypropionic acid) [lactic acid] *
Poly(3-hydroxypropionic acid) [propiolactone] *
- , 2,2-bischloromethyl- 169.01 302 1174
- , 3-chloromethyl- *
- , 2,2-dibutyl- 184.28 245 1174
- , 3-dichloromethyl- *
- , 2,2-diethyl-
- , 2,2-dimethyl- [pivalolactone] *
- , 3-ethyl- [3-hydroxyvaleric acid]
- , - , 1,1-dichloro- 169.01 235 1199
- , 2-ethyl-2-methyl-
- , 3-isopropyl- *
- , 2-methyl-
- , 3-methyl-, see Poly(3-hydroxybutyric acid) *
- , 2-methyl-2-propyl- *
Poly[4-hydroxytetramethylene-2-( 1,3-dioxolane)-caprylic acid] 270.37
cis- 23 797
trans- 23 797
Poly(3-hydroxyvaleric acid), see poly(hydroxypropionic acid), 3-ethyl- *
Poly(5-hydroxyvaleric acid) 100.12 55 1844
53 305
- , 2,3,4-trimethoxy- 190.20 138 305
Poly(2-imino-1,3-dithiapentamethylene) 119.20
- , A^-ethyl- 147.25 68 1927

References page VI-159

 Molecular Melting
Polymer weight point Refs.

-,W-methyl- 133.23 89 1927

-, N-phenyl- 195.30 128 1927
- , -209.32 89 1927
Poly(isobutene) *
Poly(isobutylene oxide) *
Poly(isobutylene sulfide) 88.17 187 548
Poly(4,4'-isobutylidenediphenylene carbonate) 268.31 180 438
Poly(isobutylvinyl ether) *
Poly(isobutyraldehyde) *
Poly(isophthalaldehyde) 134.13 80 1801
Poly(isophthalic anhydride) 148.12 259 1565
Poly[isophthalic 2,2/-(isophthaloyldiamino)-dibenzoic anhydride] 534.48 259 1871
Poly[isophthalic (4,4/-isopropylidenediphenylenedioxy)-diacetic anhydride] 474.46 65 1871
Poly[isophthalic 4,4;-(methylenedioxy)-dibenzoic anhydride] 418.36
- , 3,3'-dimethoxy- 478.41 228 1871
Poly[isophthalic (p-phenylenedioxy)-diacetic anhydride] 356.29 297 1871
Poly[isophthalic 2,2'-(terephthaloyldiamino)-dibenzoic anhydride] 534.48 291 1871
Poly[isophthalic 4,4/-(tetramethylenedioxy)-dibenzoic anhydride] 460.44 100 1871
Poly[isophthalic 4,4'-(trimethylenedioxy)-dibenzoic anhydride] 446.41 165 1871
- , 3,3'-dimethoxy- 506.46 216 1871
Poly[isophthaloyl (m-carboxyphenoxyacetyl)-dihydrazide] 354.32 125 1833
Poly[isophthaloyl (m-carboxyphenoxybutyryl)-dihydrazide] 382.38 265 1833
Poly[isophthaloyl (m-carboxyphenoxycapryl)-dihydrazide] 410.43 249 1833
Poly[isophthaloyl (m-carboxyphenoxypropionyl)-dihydrazide] 368.35 238 1833
Poly[2,2 '-(isophthaloyldiamino)-dibenzoic terephthalic anhydride] 534.48 264 1871
Poly(isophthaloyl dithionisophthaloyldihydrazide) 356.42 324 1889
Poly(isoprene), see PoIy(1,3-butadiene), 2-methyl- *
Poly(isopropenylmethyl ketone) *
Poly(4,4/-isopropylidenedibenzoic anhydride) 266.30 235 1854
240 1855
Polypsopropylidenedimethylene, 4,4/-(methylenediphenylene)-diurethane] 354.41 190 402
Poly[isopropylidenedimethylene (1,4-piperazinedithio)-dicarboxylate] 306.40
-, 2,5-dimethyl- 334.45 135 1934
Poly(4,4/-isopropylidenediphenylene adipate) 338.40
- , 3,3',5,5'-tetrachloro-
Poly(4,4/-isopropylidenediphenylene carbonate) *
- , 3,3;-dichloro- 323.18 210 540
230 736
- , 3,3'-diisopropyl- 338.45 110 1915
- , 3,3'-dimethyl- 282.34 170 540
- , 3,3',5,5'-tetrabromo- 569.87 260 540
267 736
-, 3,3',5,5'-ICtTaChIOrO- 392.06 260 540
275 736
Poly(4,4'-isopropylidenediphenylene cyclopropylene-dicarboxylate) 322.36
cw- 130 1860
trans- 180 1860
- , 1-methyl- (diacid) 336.39
trans- 90 1860
- , 3-methyl- (diacid) 336.39
trans- 130 1860
Poly[(4,4'-isopropylidenediphenylenedioxy)-diacetic anhydride] 326.35 202 1855
Poly[(4,4'-isoproylidenediphenylenedioxy)-diacetic /?-phenylenedioxydiacetic anhydride] 502.52 230 1872
Poly[(4,4'-isopropylidenediphenylenedioxy)-diacetic 4-pyridinedicarboxylic anhydride] 475.45 120 1872
Poly[(4,4'-isopropylidenediphenylenedioxy)-diacetic terephthalic anhydride] 474.47 270 1871
Poly(4,4'-isopropylidenediphenylene dithioladipate) 370.53 198 1922
Poly(4,4 '-isopropylidenediphenylene dithiol-1,3-cyclohexylenedicarboxylate) 396.57 220 1922
Poly(4,4'-isopropylidenediphenylene dithionisophthalate) 390.52 152 1889
Poly(4,4'-isopropylidenediphenylene hexamethylenediurethane) 396.49 130 402
Poly(4,4'-isopropylidenediphenylene isophthalamide) 356.42 424 1886
Poly(4,4'-isopropylidenediphenylene malonate) 296.32 96 1868
Poly(4,4'-isopropylidenediphenylene 4,4'-(methylenediphenylene)-diurethane) 478.55 193 402
Poly(4,4'-isopropylidenediphenylene 1,4-piperazinedipropionate) 422.52 145 1875
Poly(isopropylidene oxide) *
Poly(isopropylidene sulfide) 74.14 125 1882
124 1800
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Molecular Melting
Polymer weight point Refs.

