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This paper was presented at the 18th Annual OTC in Houston, Texas, May 5-8,1986. The material is subject to correction by the author. Permission
to copy is restricted to an abstract of not more than :JOO words.
Polyurethane foam is made primarily The pour process employs metering pumps
from two components, polymeric dispenyl- to push the chemicals. Pour systems generally
methane diisocyanate (MDI) and a p0lyol. have motorized mixing heads, which may be
The catalysis and blowing agents (FreGn™, powered either hydraulically or electri-
carbon dioxide, or nitrogen) are premixed cally. Pour machines often include accessor-
with these chemicals. When the MDI and the ies such as timers or recirculators. Re-
polyol are combined, the resulting mixture circulators help maintain the components
at a constant temperature and hold flow
rates constant.
References and illustrations at end of pape~
363
2 HIGH PRESSURE IMPINGEMENT MIXING METHOD FOR FOAM-IN-SALVAGE OTe 5265
The third type of foaming process-re-_ time from first mixing the two components
action injection ID01ding (RIM)-- is a varia- until the mixture begins to rise. The rise
tion of the pour process. Because RIM time of the resin system is the time from
actually describes how a molding is made, when the chemicals are mixed until they
a more accurate term is "high-pressure im- stop rising and the foam is set. Tempera-
pingement mixing (HPIM)." An HPIM machine ture affects the cream time and rise time
operates at much higher pressures (1000 to o~ a polyurethane resin system. For every
3000 psi) than pour or froth machines. In 10 0 F rise in temperature, the reaction rate
an HPIM machlne, the two components of the of the resin system doubles.
foam are separately pressurized and metered
before being impinged against one another. A non-plugging and reusable head is
necessary for producing foam successfully
Of the three basic types of foaming underwater. A head that periodically plugs
machines, the pigh-pressure impingement reduces foaming efficiency and may delay a
mixing type is the best for use under water. salvage job. Disassembling equipment under-
The major advantage of the HPIM type machine water takes several times as long as it
in this situation is the high pressure itf would take on land. Thus, changing parts
self. Freons™ are often used as blowing of a head or cleaning a head underwater
agents for the f~am. However, their low would be very time-consuming and should be
boiling points make tterr difficult to keeF avoided.
in solution until the foam is dispensed.-
The high pressure helps keep the Freon™ Underwater maintenance on a foaming head
dissal ved ir, the !-01;yol and permi.ts using can be avoided either by bringing the gun
Freons™ with lower boiling poin~s at warmsr up to the surface for maintenance or by
temperatures. An HPIM machire also typi~ making the foaming head reliable enough that
cally requii~s less maintenance, tas a it requires no underwater maintenance.
lighter head, and req~ires less flushing Bringing the head to the surface for main-
of the head. tenance could take as much or more time than
doing the maintenance underwater. Hence
the foaming head must be designed to be
reliable.
High-pressure impingement mixing has
been used successfully on land in RIM Using chemicals efficiently makes an
machines, but it had never before been economical salvage mission out of an other-
used successfully underwater. -Subaquatio ·wise very costly one. Efficiency is defined
use of this method requires some adapta- here as the ratio of the amount of component
tions. Hence tte research objectives of chemicals that become foam to the amount of
the program were to develGp HPIM t@chniqu€s component chemicals dispensed. Efficiency
and equipment for subaquatic use and te is a vital parameter when making foam under-
demonstrate that this pr0QaSS produces water, because MDI will react with water
high quality foam underwater. more readily than with the other foam com-
ponent, polyol. Thus, the nascent foam must
Developing high-pressure impingement be protected from the water until enough of
mixing techniques for underwater use en- the components have reacted for the reaction
tails selecting suitable polyurethane feam to be self-sustaining for the rest of the
components; developing a non-plugging an~ rise time.
reusable head and a mixing cham£er, both
of which will exclude wate~; ensuring that The head and the accessories attached
chemicals are used efficiently and safely; to the head must remain functional despite
and designing the machine and mi·xing the flow of chemicals being burned off and
chamber to be easy to use and maintain. on repeatedly and delays between chemical
use. If the head and accessories were not
Polyurethane foam chemistry can b~ ad- reusable, they would have to be changed
justed to produce foams with many different every time the diver stopped the foaming
properties. For underwater salvage opera~ operation. This is a time-consuming under-
tions, the lightest foam possible is de- water maintenance chore.
