Documente Academic
Documente Profesional
Documente Cultură
NON-CONDESABLE GASES
AT THE MIRAVALLES GEOTHERMAL FIELD
ABSTRACT
The Miravalles Geothermal Field has been producing
electric energy since March 1994. It has provided
steam for Unit 1 (55 MWe) since 1994, a Wellhead
Unit (5 MWe) installed in 1995, Unit 2 (55 MWe) in
1998, Unit 3 (29 MWe) in 2000 and Unit 5 (19 MWe,
a binary plant) in year 2004. The total installed
capacity (163 MWe) has been increasing since 1994,
and so have the non-condensable gases in the steam.
With these increases, the compressors at the
generating units have reached their maximum gas
capacity without ejectors, and therefore options to
decrease the non-condensable gases have been
analyzed. Field management strategies have been
implemented in order to minimize the total amount of
non-condensable gases that are sent to the generating
units.
Figure. 1. Miravalles Geothermal Field.
INTRODUCTION
binary plant came online in January of 2004. As
The Miravalles geothermal field is located on the indicated in Table 1, two wellhead units from the
southwestern slope of the Miravalles volcano. The Comisión Federal de Electricidad (Mexico) were in
extent of the geothermal field already identified is operation while Unit 2 was being built, but these
greater than 21 km2, of which about 16 km2 are have been decommissioned.
dedicated to production and 5 km2 to injection. There
are 53 geothermal wells (Figure 1), including Plant Power Belongs Start- Final
observation, production and injection wells, whose Name (MW) to up Date Date
depths range from 900 to 3,000 meters. The Unit 1 55 ICE 3/1994
production wells produce between 3 and 12 MW WHU-1 5 ICE 1/1995
each, and the injection wells each accept between 70 WHU-2 5 CFE 9/1996 4/1999
and 450 kg/s. The reservoir has a temperature of WHU-3 5 CFE 2/1997 4/1998
about 240 oC and is water-dominated (Moya, 2003). Unit 2 55 ICE 8/1998
The Miravalles geothermal field has been producing Unit 3 29 ICE 3/2000
since 1994. Normally, two or three production wells (BOT)
supply two-phase fluid to each separation station. Unit 5 19 ICE 1/2004
Seven separation stations now supply the steam
needed for Unit 1, Unit 2, Unit 3 and one active Table 1: Units at the Miravalles geothermal field.
Wellhead Unit. At present there is a need to supply
enough steam to produce 55 MWe (Unit 1), 5 MWe In Table 1, the abbreviations stand for: ICE - Instituto
(Wellhead Unit), 55 MWe (Unit 2) and 29 MWe Costarricense de Electricidad; CFE - Comisión
(Unit 3), for a total of 144 MWe. This capacity was Federal de Electricidad (México); WHU - Wellhead
increased to 163 MWe when a bottoming-cycle Unit; and BOT – build-operate-transfer.
condensable gas content ranged from 0.4 to 1.2 %
NON-CONDENSABLE GAS EVOLUTION w/w. Figure 2b shows the natural distribution of
non-condensable gas contents. In Figure 2a the
Data from the first wells drilled at the Miravalles values are disturbed by air-drilling, which had begun
geothermal field showed that there was a wide range in 1992.
of concentrations of non-condensable gases in the
steam. As new wells were drilled, it was determined
that, under natural conditions, the field´s non-
a) 1994 b) 1995
301000
294000
405000 406000 407000 408000 409000 405000 406000 407000 408000 409000
0 1000 2000 m
Figure. 2. Distribution of non-condensable gases in 1994 and 1995 (% w/w in steam separated at 7 bar a)
2.4 5,000
Chloride (ppm)
2.0 4,500
Westhern
injection
1.6 4,000
1.2 3,500
0.8 3,000
0.4 2,500
0.0 2,000
94 95 96 97 98 99 00 01 02 03 04 05
01- 01- 01- 01- 01- 01- 01- 01- 01- 01- 01- 01-
- - - - - - - - - - - -
01 01 01 01 01 01 01 01 01 01 01 01
Date
Gas % (w/w) in steam Chloride (ppm) Average Curve (gas % w/w in steam)
Figure. 3. History of non-condensable gases in well PGM-21 (% w/w in steam separated at 7 bar a)
20 1.0
16 0.8
N 2, CO2/10 (mmol/Kg)
14 0.7
12 0.6
10 0.5
8 0.4
6 0.3
4 0.2
2 0.1
0 0.0
85
86
87
88
89
90
91
92
93
94
95
96
6-
6-
6-
6-
6-
6-
6-
6-
6-
6-
6-
6-
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
07
07
07
07
07
07
07
07
07
07
07
07
Date
Figure. 4. History of non-condensable gases in well PGM-10 (% w/w in steam separated at 7 bar a)
40 1.20
30 0.90
25 0.75
20 0.60
15 0.45
10 0.30
5 0.15
0 0.00
93
93
94
94
94
94
95
95
95
95
96
96
96
9-
2-
3-
6-
9-
2-
3-
6-
9-
2-
3-
6-
9-
-0
-1
-0
-0
-0
-1
-0
-0
-0
-1
-0
-0
-0
15
15
15
15
15
15
15
15
15
15
15
15
15
Date
Figure. 5. History of non-condensable gases in well PGM-20 (% w/w in steam separated at 7 bar a)
3. Injected fluids, which are degassed, travel back to PGM-10 from supplying its two-phase flow to the
some production sectors, causing a decrease in the gathering system, which finally caused the well to
non-condensable gases in those particular zones. In stop producing.
