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Waste Management xxx (2017) xxx–xxx

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Waste Management
journal homepage: www.elsevier.com/locate/wasman

Risk assessment and quality improvement of liquid waste management


in Taiwan University chemical laboratories
Chao-Chung Ho a,1, Ming-Shu Chen b,1,⇑
a
Department of Public Administration, Nanfang College of Sun Yat-Sen University, Conghua District, Guangzhou Hot Springs Road, No. 882, China
b
Department of Health Care Administration, Oriental Institute of Technology, No.58, Sec. 2, Sihchuan Rd., Pan-Chiao Dist., New Taipei City 22061, Taiwan, ROC

a r t i c l e i n f o a b s t r a c t

Article history: The policy of establishing new universities across Taiwan has led to an increase in the number of univer-
Received 3 April 2017 sities, and many schools have constructed new laboratories to meet students’ academic needs. In recent
Revised 21 September 2017 years, there has been an increase in the number of laboratory accidents from the liquid waste in univer-
Accepted 22 September 2017
sities. Therefore, how to build a safety system for laboratory liquid waste disposal has become an impor-
Available online xxxx
tant issue in the environmental protection, safety, and hygiene of all universities. This study identifies the
risk factors of liquid waste disposal and presents an agenda for practices to laboratory managers. An
Keywords:
expert questionnaire is adopted to probe into the risk priority procedures of liquid waste disposal; then,
Waste management
Laboratory liquid waste
the fuzzy theory-based FMEA method and the traditional FMEA method are employed to analyze and
Failure Mode and Effects Analysis (FMEA) improve the procedures for liquid waste disposal. According to the research results, the fuzzy FMEA
Fuzzy theory method is the most effective, and the top 10 potential disabling factors are prioritized for improvement
according to the risk priority number (RNP), including ‘‘Unclear classification”, ‘‘Gathering liquid waste
without a funnel or a drain pan”, ‘‘Lack of a clearance and transport contract”, ‘‘Liquid waste spill during
delivery”, ‘‘Spill over”, ‘‘Decentralized storage”, ‘‘Calculating weight in the wrong way”, ‘‘Compatibility
between the container material and the liquid waste”, ‘‘Lack of dumping and disposal tools”, and ‘‘Lack
of a clear labels for liquid waste containers”. After tracking improvements, the overall improvement rate
rose to 60.2%.
Ó 2017 Elsevier Ltd. All rights reserved.

1. Introduction factors of liquid waste disposal, and presents a practice agenda


to laboratories managers. This paper contributes to the knowledge
To improve higher education and research environments in of practices to improve laboratory liquid waste management. How-
Taiwan, Taiwanese education management institutions have made ever, the continuous increase in the number of laboratories in uni-
a series of policies to promote the establishment of new universi- versities and research institutes in recent years has resulted in a
ties, departments, and research institutes in recent years, which greater number of industrial wastes, such as waste, liquid waste,
has indirectly accelerated the development of new technologies. and effluent. The increasing number of laboratories has caused
The number of Taiwanese universities has increased by 27, from an increase in industrial waste, as well as complex management
137 in 1996 to 164 in 2007, which reaches an historical peak issues. In particular, the follow-up disposal of the liquid waste gen-
(Hsu and Hsieh, 2016). As the number of universities and research erated by school laboratories has gradually attracted social atten-
institutes increases, it is necessary to provide laboratories for tion in recent years; therefore, the industrial management
students to conduct experiments or research, and thus, improve institutions responsible for waste disposal have collaborated with
their skills and abilities. While the objective of this study is 216 universities to take relevant management measures to meet the
laboratories, focus is placed on 68 laboratories for chemical engi- social expectations on universities.
neering that generate liquid wastes. This study identifies the risk Most universities in Taiwan are equipped with a laboratory.
According to Article 2 of the Waste Disposal Regulations in the
revised announcement on October 24, 2001, school laboratories
⇑ Corresponding author at: Department of Public Administration, Nanfang have become a business designated by the law, and schools must
College of Sun Yat-Sen University, No.882, Wenquan Road, Wenquan Town, report their waste disposal online since July 1, 2005. In other
Conghua District, Guangzhou, Guangdong 510970, PR China.
words, the liquid waste discharged by the laboratories of academic
E-mail address: tree1013@gmail.com (M.-S. Chen).
1
These authors contributed equally to this work.
or research institutes has been listed as an object to be strictly

https://doi.org/10.1016/j.wasman.2017.09.029
0956-053X/Ó 2017 Elsevier Ltd. All rights reserved.

Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
2 C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx

