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Waste Management
journal homepage: www.elsevier.com/locate/wasman
a r t i c l e i n f o a b s t r a c t
Article history: The policy of establishing new universities across Taiwan has led to an increase in the number of univer-
Received 3 April 2017 sities, and many schools have constructed new laboratories to meet students’ academic needs. In recent
Revised 21 September 2017 years, there has been an increase in the number of laboratory accidents from the liquid waste in univer-
Accepted 22 September 2017
sities. Therefore, how to build a safety system for laboratory liquid waste disposal has become an impor-
Available online xxxx
tant issue in the environmental protection, safety, and hygiene of all universities. This study identifies the
risk factors of liquid waste disposal and presents an agenda for practices to laboratory managers. An
Keywords:
expert questionnaire is adopted to probe into the risk priority procedures of liquid waste disposal; then,
Waste management
Laboratory liquid waste
the fuzzy theory-based FMEA method and the traditional FMEA method are employed to analyze and
Failure Mode and Effects Analysis (FMEA) improve the procedures for liquid waste disposal. According to the research results, the fuzzy FMEA
Fuzzy theory method is the most effective, and the top 10 potential disabling factors are prioritized for improvement
according to the risk priority number (RNP), including ‘‘Unclear classification”, ‘‘Gathering liquid waste
without a funnel or a drain pan”, ‘‘Lack of a clearance and transport contract”, ‘‘Liquid waste spill during
delivery”, ‘‘Spill over”, ‘‘Decentralized storage”, ‘‘Calculating weight in the wrong way”, ‘‘Compatibility
between the container material and the liquid waste”, ‘‘Lack of dumping and disposal tools”, and ‘‘Lack
of a clear labels for liquid waste containers”. After tracking improvements, the overall improvement rate
rose to 60.2%.
Ó 2017 Elsevier Ltd. All rights reserved.
https://doi.org/10.1016/j.wasman.2017.09.029
0956-053X/Ó 2017 Elsevier Ltd. All rights reserved.
Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
2 C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx
controlled, and must be well disposed of in accordance with rele- versities across the nation: 14 junior colleges, 21 technical
vant regulations for industrial waste management, as stipulated institutes, 126 universities, and 2 National Open Universities, for
in the Waste Disposal Regulations. There are regulations related a total of 160 higher education institutes. All these schools, espe-
to the management of waste; regulations related to academic insti- cially the departments of science, engineering, and chemistry, are
tutions include: Waste Disposal Act, Waste Disposal Act Enforce- equipped with a laboratory for the internship and practices of stu-
ment Rules, Methods and Facilities Standards for the Storage, dents. Chemical experiments in the laboratory would generate liq-
Clearance and Disposal of Industrial Waste, Measures for the uid waste.
Administration of the Common Disposal of Waste Disposal of Edu-
cational Institutions, Notice on the Required Waste Clearance Plan,
2.1. Laboratories liquid waste
Notice on the Regulation that the Waste Production, Storage, Clear-
ance, Disposal, Recycling, Input and Output Should Be Reported by
According to the ‘‘Improve each university campus pollution
Network Transmission, Resource Recycling Act, The handling of
control public facilities integrated planning (II)” by Taiwan’s Min-
toxic chemical substances by academic organizations management
istry of Education, Li (2000) conducted a questionnaire survey to
method, and Standards for Defining Hazardous Waste. Inspection
estimate the quantity of the laboratory wastes of schools at all
regulations for the waste management of for-profit institutions
levels in Taiwan, and the findings showed that the liquid waste
are stringent, while not-for-profit university laboratories are man-
of the laboratories of these schools in 2000 was around
aged by means of self-regulation due to their small size. The aspect
1,691,100 liters/year (as Table 1). The estimated quantity of liquid
of ‘‘waste management” is, however, marginal and relegated to the
waste of higher education institutes was about 740,100 liters/year,
administrative field due to very small quantities, which do not rep-
accounting for about 43.76%. The liquid wastes include organic liq-
resent a serious management problem. However, a lot of the acci-
uid waste, acid and alkaline liquid waste, cyanide liquid waste,
dents and personal injuries that have occurred in university
heavy metal liquid waste, hexavalent chromium liquid, mercury
laboratories or not-for-profit laboratories were caused by improper
liquid waste, and others. Specifically, heavy metal liquid waste
handling of waste from academic chemical laboratories. This
accounts for 47.9%; organic liquid waste accounts for 32.2%; acid
reveals that the disposal of the waste of school laboratories has
and alkaline liquid waste accounts for 12.4%. According to the
been controlled and standardized by relevant laws and regulations
research report, most liquid waste is hazardous industrial waste,
in Taiwan.