Figure 3 (green box) it can be seen that the non- The bubble effect was transitory; that is, it increased
condensable gases decreased from the end of the year the non-condensable gases up to 100% in some cases,
1999 to the end of 2004. The decrease coincided but it disappeared within the following year, leaving
with an increase in the chloride content, also shown non-condensable gas content of the particular zone at
in Figure 3 (green box), which indicates that injected its natural level. The other three effects
water was reaching that sector of the production zone (hydrogeology, injected fluids and pressure drop)
4. Sustained production due to continuous have been present since production started and have
exploitation generates a pressure drawdown in the influenced the increase in non-condensable gases one
reservoir and an increase in the steam fraction. This way or another. Figures 7 and 8 show that, in several
increases the steam fraction, but at the same time production wells and reservoir sectors (respectively),
increases the non-condensable gases in the steam. the non-condensable gases have been increasing from
Figure 6 shows the behavior of the non-condensable 1994 to 2004. It can be seen from these two figures
gases in well PGM-10. The well was drilled during that the non-condensable gas increase in the reservoir
1984, but air-drilling in the surrounding wells (PGM- has taken place since the three major units (Units 1, 2
09 and PGM-31) increased the non-condensable and 3) began been producing continuously.
gases to a value close to 0.8% in early 1994. The The bubble effect due to air-drilling, as well as the
gases then began to decrease (until the end of 1997) hydrogeologic effects and pressure decline caused by
and finally increased from the end of 1997 to the end the continuous exploitation of the reservoir, have
of 2004. The increment in the non-condensable gases produced a strong increase in the non-condensable
coincided with an increase in enthalpy values for the gases at the Miravalles geothermal field. Only the
same period (1997 to 2004). In well PGM-10, the effect of injected fluids has tended to decrease the
pressure drop (close to 2 bar/year from 1998 to 2003) non-condensable gas content.
caused the wellhead pressure to decrease, impeding
3.2 1,600
Unit 1 Unit 1 & 2 Unit 1, 2 & 3
2.8 1,500
gas % (w/w) in steam at 7,0 bar a
2.4
1,400
Enthalpy (Kj/Kg)
2.0
1,300
1.6
1,200
1.2
Westhern
injection 1,100
0.8
0.4 1,000
0.0 900
94 95 96 97 98 99 00 01 02 03 04 05
1- 1- 1- 1- 1- 1- 1- 1- 1- 1- 1- 1-
-0 -0 -0 -0 -0 -0 -0 -0 -0 -0 -0 -0
01 01 01 01 01 01 01 01 01 01 01 01
Date
Gas % (w/w) in steam Enthalpy Average Curve (% gas in steam)
Figure. 6. History of non-condensable gases in well PGM-10 (% w/w in steam separated at 7 bar a)
3.0
Unit 1 Unit 1 & 2 Unit 1, 2 & 3
2.7
gas % (w/w) in steam at 7,0 bar a
2.4
2.1
1.8
1.5
1.2
0.9
0.6
Westhern
injection
0.3
0.0
94 95 96 97 98 99 00 01 02 03 04 05
01- 01- 01- 01- 01- 01- 01- 01- 01- 01- 01- 01-
- - - - - - - - - - - -
01 01 01 01 01 01 01 01 01 01 01 01
Date
PGM-10 PGM-11 PGM-63 PGM-07 PGM-45 PGM-62 PGM-01
Figure. 7. History of non-condensable gases from 1994 to 2004 (% w/w in steam separated at 7 bar a)
a) 1999 b) 2004
301000
PGM-14
PGM-60 PGM-60
300000 PGM-62
PGM-63 PGM-11
PGM-05 PGM-05 3
PGM-10 PGM-11 PGM-07
2.8
PGM-10 PGM-65
PGM-42 PGM-42 2.6
299000 PGM-01 PGM-01
PGM-31 2.4
