Cu+(1/2)O2[g]=CuO ELEMENTOS

CuO:

Cu:

O2(g):

Cu(s)+(1/2)O2[g]=CuO(s) para (298⁰-1250⁰K)

∆H⁰=H⁰(CuO)-[H⁰(Cu)+(1/2)*H⁰(O2)] ∆H⁰=

∆H⁰=

∆Cp=Cp(CuO)-[Cp(Cu)+(1/2)*Cp(O2)] a=
b(T)=
c(T^-2)=

∆Cp=
∆Cp=

ʃ∆Cp*dt ʃ∆Cp*dt=

ʃ∆Cp*dt=
ʃ∆Cp*dt=

∆S⁰=S⁰(CuO)-[S⁰(Cu)+(1/2)*S⁰(O2)] ∆S⁰=

∆S⁰=

∆Cp/T=Cp(CuO)/T-[Cp(Cu)/T+(1/2)*Cp(O2)/T] ∆Cp/T=
∆Cp/T=

ʃ(∆Cp/T)*dt ʃ(∆Cp/T)*dt=

ʃ(∆Cp/T)*dt=
ʃ(∆Cp/T)*dt=

Cu(s)+(1/2)O2[g]=CuO(l) para (1250⁰-1357⁰K)

∆Cp=Cp(CuO)-[Cp(Cu)+(1/2)*Cp(O2)] a=
b(T)=
c(T^-2)=
 ∆Cp=
∆Cp=

ʃ∆Cp*dt ʃ∆Cp*dt=

ʃ∆Cp*dt=
ʃ∆Cp*dt=

∆Cp/T=Cp(CuO)/T-[Cp(Cu)/T+(1/2)*Cp(O2)/T] ∆Cp/T=
∆Cp/T=

ʃ(∆Cp/T)*dt ʃ(∆Cp/T)*dt=

ʃ(∆Cp/T)*dt=
ʃ(∆Cp/T)*dt=

Cu(l)+(1/2)O2[g]=CuO(l) para (1357⁰-1600⁰K)

∆Cp=Cp(CuO)-[Cp(Cu)+(1/2)*Cp(O2)] a=
b(T)=
c(T^-2)=

∆Cp=
∆Cp=

ʃ∆Cp*dt ʃ∆Cp*dt=

ʃ∆Cp*dt=
ʃ∆Cp*dt=

∆Cp/T=Cp(CuO)/T-[Cp(Cu)/T+(1/2)*Cp(O2)/T] ∆Cp/T=
∆Cp/T=

ʃ(∆Cp/T)*dt ʃ(∆Cp/T)*dt=

ʃ(∆Cp/T)*dt=
ʃ(∆Cp/T)*dt=

Cu+(1/2)O2[g]=CuO para (298⁰-1600⁰K)

Hallando la Ecuación de la Entalpía Total

∆H(Total)=∆H⁰+ʃ∆Cp*dT+Hf(CuO)+ʃ∆Cp*dT-Hf(Cu)+ʃ∆Cp*dT ∆H(Total)=
 ∆H(Total)=
∆H(Total)=

Hallando la Ecuación de la Entropía Total

∆S(Total)=∆S⁰+ʃ(∆Cp/T)*dT+Hf(CuO)/T+ʃ(∆Cp/T)*dT-Hf(Cu)/T+ʃ(∆Cp/T)*dT ∆S(Total)=

∆S(Total)=
∆S(Total)=

Hallando la Ecuación de la Energía Libre de Gibbs

∆G(Total)=∆H(Total)-T*∆S(Total) ∆G(Total)=

∆G(Total)=
∆G(Total)=
Rango de temp. Cp [cal/mol*K] Entalpias Estandar Entalpias de Fusion
[K] a b [T] c [T^-02] H⁰ [cal/mol] H(f) [cal/mol]
298-1250 9.27 4.80E-03 0 -37500 2820

298-1375 5.41 1.50E-03 0 0 3120

1375-1600 7.5 0 0

298-3000 7.16 1.00E-03 -4.00E+04 0 -

T(valor)

-37500 - [0 + (1/2)*0] =

-37500 [cal]

9.27 - [5,41 + (1/2)*7,16] =

4.80E-03 - [1,50E-03 + (1/2)*1,00E-03] =
0 - [0 + (1/2)*-4,00E+04] =

0.28 + 2,80E-03T + 0,20E+05(T^-2) [cal/K]

#VALUE! [cal/K]

0,28T + (2,80E-03/2)(T^2) - 0,20E+05(T^-1) +

0,28T + 1,4E-03(T^2) - 0,20E+05(T^-1) -

#VALUE! [cal]

10.19 - [7,97 + (1/2)*49,01] =

-22.285 [cal/K]

0,28(T^-1) + 2.80E-03 + 0,20E+05(T^-3) [cal/K^2]

#VALUE! [cal/K^2]

