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RE4
Chemical Engineering Guy
Yes
-ra = f(X)
If no change in moles and no Pressure Drop:
given? • Combine rate law and Stoichiometry Tables
• Get –ra = f(X)
No
Determine Rate Law f(CA)
Combine:
• Mole Balance
Use Stoichiometry Tables • Design Equation
• Rate Law + Tables
-ΔP • Pressure Drop
Solve them
Gas-Phase with Pressure Drop
Batch Reactor
Isothermal Design
Yes
-ra = f(X)
If no change in moles and no Pressure Drop:
given? • Combine rate law and Stoichiometry Tables
• Get –ra = f(X)
No
Determine Rate Law f(CA)
Combine:
• Mole Balance
Use Stoichiometry Tables • Design Equation
• Rate Law + Tables
-ΔP • Pressure Drop
Solve them
Gas-Phase with Pressure Drop
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Questions and Problems
• There are 33 problems in this Chapter 4.
• I also included some extra problems and
exercises
• All problems are solved in the next webpage
– www.ChemicalEngineeringGuy.com
• Courses
–Reactor Engineering
»Solved Problems Section
• CH4 – Isothermal Reactor Design
Time Time
tf th
Time Time
tr te
Time
tc
Yes
-ra = f(X)
If no change in moles and no Pressure Drop:
given? • Combine rate law and Stoichiometry Tables
• Get –ra = f(X)
No
Determine Rate Law f(CA)
Combine:
• Mole Balance
Use Stoichiometry Tables • Design Equation
• Rate Law + Tables
-ΔP • Pressure Drop
Solve them
Gas-Phase with Pressure Drop
www.ChemicalEngineeringGuy.com/Courses
If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
www.YouTube.com/ChemEngineeringGuy
www.ChemicalEngineeringGuy.com/Courses
If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
www.YouTube.com/ChemEngineeringGuy
www.ChemicalEngineeringGuy.com/Courses
If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
www.YouTube.com/ChemEngineeringGuy
www.ChemicalEngineeringGuy.com/Courses
If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
www.YouTube.com/ChemEngineeringGuy
CSTR in Series
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CSTR in Series
• We get this equation
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Yes
-ra = f(X)
If no change in moles and no Pressure Drop:
given? • Combine rate law and Stoichiometry Tables
• Get –ra = f(X)
No
Determine Rate Law f(CA)
Combine:
• Mole Balance
Use Stoichiometry Tables • Design Equation
• Rate Law + Tables
-ΔP • Pressure Drop
Solve them
Gas-Phase with Pressure Drop
www.ChemicalEngineeringGuy.com/Courses
If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
www.YouTube.com/ChemEngineeringGuy
www.ChemicalEngineeringGuy.com/Courses
If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
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Conversion of A
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Effect of Change in moles δ:
Second Order
• Express this Equations in terms of
Concentration
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Conversion of A
Change in Volume
“punished” by factor of 1
Change in Volume
“punished” by factor of 2
twice!
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• Laminar (term 1)
• Turbulent (term 2)
• Only gas density changes with Pressure Drop
• It is a Differential Equation!
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• Essentially:
– Set all constants with values
• R = 8.314
• Mass Flow = 4.5
– Set all variables to equations
• Volumetric Flow = Ideal Gas law
• Mass Flux = Mass Flow / Area
– Set a First Order Differential equation
• F1 (Rate Law + Design Equation + Stoichiometry)
• Set initial Point (e.g. X=0, W = W0)
– Set a Second Order Differential Equation
• F2 (Ergun Equation for PBR)
• Set Initial Point (e.g. P = P0, W = W0)
– Click “Run” to Solve in the Software
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Exercise 4-4 of TextBook
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If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
www.YouTube.com/ChemEngineeringGuy
www.ChemicalEngineeringGuy.com/Courses
If you are interested in getting this Slides, please send an email to:
Contact@ChemicalEngineeringGuy.com
www.YouTube.com/ChemEngineeringGuy
– www.ChemicalEngineeringGuy.com/Courses
• Check the Reactor Engineering Course
– Solved Problems Section
Semi-Continuous Reactor
Isothermal Design
• Start-up of a CSTR
– Seen in this Chapter
– Helps to see the “basics”
• Semi-batch Operation for Multiple Reactions
– Not shown in this Chapter
– You need to know the fundamentals of Multiple
Reactions!
– Multiple Reactions CH6
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Time needed for Steady State
Time needed for Steady State
• k·τ>>1 then model as ts= 4.6/τ
• Calculate
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the time needed to achieve Steady State