sired. Foam having a density of 2 Ib/ft J
in air can be produced. The formulation The ease with which a diver can handle
rBsulting in this density in air will ra~ the head and accessories is crucial to the
suIt in a slightly heavier foam in water successful application of the technique.
due to the higher ambient pressure, in- If the diameter, length, and weight of the
efficiencies, and water entrapment. system are too great, it will be awkward
and tiring for the diver to use. If several
Urethane foams can be eithep flexible divers are needed to handle the head, then
or rigid. Rigid foam is necessary for salvage expense is increased.
salvage. Flexible foam is compressible,
and thus does not have acceptable density Safety is a paramount concern in all
properties under water pressure. machine design. When working with poly-
urethane resin systems, the concern centers
The cream time of a polyurethane fGam on the MDI. This foam component can cause
resin system is defined as the length of a hypersensitive asthmatic reaction in
364
3
OTC 5265 -K. E. Alexander
365
L HIGH PRESSURE IMPINGEMENT MIXING METHOD FOR FOAM-IN-SALVAGE OTC 5265
the orifices in the head are. a function of ;he tank. Foaming was done at ambient air
khe desired flow rate and pressure. temperature ranging from 30°F to 70°F and
~t water temperatures ranging from 48°F to
The i.mpingemen% angle (See Figure 5) is ~5°F. The chemicals were supplied to the
critical in the design of the head. Far–best ?oam machine from 55 gallon drums by transfer
mixing, the impingement angle should be zero lumps . One pair of drums (one of polyol
so that the etreams of polyol and MDI hit on( ~nd one of MDI) lasts for about 9 minutes,
another straight on. This geonetry ensures fhich therefore was the upper limit on con-
the maximum possible turbulence and mixing. tinuous foaming. In the laboratory tests,
However, if the flow rates or pressures of lowever, the small size of the test tank was
the two streams become unequal, this geometr~ ;he real limitation. It was possible to
has the maximum potential for clogging: if ?oam for up to ~ minutes by pushing the foam
flow rates or pressures are uneqtial, one >ff the top of the tank as it was formed.
stream may enter the opposite orifice and
make foam in the head. A solvent flush sys- The field tests were performed in 40
tem must be provided to keep the orifices Lo 50 feet of seawater in the Fort Lauder-
from clogging. Iale area. The air temperature was 60°F and
Lhe water temperature was 70°F.
HEAD ACCESSORIES
The field test object was a steel box,
A mixing chamber is attached to the hea( 1.4 X 1.4 X 1.2 meters (4.5 X 4.5 X 4 ft),
to exclude water from the area where the set on legs. The box was open at the bottom
polyol and MD1 are reacting to form foam. znd had a removable top (see Figure 7).
The MDI is prone to conbining with water in- l’helegs allowed the diver to enter the
stead of with the polyol. If too much of object from below. A weight prevented the
this MDI-water mixing occurs, no foam will object from ascending, even when it was com-
be formed. IF a slight amount of the MDI pletely filled with buoyant foam. The
combines with water, then foaming will occur treight also served as a safety feature for
but the efficiency will be reduced. the tests, preventing an uncontrolled ascent
of the test object.
The length of the mixing chamber is
critical. It depends on the reaction rate. At first, the test object was lined
of the polyurethane foam, which in tiurn de- ~ith plastic to prevent the foam from ad-
pends on the chemical design of the poly- hering to.the walls. However, the foam was
urethane foam resin system, the degree of very easy to remove, even without the plastic
mixing achieved, and the temperature of lining. This was significant because In
the reaction. In designing the mixing cham- past operations, removing foam from salvage
ber, these three variablee were held constan” objects has been quite difficult.
