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·¤æðÇU Ù´.
Code No. 56/2/N
ÚUæðÜ Ù´. ÂÚUèÿææÍèü ·¤æðÇU ·¤æð ©æÚU-ÂéçSÌ·¤æ ·ð¤ ×é¹-ÂëcÆU
Roll No. ÂÚU ¥ßàØ çܹð´Ð
Candidates must write the Code on the
title page of the answer-book.
· ·ë¤ÂØæ Áæ¡¿ ·¤ÚU Üð´ ç·¤ §â ÂýàÙ-Âæ ×ð´ ×éçÎýÌ ÂëcÆU 15 ãñ´Ð
· ÂýàÙ-Âæ ×ð´ ÎæçãÙð ãæÍ ·¤è ¥æðÚU çΰ »° ·¤æðÇU ÙÕÚU ·¤æð ÀUææ ©æÚU-ÂéçSÌ·¤æ ·ð¤ ×é¹-ÂëcÆU ÂÚU çܹð´Ð
· ·ë¤ÂØæ Áæ¡¿ ·¤ÚU Üð´ ç·¤ §â ÂýàÙ-Âæ ×ð´ 26 ÂýàÙ ãñ´Ð
· ·ë¤ÂØæ ÂýàÙ ·¤æ ©æÚU çܹÙæ àæéM¤ ·¤ÚUÙð âð ÂãÜð, ÂýàÙ ·¤æ ·ý¤×æ´·¤ ¥ßàØ çܹð´Ð
· §â ÂýàÙ-Âæ ·¤æð ÂɸÙð ·ð¤ çÜ° 15 ç×ÙÅU ·¤æ â×Ø çÎØæ »Øæ ãñÐ ÂýàÙ-Âæ ·¤æ çßÌÚUæ Âêßæüq ×ð´
10.15 ÕÁð ç·¤Øæ Áæ°»æÐ 10.15 ÕÁð âð 10.30 ÕÁð Ì·¤ ÀUææ ·ð¤ßÜ ÂýàÙ-Âæ ·¤æð Âɸð´»ð ¥æñÚU §â
¥ßçÏ ·ð¤ ÎæñÚUæÙ ßð ©æÚ-ÂéçSÌ·¤æ ÂÚU ·¤æð§ü ©æÚU Ùãè´ çܹð´»ðÐ
· Please check that this question paper contains 15 printed pages.
· Code number given on the right hand side of the question paper should be written
on the title page of the answer-book by the candidate.
· Please check that this question paper contains 26 questions.
· Please write down the Serial Number of the question before attempting
it.
· 15 minute time has been allotted to read this question paper. The question paper
will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will
read the question paper only and will not write any answer on the answer-book
during this period.
56/2/N 1 P.T.O.
âæ×æØ çÙÎðüàæ Ñ
(ii) ÂýàÙ â´Øæ 1 âð 5 Ì·¤ ¥çÌ Üæé-©æÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýØð·¤ ÂýàÙ ·ð¤ çÜ° 1 ¥´·¤ ãñÐ
(iii) ÂýàÙ â´Øæ 6 âð 10 Ì·¤ Üæé-©æÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýØð·¤ ÂýàÙ ·ð¤ çÜ° 2 ¥´·¤ ãñ´Ð
(iv) ÂýàÙ â´Øæ 11 âð 22 Ì·¤ Öè Üæé-©æÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýØð·¤ ÂýàÙ ·ð¤ çÜ° 3 ¥´·¤ ãñ´Ð
(v) ÂýàÙ â´Øæ 23 ×êËØæÏæçÚUÌ ÂýàÙ ãñ ¥æñÚU §â·ð¤ çÜ° 4 ¥´·¤ ãñ´Ð
(vi) ÂýàÙ â´Øæ 24 âð 26 Ì·¤ Îèæü-©æÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýØð·¤ ÂýàÙ ·ð¤ çÜ° 5 ¥´·¤ ãñ´Ð
(vii) ØçÎ ¥æßàØ·¤Ìæ ãæð, Ìæð Üæò» ÅðUÕÜæð´ ·¤æ ÂýØæð» ·¤Úð´UÐ ·ñ¤Ë·é¤ÜðÅUÚUæ𴠷𤠩ÂØæð» ·¤è ¥Ùé×çÌ Ùãè´ ãñÐ
General Instructions :
(ii) Questions number 1 to 5 are very short answer questions and carry 1 mark each.