PGM-31
PGM-08 PGM-66 2.2
PGM-08 PGM-44
PGM-43 PGM-43 2
298000 PGM-17 PGM-17
1.8
PGM-03
PGM-45 PGM-03 PGM-45 1.6
PGM-46 PGM-46 PGM-19
1.4
297000 PGM-49 PGM-47 PGM-49
PGM-47 1.2
PGM-20 PGM-21 PGM-20 PGM-21 1
PGM-12 0.8
PGM-12
296000 0.6
0.4
0.2
295000
294000
405000 406000 407000 408000 409000 405000 406000 407000 408000 409000
0 1000 2000 m
Figure. 8. Distribution of non-condensable gases from 1999 to 2004 (% w/w in steam separated at 7 bar a)
3.2 1,600
Unit 1 Unit 1 & 2 Unit 1, 2 & 3
2.8 1,500
gas % (w/w) in steam at 7,0 bar a
2.4
Westhern 1,400
injection
Entalpy (Kj/Kg)
2.0
1,300
1.6
1,200
1.2
1,100
0.8
0.4 1,000
0.0 900
94 95 96 97 98 99 00 01 02 03 04 05
01- 01- 01- 01- 01- 01- 01- 01- 01- 01- 01- 01-
- - - - - - - - - - - -
01 01 01 01 01 01 01 01 01 01 01 01
Date
Gas % (w/w) in steam Enthalpy Average Curve (gas % w/w in steam)
Figure. 9. History of non-condensable gases in well PGM-45 (% w/w in steam separated at 7 bar a)
1.8
% gas w/w in steam at 7,0 bar a
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8 1.66
0.7
0.6
0.5 1.00 1.08 1.08
0.94
0.4 0.75
0.3 0.58
0.2 0.46 0.37 0.44
0.1
0.0
1
7
t1
t2
t3
te
te
te
te
te
te
te
ni
ni
ni
lli
lli
lli
lli
lli
lli
lli
U
U
te
te
te
te
te
te
te
Sa
Sa
Sa
Sa
Sa
Sa
Sa
Gas extraction capacity: Compressor Compressor + Ejectors
Figure. 10. Non-condensable gases per satellite in 2003 (% w/w in steam separated at 7 bar a)
1.8
% gas w/w in steam at 7,0 bar a
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
0.7 1.43 1.43
0.6
0.5 1.06
0.91
0.4
0.3 0.63 0.67 0.63
0.2 0.4 0.46 0.48
0.1
0.0
4
7
t1
t2
t3
te
te
te
te
te
te
te
ni
ni
ni
lli
lli
lli
lli
lli
lli
lli
U
U
te
te
te
te
te
te
te
Sa
Sa
Sa
Sa
Sa
Sa
Sa
Figure. 11. Non-condensable gases per satellite in 2004 (%w/w in steam separated at 7 bar a)
The effect of the switch can be observed in Figures measured data and the maximum compressor
12 and 13. Figure 12 shows the measured non- capacity at Unit 1. Once the interchange was made, a
condensable gas data, the average curve for the decrease in the total non-condensable gas content was
observed (Figure 12). In contrast, Figure 13 shows valves (upstream of the steam collectors of these
an inverse effect, that is, an increase occurred after Units) that would allow the steam from separation
switching the non-condensable gases from the stations 1 and 4 to be variably distributed to Units 1
separation stations 1 and 4. Since the non- and 2. This would permit the non-condensable gas
condensable gas content in the reservoir keeps levels to be matched as closely as possible to the
increasing, due to continuous exploitation, the gas available compressor capacities.
content at the three units has consequently increased The second and most expensive option would be to
(Figures 12, 13 and 14). increase the non-condensable extraction capacity of
Even though interchanging the separation stations the main units. This can be done by: a) increasing
had a positive effect, at present the non-condensable the current capacity of the compressor (improving it),
gas contents are getting close to the maximum b) adding a vacuum pump to the system, c)
compressor capacities at Units 1, 2 and 3 (Figures 12, increasing the existing ejectors (increasing the
13 and 14). amount of steam required per ejector), or d) buying a
In order to fully utilize the compressor capacities at new compressor with the required capacity.
