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6. Which of the following ions is most effective in the coagulation of an arsenious sulphide solution ?
(A) K+ (B) Mg2+ (C) Al3+ (D) C
7. Which of the following ions is most effective in the coagulation of ferric hydroxide solution ?
(A) Cl¯ (B) Br – (C) NO2¯ (D) SO42–
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13. Which of the following represents a multimolecular colloidal particles?
(A) Starch (B) A sol of gold (C) Proteins (D) Soaps
15. Which of the following anions will have minimum flocculation value for the ferric oxide solution ?
(A) Cl¯ (B) Br¯ (C) SO42– (D) [Fe(CN)6l3-
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24. Gold number Of haemoglobin is 0.03. Hence, 100 mL of gold sol will require haemoglobin so that gold is not
coagulated by 10 mL of 10% NaCI solution :
(A) 0.03 mg (B) 30 mg (C) 0.30 mg (D) 3 mg
27. Arsenic () sulphide forms a sol with a negative charge. Which of the following ionic substances should be
most effective in coagulating the sol ?
(A) KCl (B) MgCl2 (C) Al2(SO4)3 (D) Na3PO4
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36. Softening of hard water is done using sodium aluminium silicate (zeolite). The causes :
(A) adsorption of Ca2+ and Mg2+ ions of hard water replacing Na+ ions.
(B) adsorption of Ca2+ and Mg2+ of hard water replacing Al3+ ions
(C) both (A) and (B)
(D) none of these
38. Which one of the following statements is false for hydrophilic sols ?
(A) they do not require electrolytes for stability
(B) their coagulation is reversible
(C) their viscosity is of the order of that of water
(D) their surface tension is usually lower than that of dispersion medium.
41. Colloidal solutions of gold prepared by different methods are of different colours because of:
(A) different diameters of colloidal gold particles
(B) variable valency of gold
(C) different concentration of gold particles
(D) impurities produced by different methods
1. Which of the following colloidal solutions contain negatively charged colloidal particles?
(A) Fe(OH)3 sol (B) As2 S3 sol (C) Blood (D) Gold sol
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4. Which of the following are hydrophobic sols?
(A) Protein sol (B) Gold sol (C) Gum sol (D) Fe(OH)3 sol.
5. If Cl2 gas is enclosed in presence of powdered charcoal in a closed vessel, the pressure of the gas decreases.
It is because
(A) the gas molecules are absorbed at the surface
(B) the gas molecules concentrate at the surface of the charcoal
(C) the gas molecules are adsorbed at the surface
(D) the gas molecules are desorbed by the surface
6. When negatively charged colloids like As2S3 sol is added to positively charged Fe(OH)3 sol in suitable
amounts
(A) Both the sols are precipitated simultaneously (B) This process is called mutual coagulation
(C) They become positively charged colloids (D) They become negatively charged colloids
5. Out of sodium chloride and barium chloride, which will have greater flocculation value for As2S3 sol?
6. Gold numbers of gelatin and gum arabic are 0.005 and 0.15 respectively, which of the two has greater
protecting power?
9. What happens when a red colloidal solution of gold is subjected to an electric current?
10. What happens when smoke comes in contact with clouds?
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SECTION (B) : FILL IN THE BLANKS :
1
6. Protective action of a lyophilic colloid .
....
10. The plot showing the variation of extent of adsorption with pressure at a constant temperature is called
................ .
1. Colour of a colloidal solution depends upon the size and shape of sol particles.
2. A layer of dispersion medium around the lyophilic sol particle accounts for its stability.
3. The higher the valency of effective ion, the lower is its coagulation power.
5. Brownian motion is due to continuous bombardment of sol particles by molecules of disperson medium.
6. For a positive sol, flocculation values are in the order NaCl > K2SO4 > Na3PO4 > K4[Fe(CN)6].
8. When negatively charged smoke comes in contact with positively charged clouds, rain fall takes place.
10. The extent of adsorption increases with increase in specific area of adsorbent.
1. Assertion : All colloidal dispersions give very low osmotic pressure and show very small freezing point
depression or boiling point elevation.
Reason : Tydall effect is due to scattering of light from the surface of colloidal particles.
2. Assertion : The Brownian movement is due to the bombardment of collodial particles by the molecules of
dispersion medium which are in the constant motion like molecules in a gas.
Reason : Brownian movement provides a visible proof of the random kinetic motion of molecules in a liquid.
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3. Assertion : In the coagulation of negatively charged arsenic sulphide sol, the coagulating power decreases
in the order, Al3+ > Ba2+ > Na+.
Reason : Generally greater the valence of coagulating ion, the greater is its power of coagulation.
5. Assertion : Gelatin is added to ice cream as a protective agent so as to preserve its smoothness.
Reason : whipped cream is colloidal in nature.
6. Assertion : Mists and fogs are the colloidal systems in which liquid is dispersed in a gaseous dispersion
medium.
Reason : In smoke, solid is the dispersed phase and gas is the dispersion medium.
7. Assertion : The property of adsorption is shown by solids to a much larger extent than liquids.
Reason : Solids, particularly when finely divided, have a large surface area.
10. Assertion : Isoelectric point is pH at which colloidal can move towards either of electrode
Reason : At isoelectric point, colloidal solution become electrically neutral
11. Assertion : A gas with higher critical temperature gets adsorbed to more extent than a gas with lower critical
temperature.
Reason : The easily liquefiable gases get adsorbed to more extent which have higher critical temperature.
12. Assertion : When AgNO3 is treated with excess of KI, colloidal particles gets attracted towards anode.
Reason : Colloidal particles adsorb common ions and thus become charged.
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Exercise - 3 (JEE/REE Questions of Previous Years)
SECTION (A) : OBJECTIVE
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Exercise - 1
SECTION (A)
Q.No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. A D B A D C D C D A B A D A D B C D A B
Q.No 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. C A A C C B C C D C A A A B C A B C A C
Q.No 41 42
Ans. A C
SECTION (B)
Q.No 1 2 3 4 5 6 7 8 9 10
Ans. BCD BC AC BD BC AB CD AC ABC AC
Exercise - 2
SECTION (A) :
1. Water is the dispersed phase and Fat is the dispersion medium.
2. By applying electric field around the parchment membrane.
3. Starch sol
4. Fe(OH)3 ,Cr(OH)3 , Al(OH)3 , Ca(OH)2 , TiO2, basic dye stuffs, prussian blue.
5. Sodium chloride 6. Gelatin 7. Finely divided palladium.
8. SO2, ammonia and CO2 9. Refer text. 10. Refer text.
SECTION (B) :
1. emulsion. 2. liquid, gas 3. negatively
4. protective power, lyophilic 5. less 6. gold number
7. scattering, sol 8. gelatin 9. colloidal solution of gold 10. adsorption isotherm
SECTION (C) :
1. True 2. True 3. False 4. False 5. True
6. True 7. False 8. True 9. False 10. True
SECTION (D) :
1. B 2. B 3. A 4. C 5. B 6. B 7. A
8. A 9. A 10. B 11. A 12. D 13. B 14. B
SECTION : (E)
1. (A – P, Q) ; (B–R) ; (C – Q, T) ; (D – S) ; (E – U) 2. (A – Q) ; (B – P) ; (C – S) ; (D – R) ; (E – T)
Exercise - 3
1. C 2. A 3. B 4. D
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