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ME271
Chapter 7
Lecture 2
Entropy
Reminder
Chapter 7 - Lecture 2
Objectives
Reminder
Today’s
Subjects - Chapter 7 - Lecture 1 -
7.1-Introduction
& Definitions
7.1 Entropy
7.2-Entropy Clausius inequality:
Increase Principle
7.1-Introduction
& Definitions 7.2 The Increase of Entropy Principle
7.2-Entropy
Increase Principle Some remarks about entropy.
7.3-Entropy Change
of Pure Subs.
7.3 Entropy Change of Pure Substances
7.4-Entropy
Processes Example
7.5-Entropy
Property Diagrams
7.6-What is
Entropy ?
Summary
Chapter 7
Examples
7.5-Entropy
Property Diagrams
→
7.6-What is
Entropy ? Fig. 7.5
Summary A cycle composed of reversible
Chapter 7 and irreversible processes.
Examples
→ (7.7) → (7.8)
where: - = holds for a reversible process & represents the entropy transfer with heat.
7.3-Entropy Change
of Pure Subs.
7.4-Entropy
Processes
7.5-Entropy Conclusions:
Property Diagrams
7.6-What is
• Processes can occur in a certain direction only, not in any
Entropy ? direction.
Summary • A process must proceed in the direction that complies with
Chapter 7
the increase of entropy principle, that is: Sgen ≥ 0.
Examples
• A process that violates this principle is impossible.
• Entropy is a nonconserved property, and there is no such
Fig. 7.8
thing as the conservation of entropy principle. The entropy change of a
system can be negative, but
• The performance of engineering systems is degraded by the the entropy generation cannot.
presence of irreversibilities, and entropy generation is a
measure of the magnitudes of the irreversibilities during
that process.
Fig. 7.11
Examples
Schematic of the T-s
diagram for water.
Fig. 7.10
The entropy of a pure substance
is determined from the tables
(like other properties).