(iii) Questions number 6 to 10 are short answer questions and carry 2 marks each.
(iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each.
(vi) Questions number 24 to 26 are long answer questions and carry 5 marks each.
56/2/N 2
1. ·¤æðÜæ§ÇUè âæòÜ ·¤è çSÍÚUÌæ ·ð¤ çÜØð ·¤æÚUæ çÜç¹°Ð
2. »×ü ·¤ÚUÙð ÂÚU ZnO ÂèÜð Ú´U» ·¤è ãæð ÁæÌè ãñÐ Øæð´?
3. Pb(NO3)2 ·¤æð »×ü ·¤ÚUÙð ÂÚU °·¤ ÖêÚðU Ú´U» ·¤è »ñâ çÙ·¤ÜÌè ãñ çÁâ·¤æ Æ´UÇðU ãæðÙð ÂÚU
çmÜ·¤è·¤ÚUæ ãæð ÁæÌæ ãñÐ »ñâ ·¤è Âã¿æÙ ·¤èçÁ°Ð
56/2/N 3 P.T.O.
5. çÙÙçÜç¹Ì Îæð ¥çÖç·ý¤Øæ¥æð´ ×ð´ âð ·¤æñÙ SN2 ãñ ¥æñÚU Øæð´?
(i)
(ii)
(i)
(ii)
56/2/N 4
Write the chemical equations involved in the following reactions :
(i) Kolbes reaction
(ii) Friedal - Crafts acetylation of anisole
OR
How do you convert :
(i) Phenol to toluene
(ii) Formaldehyde to Ethanol
Pt → N (g) 1 3H (g)
7. °·¤ ¥çÖç·ý¤Øæ 2NH3 (g) 2 2
ÎÚU 5 k
(i) §â ¥çÖç·ý¤Øæ ·¤è ·¤æðçÅU ¥æñÚU ¥æéÌæ çÜç¹°Ð
(ii) k ·¤è ØêçÙÅU çÜç¹°Ð
Pt → N (g) 1 3H (g)
For a reaction : 2NH3 (g) 2 2
Rate 5 k
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.
8. (i) ©â ¥æéâ´Ø »éæÏ×ü ·¤æð çÜç¹° Áæð »éL¤ ¥æé¥æ𴠷𤠥ææçß·¤ ÎýÃØ×æÙ ·¤æð ææÌ ·¤ÚUÙð
×ð´ ÂýØæð» ×ð´ ¥æÌæ ãñÐ
(ii) ¥ÙæÎàæü çßÜØÙ ×ð´ çß¿ÜÙ ·¤æ ·¤æñÙ âæ Âý·¤æÚU ØêÙÌ× ßÍÙ °çÁØæðÅþUæ ·ð¤ çÙ×æüæ ·¤æð
ÎàææüÌæ ãñ?
(i) Write the colligative property which is used to find the molecular mass
of macromolecules.
(ii) In non-ideal solution, what type of deviation shows the formation of
minimum boiling azeotropes ?
56/2/N 5 P.T.O.
10. ÁÕ ©Ââãâ´ØæðÁ·¤ Øæñç»·¤ NiCl2.6H2O ·¤æð AgNO3 ·ð¤ âæÍ ç×ÜæØæ ÁæÌæ ãñ ÌÕ Øæñç»·¤
·ð¤ ÂýçÌ ×æðÜ ÂÚU AgCl ·ð¤ Îæð ×æðÜ ¥ßÿæðçÂÌ ãæðÌð ãñ´Ð çÜç¹°
(i) ·¤æòÜðâ ·¤æ â´ÚU¿Ùæ âêæ
(ii) ·¤æòÜðâ ·¤æ ¥æ§ü.Øê.Âè.°.âè. Ùæ×
When a coordination compound NiCl2.6H2O is mixed with AgNO3, 2 moles of
AgCl are precipitated per mole of the compound. Write
(i) Structural formula of the complex
(ii) IUPAC name of the complex
12. (a) ·¤æòÜðâ [Fe(CN)6]42 ·ð¤ çÜØð â´·¤ÚUæ, ¿éÕ·¤èØ ÃØßãæÚU ¥æñÚU çSÂÙ Âý·¤æÚU ·¤æð
çÜç¹° (Â.â´. Fe526)
(b) ·¤æòÜðâ [Co(en)2Cl2]1 ·ð¤ °·¤ Øæç×ÌèØ °·¤Ü·¤ ·¤æð çÜç¹° Áæð Âý·¤æàæ·¤èØ
âç·ý¤Ø ãæðÌæ ãñÐ
(a) For the complex [Fe(CN)6]42, write the hybridization, magnetic character
and spin type of the complex. (At. number : Fe526)
(b) Draw one of the geometrical isomers of the complex [Co(en)2Cl2]1 which
is optically active.