Units 1 and 2, there is the option of installing a set of
1.2
Unit 1, Steam Collector
1.1
Interchange: Satellite 1 by Satellite 4
gas % (w/w) in steam at 7,0 bar a
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
4 5 6 7 8 9 0 1 2 3 4 5
-9 -9 -9 -9 -9 -9 -0 -0 -0 -0 -0 -0
01 01 01 01 01 01 01 01 01 01 01 01
0 1- 0 1- 0 1- 0 1- 0 1- 0 1- 0 1- 0 1- 0 1- 0 1- 0 1- 0 1-
Date
Gas % (w/w) in steam Compressor capacity Average curve (gas % in steam)
Figure. 12. History of non-condensable gases at Unit 1 (% w/w in steam separated at 7 bar a)
1.2
Unit 2, Steam Collector
1.1
Interchange: Satellite 1 by Satellite 4
gas % (w/w) in steam at 7,0 bar a
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
4 5 6 97 8 9 0 1 2 3 04 5
1 -9 -9 -9 1- -9 -9 -0 -0 -0 -0 1- -0
-0 01 01 0 -0
1 01 01 -0
1 01 01 0 -0
1
01 0 1- 0 1- 0 1- 01 0 1- 0 1- 01 0 1- 0 1- 0 1- 01
Date
Gas % (w/w) in steam Compressor capacity Average curve (gas % in steam)
Figure. 13. History of non-condensable gases at Unit 2 (% w/w in steam separated at 7 bar a)
1.6
1.5
1.4
gas % (w/w) in steam at 7,0 bar a
1.3
1.2
1.1
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
- 94 -9
5
-9
6
-9
7
-9
8
-9
9
-0
0
-0
1
-0
2
-0
3
-0
4
-0
5
01 01 01 01 01 01 -0
1
-0
1 01 01 01 01
0 1- 0 1- 0 1- 0 1- 0 1- 0 1- 01 01 01
-
01
-
01
-
01
-
Date
Gas % (w/w) in steam Compressor capacity Average curve (gas % in steam)
Figure. 14. History of non-condensable gases at Unit 3 (% w/w in steam separated at 7 bar a) (Sánchez,
2004b).
Sánchez, E. (2004a), "Evaluación y tendencias del
FINAL REMARKS contenido de gases en el vapor entregado a las
unidades 1 y 2 de Miravalles, periodo 2000-2004,”
Air-drilling caused a temporary increase in non- ICE Internal Report, Equipo de Geoquímica, Area
condensable gases in the Miravalles reservoir that de Geociencias, 18 de setiembre de 2004.
lasted for about a year.
The arrival of the injected fluids to some production Sánchez, E. (2004b), "Evaluación del contenido de
sectors has contributed to a decrease of the non- gas en el vapor entregado a la Unidad 3 de Miravalles
condensable gases in those sectors. So far, most of y pozos del Satélite 7, causas y consecuencias,” ICE
the production wells in the western and southern Internal Report, Equipo de Geoquímica, Area de
sectors have been benefited from hot injection. Geociencias, 31 de octubre de 2004.
Hot fluid injection into PGM-63 should contribute to
stopping the current pressure drop as well as
decreasing the non-condensable gases in the northern
zone.
Minimum flow production from the wells located in
the northern sector has at least allowed the non-
condensable gas content in that particular area to be
kept constant.
Wells PGM-02 and PGM-06 are planned to be placed
online to extract fluids from the “acidic zone” instead
of the northern sector. This will allow a reduction of
both, the pressure drop and the non-condensable
gases in this part of the reservoir.
The pressure drop in the reservoir, due to continuous
exploitation, is the principal cause of the increase in
the non-condensable gas content of the system.
Interchanging the fluids from separation stations 1
and 4 contributed to obtaining a better distribution of
the non-condensable gases at Units 1 and 2.
At the present non-condensable gas levels, the
compressors of the main units are very close to their
maximum capacities. The trend of increasing non-
condensable gases suggests that in the near future the
current compressor capacities will be exceeded.
A set of valves installed upstream of the steam
collectors of Units 1 and 2 will allow diversion of
part of the non-condensable gases to the compressor
that is not operating at its maximum capacity, thus
optimizing the current compressor capacities.
Under normal exploitation of the reservoir, it is
expected that the trend of increasing non-condensable
gas contents is going to persist. Investments in
higher extraction capacities are foreseen at the
generating units.
ACKNOWLEDGEMENTS
The authors thank Roger Henneberger (GeothermEx,
Inc.) for editing and improving the manuscript.
REFERENCES