INSTITUT TEKNOLOGI DEL

Jl Sisingamangaraja, Tobasamosir -22381, Sumatera Utara

telp +62632331234, fax +626323311116, www.del.ac.id
TERMODINAMIKA KIMIA
PR 3

 Kerjakan soal-soal berikut pada kertas A4 dengan baik dan benar!

 PR dikerjakan individual dan dikumpulkan paling lambat hari Selasa (26 April 2016)
pukul 08.00 melalui ketua kelas.

1. Estimate the change in enthalpy and entropy when liquid ammonia at 270 K is compressed from
its saturation pressure of 381 kPa to 1200 kPa. For saturated liquid ammonia at 270 K,
⁄ , and

2. Calculate , , and by the Redlich/Kwong equations for these following gases:

a. Benzene at 575 K and 30 bar
b. n-Octane at 575 K and 15 bar
c. Propane 375 K and 25 bar

3. A well-insulated tank of 50 volume initially contains 16000 kg of water distributed

between liquid and vapor phases at 25C. saturated steam at 1500 kPa is admitted to the
tank until the pressure reaches 800 kPa. What mass of steam is added?

4. A 2 tank initially contains a mixture of saturated-vapor steam and saturated-liquid water

at 3000 kPa. Of the total mass, 10% is vapor. Saturated liquid water is bled from the tank
trough a valve until the total mass in the tank is 40% of the initial total mass. If during the
process the temperature of the contents is kept constant, how much heat is transferred?

5. Steam expands isentropically in a converging/diverging nozzle from inlet conditions of

1400 kPa, 325 C, and negligible velocity to a discharge pressure of 140 kPa. At the throat
the cross-sectional area is 6 . Determine the mass flow rate of the steam and the steam
quality at the exit of the nozzle.

6. The steam rate to a turbine for variable output is controlled by a throttle valve in the inlet
line. Steam is supplied to the throttle valve at 1700 kPa and 225C. during a test run, the
pressure inlet is 1000 kPa, the exhaust steam at 10 kPa has a quality of 0.95, the steam flow
rate is 0.5 kg/s, and the power output of the turbine is 180 kW.
a. What are the heat losses from the turbine?
b. What would be the power output if the steam is supplied to the throttle valve were
expanded isentropically to the final pressure?

7. Saturated steam at 125 kPa is compressed adiabatically in a centrifugal compressor to 700

kPa at the rate of 2.5 kg/s. the compressor efficiency is 78%. What is the power requirement
of the compressor and what are enthalphy and entropy of the steam in its final state?

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