56/2/N 6
13. H2O2 ·ð¤ ÂýÍ× ·¤æðçÅU çßæÅUÙ ·ð¤ ÎÚU çSÍÚUæ´·¤ ·ð¤ çÜØð çÙÙ â×è·¤ÚUæ çÎØæ ÁæÌæ ãñ Ñ
1.0 3 104 K
log k 5 14.2 2
T
§â ¥çÖç·ý¤Øæ ·ð¤ çÜØð Ea ¥æñÚU ÎÚU çSÍÚUæ´·¤ k ·¤æð ÂçÚU·¤çÜÌ ·¤èçÁ° ¥»ÚU §â·¤è ¥Ïü-¥æØé
200 ç×ÙÅU ãæðÐ (çÎØæ »Øæ Ñ R58.314 JK21 mol21)
The rate constant for the first order decomposition of H2O2 is given by the
following equation :
1.0 3 104 K
log k 5 14.2 2
T
Calculate Ea for this reaction and rate constant k if its half-life period be
200 minutes. (Given : R58.314 JK21 mol21)
15. °·¤ Ìß 400 pm ·¤æðçàæ·¤æ ·ð¤ ç·¤ÙæÚðU ·ð¤ âæÍ f.c.c. ×ð´ ç·ý¤SÅUçÜÌ ãæðÌæ ãñÐ Ìß ·¤æ æÙß
7 g cm23 ãñÐ Ìß ·ð¤ 280 g ×ð´ ç·¤ÌÙð ÂÚU×ææé ßÌü×æÙ ãñ´?
An element crystallizes in a f.c.c. lattice with cell edge of 400 pm. The density
of the element is 7 g cm23. How many atoms are present in 280 g of the
element ?
56/2/N 7 P.T.O.
16. (i) D-Üê·¤æðâ ·¤è °·¤ ¥çÖç·ý¤Øæ çÜç¹° çÁâ·¤è ÃØæØæ §â·¤è ¹éÜè oë´¹Üæ â´ÚU¿Ùæ ·ð¤
mæÚUæ Ùãè´ ·¤è Áæ â·¤Ìè ãñÐ
(ii) ØêçÜ·¤ ¥Ü ×ð´ ç·¤â Âý·¤æÚU ·¤è çÜ´·ð¤Á ãæðÌè ãñ?
(iii) ÁÜ-æéÜÙàæèÜ ¥æñÚU Èñ¤ÅU-æéÜÙàæèÜ ÂýØð·¤ ·ð¤ °·¤ °·¤ ©ÎæãÚUæ ÎèçÁ°Ð
(i) Write one reaction of D-Glucose which cannot be explained by its open
chain structure.
(ii) What type of linkage is present in Nucleic acids ?
(iii) Give one example each for water-soluble vitamins and fat-soluble
vitamins ?
17. (i) °ÍèÙ ·ð¤ ÕãéÜ·¤è·¤ÚUæ ×ð´ ÕðÁæðØÜ ÂÚU¥æòâæ§ÇU ·¤è Øæ Öêç×·¤æ ãæðÌè ãñ?
(ii) çÙÙ ÕãéÜ·¤ ×ð´ °·¤Ü·¤ ·¤è Âã¿æÙ ·¤èçÁ°Ð
(iii) ©Ù·ð¤ ¥´Ì¥æüæçß·¤ ÕÜ ·ð¤ ¥æÏæÚU ÂÚU ÕɸÌð ·ý¤× ×ð´ çÙÙ ·¤æð ÃØßçSÍÌ ·¤èçÁ°Ð
ÙæØÜæòÙ-6, 6, ÂæòÜèÍèÙ, ÕêÙæ-S
¥Íßæ
°ÍèÙ ·ð¤ Èý¤è ÚñUçÇU·¤Ü ÕãéÜ·¤è·¤ÚUæ ·¤è ç·ý¤ØæçßçÏ ·¤æð çÜç¹°Ð
(i) What is the role of benzoyl peroxide in the polymerization of ethene ?