controlled, and must be well disposed of in accordance with rele- versities across the nation: 14 junior colleges, 21 technical
vant regulations for industrial waste management, as stipulated institutes, 126 universities, and 2 National Open Universities, for
in the Waste Disposal Regulations. There are regulations related a total of 160 higher education institutes. All these schools, espe-
to the management of waste; regulations related to academic insti- cially the departments of science, engineering, and chemistry, are
tutions include: Waste Disposal Act, Waste Disposal Act Enforce- equipped with a laboratory for the internship and practices of stu-
ment Rules, Methods and Facilities Standards for the Storage, dents. Chemical experiments in the laboratory would generate liq-
Clearance and Disposal of Industrial Waste, Measures for the uid waste.
Administration of the Common Disposal of Waste Disposal of Edu-
cational Institutions, Notice on the Required Waste Clearance Plan,
2.1. Laboratories liquid waste
Notice on the Regulation that the Waste Production, Storage, Clear-
ance, Disposal, Recycling, Input and Output Should Be Reported by
According to the ‘‘Improve each university campus pollution
Network Transmission, Resource Recycling Act, The handling of
control public facilities integrated planning (II)” by Taiwan’s Min-
toxic chemical substances by academic organizations management
istry of Education, Li (2000) conducted a questionnaire survey to
method, and Standards for Defining Hazardous Waste. Inspection
estimate the quantity of the laboratory wastes of schools at all
regulations for the waste management of for-profit institutions
levels in Taiwan, and the findings showed that the liquid waste
are stringent, while not-for-profit university laboratories are man-
of the laboratories of these schools in 2000 was around
aged by means of self-regulation due to their small size. The aspect
1,691,100 liters/year (as Table 1). The estimated quantity of liquid
of ‘‘waste management” is, however, marginal and relegated to the
waste of higher education institutes was about 740,100 liters/year,
administrative field due to very small quantities, which do not rep-
accounting for about 43.76%. The liquid wastes include organic liq-
resent a serious management problem. However, a lot of the acci-
uid waste, acid and alkaline liquid waste, cyanide liquid waste,
dents and personal injuries that have occurred in university
heavy metal liquid waste, hexavalent chromium liquid, mercury
laboratories or not-for-profit laboratories were caused by improper
liquid waste, and others. Specifically, heavy metal liquid waste
handling of waste from academic chemical laboratories. This
accounts for 47.9%; organic liquid waste accounts for 32.2%; acid
reveals that the disposal of the waste of school laboratories has
and alkaline liquid waste accounts for 12.4%. According to the
been controlled and standardized by relevant laws and regulations
research report, most liquid waste is hazardous industrial waste,
in Taiwan.
which affects human health and causes environmental pollution;
According to Kuo (2005), the use of chemicals in school labora-
if appropriate control measures are not taken, such liquid waste
tories have the following features: (1) a wide variety, (2) great
will have severe impact on the environment and affect public
change, (3) specialty, and (4) small amount. Regarding school lab-
health.
oratories, generation and management may lead to environmental
According to the research data from Ni (2002), there has been
pollution, and the potential risks and hazards caused by inappro-
great quantities of wastes generated by the laboratories of schools
priate management and disposal of liquid waste are all related to
at all levels in Taiwan every year; 92 ± 7% of them were hazardous
the hazards of laboratories that use chemicals. Therefore, the lack
according to the standards of hazardous industrial wastes; annu-
of effective measures of disposing of hazard wastes may cause
ally, the schools created about 1586 metric tons of hazardous
environmental pollution and pose harm to laboratory staff.
industrial wastes, and 1556 metric tons were the liquid wastes of
Horng and Kuo (2007) analyzed the 340 cases of chemical storage
laboratories. Kuo (2005) summarized the data released by the Min-
accidents between 1997 and 2006, and found that 30% were caused
istry of Education, and found that the annual estimated quantity of
by human error; 26% by storage factors; 44% by other problems,
the liquid wastes of school laboratories across the nation from
such as malfunction of safety equipment and wire fires. While lab-
2001 to 2005 ranged between 1,650,000 l to 1,700,000 l. These data
oratories consume less chemicals than factories, the wide variety,
show that liquid wastes account for a large proportion of labora-
great change, and special uses increase the complexity of the man-
tory wastes.
agement, storage, and disposal of laboratory chemicals. Worse still,
The most important result of the comprehensive program for
there is an inadequate number of laboratory maintenance staff in
hazardous waste management is the legacy of environmental care
schools, and staff management is inefficient. Hence, human errors
imparted to the student community. Lara et al. (2017) the scientific
may be the main causes of laboratory accidents. Jose et al. (2011)
value of this paper is the development of a new classification of
found that among the 15 companies studied, only four had adopted
hazardous waste, which can be useful in the chemistry depart-
a consistent set of diversified management and human resources
ments of universities. Finally, this work acknowledges the chal-
practices. These four companies were the only companies to affirm
lenge for universities and organizations to act, develop
that diverse management requires the strong support of top man-
sustainability, and change the paradigms and assumptions on
agement and continuous organization to sustain efforts toward
which these organizations are currently based.
incorporating diversity.
Chien et al. (2000) argued that the amount of hazardous mate-
rials used in university laboratories was small in quantity, but the
2. Literature review chemicals are widely varied. Although the experimental procedure
is simple, both teachers and students tend to overlook the potential
According to Taiwan’s Ministry of Education (2016), the Depart- hazards. Yu and Chou (2001) argued that the most common hazard
ment of Statistics website data announced the total number of uni- in laboratories was chemicals – meaning immediate harm or

Table 1
Total quantity of liquid waste of laboratories of schools at all levels in Taiwan in 2000.

Variety Acid and alkaline Heavy metal liquid Hexavalent liquid Cyanide liquid Organic liquid Mercury liquid Other liquid Total
liquid waste waste waste waste waste waste waste
Liters/Year 210,300 809,800 94,700 5,000 544,600 9,900 16,900 1,691,100
Percentage 12.4 47.9 5.6 0.3 32.2 0.6 1.0 100.0
(%)

Reference Li (2000).

Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 3

cumulative pathological changes to the internal and external parts These accident reports underline the importance of laboratory
of the human body, as caused by fire, explosion, poisonous, and safety and management on campus.
erosive materials. According to Chang and Wang (2006), there According to Tsai et al. (2000), the proportion of those in
was an increasing number of equipment, facilities, and chemicals charge of safety and hygiene in the establishment of safety and
in school laboratories, and the hazardous wastes of the laboratories hygiene units of Taiwanese universities was lower than 10%,
were complex, various, and highly changeable; worse still, the lack and most of the staff was spontaneously responsible for other
of professional staff, standard operational management, and rele- tasks. To date, many universities have formed safety and hygiene
vant disposal channels would cause secondary pollution to the teams; however, the leaders have not paid adequate attention to
environment. the issues; the teachers and the students are not fully aware of
the safety problems; only a few of the people in charge of safety
2.2. Safety of laboratories and hygiene have expertise in this aspect. Although there are
schools in Taiwan conducting environment and safety manage-
Sun (2015) indicated that chemical laboratories have numerous ment by obtaining ISO certificates, ISO standards are less compul-
potential safety problems, as inflammable, explosive, and poi- sory than laws and regulations. If there is only a slight violation of
sonous chemicals are stored there. Moreover, the electrical devices ISO standards, they still have room for improvement; however,
in the chemical experiments are often in a state of high tempera- once there is violation of law, punishment and improvement are
ture and pressure, thus, they are more vulnerable to fire and explo- executed immediately. Consequently, safety and hygiene manage-
sion than common laboratories. The organic compounds in ment of the experimental rooms on campus remain to be imple-
chemical laboratories are highly inflammable and explosive, and mented. According to the research report of the ‘‘Investigation of
hazardous chemicals have different critical temperatures, critical the fires and explosions in chemicals-related university laborato-
pressures, and critical concentrations. ries”, Lin et al., (2002) observed the collected cases, and found that
Universities are places where talents are trained, and nearly all the causes of the accidents could be divided into three groups: (1)
universities are equipped with various laboratories. In recent years, inappropriate management of chemicals, (2) mechanical or device
there have been many reports of accidents in the laboratories or malfunction, and (3) natural disasters. The inappropriate manage-
practical sites of universities. Taiwan has also witnessed a series ment of chemicals includes four parts, namely, the inappropriate
of laboratory accidents in its universities since 2000 (as Table 2). storage of chemicals, the inappropriate use of chemicals, the

