JEE Advanced Sample Question paper for Chemistry

PAPER−2

Roll No.

JEE Advanced 2018

Sample Question Paper
CHEMISTRY
Section-1 (Maximum Marks : 18)
(i) This section contains 6 questions.
(ii) Each question has 4 options (a), (b), (c), and (d). ONLY ONE of these four options
is correct.
(iii) For each question, darken the bubble corresponding to the correct option in the ORS.
(iv) For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If, only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : −1 In all other cases.

 Br 
1. At what  does the following cell have its reaction at equilibrium ?

 CO  
Ag(s) | Ag2CO3(s) | Na2CO3(aq) | | KBr(aq) | AgBr(s) | Ag(s)
KSP = 8×10−12 for Ag2CO3 and KSP = 4×10−13 for AgBr
(a)  ×10−7
(b)  ×10−7
(c)  ×10−7
(d)  ×10−7

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 JEE Advanced Sample Question paper for Chemistry

2.

Infinite number of flasks are connected to one another as shown above. The volume and
pressure in each flask vary as shown. The stopcocks are initially closed. The common pressure,
when all the stopcocks are opened, is : (Assume constant temperature)
(a) P

(b)  P

P
(c) 


(d)  P


(i) CH3MgBr LiAlH4

Ph – N = C = O P Q
3. (ii) H2O

(a) P is Ph−NH−C−CH3 and Q is Ph−NH−CH2−CH3

O
(b) P is Ph−NH−CH3 and Q is NH3

CH3

(c) P is PhN=C−OH and Q is Ph−NH−CH3

(d) P is Ph−NH−CH−CH3 and Q is Ph−NH−CH−CH3
OH CH3

4. One pink solid (X) has the formula CoCl3.5NH3.H2O. A solution of this salt (X) in water is also
pink and precipitates 3 mole AgCl on treatment with silver nitrate solution. When the pink solid
(X) is heated, it loses 1 mole H2O to yield a purple solid (Y) with the same molar ratio of
NH3 : Cl : Co. The purple solid releases two of its chlorides rapidly on dissolution and after
treatment with AgNO3 solution. The coordination number of cobalt in complexes (X) and (Y) is
six. The IUPAC name of pink (X) and purple (Y) complexes respectively are :
(a) Tetraamminechloridoaquacobalt(III) chloride and pentaamminechloridocobalt(III) chloride.
(b) Pentaamminechloridocobalt(III) chloride and pentaammineaquacobalt(III) chloride.
(c) Pentaamminechloridocobalt(III) chloride and pentaamminechloridocobalt(III) chloride.
(d) Pentaamminechloridocobaltate(III) chloride and pentaamminechloridocobaltate (III) chloride.

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 JEE Advanced Sample Question paper for Chemistry

5. A hydrocarbon (R) has six membered ring in which there is no unsaturation. Two alkyl groups
are attached to the ring adjacent to each other. One group has 3 carbon atoms with branching at
1st carbon and another has 4 carbon atoms. The larger alkyl group has main chain of three
carbon atoms of which second carbon is substituted. Correct IUPAC name of compound (R) is
(a) 1-(1-Methylethyl)-2-(1-methylpropyl)cyclohexane
(b) 1-(2-Methylethyl)-2-(1-methylpropyl)cyclohexane
(c) 1-(1-Methylethyl)-2-(2-methylpropyl)cyclohexane
(d) 1-(1-Methylethyl)-2-butylcyclohexane

6. The end product `W` in the following sequence of reactions is :

CH3
(a) Ph−CH2−CH2−O−CH−Ph
CH3 CH3
(b) Ph−CH−O−CH−Ph
(c) Ph－CH2－O－CH2－CH2－Ph

(d)

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 JEE Advanced Sample Question paper for Chemistry

Section-2 (Maximum Marks : 28)

(i) This section contains 7 questions.
(ii) Each question has 4 options (a), (b), (c), and (d). ONE OR MORE THAN ONE of
these four option(s) is(are) correct.
(iii) For each question, darken the bubble(s) corresponding to the correct option(s) in the
ORS.
(iv) For each question, marks will be awarded in one of the following categories:
Full Marks : +4 If, only the bubble(s) corresponding to all the correct option(s)
is(are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option,
provided No incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : −2 In all other cases.
(v) For example, if (a), (c) and (d) are all the correct options for a question, darkening all
these three will result in +4 marks; darkening only (a) and (d) will result in +2 marks;
and darkening (a) and (b) will result in –2 marks, as a wrong option is also darkened.

7. The correct statements about the following reaction sequence is/are

(a) `R` gives an aldol condensation reaction on heating with NaOH solution
(b) The compound `Q` gives a yellow precipitate in acetone
(c) Step `4` is an aromatic nucleophilic substitution reaction
(d) The end product is a mixture of three compounds

8. Which of the following statements is/are incorrect ?

(a) Ammonia is oxidised to NO2 by oxygen at 800°C in presence of a catalyst platinum.
(b) Nitric acid on standing slowly turns yellow.
(c) Colloidal sulphur is formed when H2S gas is passed through nitric acid solution.
(d) N2O3 gas dissolves in water giving a pale blue solution.

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 JEE Advanced Sample Question paper for Chemistry

9. Which of the following are correct statements

(a) Spontaneous adsorption of gases on solid surface in an exothermic process as entropy
decreases during adsorption.
(b) Formation of micelles takes place when temperature is below Kraft Temperature (Tk) and
concentration is above critical micelle concentration (CMC).
(c) A colloid of Fe(OH)3 is prepared by adding a little excess (required to completely precipitate
Fe3+ ions as Fe(OH)3 of NaOH in FeCl3 solution the particles of this sol will move towards
cathode during electrophoresis.
(d) According to Hardy-Schulze rules the coagulation (flocculating) value of Fe3+ ion will be
more than Ba2+ or Na+.