(ii) Identify the monomers in the following polymer :
56/2/N 8
18. ÁÕ 50 g ÁÜ ×ð´ Na2SO4 (M5142 g mol21) ·¤æ 2 g æéÜæØæ ÁæÌæ ãñ ÌÕ ÂýæÌ çßÜØÙ
·ð¤ ßÍÙæ´·¤ ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð Øã ×æÙ·¤ÚU ¿çÜØð ç·¤ Na2SO4 ·¤æ ÂêÚUèU ÌÚUã ¥æØÙè·¤ÚUæ
ãæð ÁæÌæ ãñÐ
(ÁÜ ·ð¤ çÜØð Kb 50.52 K kg mol21)
Calculate the boiling point of solution when 2 g of Na2SO4 (M5142 g mol21)
was dissolved in 50 g of water, assuming Na 2SO 4 undergoes complete
ionization.
(Kb for water50.52 K kg mol21)
19. çÙÙ ¥çÖç·ý¤Øæ¥æð´ ×ð´ ÂýØð·¤ ·ð¤ ×éØ ãñ ×æðÙæðãñÜæð ©ÂæÎ ·¤æð çÜç¹° Ñ
(i)
(ii)
(iii)
(i)
(ii)
(iii)
56/2/N 9 P.T.O.
20. çÙÙ ·ð¤ ·¤æÚUæ çÙÏæüçÚUÌ ·¤èçÁ° Ñ
(i) H3PO4 ·¤è ¥Âðÿææ H3PO2 ÂýÕÜÌÚU ¥Â¿æØ·¤ ãñÐ
(ii) ¥æòâèÁÙ ·¤è ¥Âðÿææ âËȤÚU ×ð´ oë´¹ÜÙ ·¤è Âýßëçæ ¥çÏ·¤ ãñÐ
(iii) ¥Â¿æØ·¤è ÃØßãæÚU HF âð HI ·¤è ¥æðÚU ÕɸÌæ ãñÐ
Assign reason for the following :
21. (i) °·¤ ÂçÚUc·¤ÚUæ çßçÏ ·¤æ Ùæ× çÜç¹° Áæð ¥çÏàææðáæ ·ð¤ çâhæÌ ÂÚU ¥æÏæçÚUÌ ãæðÌæ ãñÐ
(ii) Ûææ» ÜßÙ çßçÏ ×ð´ ¥ßÙ×·¤ ·¤è Øæ Öêç×·¤æ ãæðÌè ãñ?
(iii) ¥æòâæ§ÇU ¥ØS·¤ âð ¥æØÚUÙ ·ð¤ çÙc·¤áüæ ×ð´ ¿êÙð ·ð¤ ÂÍÚU ·¤è Øæ Öêç×·¤æ ãæðÌè ãñ?
(i) Name the method of refining which is based on the principle of adsorption.