while the length of the mixing chamber was
varied until the optimum length was achieved EXPERIMENTAL
.—- RESULTS
The diameter and length of the mixing cham-
ber are interdependent. The smaller the Figure 8 shows the head with inherently
diameter of the mixing chamber, the faster non-clogging and reusable mixing chamber
the polyurethane foam will be forced from developed during the laboratory and field
the chamber. tests. The head, made from stainless steel,
is designed to operate at chemical pressures
Choosing the appropriate material for of 1000 to 1500 psi. This pressure range is
constructing the mixing chamber is signifi- optimum for thorough mixing, yet low enough
cant in the development of the system. The to keep the head and mixing chamber reason-
mixing chamber contacts water, polyol, MDI, ably lightweight. The head has 3/16-inch-
and. methylene chloride, thus the chosen diameter orifices for both the polyol and
material must stand up to these chemicals, a the MDI, permitting a nominal flow rate of
least in the short kerm. The material shoul 6 gpm. At this flow rate, a 100-ton salvage
be sufficiently durable, both mechanically object can be raised with the buoyancy pro-
and chemically, to last for /+ to 8 hours. duced in 8 hours of foaming.
This minimun life allows salvage personnel
to replace khe mixing chamber at convenient The orifices are positioned such that
times during a salvage mission, such as the streams are not aimed directly at each
during breaks or at the end of the day. other, but are tilted at a slight angle,
which helps prevent head clogging. The angla
TESTING
—. makes the head more tolerant of slight pres-
sure.and flow rate differences between the
The high-pressure impingement mixing polyol and MDI streams. If the impingement
technique was tested both in the laboratory angle is kept at 15 degreee or less, there
and in the field. Figure 6 shows ,the tank is still sufficient mixing to produce good
used as the laboratory equivalent of the quality foam. Also, a narrow impingement
ocean. This tank is 7.8 meters deep by angle causes some forward momentum to be im-
1.6 meters in diameter (6 ft X 5& ft). parted to the reacting components and the
resulting foam. This helps keep the foam
The head was placed at the bottom of moving through the mixing cham~er.
OTC 5265 -. ‘--”-”K.
E. u under ..__. 5
. .
The head has proved to be remarkably Without exception, all rigid PTFE and PVC
clog resistant; nevertheless ;ib_-~a_g_been tubes clogged within 2 minutes of the onset
designed so that all orifices and pas-sage- of foaming. Although polyurethane has ex-
ways can be easily accessed for cleaning. cellent adhesive qualities, the mechanism
of clogging is by mechanical expansion
The head flushing solvent enters the locking rather than by adhesion. The poly-
polyol and MDI channels ups”tream..ofthe urethane foam clogs the tube by expanding
orifices. Laboratory experience has shown until it is force fit within the tube.
that a small amount of polyol and MDI can
seep into the solvent flush lines. If the The flexible mixing chambers are in-
polyol and MDI mix in the presence of khe herently non-clogging. The operator was
methylene chloride solvent, their reaction able to foam for 10 seconds, stop foaming
is severely inhibited, but eventually-these for 10 seconds, foam again for 10 seconds,
chemicals do react. The resulting sub- and repeat this sequence for a number of
stance can clog solvent supply lines. A cycles without clogging the mixing chamber
special feature of the solvent flush system of the head.
is the use of separate flush lines for the
polyol and MDI sides of the head. Using SUMMARY AND CONCLUSIONS
separate flush lines prevents mixing the”
polyol and MDI in the flushing solvent. A high-pressure impingement mixing
Moreover, the lines carrying the solvent head with flexible nixing chamber was de-
and the components have check valves to pre- veloped for the U.S. Navy for producing
vent the backward seepage of chemicals. polyurethane foam underwater. This foam
is to be used to displace water and to pro-
In addition to the check valves- in the vide buoyancy in sunken objects so that the
polyol, MDI and solvent lines, ball valves objects can be raised to the surface for
were installed in the polyol and MDI lines salvage. The head design is vastly simpler
just upstream of the head. Th-a ball valve than other existing impingement mixing de-
handles were ”yoked together so that the signs. The foam-producing system described
diver could shut off both valves at the in this paper features a combination of
same time. These valves stopped seepage high-pressure impingement mixing, a flexi-
from the polyol and MDI lines through “the ble mixing chamber, and ultra fast cream
orifices. time (1 to 2 second) foam.
