P(saturacion) T(saturacion)

Componente A B C mmHg Celcius

Benceno 6.9056 1211.033 220.79 391.427037506 80.1037313238
Tolueno 6.9533 1343.943 219.377 138.931335159 110.628521308

T 60 C
P 760 mmhg

1) Punto

Calcular la presion total y las fracciones molares de cada sustancia

en la fase de vapor que se encuentran en equlibrio con la mezcla
liquida que se enuentra a 60°C

Peso molecular(benceno) 78 gr/mol

Una mezcla de 50% Benceno y 50% de toluenoen en peso
Peso molecular(tolueno) 92 gr/mol

%masa=masa de
soluto/masa de solucion Benceno 0.64102564 Xb 0.5411764706
Tolueno 0.54347826 Xt 0.4588235294
X(total) 1

P(total) 275.576068 mmhg

Yb 0.76868468
Yt 0.23131532
Y(total) 1
Columna1 Columna2 Columna3 Columna4 P(saturacion) T(saturacion)
Componente A B C mmHg Celcius
Benceno 6.9056 1211.033 220.79 757.5749269221 69.592136767
Tolueno 6.9533 1343.943 219.377 291.1840406748 99.2302864164

Demuestre que a la temperatura de ebullicion de la

mezcla liquida se encuentra a una presion total de 0,715
atm(543mmHg) y a 80 grados centigrados

T 80 C
P(total) 543.4 mmhg

Xb 0.54078235
Xt 0.45921765
X(total) 1

Demostracion
P(total) 543.4
 P(saturacion)T(saturacion)
Componente A B C mmHg Celcius
Benceno 6.9056 1211.033 220.79 1049.06449 80.1037313
Tolueno 6.9533 1343.943 219.377 419.293756 110.628521

T 90.9464295 C
P 760 mmhg

Xb 0.541 Yb 0.74676827 Es necesario utilizar el programa solver p

obtener resultados coherentes con cad
Xt 0.459 Yt 0.25323136 concentracion de liquido
Y total 0.99999963
Kb 1.38034801
Kt 0.55170231

Componente a b c Psat Tsat

benceno 3.98523 1187.24 217.572 9.44163772 385.401362 0.05
ethilbenceno 4.0686 1415.77 212.3 2.69376697 445.257388 0.25
metilbenceno 4.06112 1460.766 207.83 1.8349648 462.75179 0.7
1
T 449.985958
P 2.43

k1 3.88544762 y1 0.19427238
k2 1.10854608 y2 0.27713652
k3 0.75512955 y3 0.52859068
Y(total) 0.99999958
io utilizar el programa solver para
resultados coherentes con cada
oncentracion de liquido
 P(saturacion)T(saturacion)
Componente A B C mmHg Celcius
Benceno 6.90565 1211.033 220.79 759.976747 80.0999934 Condiciones del proceso
Tolueno 6.9533 1343.943 219.377 292.180733 110.628521

T 80.099 C
P 760 mmhg

n 20
h 1.5264264

T(sat)C Pb(Sat) Pt(Sat) Xb Xt Yb Yt

80.0999933616 760 292.190748 1 0 1 0
81.6264197589 796.395287 307.910016 0.92549358 0.07450642 0.96981412 0.03018588
115
83.1528461562 834.141488 324.303419 0.85457836 0.14542164 0.9379464 0.0620536
84.6792725536 873.27248 341.391772 0.78703405 0.21296595 0.90433576 0.09566424
110
86.2056989509 913.822474 359.196235 0.72265561 0.27734439 0.86891966 0.13108034
87.7321253482 955.826006 377.738302 0.66125208 0.33874792 0.83163413 0.16836587 105
89.2585517456 999.317929 397.039809 0.60264549 0.39735451 0.79241374 0.20758626
90.7849781429 1044.3334 417.122921 0.54666988 0.45333012 0.7511916 0.2488084 100
92.3114045402 1090.90788 438.010135 0.49317043 0.50682957 0.70789936 0.29210064

Axis Title
95
93.8378309376 1139.07712 459.724273 0.4420026 0.5579974 0.66246717 0.33753283
95.3642573349 1188.87714 482.288483 0.39303138 0.60696862 0.61482372 0.38517628 90
96.8906837322 1240.34425 505.726229 0.34613059 0.65386941 0.56489617 0.43510383
98.4171101296 1293.51502 530.061293 0.30118225 0.69881775 0.51261021 0.48738979 85
99.9435365269 1348.42625 555.317769 0.25807596 0.74192404 0.45788999 0.54211001
101.4699629242 1405.11502 581.520057 0.21670839 0.78329161 0.40065819 0.59934181 80

102.9963893216 1463.61863 608.692863 0.17698278 0.82301722 0.34083591 0.65916409

75
104.5228157189 1523.97458 636.861189 0.13880842 0.86119158 0.27834277 0.72165723 0 0.1
106.0492421162 1586.22064 666.050335 0.1021003 0.8978997 0.21309685 0.78690315
107.5756685136 1650.39474 696.28589 0.06677866 0.93322134 0.14501467 0.85498533
109.1020949109 1716.53502 727.593726 0.03276865 0.96723135 0.07401124 0.92598876
110.6285213082 1784.67983 760 -2E-15 1 -4.9502E-15 1
Condiciones del proceso presion constante 760 mmHg

Grafico Txy
115

110

105

100
Axis Title

Burbuja
95
Roci o

90

85

80

75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xy
 P(saturacion) T(saturacion)
Componente A B C mmHg Celcius
Benceno 6.90565 1211.033 220.79 757.66215098 80.0999934 Condiciones del proc
Tolueno 6.9533 1343.943 219.377 291.18404067 110.628521

T 80 C
P 760 mmhg

n 20
h 0.05

xb P(total) yb
0 291.184041 0 Pxy
0.05 314.507946 0.12045199
780
0.1 337.831852 0.22427197
0.15 361.155757 0.3146823
0.2 384.479663 0.3941234 680
0.25 407.803568 0.46447739
0.3 431.127474 0.52721912
0.35 454.451379 0.58352062 580
Temperatura C

0.4 477.775285 0.63432511 Burbuja

0.45 501.09919 0.68040016 Roci o
480
0.5 524.423096 0.7223768
0.55 547.747001 0.76077857
0.6 571.070907 0.79604351 380
0.65 594.394812 0.82854088
0.7 617.718718 0.85858416
0.75 641.042623 0.88644123 280
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.8 664.366529 0.91234235
0.85 687.690434 0.93648653 xy
0.9 711.01434 0.95904667
0.95 734.338245 0.98017371
1 757.662151 1
 Condiciones del proceso temperatura constante 80 C

xy
1
0.9
0.8
0.7
0.6 xy
Burbuja 0.5
Roci o
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.8 0.9 1