Table 2
A list of laboratory accidents in Taiwanese Universities since 2000. Source: Cases of Poisonous and Chemical Disasters in Laboratories (Tsai, 2012); news events and the data
summarized by the authors of this paper.

Date Location Cause


2001/04/24 The laboratory of School of Sciences at Sun Yat-sen University Alcohol mixed with chemicals was poured into a waste container
2001/07/22 The laboratory of Kaohsiung Medical University 1, 2-Dimethoxyethane spilled due to high temperature, and there was a fierce
reaction between the spilled chemical and the adjacent Potassium
Permanganate
2002/02/27 Fire in the laboratory of Tainan University of Technology The control line of the heater caught fire and ignited the exhaust cabinet
2003/03/06 Fire in the air pollution analysis laboratory of Chia Nan University of In the extraction experiment in the exhaust cabinet of the air pollution analysis
Pharmacy & Science laboratory, a bottle was broken and the evaporated materials were ignited,
which led to the fire
2003/12/10 The spilling of formalin at National Taitung University, National It was alleged that the sample containers fell onto the floor and broke due to an
Primary School, and the Aquaculture Laboratory of National Cheng earthquake, emitting a pungent odor
Kung University
2007/09/20 Fire in the laboratory of National Pingtung University A collision in the delivery of chemicals stored in the chemical cabinet (it is
alleged that the collision caused the mixture of Toluene and other solvents and
Hydrogen dioxide and other oxidants, which led to fierce chemical reaction due
to the incompatibility of the chemical materials) (Heat and smoke)
2007/10/19 Fire in the research room of the Kaohsiung Medical University The inappropriate storage of chemicals led to a spontaneous reaction, which
led to a gas explosion
2009/07/21 Gas explosion in the teaching building of Kaohsiung Medical It was alleged that the wire fire of the paraffin embedding machine caused the
University fire
2012/03/10 Fire alarm in the laboratory of the water conservancy engineering The accident occurred in the Termovap Sample Concentrator, and only Toluene
institute of National Cheng Kung University Hexane was affected
2013/05/11 Chemical explosion in the Chemical Building of National Chung It was alleged that too much activated carbon was added into the Isopropyl
Hsing University Alcohol in the experiment of re-crystallization, which led to excessive heat in a
short time
2013/06/25 Fire in the dumpcart of National Yunlin University of Science and There were substances that should be kept away from water in the waste. It
Technology was alleged that the fire was caused by the exposure of the substances to water
2013/09/20 Fire in the laboratory of the Material Department of the Electrical Chemicals featuring strong acid and base were not appropriately placed around
Science and Engineering Building of National Dong Hwa University the air exhaust cabinet of the laboratory, which led to the fire
2014/01/28 Fire alarm in the Chemical Engineering Building of National Tsing The laboratory counter caught fire for no reason. It was alleged that there was a
Hua University wire fire
2014/05/14 White smoke in the laboratory of Chemical Engineering Department Solid zinc was thrown onto a pile of solid wastes, including used test paper and
of National Cheng Kung University filtering paper used in the experiment. Active zinc should not be mixed with
other chemical substances
2015/05/19 Gas explosion in the laboratory of Civic Engineering Research In a concrete pressure reinforcement device experiment, the inappropriate use
Institute of National Taiwan University of high pressure gas cylinders resulted in the explosion
2016/05/08 Poisonous gases spilled from the Mimicry Center of Physics It was alleged that a little fluorine gas spilled due to a worn-out connection line
Department of National Taiwan University of the laser gun. Highly poisonous, this gas is pungent to eyes, skin, and
respiratory mucous membranes. A high concentration of the gas is lethal
2016/05/13 White smoke in the Petroleum Chemical Industry Research Center of It was alleged that the smoke and fire were caused by the inappropriate
National Taiwan University maintenance of the circuit board of the Chemical Engineering Research Room

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inappropriate delivery of chemicals, and the inappropriate dis- 2.4. Objectives


