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ASSIGNMENT BOOKLET
Organic Chemistry
Please Note
You can take electives (56 to 64 credits) from a minimum of TWO and a
maximum of FOUR science disciplines, viz. Physics, Chemistry, Life
Sciences and Mathematics.
You can opt for elective courses worth a MINIMUM OF 8 CREDITS and a
MAXIMUM OF 48 CREDITS from any of these four disciplines.
At least 25% of the total credits that you register for in the elective
courses from Life Sciences, Chemistry and Physics disciplines must be
from the laboratory courses. For example, if you opt for a total of 64
credits of electives in these 3 disciplines, at least 16 credits should be
from lab courses.
School of Sciences
Indira Gandhi National Open University
New Delhi
(2017)
1
Dear Student,
We hope, you are familiar with the system of evaluation to be followed for the Bachelor’s Degree
Programme. At this stage you may probably like to re-read the section on assignments in the Programme
Guide that we sent you after your enrolment. A weightage of 30 percent, as you are aware, has been
earmarked for continuous evaluation, which would consist of one tutor-marked assignment. The
assignment is based on Blocks 1, 2, 3 and 4.
Instructions for Formatting Your Assignments
Before attempting the assignments, please read the following instructions carefully.
1 On top of the first page of your answer sheet, please write the details exactly in the following
format:
ENROLMENT NO.….………………….………
NAME:…………..…………………
ADDRESS:.…..............………………
………………………………
………………………………
COURSE CODE : …..........................…………
COURSE TITLE : …..........................…………
2 Use only foolscap size writing paper (but not of very thin variety) for writing your answers.
3 Leave 4 cm margin on the left, top and bottom of your answer sheet.
5 While writing answers, clearly indicate the Question No. and part of the question being solved.
7 We strongly suggest that you should retain a copy of your assignment responses.
Wishing you all good luck.
2
Tutor Marked Assignment
Organic Chemistry
Course Code: CHE-05
Assignment Code: CHE-05/TMA/2017
Maximum Marks: 100
Note: * This assignment is based on all the four Blocks of the entire course.
* All questions are compulsory. Marks for the questions are shown within brackets on the right hand side.
* Please answer in your own words; do not copy from the course material.
O
(i) CH CHCCH 3
NHCH 3
(iii)
3
6. a) How would you prepare alkanes from the following (Give only one example)? (3)
(i) Alkyl halide
(ii) Carboxylic acid
(iii) Alkene
b) Explain the following: (2)
(i) In the mass spectra, alkanes give a series of peaks separated by 14 mass units.
(ii) Alkanes with odd number of carbon atoms have lower melting point than those
with an even number of carbon atoms.
7. a) Explain the following briefly: (3)
(i) Alkenes are more soluble in water than corresponding alkanes.
(ii) Addition reactions of alkenes are exothermic processes.
(iii) Hydroboration appear as anti-Markownikoff’s addition.
b) An alkene having molecular formula C6H12 an ozonolysis yielded butanal and (2)
ethanal. What is the structural formula of alkene?
8. a) Explain the following: (2)
(i) Alkynes are more acidic than alkanes.
(ii) In NMR, the value of alkynyl proton is less than the value of alkenyl proton.
b) How would you prepare the following? (3)
(i) 3-Octyne from 1-hexyne
(ii) 1,2-Dibromoethene from ethyne
(iii) Ethanal from ethyne
9. a) Explain the following: (2)
(i) The theoretical value of heat evolved, when hydrogens are added to benzene,
is quite high as compared to the experimental value.
(ii) Nitrobenzene not undergo Friedel-Crafts alkylation.
b) Write all the possible resonance structures of cation formed from ortho nitration (1)
of methyl benzene.
c) What do you understand by para-directing activators, para- directing deactivators (2)
and meta-directing deactivators?
10. a) Explain the following: (22)
(i) 1-Position in naphthalene is more reactive than the 2-position towards
electrophilic substitution.
(ii) Pyrrole is more basic than pyridine.
b) Predict the products of the following reactions:
(i) Oxidation of propylbenzene
(ii) Friedel-Crafts acylation of pyrrole
(iii) Friedel-Crafts alkylation of pyridine
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11. Complete the following reactions. Predict whether each reaction proceeds (5)
predominantly by SN1 or SN2 or E1 or E2.
Br NaOH
(a) (b) NaCN
353 K, H2O Cl
DMF
C2H5ONa
(c) (d) C2H5OH
Cl Ethanol
Br Ethanol
(e) 306 K
Br + (C2H5)3N
CH2Cl2
12. Complete the following reaction and write its mechanism. (5)
aq HBr
OH
13. Taking suitable examples discuss the Zeisel procedure used for estimation of (5)
methoxy group in alkyl aryl ethers.
14. Write the chemical reactions for the different methods used for the reduction of (5)
aldehydes and ketones.
15. Explain Fischer esterification with the help of a suitable example. (5)
16. Give the products of the following reactions: (5)
HBr
(i) CH 2 CHCOOH ?
V2O5 hydrolysis
(iii) ? ?
+
H / H2O
(iv) CH 2CH 2CN ?
alc. KOH
(v) CH 3CHClCH 2COOH ?
17. Explain the following reactions using suitable examples: (5)
(i) Rosenmund reduction
(ii) Transesterification
18. Give the products of reduction of nitrobenzene under acidic, alkaline and neutral (5)
conditions.
19. Explain the following reactions and their utility: (5)
(i) Sandmeyer reaction
(ii) Diazo coupling
20. Illustrate Edman degradation and explain its importance. (5)
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