Poly(isopropylvinyl ether) *
Poly(ketone), see Poly(carbon monoxide-a/f-ethylene) *
Poly(lactic acid), see Poly(2-hydroxypropionic acid) *
Poly(Af,Af'-lysyl nonamethylenediurea) 356.47
- , methyl ester 370.49 185 1768
PoIy(WVMySyI pentamethylenediurea) 300.36
- , methyl ester 314.38 175 1768
PoIy(WVMySyI propylenediurea) 272.30
- , methyl ester 286.33
racemic 175 1768
Poly(WV;-lysyl tetramethylenediurea) 286.33
- , methyl ester 300.36 185 1768
Poly(WV'-lysyl trimethylenediurea) 272.30
- , methyl ester 286.33 205 1768
Poly(WV'-lysylurea) 172.18
- , methyl ester 186.21 175 1768
Poly(2-mercaptoacetic acid) 74.10 169 1922
-, 2-methyl- 88.13 152 1922
Poly(6-mercaptocaproic acid) *
- , 4-methyl- 144.24 62 1922
Poly(3-mercaptopropionic acid) 88.13 145 1922
-, 2-phthalimido- 233.24 260 1922
-, 2-(p-toluenesulfonamido)- 257.33 250 1922
Poly(methacrylic acid) 86.09
- , tert-butyl ester 142.12
isotactic 104 1851
syndiotactic 165 1851
- , hexadecyl ester 310.52 22 1900
- , methyl ester *
- , octadecyl ester *
Poly(methacrylonitrile) *
Poly(methylene) (see also Poly(ethylene)) 14.03
- , diphenyl- 166.22 220 1831
- , di-/?-tolyl- 194.28 180 1831
Poly(methylene adipamide) *
Poly (4,4'-methylenedibenzoic anhydride) 238.24 332 1854
Poly[4,4 '-(methylenedioxy)-dibenzoic anhydride] 270.24 220 1854
Poly[4,4/-(methylenedioxy)-dibenzoic terephthalic anhydride] 418.36
- , 3,3'-dimethoxy- 478.41 267 1871
Pory(4,4'-metriylenediphenylene adipamide) 308.38 356 402
- , 3,3'-dimethyl- (diamine) 336.44 326 402
- , - , WV'-dibutyl- 448.65 57 402
- , - , WV'-diethyl- 392.54 79 402
- , - , AW-dihexyl- 504.76 45 402
- , - , AW'-diisoamyl- 476.70 45 402
- , - , WV'-diisopropyl- 420.60 61 402
- , WV'-diethyl- 364.49 62 402
- , A^V'-dimethyl- 336.44 120 402
Poly(4,4/-methylenediphenylene adipate) 310.35 140 1901
Poly(4,4/-methylenediphenylene azelamide) 350.46 275 402
268 1443
290 1946
- , WV'-diethyl- 406.57 41 402
- , WV'-dimethyl- 378.52 58 402
Poly(4,4/-methylenediphenylene carbonate) *
-,3,3'-dimethyl- 254.29 250 736
-,diphenyl- 378.43 230 540
- , phenyl- 302.33 215 438
Poly[4,4/-(methylenediphenylene)-diethylene sulfide] 254.39 108 1819
Poly(4,4'-methylenediphenylene disiloxanylenedipropionamide) 384.58
-, tetramethyl- (Si) 440.69 90 402
- , - , 3,3'-dimethyl- (diamine) 454.72 265 402
Poly[3,3'-(4,4/-methylenediphenylene-A^,A^/-disuccinimidediyl)-imino-4,4/- methylenediphenylene amine] 556.62 295 1876
Poly(4,4/-methylenediphenylene dodecanediamide) *
Poly(4,4'-methylenediphenylene isophthalamide) 328.37 416 1886

References page VI-159