posal of chemicals.
According to the disposal of liquid wastes of laboratories, as This is a case study based on TK University (TKU); while the
described by Wu (2007), liquid wastes were first classified and objectives of this university are 216 laboratories, focus is placed
gathered in liquid waste containers, and then, stored in the labora- on the 68 laboratories of chemical engineering that generate waste
tory or a regular liquid waste storage room. At the end of the seme- liquids. Most of the waste liquid production comes from the
ster, they would be transported to the school’s liquid waste storage department of science and engineering, including the Physics
field, and a clearance company was called to deliver them to the Department and Chemistry Department from the School of
waste disposal plant when the quantity of liquid waste reached Science; Environmental Engineering, Mechanical Engineering,
the designated level. In addition to external factors, such as time, Chemical Engineering, and Electrical Engineering from the School
space, and quantity, human errors, such as an unclear labelling of of Engineering, among which the Chemistry Department accounts
liquid waste containers, a wrong record, an incorrect classification, for the largest proportion of waste liquid production.
and overlooked compatibility would also lead to follow-up hazards
and threaten the safety of the campus. Therefore, relevant safety
3. Material and methods
measures should be added to waste management procedures in
addition to control over the environment and operation, in order
To confirm the effectiveness of the research tools in the evalu-
to avoid unexpected chemical hazards caused by human errors
ation and analysis of the causes and risk of potential faults in lab-
and external factors. However, how to improve the automatic
oratory liquid waste disposal procedures, this study bases the
examination and alarm mechanism in the procedure is a critical
settings of the evaluation norms on the Guideline of ‘‘Safety and
part of liquid waste management.
Hygiene Plan for Laboratory Chemicals” (Jia and Shi, 2005) of the
Institute of Labor, Occupational Safety, And Health, Ministry of
Labor. The seriousness of evaluation norms and incident evaluation
norms are taken as the evaluation norms of laboratory liquid waste
disposal. Meanwhile, three directors in the Environment Safety
2.3. Failure mode and effects analysis, FMEA
Center, including the head of the Toxic Substance Management
Team, the head of the Safety and Hygiene Team, and the Head of
FMEA was developed in the 1950s in response to the low level
the Environmental Protection Team, constructed an attribute fac-
of reliability of oil pressure devices and the electrical devices of
tor graph through discussions to determine the risk and hazard
American fighter planes, which often resulted in plane crashes.
factors in the procedures (Fig. 1). Then, prevention and improve-
The aircraft company Grumman was the first to apply the concept
ment measures were sought according to the faults in the recy-
of FMEA to the fault analysis of the main control system of planes.
cling, storage, clearance, and delivery procedures of the
In fact, FMEA has been widely used in space, aviation, national
laboratory liquid waste disposal of universities. Therefore, this
defense, automobiles, electronics, mechanics, shipbuilding, medi-
study begins with the problems of the previous recycling, storage,
cine, and even in the service industry. Willy (1998) applied FMEA
clearance, and delivery procedures of laboratory liquid wastes, and
to the ISO14001 environment management system, and analyzed
creates a fault mode factor table (Table 3) of the laboratory liquid
the potential environmental risks of new product manufacturing.
waste disposal procedures, which is comprised of 4 systems and 26
Chen et al. (2016a,b) adopted FMEA to evaluate the priority of
indices” according to FMEA and discussions of the above three
the service demands of the elderly in policies regarding aging. Ho
experts. The table is taken as the analysis tool of this study.
and Liao (2011) employed the FMEA method to appraise the risk
This study adopts an expert questionnaire survey involving 8
factors of infectious waste disposal procedures according to the
experts of liquid waste disposal. The fault model factors in Table 3
score of the risk priority index. Additionally, Liao and Ho (2014)
are taken as the subjects to evaluate the risks in the recycling, stor-
used FMEA to evaluate risk in the evaluation of bio-waste disposal
age, clearance, and delivery of laboratory liquid wastes. The
plants. In addition to being applied to the disposal of bio-waste, the
detailed information about the experts is, as follows (Table 4):
revised FMEA was adopted for medical improvement. By applying
Unlike the traditional application of FMEA, this study adopts the
FMEA to the medical procedure, Burgmeier (2002) redesigned and
fuzzy theory to calculate the severity (S), detection (D), occurrence
improved blood transfusion procedures, and thus, reduced the inci-
(O), and risk priority number (RNP) of the factors in the analysis of
dents of untoward reactions in blood transfusions. Therefore, FMEA
potential risks, in order to define the priority of disposal. The fuzzy
will be of great help in strengthening the management of chemical
set theory is, as follows:
laboratories and reducing the risks of accidents. Cheng et al. (2004)
first conducted lithography process hazard analysis, and compiled
statistical analysis of the causes of the fires and losses at high-tech 3.1. Fuzzy set theory
plants in Taiwan. The research of Panchal and Kumar (2016) sought
to propose a quantitative and qualitative approach based inte- The Fuzzy Set Theory was proposed by L. A. Zadeh in 1965,
grated framework for the behavior analysis of a process plant sys- which was different from the crisp set and definite value of tradi-
tem. Escande et al. (2016) identified a set of safety measures, tional mathematics; the proposed fuzzy set and Membership
including design, technical, management, and emergency actions, Degree refer to the Quantification of Meaning, which is used for
which shall be implemented in each step of a system’s life cycle. solving uncertainty, fuzziness, and other phenomena in realistic
Deus et al. (2017) aimed to evaluate the Greenhouse Gas emissions environments.
and energy use of six scenarios in two landfills contexts (private
and consortium) for small municipalities (less than 100,000 inhab- 3.2. Membership function (Zadeh, 1965)
itants, as per Brazilian standards) located in São Paulo, Brazil. A
landfill consortium will only be advantageous if the location is The fuzzy set Ae on the universe of discourse X must satisfy
the most ideal. Small municipalities that do not dispose of their function le on the following X, calling function le as membership
A A
waste in landfills compatible with regulatory standards may seek e that is, v 2 X, only exists in one value l (v) 2 [0,1],
function of A, e
inter-municipal cooperation, and adopt integrated waste- A

management programs to reduce their environmental impacts. leA (v) means level of v belonging to. A. e

Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
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C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 5

The substances would


Storage evaporate and spill Recycling
over the container
Use a designated container
(a 20-liter HDPE container) Not stored in a low-temperature environment
Unclear classification
Lack of an alarm system Gathering liquid waste without
a funnel or a drain pan
Spill over
Decentralized storage Not using protective
tools during recycling
The data about newly-added
liquids waste are not added into Compatibility between the container
the waste liquid collection list material and the liquid waste Analysis of reducing
the risk in laboratory
Correctness of the data about liquid waste disposal
clearance and transport Lack of a clear label for
hazardous industrial wastes
Lack of a clear label for liquid Lack of a clearance and transport
waste container Waste liquid spills during delivery
contract
Label of conformity to the Lack of a plan for emergencies
demands of the regulation Lack of dumping and disposal tools
Irregular check on the alarm and Lack of the weight
monitoring system Lack of special of the liquid waste Lack of correct weight
management container
Lack of a plan for the clearance The clearance vehicle should meet
of wastes Lack of confirmation within 48 hours the regulations
Lack of a clearance
and transport triplicate Management Clearance and transport

Fig. 1. Factor attribute causes of risk hazards of laboratory liquid waste.

Table 3
Potential factors of the default model of laboratory liquid waste disposal procedures.

