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Documente Profesional
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F+A
Products
Fuel Fuel Air
Air + Air
Fuel + Air (+ F?)
φ≤1 φ>1
Turbulent
Propane torch diffusion
Flame
Premixed Flame Images
Propagating premixed
flame in SI engine
Partially Premixed Flame
n-heptane
PPF *
Diesel
Engine
Combustion **
(Propane/Air)
(Methane/Air)
NP
Le≈1 Le<1
Nonpremixed and Partially Premixed (Double) Flames
Flames Established in a Counterflow Burner
strain rate 50 s -1
φ = 10
φ=5
φ = 3.5
φ = 2.5
2500 300
Stagnation plane
200
2000
100
v (cm)
1500
T(K)
T (K)
0
1000 V(cm/s)
-100
500
-200
0 -300
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Distance from the nozzle (cm)
0.2
O2
n-heptane * 10
Mole fraction
0.15
O2
H2O CO
0.1 H2 * 10
CO2 H2O
0.05 CO2
H2
0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5
Distance from the nozzle (cm)
• Introduction
• Scale analysis for laminar flame speed and flame thickness
• Simplified analysis due to Spalding
• Detailed analysis; numerical solution
• Effects of important parameters on the flame speed and
thickness
• Counterflow flames
• Partially Premixed Flames
Laminar Premixed Flames
Introduction
Ø In premixed flames, the reaction zone separates the reactants (i.e. a mixture of fuel
and oxidizer that are mixed at the molecular level) and products.
Ø Safety is a major concern for premixed flames. Consequently, such flames are not
as common as the nonpremixed and partially premixed flames. Nevertheless, they
are still very important in numerous combustion systems. Examples include:
§ Gas turbine combustors using lean premixed combustion
§ Spark ignition engines
§ Fires in coal mines
§ Numerous other systems, such as residential burners, furnaces, diesel engines,
rocket engines in which the combustion is characterized by a partially premixed
flame containing multiple reaction zones
Ø A premixed flame is characterized by the propagation of a wave. Broadly speaking,
there are two types of combustion waves; detonation waves and deflagration waves.
A detonation wave is a shock wave, which propagates at a supersonic speed,
accompanied by combustion. A deflagration wave or a laminar flame on the other
hand is a relatively low-speed wave, and pressure change across it is negligible.
Laminar Premixed Flames
Ø A laminar flame is of fundamental importance in most practical systems. Even in
systems that involve nonpremixed flames, the laminar flame speed is important
with regards to flame liftoff and stabilization.
Ø Commonly used premixed flame configurations for fundamental studies include:
§ Bunsen burner flame
§ Flame stabilized on a flat flame burner
§ Propagating flame in a tube
§ Spherical flames
§ Counterflow premixed flame
§ Flame stabilized on a rod
Ø This chapter deals with the fundamental aspects of laminar premixed flames. In
particular, we will discuss:
§ Laminar flame speed and flame thickness
§ Flame structure
§ Fundamental analysis of a laminar premixed flame
§ Effects of important parameters
§ Flame stretch and flame stability (advanced topic, not covered)
Laminar Premixed Flames
Laminar flame speed represents a fundamental property of fuel-oxidizer
mixtures. It is defined as the mixture velocity normal to the flame surface. It
provides the mixture burning rate in the flame.
Conservation of mass: ρ u SL = ω
˙δ Also equating convection and reaction times
SL = vu,n = vu sin α
It is important to know the laminar flame speed for any given fuel for a range of
equivalence ratios, temperatures, pressures, etc.
Laminar Premixed Flames
Simplified Analysis (Due to Spalding)
δ
∂ρ ∂ ( ρv x )
=− =0
∂t ∂x ρ u SL ρ bU b
ρu SL = ρ bU b
∂ρ i ∂(m˙ %i%)
=− ˙ %i%%= 0
+m
∂t ∂x € T €
˙ "i" = m
m ˙ ""Yi − ρDi (∂Yi /∂x) δr
dp
=0 δd
dx x
Using energy equation as derived in
the Shvab Zeldovich Formulation
T(x → −∞) = Tu
dT d ∂T
!!c p
m − (λ i!!!