which affects human health and causes environmental pollution;
According to Kuo (2005), the use of chemicals in school labora-
if appropriate control measures are not taken, such liquid waste
tories have the following features: (1) a wide variety, (2) great
will have severe impact on the environment and affect public
change, (3) specialty, and (4) small amount. Regarding school lab-
health.
oratories, generation and management may lead to environmental
According to the research data from Ni (2002), there has been
pollution, and the potential risks and hazards caused by inappro-
great quantities of wastes generated by the laboratories of schools
priate management and disposal of liquid waste are all related to
at all levels in Taiwan every year; 92 ± 7% of them were hazardous
the hazards of laboratories that use chemicals. Therefore, the lack
according to the standards of hazardous industrial wastes; annu-
of effective measures of disposing of hazard wastes may cause
ally, the schools created about 1586 metric tons of hazardous
environmental pollution and pose harm to laboratory staff.
industrial wastes, and 1556 metric tons were the liquid wastes of
Horng and Kuo (2007) analyzed the 340 cases of chemical storage
laboratories. Kuo (2005) summarized the data released by the Min-
accidents between 1997 and 2006, and found that 30% were caused
istry of Education, and found that the annual estimated quantity of
by human error; 26% by storage factors; 44% by other problems,
the liquid wastes of school laboratories across the nation from
such as malfunction of safety equipment and wire fires. While lab-
2001 to 2005 ranged between 1,650,000 l to 1,700,000 l. These data
oratories consume less chemicals than factories, the wide variety,
show that liquid wastes account for a large proportion of labora-
great change, and special uses increase the complexity of the man-
tory wastes.
agement, storage, and disposal of laboratory chemicals. Worse still,
The most important result of the comprehensive program for
there is an inadequate number of laboratory maintenance staff in
hazardous waste management is the legacy of environmental care
schools, and staff management is inefficient. Hence, human errors
imparted to the student community. Lara et al. (2017) the scientific
may be the main causes of laboratory accidents. Jose et al. (2011)
value of this paper is the development of a new classification of
found that among the 15 companies studied, only four had adopted
hazardous waste, which can be useful in the chemistry depart-
a consistent set of diversified management and human resources
ments of universities. Finally, this work acknowledges the chal-
practices. These four companies were the only companies to affirm
lenge for universities and organizations to act, develop
that diverse management requires the strong support of top man-
sustainability, and change the paradigms and assumptions on
agement and continuous organization to sustain efforts toward
which these organizations are currently based.
incorporating diversity.
Chien et al. (2000) argued that the amount of hazardous mate-
rials used in university laboratories was small in quantity, but the
2. Literature review chemicals are widely varied. Although the experimental procedure
is simple, both teachers and students tend to overlook the potential
According to Taiwan’s Ministry of Education (2016), the Depart- hazards. Yu and Chou (2001) argued that the most common hazard
ment of Statistics website data announced the total number of uni- in laboratories was chemicals – meaning immediate harm or
Table 1
Total quantity of liquid waste of laboratories of schools at all levels in Taiwan in 2000.
Variety Acid and alkaline Heavy metal liquid Hexavalent liquid Cyanide liquid Organic liquid Mercury liquid Other liquid Total
liquid waste waste waste waste waste waste waste
Liters/Year 210,300 809,800 94,700 5,000 544,600 9,900 16,900 1,691,100
Percentage 12.4 47.9 5.6 0.3 32.2 0.6 1.0 100.0
(%)
Reference Li (2000).
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ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 3
cumulative pathological changes to the internal and external parts These accident reports underline the importance of laboratory
of the human body, as caused by fire, explosion, poisonous, and safety and management on campus.
erosive materials. According to Chang and Wang (2006), there According to Tsai et al. (2000), the proportion of those in
was an increasing number of equipment, facilities, and chemicals charge of safety and hygiene in the establishment of safety and
in school laboratories, and the hazardous wastes of the laboratories hygiene units of Taiwanese universities was lower than 10%,
were complex, various, and highly changeable; worse still, the lack and most of the staff was spontaneously responsible for other
of professional staff, standard operational management, and rele- tasks. To date, many universities have formed safety and hygiene
vant disposal channels would cause secondary pollution to the teams; however, the leaders have not paid adequate attention to
environment. the issues; the teachers and the students are not fully aware of
the safety problems; only a few of the people in charge of safety
2.2. Safety of laboratories and hygiene have expertise in this aspect. Although there are
schools in Taiwan conducting environment and safety manage-
Sun (2015) indicated that chemical laboratories have numerous ment by obtaining ISO certificates, ISO standards are less compul-
potential safety problems, as inflammable, explosive, and poi- sory than laws and regulations. If there is only a slight violation of
sonous chemicals are stored there. Moreover, the electrical devices ISO standards, they still have room for improvement; however,
in the chemical experiments are often in a state of high tempera- once there is violation of law, punishment and improvement are
ture and pressure, thus, they are more vulnerable to fire and explo- executed immediately. Consequently, safety and hygiene manage-
sion than common laboratories. The organic compounds in ment of the experimental rooms on campus remain to be imple-
chemical laboratories are highly inflammable and explosive, and mented. According to the research report of the ‘‘Investigation of
hazardous chemicals have different critical temperatures, critical the fires and explosions in chemicals-related university laborato-
pressures, and critical concentrations. ries”, Lin et al., (2002) observed the collected cases, and found that
Universities are places where talents are trained, and nearly all the causes of the accidents could be divided into three groups: (1)
universities are equipped with various laboratories. In recent years, inappropriate management of chemicals, (2) mechanical or device
there have been many reports of accidents in the laboratories or malfunction, and (3) natural disasters. The inappropriate manage-
practical sites of universities. Taiwan has also witnessed a series ment of chemicals includes four parts, namely, the inappropriate
of laboratory accidents in its universities since 2000 (as Table 2). storage of chemicals, the inappropriate use of chemicals, the
Table 2
A list of laboratory accidents in Taiwanese Universities since 2000. Source: Cases of Poisonous and Chemical Disasters in Laboratories (Tsai, 2012); news events and the data
summarized by the authors of this paper.
