Documente Academic
Documente Profesional
Documente Cultură
rain, tides, waves, and geothermal heat. Water electrolysis is a well-known technology that is used
for production of hydrogen gas for its high energy conversion efficiency.
In this research study, the effect of Potassium Hydroxide (KOH) in the production rate of
hydrogen and oxygen during electrolysis was studied. 316 stainless steel were chosen as electrodes
for its resistance to corrosion. The molar concentrations of KOH that were used as alkaline
solutions in the electrolysis system were 0.1, 0.5 M, 1 M, 2 M, and 3M . Varying voltages were
used (1.5 V, 3 V, 6 V, 9 V, 12 V) to determine and compare the obtained results with each other.
Pure water and a widely known catalyst Sodium Hydroxide (NaOH) were also used as a basis to
be able to differ results with KOH. The preliminary results showed that 0.5 M showed the most
efficient results in terms of usage of catalyst. ___/min were of hydrogen and __/min were produced
with 0.5 M of KOH. While, the 1 M, 2 M, 3 M, and 4 M produced small differences in volume
displacement when compared to 0.5 M that it was considered negligible.
An electrolysis prototype was fabricated to be able to test the chosen concentrations for
longer amount of time, a closed vessel, and a large volume.
KOH @ 0.5 M
1 M-negligible difference
2 M-slight difference from 1 M and 0.5
3 M- same
5 M- same
constructed for the purpose of measuring a significant amount of hydrogen and oxygen gas
with Potassium Hydroxide (KOH) as catalyst when compared to pure water only. Laboratory
apparatus such as burette, 50 mL graduated cylinders, iron stand, and a burette clamp were used
during experimental runs. The electrolyte used differs in molar concentration of KOH (0.5M, 1M,
2M). Two stainless steel having a 15 cm length (0.7 mm OD) were used as the cathode electrode
while three single strand wire copper having 20 cm length (0.5 mm OD) as anode. The
experimental runs were conducted at room temperature. The electrolytic device was operated 2
the 0.5 moles/Liter of KOH produced a larger amount of the two gases even when the
molarity was increased to 3 and 5 M. The difference in results (mol/min) from the 3 and 5 M to
The qualitative result from the preliminary setup provided the conduct of experimental runs
using potassium hydroxide solution as an electrolyte. The second setup as shown in Figure 3.3 is
an open area where ions moves freely resulting to a desirable production rate of hydrogen and
oxygen gases. All surface area of the electrodes was submerged in the electrolyte solution therefore
are participating in the electrolysis process. However, hydrogen, oxygen and other by-product
In determining the power requirement for the electrolysis device, the researchers used an
AC to DC converter (Zoren Heavy Duty converter/charger), voltage ranges from 3V, 4.5V, 6V,
7.5V, 9V and 12V and an analog multi-meter for each setup until it reach a variation in the bubbling
effect on the surface area of the submerged electrode which is then the current readings was
recorded for every 10 minutes. A total of 12 readings was done for each voltage selection for each
amount of water that was displacing through the two tubes were scarce to measure. However, it
was observed that at some point, the reading reach the highest value of hydrogen gas produced at
100th minute mark as shown in the Table 4.1. This only shows that in electrolysis, pure water needs
some kind of catalyst in order for it to yield more hydrogen and oxygen gas.