The optimum mixing chamber was a flexi- The technique of generating p~ly-
ble tube, 9 to 12 inches long by 3 inches urethar:e foam in air by high pressure im-
in diameter. An important characteristic pingement mixing is well known as RIM.
of this chamber is its flexibility, which However, this method has not previously
allows the operator to squeeze the chamber been used to produce polyurethane foam
temporarily shut when foaming begins. ‘This underwater . Earlier systems included rigid
manual shut-off excludes water from the foam mixing chambers and used precision pistons
until the foam has risen enough for the re- and seals to wipe the reacted materials from
action to be self-sustaining for the rest the chamber. These devices are not suitable
of the rise time. In addition, the chamber for subaquatic use because the piston and
flexes slightly as a plug forms, allowing wiping mechanism make the head too large
the plug to be expelled periodically. and too heavy for portability; the rigid
chamber becomes clogged with expanding,
Flexible mixing chambers of fluori- hardening, and adhering foam; and water
nated ethylene propylene (FEP) , butyl rubber migrates into the mixing chamber and chemi-
and gum rubber were all successful. The gum cally combines with the MDI, preventing the
rubber was less satisfactory than the other formation of foam. Also, earlier equipment
two materials because the methylene chloride was designed to produce foam on a very small
flush deteriorated the gum rubber within scale, compared with the volume needed for
minutes of contacting it. Because it is- a salvaging sunken vessels.
fluroplastic, FEP has the lowest coefficient
of friction of the three flexible materials. MDI and polyol are the components that
Nevertheless, despite khe vast difference react to form polyurethane. These compo-
in friction qualities between I?EP and butyl nents are mixed at the impingement site
rubber, both worked quite well. The opera- inside the flexible mixing chamber by the
tor could feel the clogs forming ,and being high-pressure impingement mixing technique.
expelled from the chamber about once every In this technique, two streams of fluid
20 seconds. chemicals, directed at each other at 1000
to 1500 psi, mix instantaneously as the
Rigid-tube mixing chambers were also streams collide. Since the streams are
investigated. Various length of poly- directed at each other at an angle between
tetrafluoroethylene (PTFE) and of polyvinyl O and 15 degrees away from straight on,
chloride (PVC) were used. PTFE is a fluro- some forward momentum is maintained to
plastic, thus it has an extremely low co- spray the foa~ forward. The flexible
efficient of friction compared with PVC. mixing chamber collapses to exclude water
Yet rigid tubes of both materials clogged. and expands to allow the reaching foam to
rise. A chemical solvent flush prevents
6 HIGH PRESSURE IMPINGEMENT MIXING METHOD FOR FOAM-IN-SALVAGE OTC 5265
the head from clogging. Myers, J.R., D.W. Caudy and D.J. Hackman.
Prototyp e Salvage Foaming~tem.
The flush system reliably keeps. the Battelle, 1985.
head from clogging during use. The hixing
chamber inherently does not clog. Access Myers, J.R., K.E. Alexander, D.J. Hackman
for cleaning at the end of a mission is and D.W. Caudy. Protot ype Salvage
easily obtained by disconnecting the chemic- Foaming System. Battelle, 1985.
al supply lines, removing the flextble ~
mixing chamber from the head, and removing
2 plugs.
ACKNOWLEDGEMENTS
~EFERENCES
ON
FLUSH
OFF
7-
2-.
P
t-j9--
P
T
a 1 II=
FLUSHING FLUSHING
1. *- .
/i
VALVE VALVE
,-
1 ,1.
//
..-. -..
20HP
, I
7EMP
CONT b
/(
3
\
ELEC
HEAT
AIR
PRESS
.-
TEMP
CONT
Q-.
Q3
‘f
FROM
PRESSURIZED
POLYOL
SUPPLY
FFROM
PRESSURIZE
MO!
SUPPLY
MD I IN
————
--
—,.
FLEXIBLE FLUSH IN
MIXING
.-.
–..-
.-
.—.-
-----
.--
— -
CHAMBER HOSE CLAMP
\ /
-, .—
3— ——-
~ .——
:—:_ \
FOAMING HEAD
Fig. 8—HPIM head and mixing chamber.