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ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
4 C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx
management programs to reduce their environmental impacts. leA (v) means level of v belonging to. A. e
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ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 5
Table 3
Potential factors of the default model of laboratory liquid waste disposal procedures.
3.3. Positive Triangular fuzzy number (Kaufman and Gupta, 1991) According to the characteristics of triangular fuzzy numbers
and the extension principle (Zimmerman, 1991; George et al.,
Positive Triangular Fuzzy Number A e is a fuzzy set, as indicated 2008), the operational laws of two triangular fuzzy numbers
e A e 2 = (L2, M2, U2) are, as follows:
e 1 = (L1, M1, U1) and A
by A = (L, M, U), and the definition of the membership function
(Fig. 2) is, as follows: e 2 ðL1 þ L2 ; M1 þ M2 ; U1 þ U2 Þ
e1 A
8 A ð2Þ
< ML ; L 6 X 6 M
> XL
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Table 4
The name list of those filling the expert questionnaire.
Expert no. Work unit Position Tasks in the environment safety center
Expert 1 Environment Engineering Department of a university Director Leader of the Environmental Protection Group
Expert 2 Environment Engineering Department of a university Technician Handle affairs related to environmental protection
Expert 3 Chemistry Department of a university Director Leader of the Safety and Hygiene Group
Expert 4 Chemistry Department of a university Technician Handle affairs related to safety and hygiene
Expert 5 Chemical Engineering and Material Department of a university Director Leader of the Toxic Substance Management Group
Expert 6 Chemical Engineering and Material Department of a university Specialist Handle affairs related to toxic substance management
Expert 7 General Affairs Office of a university Leader Executive secretary of the Environment Safety and Hygiene Committee
Expert 8 Environment Safety Center Technician Handle affairs related to environment safety and hygiene
method for each service aspect and item in the service quality
model.
As the cognition and opinions of each evaluator are different,
the delimited scope is not same, thus, the average value concept
is adopted to integrate fuzzy judgment, and the formula is shown,
as follows:
Fig. 2. Positive triangular Fuzzy numbers. Endpoint values LEij, MEij and UEij in the above formula can be
calculated with the plan proposed by Buckley (1985).
!
X
m
LEij LEkij =m ð6Þ
k¼1
!
X
m
k
MEij MEij =m ð7Þ
k¼1
!
X
m
k
UEij UEij =m ð8Þ
k¼1
3.5.1. Defuzzification
Transforming fuzzy numbers, as calculated by fuzzification into
definite values, is called defuzzification. Normal defuzzification
methods include Center of Gravity Defuzzification; Center of Sum
e
Fig. 3. a-cut of positive triangular Fuzzy number A. Defuzzification; Center of Largest Area Defuzzification; First of
Maxima Defuzzification; Last of Maxima Defuzzification; Middle
of Maxima Defuzzification, and Height Defuzzification.
3.4. a-cut (Zimmerman,1991) This research adopts the relatively simple Center of Gravity
Defuzzification; according to Tseng and Klein (1989), the member-
For the given real number a, a [1, 0]; definition Aa = {v|le e is u ðxi Þ, when the fuzzy
A ship function of hypothetical fuzzy set A eA
(v) = a, v 2 X} is a-cut of fuzzy set A. e Aa = [ A
e lðaÞ , A
e uðaÞ ], in which
number is a Triangular Fuzzy Number, hypothetical Triangular
e e
A lðaÞ , A uðaÞ are left and right edge points, respectively, as shown in e i ¼ ðLi ; M i ; U i Þ; the formula is:
Fuzzy Number A
Fig. 3.