NaNO /Cu
Sn/HCl CHCl 1alc. KOH
(ii) C6 H5N1 2
2 BF4
2 → A → B →
3 C
D
D
(i) C6H5 2 COO2NH1
4
Br2/KOH
→ A
CH3COCl/pyridine
→ B →C
NaNO /Cu
Sn/HCl CHCl 1alc. KOH
(ii) C6 H5N1 2
2 BF4
2 → A → B →
3 C
D
56/2/N 10
23. ¥ØÌ ÃØSÌÌæ ·ð¤ ·¤æÚUæ æè×æÙ÷ ¥ßSÍè Ùð ¥ÂÙæ ÁèßÙ ÌÙæßÂêæü ÕÙæ ÚU¹æ ÍæÐ ¥ßÙ×Ù
·¤æð ÎêÚU ·¤ÚUÙð ·ð¤ çÜØð ©ãæð´ðÙð çÕÙæ ÇUæòÅUÚU ·¤è âÜæã ·ð¤ Ùè´Î ·¤è »æðçÜØæ¡ ÜðÙæ àæéM¤ ·¤ÚU çÎØæÐ
æè×æÙ÷ ¥ßSÍè ·ð¤ °·¤ ÙÁÎè·¤è ç×æ æè×æÙ÷ ÚUæòØ Ùð ©ã´ð Ùè´Î ·¤è »æðÜè Ù ÜðÙð ·¤è âÜæã
Îè âæÍ ãè ©ã´ð Øæð»æâÙ ·¤ÚUÙð ·¤æð ·¤ãæÐ ¥ßSÍè Áè ¥ÂÙð ç×æ ·¤è âÜæã ×æÙ·¤ÚU Øæð»æâÙ
¥æñÚU ·é¤ÀU ÃØæØæ× ·¤ÚUÙæ àæéM¤ ·¤ÚU çÎØæÐ ÍæðǸð ãè çÎÙ ×ð´ ¥ßSÍè ¥ÂÙð ·¤æð SßSÍ ×ãâêâ
·¤ÚUÙð Ü»ðÐ
©ÂÚUæðÌ ÂñâðÁ ·¤æð Âɸ·¤ÚU çÙÙ ·ð¤ ©æÚU çܹð´ Ñ
(i) æè×æÙ÷ ÚUæòØ ç·¤Ù ×êËØæð´ (·¤× âð ·¤× Îæð) ·¤æð ÂýÎçàæüÌ ç·¤Øæ?
(ii) çÕÙæ ÇUæòÅUÚU ·¤è âÜæã ·ð¤ Ùè´Î ·¤è »æðÜè Øæð´ Ùãè´ ÜðÙè ¿æçãØð?
(iii) Ùè´Î·¤æÚUè »æðçÜØæ¡ Øæ ãæðÌè ãñ´? Îæð ©ÎæãÚUæ ÎèçÁ°Ð
Due to hectic and busy schedule, Mr. Awasthi made his life full of tensions and
anxiety. He started taking sleeping pills to overcome the depression without
consulting the doctor. Mr. Roy, a close friend of Mr. Awasthi advised him to
stop taking sleeping pills and suggested to change his lifestyle by doing Yoga,
meditation and some physical exercise. Mr. Awasthi followed his friends advice
and after few days he started feeling better.
After reading the above passage, answer the following :
(i) What are the values (at least two) displayed by Mr. Roy ?
(ii) Why it is not advisable to take sleeping pills without consulting doctor ?
(iii) What are tanquilizers ? Give two examples.
56/2/N 11 P.T.O.
¥Íßæ
3d â´·ý¤×æ æðæè ·ð¤ Ìß Ùè¿ð çÎØð ÁæÌð ãñ´ Ñ
Sc Ti V Cr Mn Fe Co Ni Cu Zn
(i) D
2MnO2 14KOH1O2 →
OR
The elements of 3d transition series are given as :
Sc Ti V Cr Mn Fe Co Ni Cu Zn
Answer the following :
(i) Write the element which is not regarded as a transition element. Give
reason.
(ii) Which element has the highest m.p ?
(iii) Write the element which can show an oxidation state of 11.
(iv) Which element is a strong oxidizing agent in 13 oxidation state and
why ?
56/2/N 12
25. (a) çÙÙ ¥çÖç·ý¤Øæ¥æð´ ×ð´ A, B, C ¥æñÚU D ·¤è â´ÚU¿Ùæ¥æð´ ·¤æð çÜç¹° Ñ
(c) çÙÙ ·¤æð ©Ù·ð¤ ÕɸÌð ßÍÙæ´·¤ ·ð¤ ·ý¤× ×ð´ çÜç¹° Ñ
CH3CH2OH, CH3COCH3, CH3COOH
¥Íßæ
(a) §üÅUæÇüU ¥çÖç·ý¤Øæ âð âÕçÏÌ ÚUæâæØçÙ·¤ ¥çÖç·ý¤Øæ ·¤æð çÜç¹°Ð
(b) ØêçÜØæðçȤçÜ·¤ Øæð»æ×·¤ ¥çÖç·ý¤Øæ ·ð¤ ÂýçÌ ©Ù·¤è ÕɸÌè âç·ý¤ØÌæ ·ð¤ ·ý¤× ×ð´ çÙÙ
·¤æð ÃØßçSÍÌ ·¤èçÁ° Ñ
CH32CHO, C6H5COCH3, HCHO
(c) Cl2CH22COOH ·¤æ pKa CH3COOH ·ð¤ pKa âð ·¤× Øæð´ ãñ?