Cause Systematic function Potential factors of the default mode Item


Risk analysis of liquid (Type A) Unclear classification A1
waste recycling Recycling Gathering liquid waste without a funnel or a drain pan A2
Spill over A3
Not using protective tools during recycling A4
(Type B) The substances would evaporate and spill over the container B1
Storage Compatibility between the container material and the liquid waste B2
Use a designated container (a 20-liter HDPE container B3
Lack of an alarm system B4
Not stored in a low-temperature environment B5
Decentralized storage B6
(Type C) Lack of a clearance and transport contract C1
Clearance and transport Lack of dumping and disposal tools C2
Liquid waste spills during delivery C3
Lack of correct weight C4
The clearance vehicle should meet the regulations C5
Lack of weight of the liquid waste container C6
(Type D) Lack of a clear label for liquid waste containers D1
Management Irregular checks on the alarm and monitoring system D2
The data about the newly-added liquid wastes are not D3
added into the liquid waste collection list
Lack of a clearance and transport triplicate D4
Lack of special management D5
Lack of a plan for the clearance of wastes D6
Lack of confirmation within 48 h D7
Correctness of the data about clearance and transport D8
Lack of a clear label for hazardous industrial wastes D9
Lack of a plan for emergencies D10

3.3. Positive Triangular fuzzy number (Kaufman and Gupta, 1991) According to the characteristics of triangular fuzzy numbers
and the extension principle (Zimmerman, 1991; George et al.,
Positive Triangular Fuzzy Number A e is a fuzzy set, as indicated 2008), the operational laws of two triangular fuzzy numbers
e A e 2 = (L2, M2, U2) are, as follows:
e 1 = (L1, M1, U1) and A
by A = (L, M, U), and the definition of the membership function
(Fig. 2) is, as follows: e 2 ðL1 þ L2 ; M1 þ M2 ; U1 þ U2 Þ
e1  A
8 A ð2Þ
< ML ; L 6 X 6 M
> XL

leA ðvÞ ¼ MU


XU
; M6X6U ð1Þ e1  A
A e 2 ðL1  L2 ; M1  M2 ; U1  U2 Þ ð3Þ
>
:
0; otherwise

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Table 4
The name list of those filling the expert questionnaire.

Expert no. Work unit Position Tasks in the environment safety center
Expert 1 Environment Engineering Department of a university Director Leader of the Environmental Protection Group
Expert 2 Environment Engineering Department of a university Technician Handle affairs related to environmental protection
Expert 3 Chemistry Department of a university Director Leader of the Safety and Hygiene Group
Expert 4 Chemistry Department of a university Technician Handle affairs related to safety and hygiene
Expert 5 Chemical Engineering and Material Department of a university Director Leader of the Toxic Substance Management Group
Expert 6 Chemical Engineering and Material Department of a university Specialist Handle affairs related to toxic substance management
Expert 7 General Affairs Office of a university Leader Executive secretary of the Environment Safety and Hygiene Committee
Expert 8 Environment Safety Center Technician Handle affairs related to environment safety and hygiene

method for each service aspect and item in the service quality
model.
As the cognition and opinions of each evaluator are different,
the delimited scope is not same, thus, the average value concept
is adopted to integrate fuzzy judgment, and the formula is shown,
as follows:

Ekij ð1=mÞ  ðE1ij  E2ij  :::  Ekij Þ ð4Þ

In which  refers to fuzzy number multiplication,  refers to


fuzzy number addition, Ekij refers to the average value of level m
evaluator reaching the j standard for i plan, which can be shown
with Triangular Fuzzy Number, as follows:
EijðLEi ; MEij; UEijÞ ð5Þ

Fig. 2. Positive triangular Fuzzy numbers. Endpoint values LEij, MEij and UEij in the above formula can be
calculated with the plan proposed by Buckley (1985).
!
X
m
LEij LEkij =m ð6Þ
k¼1

!
X
m
k
MEij MEij =m ð7Þ
k¼1

!
X
m
k
UEij UEij =m ð8Þ
k¼1

3.5.1. Defuzzification
Transforming fuzzy numbers, as calculated by fuzzification into
definite values, is called defuzzification. Normal defuzzification
methods include Center of Gravity Defuzzification; Center of Sum
e
Fig. 3. a-cut of positive triangular Fuzzy number A. Defuzzification; Center of Largest Area Defuzzification; First of
Maxima Defuzzification; Last of Maxima Defuzzification; Middle
of Maxima Defuzzification, and Height Defuzzification.
3.4. a-cut (Zimmerman,1991) This research adopts the relatively simple Center of Gravity
Defuzzification; according to Tseng and Klein (1989), the member-
For the given real number a, a [1, 0]; definition Aa = {v|le e is u ðxi Þ, when the fuzzy
A ship function of hypothetical fuzzy set A eA
(v) = a, v 2 X} is a-cut of fuzzy set A. e Aa = [ A
e lðaÞ , A
e uðaÞ ], in which
number is a Triangular Fuzzy Number, hypothetical Triangular
e e
A lðaÞ , A uðaÞ are left and right edge points, respectively, as shown in e i ¼ ðLi ; M i ; U i Þ; the formula is:
Fuzzy Number A
Fig. 3.
½ðU i  Li Þ þ ðM i  Li Þ
Fi ¼ þ Li ; 8i ð9Þ
3.5. Linguistic Variable and fuzzification 3

The so-called Linguistic Variable is to consider the phraseology 3.6. FMEA


used in language as variables. This research adopts the methods of
Chen and Hwang (1992) to design five linguistic universal wording The FMEA risk evaluation method has been widely used in dif-
sets (quite important, very important, ordinary, not important, ferent industries, and the data of risk priority number (RPN) play
quite not important) to collect relevant information about the the main role in evaluating the priority of disposal default factors.
importance degrees of interviewees in each service item. The In the traditional RPN calculation, risks are divided into three
membership function of these linguistic values can be shown in parameter sources – severity (S), detection (D), and occurrence
Triangular Fuzzy Numbers to evaluate linguistic sequences of ser- (O). According to the Guidelines of ‘‘Safety and Hygiene Plan for
vice quality evaluators, which can be taken as the evaluation Laboratory Chemicals”, this study sets 4-level scoring for (S) and