½ðU i Li Þ þ ðM i Li Þ
Fi ¼ þ Li ; 8i ð9Þ
3.5. Linguistic Variable and fuzzification 3
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C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 7
5-level scoring for (D) and (O) (Jia and Shi, 2005). The details of the weeks to meet the criteria that each laboratory was checked at
research calculations are, as follows: least once. Each inspection was checked by the laboratory admin-
istrative staff, and each department calculated the error items of
(1) Severity (S), describes the degree of impact upon a system the project for verification. Some laboratories that conform to the
caused by the failure of an individual component or an oper- regulations might have no errors in the items, while some that
ational procedure. do not follow the regulations might have several errors in the
(2) Detection (D) describes the degree of impact caused by the items. Finally, after adding up all of the error items of the depart-
failure of an individual component or operational process, ments, the data was reported to the Safety and Hygiene Center for
which cannot be detected by the customer or the integration.
manufacturer. Hsieh (2006) argued that there were some disadvantages in the
(3) Occurrence (O) describers the degree of frequency with traditional FMEA: (1) the information in FMEA was represented in
which an individual component failure or an operation pro- the form of subjective language, which renders the information
cess failure may occur. inadequately objective and definite; (2) the relative importance
among the three parameters was not necessarily the same; (3)
The RPN (Risk Priority Numbers) are calculated using the fol- the same RPN did not necessarily indicate the same risk. To address
lowing formula: these problems, he suggested evaluating the RPN importance on
the bases of fuzzy theory. With the data collected from the expert
RPNðSÞ ðDÞ ðOÞ ð10Þ questionnaire survey, this study aggregates and averages the hier-
archical scores of (S), (D), and (O) of the 26 potential default factors
in Table 3. First, Eq. (10) is adopted to calculate the RPN and
4. Result sequence of the traditional FMEA method. Meanwhile, Eqs. (1)-
(10) are employed to calculate the RPN and prior disposal sequence
In order to obtain the relevant data of errors in laboratories, (as Table 5) of the fuzzy theory method, and the two sequences are
basic inspections of the laboratories are conducted. Before the compared. After discussions with the experts, it was agreed that
improvements, sampling inspection was carried out twice a week the RPN and sequence calculated with the fuzzy theory were more
in accordance with the proportion of laboratories during the 5th– consistent with the actual disposal procedures, and thus, more
8th week of the semester, which continued for one month. Inspec- suitable for improvement.
tion data was collected, and at the beginning of the 9th week, the As shown in Table 5, the RNP percentages calculated with the
administrative staff of the laboratories was asked to carry out lab- fuzzy theory are sequenced, and the top 10 factors are listed for
oratory waste recycle management and relevant training for the ‘‘priority improvement”, including (Type A) A1 ‘‘Unclear classifica-
above items until the end of the 12th week, which lasted for one tion”, A2 ‘‘Gathering liquid waste without a funnel or a drain pan”,
month. In the 13th–16th week, the laboratories were re- A3 ‘‘Spill over”, (Type B) B6 ‘‘Decentralized storage”, B2 ‘‘Compati-
inspected, and the inspection data was collected from the results. bility between the container material and the liquid waste”, (Type
This study only inspected the laboratories that produce waste liq- C) C1 ‘‘Lack of a clearance and transport contract”, C3 ‘‘Liquid waste
uid. Each inspection was checked by the laboratory administrative spill during delivery”, C4 ‘‘Lack of correct weight”, C2 ‘‘Lack of
staff, which divided the laboratories evenly to the four inspection
Table 5
RPN numbers and sequences of potential factors of the two methods. Source: Compiled by this study.
Food note: S(T): Severity by Traditional FEMA method, etc., S(F): Severity by Fuzzy theory FEMA method, etc., R: Ranking.
Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
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8 C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx
dumping and disposal tools”, and (Type D) D1 ‘‘Lack of a clearance (42.9%), which is the only item with an improvement rate of less
and transport contract”. The top 3 are A1, A2, and C1. than 50%. This indicates that the 10 items chosen according to
To confirm the ranking relevance of the top 10 default factor RPN ranking, as based on the fuzzy theory FMEA method, are
indices of RPN, and obtain the data regarding errors in laboratories, indeed important potential risk factors of laboratory liquid waste
this study undertakes follow-up laboratory sampling inspection disposal, and thus, must be improved. For the 26 risk factors sorted
and checking. This case study is based on TK University; while by this study, the average RPN calculated by the traditional FMEA
the objectives of this study are 216 laboratories, focus was placed is 18.50 ± 13.13, while the average RPN calculated by the fuzzy
on the 68 laboratories of chemical engineering that had generated FMEA is 17.63 ± 10.84. After one-tailed testing, the P value equals
liquid wastes. The administrative staff evenly divided the laborato- 0.08, and although it does not reach the significant difference of
ries into four weeks, in order that each laboratory was checked at 0.05 in statistics, it does indicate that the PRN calculated by fuzzi-
least once. The checking was performed by the same laboratory fication is different from the result produced by the traditional
administrators before and after the improvements. All the depart- method.
