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Article history: The treatment and disposal of sewage sludge are significant environmental problems in China. The reuse
Received 3 December 2009 of sewage sludge for fuel could be an effective solution. The aim of this study was to characterize the
Accepted 9 March 2010 behavior of sludge-derived fuel during combustion by a thermogravimetric method. The combustion pro-
Available online xxxx
files obtained showed four obvious weight loss regions. The results of dynamics analysis showed that
first-order reactions together with Arrhenius’ law explained reasonably well the different stages of
weight loss in the samples. Three temperature regions (162–327 °C, 367–445 °C, and 559–653 °C for saw-
dust and 162–286 °C, 343–532 °C, and 609–653 °C for coal) in each derivative thermogravimetry (DTG)
curve corresponded well with the Arrhenius equation. The reactivity of sludge was lower than that of
samples containing sawdust, but higher than that of coal-containing samples. These data demonstrate
that sludge-derived fuel has better combustion characteristics than sludge, sawdust, or coal.
Ó 2010 Elsevier Ltd. All rights reserved.
0956-053X/$ - see front matter Ó 2010 Elsevier Ltd. All rights reserved.
doi:10.1016/j.wasman.2010.03.009
Please cite this article in press as: Jiang, J., et al. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste
Management (2010), doi:10.1016/j.wasman.2010.03.009
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Table 1
Characterization of materials.
Sample Moisture Volatiles Ashes Fixed carbon C (d.b.) H (d.b.) N (d.b.) S (d.b.) Cl (d.b.) HHV (d.b.)
content (%) (d.b.) (%) (d.b.) (%) (d.b) (%) (%) (%) (%) (%) (%) (kcal/kg)
Sewage sludge 73.57 43.67 52.85 3.48 35.08 5.48 3.63 1.42 0.16 2591
Coal 1.75 13.48 26.45 60.07 62.14 – 0.75 – 5212
Sawdust 12.71 82.52 1.38 16.10 50.54 – 0.04 – 4531
Please cite this article in press as: Jiang, J., et al. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste
Management (2010), doi:10.1016/j.wasman.2010.03.009
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Table 2
Sample composition of sewage sludge-derived fuel in grams. (a) 0.6
Sludge Auxiliary fuels Preservatives Binder agents 0.5
ash content/%
(60% moisture)
Coal Sawdust 0.4
Sludge 400 0 0 8 8
0.3
M2 400 80 0 8 8
coal
M3 400 160 0 8 8 0.2
M4 400 240 0 8 8 sawdust
M5 400 320 0 8 8 0.1
J2 400 0 80 8 8
J3 400 0 160 8 8 0
J4 400 0 240 8 8 0 0.5 1 1.5 2
J5 400 0 320 8 8
ratio of auxiliary fuel to sludge/g·g -1
In contrast, when coal served as the auxiliary fuel, the ash, and (b) 0.9
volatile matter content in the samples decreased slightly, and the 0.8
volatiles content/%
fixed carbon content increased notably. When the proportion of 0.7
coal was increased to 2, the ash content was reduced to 38.84%, 0.6 coal
which is about 70% of that in sewage sludge. Using this proportion 0.5 sawdust
of coal decreased the volatile matter content to 35.49%; the fixed 0.4
carbon content increased to 25.67%, and the heating value in-
0.3
creased to 4029 kcal/kg.
0.2
0.1
3.2. Combustion performance analysis 0 0.5 1 1.5 2
ratio of auxiliary fuel to sludge/g·g -1
Fig. 3 shows the combustion curves – weight loss curves (TG)
and weight loss rate curves (DTG) – of sewage sludge and other (c) 0.3
samples. As shown in Fig. 3b and d, each of the DTG curves from coal
(b)
all samples had four peaks, representing the water content sepa- fixed carbon content/% 0.25 sawdust
rating phase, the emanation of volatile matter, the combustion of 0.2
volatile matter, and the combustion of fixed carbon. The burning
profiles for the samples using the two different auxiliary fuels 0.15
are shown. 0.1
In Fig. 3b, sawdust dose-dependently increased the weight loss
speed of the second phase compared to the third phase; increased 0.05
quantities of sawdust increased the difference between the weight 0
loss speed phases. The onset temperature for volatile release and 0 0.5 1 1.5 2
weight loss of all samples were close. However, as the proportion ratio of auxiliary fuel to sludge/g·g-1
of sawdust increased, the maximum weight loss rate in volatile re-
lease phase increased notably, and the combustion of volatiles
started earlier. In the forth phase, the combustion of fixed carbon
(d) 5000
started at lower temperature when sawdust added.
heating value/kcal·kg-1
4000
In contrast, when coal was used, the weight loss speed of the
second phase was notably lower than that of the third phase, and 3000
increased quantities of coal decreased the weight loss speed in
2000 coal
the second phase and increased the weight loss speed in the third
phase. As the increase of coal proportion, the maximum weight sawdust
loss rate of volatiles decreased gradually and the combustion 1000
started later.