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ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 7

5-level scoring for (D) and (O) (Jia and Shi, 2005). The details of the weeks to meet the criteria that each laboratory was checked at
research calculations are, as follows: least once. Each inspection was checked by the laboratory admin-
istrative staff, and each department calculated the error items of
(1) Severity (S), describes the degree of impact upon a system the project for verification. Some laboratories that conform to the
caused by the failure of an individual component or an oper- regulations might have no errors in the items, while some that
ational procedure. do not follow the regulations might have several errors in the
(2) Detection (D) describes the degree of impact caused by the items. Finally, after adding up all of the error items of the depart-
failure of an individual component or operational process, ments, the data was reported to the Safety and Hygiene Center for
which cannot be detected by the customer or the integration.
manufacturer. Hsieh (2006) argued that there were some disadvantages in the
(3) Occurrence (O) describers the degree of frequency with traditional FMEA: (1) the information in FMEA was represented in
which an individual component failure or an operation pro- the form of subjective language, which renders the information
cess failure may occur. inadequately objective and definite; (2) the relative importance
among the three parameters was not necessarily the same; (3)
The RPN (Risk Priority Numbers) are calculated using the fol- the same RPN did not necessarily indicate the same risk. To address
lowing formula: these problems, he suggested evaluating the RPN importance on
the bases of fuzzy theory. With the data collected from the expert
RPNðSÞ  ðDÞ  ðOÞ ð10Þ questionnaire survey, this study aggregates and averages the hier-
archical scores of (S), (D), and (O) of the 26 potential default factors
in Table 3. First, Eq. (10) is adopted to calculate the RPN and
4. Result sequence of the traditional FMEA method. Meanwhile, Eqs. (1)-
(10) are employed to calculate the RPN and prior disposal sequence
In order to obtain the relevant data of errors in laboratories, (as Table 5) of the fuzzy theory method, and the two sequences are
basic inspections of the laboratories are conducted. Before the compared. After discussions with the experts, it was agreed that
improvements, sampling inspection was carried out twice a week the RPN and sequence calculated with the fuzzy theory were more
in accordance with the proportion of laboratories during the 5th– consistent with the actual disposal procedures, and thus, more
8th week of the semester, which continued for one month. Inspec- suitable for improvement.
tion data was collected, and at the beginning of the 9th week, the As shown in Table 5, the RNP percentages calculated with the
administrative staff of the laboratories was asked to carry out lab- fuzzy theory are sequenced, and the top 10 factors are listed for
oratory waste recycle management and relevant training for the ‘‘priority improvement”, including (Type A) A1 ‘‘Unclear classifica-
above items until the end of the 12th week, which lasted for one tion”, A2 ‘‘Gathering liquid waste without a funnel or a drain pan”,
month. In the 13th–16th week, the laboratories were re- A3 ‘‘Spill over”, (Type B) B6 ‘‘Decentralized storage”, B2 ‘‘Compati-
inspected, and the inspection data was collected from the results. bility between the container material and the liquid waste”, (Type
This study only inspected the laboratories that produce waste liq- C) C1 ‘‘Lack of a clearance and transport contract”, C3 ‘‘Liquid waste
uid. Each inspection was checked by the laboratory administrative spill during delivery”, C4 ‘‘Lack of correct weight”, C2 ‘‘Lack of
staff, which divided the laboratories evenly to the four inspection

Table 5
RPN numbers and sequences of potential factors of the two methods. Source: Compiled by this study.

Item Traditional FMEA method R Fuzzy Theory FMEA method R


S(T) D(T) O(T) RPN (%) S(F) D(F) O(F) RPN (%)
(Type A) A1 3.50 4.25 4.38 65.08 13.53 1 3.14 4.05 4.10 52.21 11.39 1
Recycling A2 2.88 3.50 3.50 35.22 7.32 2 2.94 3.49 3.14 32.14 7.01 2
A3 2.75 3.25 3.13 27.93 5.81 4 2.57 3.41 3.01 26.33 5.74 5
A4 1.38 2.25 2.25 6.96 1.45 20 1.43 2.02 2.05 5.92 1.29 21
(Type B) B1 2.75 3.38 2.63 24.36 5.06 9 2.57 3.08 2.53 20.00 4.36 12
Storage B2 2.88 3.00 2.88 24.80 5.15 8 2.62 2.96 2.94 22.73 4.96 8
B3 1.13 3.00 4.50 15.19 3.16 15 1.36 2.96 4.49 18.10 3.95 14
B4 1.13 1.38 2.50 3.87 0.80 26 1.36 1.43 2.48 4.85 1.06 26
B5 1.88 1.75 1.88 6.15 1.28 21 1.92 1.56 1.92 5.77 1.26 22
B6 2.50 3.25 3.25 26.41 5.49 5 2.48 3.37 3.06 25.58 5.58 6
(Type C) C1 3.75 1.75 4.00 26.25 5.46 6 3.57 1.87 4.00 26.79 5.84 3
Clearance and transport C2 2.63 2.75 3.63 26.17 5.44 7 2.53 2.51 3.53 22.41 4.89 9
C3 2.50 3.13 3.75 29.30 6.09 3 2.48 3.01 3.57 26.68 5.82 4
C4 1.88 2.88 4.50 24.26 5.04 10 1.92 2.92 4.49 25.24 5.50 7
C5 3.75 1.00 1.38 5.16 1.07 24 3.57 1.00 1.43 5.12 1.12 24
C6 1.63 2.00 3.63 11.78 2.45 16 1.51 1.95 3.47 10.26 2.24 18
(Type D) D1 3.13 2.38 3.25 24.12 5.01 11 3.02 2.38 3.06 21.98 4.79 10
Management D2 2.13 1.50 3.25 10.36 2.15 18 2.37 1.79 3.06 12.95 2.82 16
D3 1.63 2.88 1.25 5.84 1.21 22 1.83 2.94 1.40 7.50 1.64 20
D4 4.00 1.00 1.38 5.50 1.14 23 4.00 1.00 1.43 5.73 1.25 23
D5 2.00 2.25 3.63 16.31 3.39 14 1.95 2.40 3.50 16.46 3.59 15
D6 3.75 1.00 1.25 4.69 0.97 25 3.57 1.00 1.40 4.99 1.09 25
D7 3.38 1.63 1.38 7.54 1.57 19 3.10 1.83 1.43 8.12 1.77 19
D8 2.75 1.00 3.88 10.66 2.22 17 2.89 1.00 3.94 11.40 2.49 17
D9 3.63 1.50 3.63 19.71 4.10 12 3.53 1.47 3.85 20.02 4.37 11
D10 3.63 1.38 3.50 17.45 3.63 13 3.53 1.43 3.81 19.28 4.20 13

Food note: S(T): Severity by Traditional FEMA method, etc., S(F): Severity by Fuzzy theory FEMA method, etc., R: Ranking.

Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
8 C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx

dumping and disposal tools”, and (Type D) D1 ‘‘Lack of a clearance (42.9%), which is the only item with an improvement rate of less
and transport contract”. The top 3 are A1, A2, and C1. than 50%. This indicates that the 10 items chosen according to
To confirm the ranking relevance of the top 10 default factor RPN ranking, as based on the fuzzy theory FMEA method, are
indices of RPN, and obtain the data regarding errors in laboratories, indeed important potential risk factors of laboratory liquid waste
this study undertakes follow-up laboratory sampling inspection disposal, and thus, must be improved. For the 26 risk factors sorted
and checking. This case study is based on TK University; while by this study, the average RPN calculated by the traditional FMEA
the objectives of this study are 216 laboratories, focus was placed is 18.50 ± 13.13, while the average RPN calculated by the fuzzy
on the 68 laboratories of chemical engineering that had generated FMEA is 17.63 ± 10.84. After one-tailed testing, the P value equals
liquid wastes. The administrative staff evenly divided the laborato- 0.08, and although it does not reach the significant difference of
ries into four weeks, in order that each laboratory was checked at 0.05 in statistics, it does indicate that the PRN calculated by fuzzi-
least once. The checking was performed by the same laboratory fication is different from the result produced by the traditional
administrators before and after the improvements. All the depart- method.
ments counted the 10 default items to be checked. Some laborato-
ries that conformed to the regulations might have no errors in the
items, while some that did not follow the regulations might have 5. Discussion
several errors in the items. Then, all the error items of the depart-
ments are counted and reported to the Safety and Hygiene center. Further analysis of the data sources of the error items show that
The error items before and after the improvement are as shown in the Physics Department had the highest improvement rate
Table 6, which reveals the differences in the 10 factors before and (100.0%); followed by the Department of Mechanical and Electrical
after the improvements. The total improvement rate is 60.2%, and Engineering and Department of Electric Machines (66.7%); the
the item with the highest improvement rate is A3 ‘‘Spill over” (80%) Environmental Engineering Department (56.3%), the Chemical
(Table 6). It is obvious that setting special requirements when Engineering and Material Department (55.0%); and the Chemistry
pouring liquid wastes into a recycling container could effectively Department (56.8%). As the Physics Department disposes of fewer
reduce spill over incidents. The items that followed A3 are: A2 liquid wastes, those in charge of laboratories could focus on the
‘‘Gathering liquid waste without a funnel or a drain pan” (66.7%), small number of laboratories that do generate liquid wastes, thus,
A1 ‘‘Unclear classification” (64.3%), B6 ‘‘Decentralized storage” it could achieve a higher improvement rate. The departments that
(55.6%). With the exception of C1 ‘‘Lack of a clearance and trans- had many error items before the improvements, including the
port contract”, which had no errors, the item with the lowest Chemistry Department; the Chemical Engineering and Material
improvement rate is C3 ‘‘liquid waste spill during delivery” Department, and the Environmental Engineering Department, have

Table 6
Data about the error items of laboratory liquid waste disposal before and after improvements. Source: Compiled by this study.

Item Before After Reduction in number Percentage after Reduction in


(n1) (n2) after improvement improvement percentage
(N)a (%)b after improvement (%)c
A1: Unclear classification 14 5 9 64.3 16.1
A2: Gathering liquid waste without a funnel or a drain pan 6 2 4 66.7 7.1
C1: Lack of a clearance and transport contract 0 0 0 NA NA
C3: Liquid waste spill during delivery 7 4 3 42.9 5.4
A3: Spill over 5 1 4 80.0 7.1
B6: Decentralized storage 18 8 10 55.6 17.9
C4: Lack of correct weight 11 5 6 54.5 10.1
B2: Compatibility between the container material and the liquid 5 2 3 60.0 5.4
waste
C2: Lack of dumping and disposal tools 6 2 4 66.7 7.1
D1: Lack of clear labels for liquid waste containers 21 8 13 61.9 23.2
Total 93 37 56 60.2 100
a
N = n1  n2.
b
N/n1.
N/RNi, eg, 9/56 = 16.1%.
c

Table 7
Data about the liquid waste disposal of the laboratories of science institute and engineering institute before and after improvements. Source: Compiled by this study.

Institute of science Institute of engineering Total


Item Department Department Department of Department of Department of chemical Department of
of physics of chemistry environmental mechanical and electrical engineering and electric
engineering engineering material machine
Before improvement 5 37 16 9 20 6 93.0
After improvement 0 16 7 3 9 2 37.0
Reduction in Number after 5 21 9 6 11 4 56.0
improvement
Percentage after 100 56.8 56.3 66.7 55.0 66.7 60.2
improvement (%)
Percentage of reduction in 8.9 37.5 16.1 10.7 19.6 7.1 100.0
number after
improvement (%)