ments counted the 10 default items to be checked. Some laborato-
ries that conformed to the regulations might have no errors in the
items, while some that did not follow the regulations might have 5. Discussion
several errors in the items. Then, all the error items of the depart-
ments are counted and reported to the Safety and Hygiene center. Further analysis of the data sources of the error items show that
The error items before and after the improvement are as shown in the Physics Department had the highest improvement rate
Table 6, which reveals the differences in the 10 factors before and (100.0%); followed by the Department of Mechanical and Electrical
after the improvements. The total improvement rate is 60.2%, and Engineering and Department of Electric Machines (66.7%); the
the item with the highest improvement rate is A3 ‘‘Spill over” (80%) Environmental Engineering Department (56.3%), the Chemical
(Table 6). It is obvious that setting special requirements when Engineering and Material Department (55.0%); and the Chemistry
pouring liquid wastes into a recycling container could effectively Department (56.8%). As the Physics Department disposes of fewer
reduce spill over incidents. The items that followed A3 are: A2 liquid wastes, those in charge of laboratories could focus on the
‘‘Gathering liquid waste without a funnel or a drain pan” (66.7%), small number of laboratories that do generate liquid wastes, thus,
A1 ‘‘Unclear classification” (64.3%), B6 ‘‘Decentralized storage” it could achieve a higher improvement rate. The departments that
(55.6%). With the exception of C1 ‘‘Lack of a clearance and trans- had many error items before the improvements, including the
port contract”, which had no errors, the item with the lowest Chemistry Department; the Chemical Engineering and Material
improvement rate is C3 ‘‘liquid waste spill during delivery” Department, and the Environmental Engineering Department, have
Table 6
Data about the error items of laboratory liquid waste disposal before and after improvements. Source: Compiled by this study.
Table 7
Data about the liquid waste disposal of the laboratories of science institute and engineering institute before and after improvements. Source: Compiled by this study.
Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 9
a greater number of laboratories that generate liquid waste. In par- by the Fuzzy Theory FMEA method, is more appropriate than that
ticular, the Chemistry Department has the largest number of labo- produced by the Traditional FMEA method. According to the
ratories, and each experiment involves chemicals; therefore, more research results, the following conclusions were drawn:
errors are detected in these three departments. Conversely, the
reduced percentage in the number of accidents after improvement 1. In this study, the fuzzy theory FMEA method was adopted to
(Table 7) of the Chemistry Department is 37.5%; the Chemical Engi- analyze the 68 laboratories of chemical engineering that had
neering and Material Department is 19.6%; the Environmental generated liquid wastes, and 26 items for improvement were
Engineering Department is 16.1%. The total of the percentages of proposed. The number of the improvement items whose RPN
improvements of these three departments is 73.2%; hence, these percentage exceeded 40 was 10, and an improvement scheme
three departments made the biggest contribution to the improve- was made according to the 10 items. After re-checking, the
ment rate. improvement rate was 60.2%, which indicated significant
improvement. The major action plans were education and train-
ing methods as the results section.
6. Conclusion 2. Regarding the improvement rate, the top three departments
were the Chemistry Department (37.5%), the Chemical Engi-
With a sewage disposal plant as a case study, Hsieh (2006) neering and Material Department (19.6%), and the Environmen-
adopted the traditional FMEA method and fuzzy theory to analyze tal Engineering Department (16.1%). The total improvement
the reliability of the sewage disposal system. In this study, the rate of the three departments was 73.2%.
fuzzy theory FMEA method was employed to discuss the causes 3. According to the improvement rates of the factors, the item
of the defaults in the liquid waste management of school laborato- with the highest improvement rate was D1 ‘‘Lack of clear labels
ries. If the traditional FMEA method was applied to calculate and for liquid waste containers” (23.2%), followed by B6 ‘‘Decentral-
rank RPN, it would be impossible to detect D1 ‘‘Lack of clear labels ized storage” (17.9%) and A1 ‘‘Unclear classification” (16.1%).
for liquid waste containers”, which is an important potential The total improvement rate of the three items was 57.2%.
default factor ranked 10th. According to the check after the
improvement, the number of error items in D1 was 21, and the In addition, Christensen et al. (2007) provided Life-cycle assess-
reduction percentage was 23.2%, which had the highest improve- ment (LCA) models, which are becoming the principal decision
ment rate among the 10 factors (Table 6). It is obvious that the support tools of waste management systems. Bakas et al. (2018),
fuzzy theory FMEA method is better than the traditional FMEA which provides the application of LCA to solid waste management
method. Although liquid waste accounts for a small proportion of systems, is distinctive in that system boundaries are rigorously
waste management, it is an important part of school waste, and defined to exclude all life cycle stages, with the exception of the
is subject to regulatory requirements for recycling, storage, collec- end-of-life. Moreover, specific methodological challenges arise
tion, and management. In the laboratory accidents presented in when investigating waste systems. This study provides a similar
Table 2, improper management of laboratory liquid waste occurs LCA model for ISO systems for continuous quality improvement,
frequently, resulting in different sizes of accidents. and gives some suggestions to follow-up laboratory managers.