(d) çÙÙ ¥çÖç·ý¤Øæ ×ð´ ©ÂæÎ ·¤æð çÜç¹° Ñ
2 1. (i-Bu) AlH
CH3CH 2CH5CH2CH2CN
2.H O
→
2
(e) Øæñç»·¤ C3H6O ·ð¤ Îæð ç·ý¤Øæ×·¤ â×æßØßè A ¥æñÚU B ãñ´Ð NaOH ¥æñÚU I2 ·ð¤ âæÍ »×ü
·¤ÚUÙð ÂÚU â×æßØßè A ¥æØÇUæðȤæ×ü ·¤æ ÂèÜæ ¥ßÿæð ÎðÌæ ãñ æÕç·¤ â×æßØßè B ·¤æð§ü
¥ßÿæð Ùãè´ ÎðÌæ ãñÐ A ¥æñÚU B ·ð¤ ¥æéâêæ çÜç¹°Ð
56/2/N 13 P.T.O.
(a) Write the structures of A, B, C and D in the following reactions :
2 1. (i-Bu) AlH
CH3CH 2CH5CH2CH2CN
2.H O
→
2
(e) A and B are two functional isomers of compound C3H6O. On heating with
NaOH and I2, isomer A forms yellow precipitate of iodoform whereas
isomer B does not form any precipitate. Write the formulae of A and B.
26. (a) çÙÙ ¥çÖç·ý¤Øæ ·ð¤ çÜØð 298 K ÂÚU E8cell ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ° Ñ
2Cr(s)1 3Fe21(0.01M) ® 2Cr31(0.01M) 1 3Fe(s)
çÎØæ »Øæ ãñ : Ecell50.261 V
(b) A ¥æñÚU B ·ð¤ E8 ×æÙæð´ ·¤æ ©ÂØæð» ·¤ÚUÌð ãé° Âýæ»éçÌ ·¤èçÁ° ç·¤ §Ù×ð´ ·¤æñÙ ¥æØÚUÙ ·ð¤
âÌã ÜðÂÙ ·ð¤ çÜØð ÕðãÌÚU ãæð»æ çÁââð ©âÂÚU Á´» Ù Ü»ð ¥æñÚU Øæð´?
[E8(Fe21/Fe)520.44 V]
¥æñÚU çÎØæ »Øæ E8(A21/A)522.37V : E8(B21/B)520.14 V
56/2/N 14
¥Íßæ
(a) CH3COOH ·ð¤ °·¤ 0.001 mol L21 çßÜØÙ ·¤è ¿æÜ·¤Ìæ 3.90531025 S cm21
ãñÐ §â·¤è ×æðÜÚU ¿æÜ·¤Ìæ ¥æñÚU çßØæðÁÙ (a) ·¤è çÇU»ýè ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð
çÎØæ »Øæ l8(H1)5349.6 S cm2 mol21 ¥æñÚU l8 (CH3COO2)540.9 S cm2 mol21.
(b) çßléÌ ÚUæâæØçÙ·¤ âðÜ ·¤æð ÂçÚUÖæçáÌ ·¤èçÁ°Ð Øæ ãæðÌæ ãñ ÁÕ çßléÌ÷ ÚUæâæØçÙ·¤ âðÜ
·ð¤ E8cell âð Ü»æØæ »Øæ Õæs çßÖß ØæÎæ ãæð ÁæÌæ ãñÐ
(a) Calculate E8cell for the following reaction at 298 K :
2Cr(s)1 3Fe21(0.01M) ® 2Cr31(0.01M) 1 3Fe(s)
Given : Ecell50.261 V
(b) Using the E8 values of A and B, predict which one is better for coating the
surface of iron [E8(Fe21/Fe)520.44 V] to prevent corrosion and why ?
Given : E8(A21/A)522.37 V : E8(B21/B)520.14 V
OR
(a) The conductivity of 0.001 mol L 21 solution of CH 3 COOH is
3.90531025 S cm21. Calculate its molar conductivity and degree of
dissociation(a).
Given l8(H1)5349.6 S cm2 mol21 and l8 (CH3COO2)540.9 S cm2 mol21.
(b) Define electrochemical cell. What happens if external potential applied
becomes greater than E8cell of electrochemical cell ?
56/2/N 15 P.T.O.