1.

Write balance net ionic equation for the following oxidation-reduction reaction :

a. Hydrogen sulfide is added to solution of Fe(NO3)3.

b. Hydrogen peroxide is added to an acidic solution of an iron (II) salt.

c. The Mn2+ ion is oxidized to MnO2 by KClO3 in acidic solution (assuming

reduction of ClO3- to Cl-).

d. The Cr2O72- complex ion is reduced to Cr3+ by H2S in acidic solution.

e. The compound Co(OH)2 is oxidized to Co(OH)3 upon standing in contact with air.

Answer :

1.

a. H2S dengan Fe(NO3)3

Reaksi ionik : 2Fe3+ +

(aq) + H2 S(g) → FeS(s) ↓ (hitam) + 2H(aq)

b. H2O2 dengan Fe2+

Reaksi ionik : 2Fe2+ + 3+

(aq) + H2 O2(aq) + 2H(aq) → 2Fe(aq) + H2 O(aq)

c. Mn2+ menjadi MnO2 dengan ClO3-

Mn2+
(aq) → MnO2(aq)

ClO−
3(aq) → Cl−
(aq)

Mn2+ − −
(aq) + ClO3(aq) → MnO2(aq) + Cl(aq)

d. Cr2O72- menjadi Cr3+ dengan H2S

+ 3+
reaksi ionik ∶ Cr2 O2−
7(aq) + 8H(aq) + 3H2 S(g) → 2Cr(aq) + 3S ↓ (kuning) + 7H2 O(aq)

e. Co(OH)2 menjadi Co(OH)3 dengan udara

Reaksi ionik : Co(OH)2 + O2 → Co(OH)3

7. indicate how you would determine wether the ions listed as questionable in
problem 6 are present.
 Sampel

H2S
FeS, Al( (OH)3 , ZnS, NiS, MnS, Cr(OH)3, CoS, CdS

HCl

CoS, NiS Fe3+, Al3+, Zn2+, Mn2+, Cd2+, Ni2+, Cr3

NaClO, NaOH

Fe((OH)3, MnO2 Ni(OH)2 ,Cd(OH)2 CrO42-, Al(OH)4-, Zn(OH)42-

H2SO4

MnO2 Fe3+, Cd2+, Ni2+

Yang dipertanyakan : Fe3+, Cd2+, Ni2+

Yang ada : MnO2
Yang tidak ada : CrO42-, Al(OH)4-, Zn(OH)42-
106. A Group III unknown exhibits the following behavior. State which ions are present,
which are absent, and which are questionable.
Addition of NH3 and NH4Cl to the unknown gives a reddish precipitate that turn black when
H2S is added. The final precipitate is completely soluble in HCl. Treatment of the HCl
solution with NaClO and NaOH gives a colorless solution and a precipitate that is completely
soluble in H2SO4.

Sampel
NH3, NH4Cl, H2S
FeS, Al( (OH)3 , ZnS, NiS, MnS, Cr(OH)3, CoS, CdS

HCl

CoS, NiS Fe3+, Al3+, Zn2+, Mn2+, Cd2+, Ni2+, Cr3

NaClO, NaOH

Fe((OH)3, MnO2 Ni(OH)2 ,Cd(OH)2 CrO42-, Al(OH)4-, Zn(OH)42-

H2SO4

MnO2 Fe3+, Cd2+, Ni2+

Yang dipertanyakan : Al3+, Zn2+

Yang ada : Fe3+,
Yang tidak ada : Mn2+, Co2+, Ni2+, Cr3+
8. An unknown that may contain any of the ions in Groups II and III is analyzed with the
following results. Indicate, for each of the ions in these two groups, whether it is present,
absent, or questionable.
Addition of H2S in acidic solution gives a precipitate that is partially soluble in NaOH. The
precipitate remaining is dissolved in HNO3 and treated with NH3 to give a colored solution
and no precipitate. On acidification with HCl, the NaOH solution gives a precipitate that is
completely sluble in hot HCl. Treatment of the solution remaining after removal of Group II
ions with H2S in basic solution gives a pure white precipitate.
 Sampel

H2S
FeS, CuS, Bi2S3, PbS, SnS2,Sb2S3, Sb2S5, HgS, ZnS, NiS, MnS, CoS, CdS

NaOH

Sn(OH)62-, Sb(OH)4- FeS, CuS, Bi2S3, PbS, HgS, ZnS, NiS, MnS, CoS, CdS
HNO3
Cu2+, Bi3+, Cd2+, Pb2+

NH3
Yang hadir : Cu2+, Cd2+
Cu(NH3)42+, Cd(NH3)42+ , biru
Yang absen : Al3+, Cr3+
Yang dipertanyakan : Fe3+, Zn2+, Co2+, Ni2+, Cd2+ , Mn2+
110. A solid unknown may contain any of the sulfides PbS, Bi2S3, FeS, NiS, and Al2S3. The
solid is completely insoluble in concentrated NaOH. It is partially soluble in cold, dilute HCl.
Following the treatment with HCl, the precipitate is brough into solution with HNO3. When
this solution is treated with NH3, no precipitate forms.
On the basis of this information, identify the solid as completely as possible.

PbS, Bi2S3, FeS, NiS, Al2S3

NaOH
Fe(OH)3, Bi2S3, PbS, Ni(OH)2, Al(OH)3
HCl

PbCl2 Bi3+, Fe3+, Ni2+

NH3

Fe(OH)3 Ni(NH3)62+

Yang hadir : Ni2+

Yang absen : Pb2+, Fe3+
Yang dipertanyakan : Bi3+, Al3+