This study aimed to explore the problems in the liquid waste There are four steps to this LCA model, as follows:
recycling and disposal of chemical laboratories in universities,
and mainly compared the two tools of the FMEA method. First, 1. Define goals and scope
the feature factor table was used to identify the default factors of First, definition of goal is to reduce risk of laboratory risk, the
liquid waste recycling. Then, the scoring levels of severity, detec- higher probability of risk, the laboratory is in high unsafe state,
tion, and occurrence of the potential default factors of liquid waste only to reduce risk, laboratory can be in a safe situation. The
recycling and disposal were obtained from literature, and the RPNs scope of laboratory is to improve the liquid wastes, laboratory
of the potential factors of liquid waste recycling and disposal were accidents cause from many risk factors, this study focus on
calculated, in order to achieve a more objective and accurate eval- the laboratory liquid wastes treatment to improve process
uation benchmark for liquid waste recycling and disposal. With the and reduce of liquid wastes treatment risk.
fuzzy theory FMEA method, this study identified the important 2. Risk factor analysis
potential risk factors of laboratory liquid waste, and established There are many methods to determine risk factors. This study
recycling and disposal procedures for school liquid waste. Cheng uses an attribute factor graph (Fig. 1) to identify laboratory
et al. (2004) indicated that the fuzzy theory has been applied to lin- waste risks according to related factors. This method identifies
ear and nonlinear programming, integer programming, networks, laboratory waste treatment problems, which form the risk fac-
multi-rating decision making, group decision making, and expert tors this study aims to improve.
systems. As it can make up for the simplicity of the simplified 3. Impact assessment
model, it can provide a more flexible model to simulate real-life After the two above steps, risk factor assessment is conducted,
large-scale and complex systems. As can be seen from Table 5, in order to determine the influencing risks, the major effects,
the top 10 ranking from the Traditional FMEA method only and the risk priority number (RNP) of the laboratory risk factors.
accounts for Type A, B, and C in Systematic Functions, while in This study uses the FMEA method, and applies an expert ques-
the Fuzzy Theory FMEA method, we can see it in all four Systematic tionnaire to establish the quantitative index parameters. As
Functions, Types A, B, C, and D. Therefore, the Fuzzy Theory FMEA high RNP values mean larger risk factors, this study conducts
method can be more balanced in the direction of each Systematic detailed analysis and provides suggestions or solutions for
Function. The difference of the two methods lies in Type C and D. improvement. The assessment process must consider Severity,
Type C C1 ranked 6th in the Traditional FMEA method, while in Detection, and Occurrence.
the Fuzzy Theory FMEA method, its importance is ranked 3rd. 4. Continuous tracking
Another important factor is in Type D, and there is no factor reach- After implementing the improvement suggestions, it is neces-
ing the top 10 in the Traditional FMEA method; while in the Fuzzy sary to regularly conduct laboratory liquid waste checks, in
Theory FMEA method, we have the D1 factor in the top 10, which is order to determine whether the improvement suggestions or
an important item for improvement. Through this study, the solutions reach their intended goals. If improvement goals are
experts agreed that the ranking of the top 10 factors, as calculated not achieved, re-establish new risk factors and provide new
Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
10 C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx
solutions, as necessary. If the original risk factors are improved, Buckley, J.J., 1985. Fuzzy hierarchical analysis. Fuzzy Set Syst. 17, 233–247.
Burgmeier, J., 2002. Failure mode and effect analysis: an application in reducing risk
re-check to determine the degree that those risk factors have
in blood transfusion. Joint Commiss. J. Quality Patient Saf. 28, 331–339.
been reduced. In addition, lower PRN values must also be Chang, Y.M., Wang, Y.X., 2006. Waste Disposal. New WunChing Developmental
checked, one by one, and improved. Publishing Co., Ltd.
