61. Which among the following will show maximum osmotic pressure?

1) 1M NaCl 2) 1M MgCl2
3) 1M (NH4)3PO4 4) 1M Na2SO4
89. Equal volumes of 0.1 M and 0.2 M NaCl solutions are mixed. The concentration of nitrate ions in
the resultant mixture will be ______
1) 0.1 M 2) 0.2 M
3) 0.05 M 4) 0.15 M

102 Volume of 0.1 M K2 Cr2 O7 required to oxidise 35ml of 0.5 M FeSO4 solution is
1.35ml 2.29ml
3.17.5ml 4.175ml

128. The vapour pressure of water at 230C is 19.8 mm. 0.1 mole of glucose is dissolved in 178.2 g of
water. What is the vapour pressure (in mm) of the resultant solution?
1) 19.0 2) 19.602
3) 19.402 4) 19.202

139. Which of the following aqueous solution will have highest depression in freezing point ?
1) 0.1 M urea 2) 0.1 M Sucrose
3) 0.1 M AlCl3 4) 0.1 M K4[Fe(CN)6]
142. 200 c.c of an aqueous soloution contains 1.26 gms of a polymer. The osmotic pressure of such
solution at 300 K is found to be bar. Calculate the molar mass of the polymer
1) 61038 g/mole 2) 122076 g/mole
3) 610.38 g/mole 4) 122.076 g/mole
213. The elements X and Y form two different binary compounds and . When dissolved in 20g of
solvent, 1g of lowers the freezing point by C, whereas 1g of lowers the freezing point by C. The
moral depression constant for is 5. The atomic mass of element Y will be:
1) 42.64 2) 64.42
3)33.34 4) 12.8
218. A 5% solution of cane sugar (mol.wt.=342) is isotonic with 1% solution of substance X. The
molecular weight of X is
1) 34.2 2) 171.2 3) 68.4 4) 136.8
292. The vapour pressure of a solvent decreased by 10 mm of Hg when a non-volatile solute was
added to the solvent. The mole fraction of solute in solution is 0.2, what would be the mole fraction of
solvent if decrease in vapour pressure is 20 mm of Hg ?
1) 0.8 2) 0.6 3) 0.4 4) 0.2
295. For a solution of density, d in g/ml containing solute of molecular weight W the
molarity and molality are related by:
d 1 W d 1 W
   
1) M m 100 2) m M 1000
W 1 d d W 1
   
3) M m 1000 4) m M 1000
298. A non ideal solution was prepared by mixing 30ml chloroform and 50ml acetone. The volume of
mixture will be
1) > 80ml 2) < 80ml
3) = 80ml 4)  80ml
315. y g of a non -volatile organic substance of molecular mass M is dissolved in 250g benzeneMolal
elevation constant of benzene is . Elevation in its boiling point is given
by :
M 4Kb y Kb y Kb y
1)
Kb y 2) M 3) 4) 4M M
322. pH of a 0.1M monobaic acid is measured to be 2. Its osmotic pressure at a given
temperature T K is:
1) 0.1 RT 2) 0.11 RT 3) 1.1 RT 4) 0.01 RT
325. Lowering of vapour pressure in 1 molal aqueous solution at is:
1) 13.44mm Hg 2) 14.12mm Hg
3) 31.2mm Hg 4) 35.2mm Hg
91. When LiCl is doped with Li vapours the colour developed is
1) Violet 2) Yellow 3) Pink 4) Green
75. The oxide that is insulator is
1) VO 2) MnO 3) ReO3 4) Ti2O3
29. Which of the following systems is not correctly characterised ?

1) cubic : a = b = c;       900 2) tetragonal : a = b ≠c;       900

3) orthorhombic : a b  c; 4) rhombohedral : a = b  c;
      900
64. 8:8 co-ordination of CsCl is found to change into 6:6 on
a) applying high pressure b) increases in temperature
c) applying low pressure d) decrease in KCl temperature
70. The formula of an oxide of iron is . If the compound has hundred ions, then it contains
2 3
1) 93Fe ions 2) 93Fe ions 3) 79 Fe2 ,14Fe3 4) 93 Fe2 ,14Fe3
25. The mass of unit cell of corresponds to

a) 1Na and 6Cl  b) 1Cl  and 6Na  
c) 1Na and 1Cl

d) 4Cl  and 4Na 

44. Copper crystallises in a f.c.c. lattice, the length of the unit cell is 3.63 A°. The radius of Cu-atom is :
1) 0.6 A° 2) 2.9 A° 3) 1.28 A° 4) 5.7 A°
42. The percentage of void space of a metallic element crystallising in a ABCABC .....type lattice
pattern is
1) 24% 2) 26% 3) 34% 4) 74%
48. In a face centred cubic arrangement of A and B atoms, A atoms are at corners of unit cell and B
atoms at edge centres. One of the “A” atom is missing from one corner in each unit cell. The
simplest formula of the compound is
1) A2B3 2) AB3 3) A7B4 4) A7/8B3

70. The vapour pressure of pure liquid is 70 Torr at 270C. The vapour pressure of a solution of this
liquid and another liquid(mole fraction 0.2) is 84 Torr at 270C. The vapour pressure of pure liquid
B at 270C is
a) 140 Torr b) 280 Torr c) 160 Torr d) 200 Torr
73. Which of the following solutions is excepted to show negative deviations from Raoult's law?
a) Ethanol-hexane b) Ethanol-water c) Acetone-hexane d) Ethyl ether-acetone
11. Which has the highest boiling point?

a) 0.1M
Na2 SO4 C H O
b) 0.1M 6 12 6 (glucose)
MgCl2 Al  NO3 3
c) 0.1M d) 0.1M

6. A complex containing K+, Pt(IV) and Cl is 100% ionised giving i = 3. Thus, complex is:


K PtCl4  Fe  CN  2  
K4  Fe CN 6  Fe  CN  4
a) 2 b) c) d)
66. An azeotropic solution of two liquids has a boiling point higher than either of the boiling points of
the liquids when it
a) shows negative deviation from Raoult's law b) shows positiv deviation from Raoult's law
c) shows no deviation from Raoult's law d) is saturated

1. The number of octahedral voids per unit cell BCC cell is

1) 1.0 2) 2.0 3) 1.5 4) 0

2. The unit cell of a metallic element of atomic mass 108 and density 10.5g/cm3 is a cube with edge
length of 409pm. The structure of the crystal lattice is
1) FCC 2) BCC 3)edge centred cubic 4) simple cubic