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C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx 9

a greater number of laboratories that generate liquid waste. In par- by the Fuzzy Theory FMEA method, is more appropriate than that
ticular, the Chemistry Department has the largest number of labo- produced by the Traditional FMEA method. According to the
ratories, and each experiment involves chemicals; therefore, more research results, the following conclusions were drawn:
errors are detected in these three departments. Conversely, the
reduced percentage in the number of accidents after improvement 1. In this study, the fuzzy theory FMEA method was adopted to
(Table 7) of the Chemistry Department is 37.5%; the Chemical Engi- analyze the 68 laboratories of chemical engineering that had
neering and Material Department is 19.6%; the Environmental generated liquid wastes, and 26 items for improvement were
Engineering Department is 16.1%. The total of the percentages of proposed. The number of the improvement items whose RPN
improvements of these three departments is 73.2%; hence, these percentage exceeded 40 was 10, and an improvement scheme
three departments made the biggest contribution to the improve- was made according to the 10 items. After re-checking, the
ment rate. improvement rate was 60.2%, which indicated significant
improvement. The major action plans were education and train-
ing methods as the results section.
6. Conclusion 2. Regarding the improvement rate, the top three departments
were the Chemistry Department (37.5%), the Chemical Engi-
With a sewage disposal plant as a case study, Hsieh (2006) neering and Material Department (19.6%), and the Environmen-
adopted the traditional FMEA method and fuzzy theory to analyze tal Engineering Department (16.1%). The total improvement
the reliability of the sewage disposal system. In this study, the rate of the three departments was 73.2%.
fuzzy theory FMEA method was employed to discuss the causes 3. According to the improvement rates of the factors, the item
of the defaults in the liquid waste management of school laborato- with the highest improvement rate was D1 ‘‘Lack of clear labels
ries. If the traditional FMEA method was applied to calculate and for liquid waste containers” (23.2%), followed by B6 ‘‘Decentral-
rank RPN, it would be impossible to detect D1 ‘‘Lack of clear labels ized storage” (17.9%) and A1 ‘‘Unclear classification” (16.1%).
for liquid waste containers”, which is an important potential The total improvement rate of the three items was 57.2%.
default factor ranked 10th. According to the check after the
improvement, the number of error items in D1 was 21, and the In addition, Christensen et al. (2007) provided Life-cycle assess-
reduction percentage was 23.2%, which had the highest improve- ment (LCA) models, which are becoming the principal decision
ment rate among the 10 factors (Table 6). It is obvious that the support tools of waste management systems. Bakas et al. (2018),
fuzzy theory FMEA method is better than the traditional FMEA which provides the application of LCA to solid waste management
method. Although liquid waste accounts for a small proportion of systems, is distinctive in that system boundaries are rigorously
waste management, it is an important part of school waste, and defined to exclude all life cycle stages, with the exception of the
is subject to regulatory requirements for recycling, storage, collec- end-of-life. Moreover, specific methodological challenges arise
tion, and management. In the laboratory accidents presented in when investigating waste systems. This study provides a similar
Table 2, improper management of laboratory liquid waste occurs LCA model for ISO systems for continuous quality improvement,
frequently, resulting in different sizes of accidents. and gives some suggestions to follow-up laboratory managers.
This study aimed to explore the problems in the liquid waste There are four steps to this LCA model, as follows:
recycling and disposal of chemical laboratories in universities,
and mainly compared the two tools of the FMEA method. First, 1. Define goals and scope
the feature factor table was used to identify the default factors of First, definition of goal is to reduce risk of laboratory risk, the
liquid waste recycling. Then, the scoring levels of severity, detec- higher probability of risk, the laboratory is in high unsafe state,
tion, and occurrence of the potential default factors of liquid waste only to reduce risk, laboratory can be in a safe situation. The
recycling and disposal were obtained from literature, and the RPNs scope of laboratory is to improve the liquid wastes, laboratory
of the potential factors of liquid waste recycling and disposal were accidents cause from many risk factors, this study focus on
calculated, in order to achieve a more objective and accurate eval- the laboratory liquid wastes treatment to improve process
uation benchmark for liquid waste recycling and disposal. With the and reduce of liquid wastes treatment risk.
fuzzy theory FMEA method, this study identified the important 2. Risk factor analysis
potential risk factors of laboratory liquid waste, and established There are many methods to determine risk factors. This study
recycling and disposal procedures for school liquid waste. Cheng uses an attribute factor graph (Fig. 1) to identify laboratory
et al. (2004) indicated that the fuzzy theory has been applied to lin- waste risks according to related factors. This method identifies
ear and nonlinear programming, integer programming, networks, laboratory waste treatment problems, which form the risk fac-
multi-rating decision making, group decision making, and expert tors this study aims to improve.
systems. As it can make up for the simplicity of the simplified 3. Impact assessment
model, it can provide a more flexible model to simulate real-life After the two above steps, risk factor assessment is conducted,
large-scale and complex systems. As can be seen from Table 5, in order to determine the influencing risks, the major effects,
the top 10 ranking from the Traditional FMEA method only and the risk priority number (RNP) of the laboratory risk factors.
accounts for Type A, B, and C in Systematic Functions, while in This study uses the FMEA method, and applies an expert ques-
the Fuzzy Theory FMEA method, we can see it in all four Systematic tionnaire to establish the quantitative index parameters. As
Functions, Types A, B, C, and D. Therefore, the Fuzzy Theory FMEA high RNP values mean larger risk factors, this study conducts
method can be more balanced in the direction of each Systematic detailed analysis and provides suggestions or solutions for
Function. The difference of the two methods lies in Type C and D. improvement. The assessment process must consider Severity,
Type C C1 ranked 6th in the Traditional FMEA method, while in Detection, and Occurrence.
the Fuzzy Theory FMEA method, its importance is ranked 3rd. 4. Continuous tracking
Another important factor is in Type D, and there is no factor reach- After implementing the improvement suggestions, it is neces-
ing the top 10 in the Traditional FMEA method; while in the Fuzzy sary to regularly conduct laboratory liquid waste checks, in
Theory FMEA method, we have the D1 factor in the top 10, which is order to determine whether the improvement suggestions or
an important item for improvement. Through this study, the solutions reach their intended goals. If improvement goals are
experts agreed that the ranking of the top 10 factors, as calculated not achieved, re-establish new risk factors and provide new

Please cite this article in press as: Ho, C.-C., Chen, M.-S. Risk assessment and quality improvement of liquid waste management in Taiwan University chem-
ical laboratories. Waste Management (2017), https://doi.org/10.1016/j.wasman.2017.09.029
10 C.-C. Ho, M.-S. Chen / Waste Management xxx (2017) xxx–xxx

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