) = −∑ h 0f ,i m T(x → ∞) = Tb
dx dx dx
€ dT (x → −∞) = dT (x → +∞) = 0
Two extra boundary conditions for δ and SL
dx dx
€
Simplified Analysis: Thermal Theory of Spalding
1. A planar steady, one-dimensional, adiabatic flame, which is either stationary or
propagating at a fixed speed of SL.
2. p=constant
3. Constant transport properties. Also constant and equal specific heats, and Le=1.
4. Three species with a single global reaction. The Spalding analysis provides the
following results:
Propane-air
Φ=1
Laminar Premixed Flames
Effects of Various Parameters on Flame Speed and Thickness
Considering global 1-step reaction
ω˙ F n−1
€b k Tu
−( E / R u T ) p a α= ≈ (T ) c
≈ Tue n
(YF ) (YOx ) ρc p p
ρu Tb
€ €
SL ≈ (T ) c / 2 Tu (Tb )−n / 2 e−(E / 2R u Tb ) p(n−2)/ 2
€
• The effect of equivalence ratio (φ) on flame speed and thickness appears
mainly through its effect on Tb, and also through its effect on YF and Yo.
€ €
Thus flame speed and thickness are, respectively maximum and minimum
near φ =1 for hydrocarbon flames.
• Effect of molecular weight of reactant (M):
• α ≈ 1/M and ρ ≈ M, ==> SL ≈ 1/M
• Shifts the peak in SL to richer mixture (φ >1) for lighter fuels, such as
H2
• Flame speed can also be modified by using diluents, which mainly affect
the specific heat and thereby the flame temperature in the order:
CpCO2>CpN2>CpAr (≈CpHe)
• Some diluents such as He can also modify the transport property (thermal
conductivity or diffusivity), and molecular weight
Methane-Air Flames
210
McLean et al. [1994]
a) Mueller et al. Mechanism
Davis et al. Mechanism
Laminar Burning Velocity [cm/s]
120
90
60
0
0 1 2 3 4 5 6
Equivalence Ratio
Variation of laminar burning velocity with
Flame A: 50% CO- 50% H2
volume percent of CO in syngas at φ = 2.0
Flame B: 95% CO- 5% H2
λ SL
! =−m # dT &
QV ! F ΔhcV = −λ A % (
$ dx 'wall δ
These equations provide results that are qualitatively in agreement with experimental data, such
as shown in Fig. 8.16 (Turns), indicating quenching distance to be greater than flame thickness.
See data in Table. Note X values are in percentage.
€
Flammability Limits
• Flammability limits are generally expressed in terms of mixture compositions
(equivalence ratio or fuel fraction by volume), for fixed temperature and pressure,
beyond which a fuel-air mixture cannot be made to burn.
• These limits can be determined experimentally by igniting a fuel-air mixture at one
end of a long tube. If the mixture is within flammability limit, the ignition leads to a
flame propagating in the tube. However, there are equivalence ratios (outside the
flammability limits) that will not lead to propagating flame after the ignition source
is removed. Using a large-diameter tube provides more consistent results.
• Table shows flammability limits for some fuels, expressed in terms of lean and rich
equivalence ratios (or fuel mole fractions for lean and rich mixtures).
• These limits are strongly influenced by temperature, pressure, and other conditions,
such as oxygen fraction, and gravity for upward/downward propagating flames.
Figure depicts the effect of gravity on the lower flammability limit. Note that the
fuel-air mixture gets preheated due to hot buoyant gases in case of upward
propagating flame.
Flammability Limits
Turns
Thermo-Diffusive Instability
Lean hydrogen flames: Le<1 ⇒ Flame Lean propane flames: Le>1 ⇒ Flame
speed increases with stretch speed decreases with stretch
NP
φ = 1.4
RP Vin = 30cms-1 φ = 1.6 φ = 1.7 φ = 1.9
Vout = 30cms-1 Vin = 30cms-1 Vin = 30cms-1 Vin = 30cms-1
Vout = 30cms-1 Vout = 30cms-1 Vout = 30cms-1
Le<1
Le≈1 • Flame tip is negatively stretched, and
Lb is positive for rich propane flames
• Burning rate decreases with stretch
Thermal-Diffusive Instability: H2-C3H8 Blend
Hydrogen (Le<1) Propane (Le>1)