Chen, C.Y., Chang, K.C., Huang, C.H., Lu, C.C., 2016a. Study of chemical supply system
of high-tech process using inherently safer design strategies in Taiwan. J. Loss
According to the results of this study, the fuzzy theory FMEA Prevent. Proc. 29, 72–84.
method can effectively determine the major risk factors, enhance Chen, Y.H., Lai, J.W., Wang, S.Y., Chen, J.L., Huang, Z.J., Li, B.W., Wu, Y.W., Chen, M.S.,
the safety of laboratory liquid waste disposal, and protect the 2016b. Risk assessment of radiopharmaceutical administration and
enhancement of the safety and imaging quality by using healthcare failure
safety and health of laboratory staff in the disposal of laboratory mode and effect analysis (HFMEA) model. Ann. Nucl. Med. Mol. Imag. 29, 105–
liquid waste in universities. In addition to identifying the top 10 125.
causes of abnormal liquid waste, the two methods of fuzzy FMEA Chen, S.J., Hwang, C.L., 1992. Fuzzy Multiple Attribute Decision Marketing Methods.
In Fuzzy Multiple Attribute Decision Making. Springer, Berlin Heidelberg, pp.
and traditional FMEA were analyzed and compared, which found 289–486.
that the innovative fuzzy FMEA method is more discriminatory. Cheng, C.C., Tsai, L.M., Shyu, J.Z., Tzeng, G.H., 2004. Fuzzy heuristic algorithm
Moreover, the method is more effective than the traditional FMEA method for transport route-choice of low-radiation waste junk. Chung Hua J.
Manage. 5, 41–56 (http://people.chu.edu.tw/chjm/document/5-1/003.pdf).
method, which will be useful for higher education institutions that Chien, Y.S., Lin, C.L., Lu, C.W., Chiu, W.M., Wang, T.C., Tao, C.J., Kuo, Y.P., 2000. The
are equipped with chemical laboratories. It is suggested that train- study on hazard assessment of school dangerous laboratories. Qin Yi J. 18, 95–
ing for administrative staff regarding control over school chemical 104.
Christensen, T.H., Bhander, G., Lindvall, H., Larsen, A.W., Fruergaard, T., Damgaard,
laboratories should be intensified; students’ awareness of environ-
A., Hauschild, M., 2007. Experience with the use of LCA-modelling
mental protection and safety should be enhanced; the liquid waste (EASEWASTE) in waste management. Waste Manage. Res. 25 (3), 257–262.
control procedures and laboratory management mechanisms Deus, R.M., Battistelle, R.A.G., Silva, G.H.R., 2017. Scenario evaluation for the
should be further defined to reduce the chance of accidents. In management of household solid waste in small Brazilian municipalities. Clean
Technol. Environ. Policy 19 (1), 205–214.
terms of school management, it is suggested that the number of Escande, J., Proust, C., Coze, J.C.L., 2016. Limitations of current risk assessment
administrative positions in safety and hygiene management units methods to foresee emerging risks: Towards a new methodology? J. Loss
should be increased, and the professionals in charge of school man- Prevent. Proc. 43, 730–735.
George, J., Klir, Yuan, B., 2008. Fuzzy Set and Fuzzy Logic. Theory and Application,
agement should implement the tasks of checking and manage- ISSN 0-13-101171-5.
ment, in order to improve the publicity of safety and hygiene Hsieh, M.H., 2006. Application of Failure Mode and Effect Analysis based on Fuzzy
management. Finally, it is suggested that school leaders pay close Theory-The Case of Sewage Treatment Plant. National Taiwan University of
Science and Technology. PhD thesis.
attention to school safety and hygiene, and require faculties and Hsu, P.C., Hsieh, P.H., 2016. The trend of changes in the number of Taiwanese
students to attach importance to this aspect, thus, forming a safety students over the Past 25 Years. Evaluat. Bimonthly 60, 30–31 (http://www.
and hygiene network on campus, which will reduce the possibility airitilibrary.com/Publication/alDetailedMesh?docid=a0000268-201603-
201603080007-201603080007-30-31).
of accidents in an effective manner. The advantages of the applica- Ho, C.C., Liao, C.J., 2011. The use of failure mode and effects analysis to construct an
tion of refined methods to understand quality control arise rather effective disposal and prevention mechanism for infectious hospital waste.
clearly from this work. However, in specific field applications of Waste Manage. 31, 2631–2637.