0
0 0.5 1 1.5 2
3.3. Dynamics analysis
ratio of auxiliary fuel to sludge/g·g -1
The kinetic equation of the combustion process of each sample Fig. 2. The results of proximate analyses for the samples: (a) ash content; (b)
can be expressed as follows (Qin et al., 2004): volatiles content; (c) fixed carbon content; and (d) heating value.
da
¼ kf ðaÞ;
dt da E
¼ kf ðaÞ ¼ A exp ð1 aÞn ;
where a is the conversion rate of combustion products or the weigh dt RT
loss rate of the samples in this experiment, t is the time, and k is the
reaction rate constant. and calculation of the natural logarithm of both sides yields
Assuming that the combustion reaction is an nth-order simple
reaction, then
da E
n ln ð1 aÞn ¼ þ ln A:
f ðaÞ ¼ ð1 aÞ : dt RT
Application of the Arrhenius equation over the above formulas Let Y ¼ ln ð1 aÞn ddta , and X ¼ T1, and the above equation can
gives be expressed as a linear equation as follows:
Please cite this article in press as: Jiang, J., et al. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste
Management (2010), doi:10.1016/j.wasman.2010.03.009
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Fig. 3. TG and DTG curves for the samples: (a) weight loss curves for samples added coal; (b) weight loss rate curves for samples added coal; (c) weight loss curves for
samples added sawdust; and (d) weight loss rate curves for samples added sawdust.
E well with the Arrhenius equation. The durations were 5.61 min,
Y ¼ X þ ln A:
R 3.49 min, and 2.17 min, respectively, and the weight loss rates
The combustion of the samples can be recognized as a series of were 10.1%, 9.2%, and 2.1%, respectively. The correlation coeffi-
first-order reactions. From the TG and DTG profiles, the tempera- cients of the linear fitting equations of the three phases were all
ture, sample weight, and weight loss rate at any time can be ob- above 0.97. The data obtained show that each of the Y–X curves
tained, and the corresponding Y and X can be calculated. Take of all samples has three lines with negative slope during the heat-
sludge as an example, using the data obtained from the TG and ing process, fitting well with the Arrhenius equation in three
DTG profiles, Y and X can be calculated. In the Y–X curve, there phases (Fig. 4). The activation energy, E, and the frequency gene,
are three lines with negative slope. These three phases of sludge A, can be calculated by linear fitting. Table 3 shows the kinetic
are 162–274 °C, 367–437 °C, and 609–653 °C, which fit relatively parameters of all samples.
Please cite this article in press as: Jiang, J., et al. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste
Management (2010), doi:10.1016/j.wasman.2010.03.009
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(a) 4.0
sludge
3.5 J5
J4
3.0
J3
J2
2.5
2.0
ln (k)
1.5
1.0
0.5
0.0
0.0010 0.0012 0.0014 0.0016 0.0018 0.0020 0.0022 0.0024
-0.5
1/T
1.5
ln (k)
1.0
0.5
0.0
0.0010 0.0012 0.0014 0.0016 0.0018 0.0020 0.0022 0.0024
-0.5
-1.0
1/T
Fig. 4. Arrhenius plots for the combustion of different samples: (a) samples added coal and (b) samples added sawdust.
When sawdust served as the auxiliary fuel, the starting temper- When coal was adopted as the auxiliary fuel, the first phase
ature of the first phase was 162–171 °C, and the end-point temper- starting-point and end-point temperatures were 162–194 °C and
ature was 274–327 °C. As the proportion of sawdust increased, the 274–286 °C, respectively. With increased proportions of coal dust,
duration rose from 5.61 min to 8.22 min, and the weight loss rate the weight loss rate fell from 10.l% to 3.8%. In the second phase, the
increased from 10.1% to 37.8%. For the second phase, the start- starting-point and end-point temperatures were 343–400 °C and
ing-point and end-point temperatures were 367–375 °C and 407– 437–532 °C, respectively. As the proportion of coal dust increased,
445 °C, respectively. The duration increased from 1.68 min to the duration rose from 3.49 min to 9.35 min, and the weight loss
3.51 min, and the weight loss rate also increased from 5.8% to rate increased from 9.2% to 37.5%. In the third phase, the start-
9.2%. The beginning and end temperatures for the third phase were ing-point and end-point temperatures were 609–621 °C and 640–
559–609 °C and 627–653 °C, respectively; the duration increased 653 °C. As the proportion of coal dust increased, the duration rose
from 2.15 min to 3.36 min, and the weight loss rate rose from from 1.04 min to 2.17 min, and the weight loss rate increased from
1.3% to 2.1%. 0.8% to 2.1%.