10. Following three planes (P1, P2, P3,) in an FCC unit cell are shown. Consider the following
statements and choose the correct option that follow :

(a) P1 contains no three dimensional voids.

(b) P2 contains only octahedral voids.
(c) P3 contains both octahedral and tetrahedral voids.
(d) All are true.

11. Which of the following statements is/are correct :

(a) Equivalent mass of Br3O8 in the given reaction is 23.
Br3O8 + I－ + H+ → Br2 + I2 + H2O
(b) In case of oxalic acid (H2C2O4), the average oxidation number and individual oxidation
number of carbon have the same value.
(c) In case of iodimetric titration, Kl is made to react with an oxidising agent and the
liberates I2 gas is made to titrate with hypo solution.
(d) Equivalent mass of Cu3P in the given reaction is M/11 (where M = mol. mass)
Cu3P + KMnO4 + H+ → Cu2+ + H2PO4－ + K+ + Mn2+

12. Peroxodisulphate salts (Na2S2O8) are strong oxidizing agents used as bleaching agents for fats,
oil etc. Given
O2(g) + 4H+(aq) + 4e－ → 2H2O() E° = 1.23 V
S2O8－2 + 2e－ → 2SO4－2 (aq) E° = 2.01 V
Which of the following statements is (are) correct ?
(a) Oxygen gas can oxidize sulphate ion to per-oxo disulphate ion (S2O8－2) in acidic solution.
(b) O2(g) is reduced to water
(c) Water is oxidised to O2
(d) S2O8－2 ions are reduced to SO4－2 ions.

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 JEE Advanced Sample Question paper for Chemistry

13. Which order/s is/are correct regarding melting point ?

(a)

(b)

(c)

(d)

Section-3 (Maximum Marks : 24)

(i) This section contains 2 paragraphs.
(ii) Based on each paragraph, there are few questions.
(iii) Each question has FOUR options (a), (b) (c) (d). ONLY ONE of these four options is
correct.
(iv) For each question, darken the bubble corresponding to the correct option in the ORS.
(v) For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If, only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 In all other cases.

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 JEE Advanced Sample Question paper for Chemistry

14. For certain substances such as ammonium chloride, nitrogen peroxide, phosphorus pentachloride,
etc. the measured densities are found to be less than those calculated from their molecular
formula. The observed densities decrease towards a limit as the temperature is raised. This is
due to the splitting of the molecules into simpler once. The process is reversible and is called
thermal dissociation.
Examples : NH4Cl ⇌ NH3 + HCl I2 ⇌ 2I
N2O2 ⇌ 2NO2 PCl5 ⇌ PCl3 + Cl2
With increase in the number of molecules, the volume increases (pressure remaining constant)
and, in consequence, the density decreases. As the temperature rises, more and more
dissociation takes place, and when practically complete dissociation occurs the density reaches
its lowest limit.
The extent of dissociation, i.e. the fraction of the total number of molecules which suffers
dissociation is called the degree of dissociation. Gas density measurements can be used to
determine the degree of dissociation. Let us take by general case where one molecule of a
substance A splits up into n molecule of A on heating; i.e.,
An(g) ⇌ nA(g)
t = 0 a 0
x
t = teq a−x n.x α =  ⇒ x = aα.
a
a−aα naα
Total no. of moles = a − aα + naα
= [1 + (n – 1) α]a
Observed molecular weight or molar mass of the mixture
mA n
Mmixture =  , MA n = Molar mass of gas An
   n   
(i) A sample of mixture of A(g), B(g) and C(g) under equilibrium has a mean molecular
weight (observed) is 80. The equilibrium is
A(g) ⇌ B(g) + C(g)
(mol. wt. = 100) (mol. wt. = 60) (mol. wt. = 40)
Find the degree of dissociation α for A(g).
(a) 0.25
(b) 0.5
(c) 0.75
(d) 0.8

(ii) If the total mass of the mixture in the above case is 300 gm, the moles of C(g) present
are.

(a)  mole


(b)  mole


(c)  mole

(d) None

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 JEE Advanced Sample Question paper for Chemistry

(iii) The Kp for the reaction N2O4 ⇌ 2NO2 is 640 mm at 775 K. The percentage dissociation
N2O4 at equilibrium pressure of 160 mm is :
(a) 80%
(b) 30%
(c) 50%
(d) 70%

D
(iv) x(degree of dissociation) varies with  in the above reaction according to:
d

(a) (c)

(b) (d)

Dd
(v) The equation α =  is correctly matched for :
n  d
(a) A ⇌ nB/2 + nC/3
(b) A ⇌ nB/2 + (2n/3)C
(c) A → (n/2)B + (n/4)C
(d) A ⇌ (n/2)B + C

15. Two alophatic aldehydes P and Q react in the presence of aqueous K2CO3 to give compound
R, which upon treatment with HCN provides compound S. On acidification and heating, S gives
the product shown below.

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 JEE Advanced Sample Question paper for Chemistry

(i) The compound P and Q respectively are :

(a)

(b)

(c)

(d)

(ii) The compound R is

(a) (c)

(b) (d)

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 JEE Advanced Sample Question paper for Chemistry

(iii) The compound S is :

(a) (c)

(b) (d)

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