Horng, J.J., Kuo, J.Y., 2007. A preliminary study on the management system of
laboratories, the results seem to be well identifiable, even without
chemical storage and transportation in Taiwan. Environmental poison E-
complex analysis, and the observed improvements attributable to paper5. (https://toxicdms.epa.gov.tw/edm/EpaperContent.aspx?EpaperTitleid=
expert follow-up are due to the ranking exercise, and not to the 50&type=5&id=610)
method itself. The ranking of the principal default factors seem Jia, T.B., Shi, D.S., 2005. The Guideline of ‘‘Safety and Hygiene Plan for Laboratory
Chemicals”. Institute of Labor, Occupational Safety And Health, Ministry of
to result in typical situations, where the lack of proper control by Labor. https://laws.ilosh.gov.tw/Book/Public_Publish.aspx?P=22/.
technical operators on students and/or untrained user activities Jose Chiappetta Jabbour, C., Serotini Gordono, F., Henrique Caldeira de Oliveira, J.,
could be the most significant issue, and beyond all the other high- Carlos Martinez, J., Aparecida Gomes Battistelle, R., 2011. Diversity
management: challenges, benefits, and the role of human resource
lighted causalities. Despite the content not being strictly included management in Brazilian organizations. Equal., Divers. Inclus.: Int. J. 30(1),
in a scientific or technological issue, the topic of wastes, risks, pp. 58–74.
and security in laboratories is of potential interest for many oper- Kaufman, A., Gupta, M.M., 1991. Introduction to Fuzzy Arithmetic: Theory and
Application. Van Nostrand Reinhold Company, New York.
ators. Furthermore, the utilization of a chemometric statistical Kuo, T.Y., 2005. Discussion of waste liquid flowing arrangement and control system
approach to understand quality issues adds valuable elements to in lab of college. Graduate Institute of Environment Engineering National
this paper. Central University Master thesis. (http://handle.ncl.edu.tw/11296/ndltd/
02156482194155666466)
Lara, E.R., De la Rosa, J.R., Castillo, A.I.R., de Jesús Cerino-Córdova, F., Chuken, U.J.L.,
Acknowledgements Delgadillo, S.S.F., Rivas-García, P., 2017. A comprehensive hazardous waste
management program in a Chemistry School at a Mexican university. J. Clean.
Prod. 142, 1486–1491.
The authors wish to thank the administration support of TK Liao, C.J., Ho, C.C., 2014. Risk management for outsourcing biomedical waste
University and Taiwan University of Science and Technology. The disposal – Using the failure mode and effects analysis. Waste Manage. 34,
1324–1329.
authors would also like to thank the Directors of the Department
Li, K.C., 2000. Improve each university campus pollution control public facilities
of Environment Engineering; Chemistry; Chemical Engineering integrated planning (II). Taiwan’s Ministry of Education commissioned of
and Material; the leader of the General Affairs Office of TKU, and environmental group plan.
all other team members at the Environment Safety Center in TKU Lin, C.W., Kuo, Y.C., Kuo, S.H., 2002. Investigation on the fires and explosions in
chemicals-related university laboratories. Taiwan’s Ministry of Labor. Laborand
for their support and help. Occupational Safety and Health Institutereport.
Ni, B.X., 2002. A study on treatment and management for hazardous wastes
generated from laboratories. Institute of Environment Engineering and
Conflict of interest Management National Taipei University of Technology, Master thesis.
Panchal, D., Kumar, D., 2016. Sntegrated framework for behaviour analysis in a
The authors declare that they have no conflicts of interest. process plant. J. Loss Prevent. Proc. 40, 147–161.
Sun, Y.M., 2015. Tsinghua Laboratory Explosion - the Campus Safety Management of
Dangerous Chemicals Cannot Be Underestimated, iRead, (https://read01.com/
References QE6jAk.html).
Taiwan’s Ministry of Education, 2016. Department of Statistics. Education statistics
Search website. https://stats.moe.gov.tw/qframe.aspx?qno=MQAxAA2.
Bakas, I., Laurent, A., Clavreul, J., Saraiva, A.B., Niero, M., Gentil, E., Hauschild, M.Z.,
Tsai, H.Y., 2012. Laboratory poisoning case and strain mechanism. Taiwan’s
2018. LCA of solid waste management systems. In Life Cycle Assess. 2018, 887–
Environmental Protection Administration, Executive Yuan report.
926.
Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 11
Tsai, P.J., Su, H.J., Tong, Y.H., 2000. Sustainable campus environmental management Willy, W.V., 1998. How to FMEA to reduce the size of your quality toolbox. Qual.
- evaluation and improvement of safety and health field in Chinese Universities. Progress 31, 97–100.
Quart. J. Environ. Educ. 44, 18–29. Yu, S.W., Chou, K.S., 2001. Introduction to Chemical Process Safety. GauLih Book Co.,
Tseng, T.Y., Klein, C.M., 1989. New algorithm for the ranking procedure in fuzzy Ltd.
decision making. IEEE Trans. Syst. Man. Cybernetics 19, 1289–1296. Zadeh, L.A., 1965. Fuzzy sets. Inform. Control 8, 338–353.
Wu, H.T., 2007. The Development of a Chemical Incompatibility Warning System for Zimmerman, H.J., 1991. Fuzzy Set Theory and Its Application. Kluwer Academic
Wastewater of Laboratory. Graduate Institute of Environment Engineering Publishers, Boston.
National Central University, Master thesis.
Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029