0,28*ln(T) + 2,80E-03T - (0,20E+05/2)(T^-2) +

0,28*ln(T) + 2,80E-03T - 0,10E+05(T^-2) -

#VALUE! [cal/K]

T(valor)

9.27 - [5,41 + (1/2)*7,16] =

4.80E-03 - [1,50E-03 + (1/2)*1,00E-03] =
0 - [0 + (1/2)*-4,00E+04] =
 0.28 + 2,80E-03T + 0,20E+05(T^-2) [cal/K]
#VALUE! [cal/K]

0,28T + (2,80E-03/2)(T^2) - 0,20E+05(T^-1) +

0,28T + 1,4E-03(T^2) - 0,20E+05(T^-1) -

#VALUE! [cal]

0,28(T^-1) + 2.80E-03 + 0,20E+05(T^-3) [cal/K^2]

#VALUE! [cal/K^2]

0,28*ln(T) + 2,80E-03T - (0,20E+05/2)(T^-2) +

0,28*ln(T) + 2,80E-03T - 0,10E+05(T^-2) -

#VALUE! [cal/K]

T(valor)

9.27 - [7,5 + (1/2)*7,16] =

4.80E-03 - [0 + (1/2)*1,00E-03] =
0 - [0 + (1/2)*-4,00E+04] =

-1.81 + 4,30E-03T + 2,00E+04(T^-2) [cal/K]

#VALUE! [cal/K]

- 1,81T + (4,30E-03/2)(T^2) - 2,00E+04(T^-1)

- 1,81T + 2,15E-03(T^2) - 2,00E+04(T^-1)

#VALUE! [cal]

- 1,81(T^-1) + 4.30E-03 + 2,00E+04(T^-3)

#VALUE! [cal/K^2]

- 1,81*ln(T) + 4,30E-03T - (2,00E+04/2)(T^-2)

- 1,81*ln(T) + 4,30E-03T - 1,00E+04(T^-2)

#VALUE! [cal/K]

T(valor total)

∆H⁰ + ʃ∆Cp*dt + Hf(CuO) +

-37500 - 140.65 + 2820 -
0 + 0,28T + 0 +
0 + 1,4E-03(T^2) + 0 +
0 - 0,20E+05(T^-1) + 0 -
 -41950.36 - 1,25T + 4,95E-03(T^2) -
#VALUE! [cal]

∆S⁰ + ʃ(∆Cp/T)*dT + Hf(CuO)/T +

-22.285 - 2.32 + 0 -
0 + 0,28*ln(T) + 0 +
0 + 2,80E-03T + 0 +
0 - 0,10E+05(T^-2) + 0 -
0 + 0 + 2820(T^-1) +

-22.865 - 1,25*ln(T) + 9,9E-03T +

#VALUE! [cal/K]

∆H(Total) - T*∆S(Total)
-41950.36 + 300 = -41650.36
1,25T + 22,865T = 21,625T
4,95E-03(T^2) - 9,9E-03(T^2) = - 4,95(T^2)
0,60E+05(T^-1) - 0,30E+05(T^-1) = - 0,90E+05(T^-1)
0 + 1,25T*Ln(T) = 1,25T*Ln(T)

-41650.36 + 21,625T - 4,95(T^2) -

#VALUE! [cal]
Entropias Estandar
S⁰ [cal/K]
10.19

7.97

49.01

-37500

0.28
2.80E-03
2.00E+04

140.65 [cal]

-22.285

2.32 [cal/K]

0.28
2.80E-03
2.00E+04
 C

2521.5 [cal]

5.49 [cal/K]

-1.81
4.30E-03
2.00E+04

+ C

- 1488.21 [cal]

[cal/K^2]

+ C

+ 7.23 [cal/K]

ʃ∆Cp*dt - Hf(Cu) + ʃ∆Cp*dt

2521.5 - 3120 - 1488.21 =
0,28T - 0 - 1,81T =
1,4E-03(T^2) - 0 + 2,15E-03(T^2) =
0,20E+05(T^-1) - 0 - 2,00E+04(T^-1) =
0,60E+05(T^-1) [cal]

ʃ(∆Cp/T)*dT - Hf(Cu)/T + ʃ(∆Cp/T)*dT

5.49 - 0 + 7.23 =
0,28*ln(T) - 0 - 1,81*ln(T) =
2,80E-03T - 0 + 4,30E-03T =
0,10E+05(T^-2) - 0 - 1,00E+04(T^-2) =
0 - 3120(T^-1) + 0 =

0,30E+05(T^-2) - 300(T^-1) [cal/K]

0,90E+05(T^-1) + 1,25T*Ln(T) [cal]

 -41950.36
- 1,25T
4,95E-03(T^2)
- 0,60E+05(T^-1)
 -22.865
- 1,25*ln(T)
9,9E-03T
0,30E+05(T^-2)
- 300(T^-1)