Please cite this article in press as: Jiang, J., et al. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste
Management (2010), doi:10.1016/j.wasman.2010.03.009
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Table 3
Kinetic parameters of the samples.
As sawdust added, the starting temperature increased slightly in respectively, and the activation energy and the frequency gene of
the second stage, but decreased notably in the third stage, from the first and second stages were 62.3 kJ/mol, 2.3E+5 min1, and
609 °C to 559 °C. The ending temperature in the third stage de- 56.5 k J/mol, 1.2E+3 min1. As the increase of coal, E and A were
creased from 653 °C to 627 °C, indicating that the samples can be not accordingly affected. Comparing to the results in this paper,
incinerated under lower temperature. As coal added, the starting the kinetic parameters of combustion process of different sludge
temperature of the first stage increased significantly from 162 °C varies significantly. The combustion characteristics are relevant
to 193 °C. The ending temperature in the third stage decreased from to the content and also to the structure of the samples. The com-
653 °C to 644 °C. These data showed that the combustion character- bustion characteristics of coal and sludge blends (Folgueras et al.,
istics of the samples were significantly influenced by the addition of 2004; Liu et al., 2006) are quite different from the SDF made by
auxiliary fuel. The sawdust includes more volatiles, while the coal in- coal and sludge.
cludes more fixed carbon. The more the volatile matter is, the easier
the samples can be ignited. The more the fixed carbon is, the more 3.4. Reactivity assessment by weighted mean activation energy
furious the combustion can be and also the more energy can be ob-
tained (Guan, 2008). The decrease of the ending temperature in Cumming (1984) put forward the concept of the weighted mean
the third stage suggests that SDF can be burnt under lower activation energy, namely,
temperature.
As shown in Table 3, the reactivity of the sample increased with Em ¼ F 1 E1 þ F 2 E2 þ þ F i Ei þ ;
increased quantities of sawdust added to the fuel; J5 was the most
where Em is the weighted mean activation energy, F i is the matter
reactive sample at all three stages. In contrast, addition of coal de-
quality percentage of the action in some phase, and Ei is the activa-
creased the reactivity of the samples, and in this group the sludge
tion energy for the phase. F i is calculated from Table 3, and Ei is
itself was most reactive. By Folgueras et al. (2004), sludge, coal, and
shown in Table 3. The weighted mean activation energy of the sam-
their blends were tested. In the Arrhenius plot for each type of
ples can be then calculated accordingly (Fig. 5). When the propor-
sludge and its blends with coal, there are two wide regions of lin-
tion of sawdust increased from 0 to 2, the weighted mean
earity in which sludge is the most reactive material. These results
activation energy increased 2.75-fold from 10,153 J/mol to
are consistent with the findings in this paper.
27,960 J/mol. When the proportion of coal added to the sludge in-
By Liu et al. (2006), the ash, volatile matter, and fixed carbon
creased from 0 to 2, the weighted mean activation energy increased
content of sludge used were 54.09%, 38.23%, and 2.88%, respec-
2.16-fold from 10,153 J/mol to 21,907 J/mol. Therefore, the
tively, which were close to the content of sludge in this paper.
weighted mean activation energy of the sludge fuel with sawdust
The starting temperature of the three stages were 215 °C, 430 °C,
was higher than that of the sludge fuel with coal.
and 712 °C, and the activation energy and the frequency gene of
the first and second stages were 41.783 kJ/mol, 7E+3 min1, and
46.377 kJ/mol, 2E+3 min1, respectively. As the increase of coal, E 4. Conclusions
and A of the first stage decreased, while E and A of the second stage
increased. By Folgueras et al. (2004), the ash, volatile matter and A series of thermogravimetric tests on sludge-derived fuel were
fixed carbon content of F sludge were 49.6%, 44.0%, and 6.4%, performed with different ratios of sludge to coal/sawdust. Combus-
Please cite this article in press as: Jiang, J., et al. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste
Management (2010), doi:10.1016/j.wasman.2010.03.009
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Acknowledgement Beijing.
Please cite this article in press as: Jiang, J., et al. Analysis of the combustion of sewage sludge-derived fuel by a thermogravimetric method in China. Waste
Management (2010), doi:10.1016/j.wasman.2010.03.009