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REFINERY FEEDSTOCKS:
A refinery feedstock is product or a combination of products derived from crude
oil and destined for further processing other than blending in the refining industry.
It is transformed into one or more components and/or finished products. (feedstock
means any raw material from crude oil).
Basic Raw materials for refineries is crude oil itself.
Other feedstocks may include Gilsonite, a solid asphalt of low melting point, oil
sands; unconsolidated or consolidation formation’s oil and natural gas liquid
(NGL).
The basic raw material for refineries is petroleum or crude oil, even though in
some areas synthetic crude oils from other sources (Gilsonite, oil sands, etc.) and
natural gas liquids are included in the refinery feedstocks. The chemical
compositions of crude oils are surprisingly uniform even though their physical
characteristics vary widely. Since 1980, crude oils charged to U.S. refineries have
become heavier (lower °API, higher sp. gr.) and have higher sulfur contents. Both
of these properties require more severe and more costly processing. In 1980, the
average gravity was 33.8°API (sp. gr. 0.856) and the sulfur content, 0.89 wt%. By
2004, the gravity had decreased to 30.5°API (sp. gr. 0.874) and the sulfur content
had increased to 1.42 wt%.
CRUDE OIL PROPERTIES:
API gravity
Sulphur Content
Pour Point
Carbon Residue
Characterization Factor
Nitrogen Content
Metal Content, ppm
Total Acid Number (TAN)
1. API Gravity:
The density of petroleum oils is expressed in the United States in terms of API
gravity rather than specific gravity; it is related to specific gravity in such a fashion
PE-406 Petroleum Refinery Engineering (notes by maisam abbas)
Department of Petroleum Engineering- NED University of Engineering and Technology
PRODUCT ANALYSIS:
PE-406 Petroleum Refinery Engineering (notes by maisam abbas)
Department of Petroleum Engineering- NED University of Engineering and Technology
Natural gas liquids (NGL) are components of natural gas that are separated from
the gas state in the form of liquids. This separation occurs in a field facility or in a
gas processing plant through absorption, condensation or other method. Natural
gas liquids are classified based on their vapor pressure, as low (condensate),
intermediate (natural gas) and high vapor pressure (liquified petroleum gas, LPG).
REFLUX RATIO: it is the ratio between boil up rate and the takeoff rate. In other
words, it is the ratio between the amount of reflux that goes back down the
distillation column, and the amount of reflux that is collected in the receiver
(distillate).
PE-406 Petroleum Refinery Engineering (notes by maisam abbas)
Department of Petroleum Engineering- NED University of Engineering and Technology
ANTI-KNOCK INDEX:
In the United States the "octane" rating of a gasoline is based on the anti-knock
index (AKI). This reflects the tendency of the fuel to burn in a controlled manner.
The greater the tendency to burn in a controlled manner, the less the amount of
engine knocking and the greater the engine's efficiency.
VISCOSITY INDEX:
these processes.
Na2CO3 and NaOH chemicals are generally used for desalting of crude oil.
PE-406 Petroleum Refinery Engineering (notes by maisam abbas)
Department of Petroleum Engineering- NED University of Engineering and Technology
The main (primary) purpose of using desalter is to remove the salts typically
calcium, magnesium and sodium to minimize corrosion . Among the different type
of desalting , electric desalting is better in performance than other types. It requires
less cost and less time and is effective. This mechanism is called electrostatic water
separation. Desalting and dehydration is achieved simultaneously with a
spectacular removal of more than 90% of salt from raw crude oil in just less than
an hour. Electric desalting is a combination process to remove inorganic salts and
other impurities from the crude oil.
The principle in the electric desalting method is simple; under a charged electric
field the polar molecules orient. A potential of 20,000 to 30000 volts is applied
between the electrodes through which the crude oil is passed. Water presents in the
form of emulsion also coalesces and agglomerates in to stream entrapping all the
salts in this process. Brine collects at the bottom of the desalter, which crude floats
above and forms a separate stream.
The salt in the crude in the form of dissolved or suspended salt crystals in water are
emulsified with crude oil. De-emulsifiers break emulsion into brine and crude oil.
(crystals are emulsified with crude oil)
EMULSION:
An emulsion is a mixture of two or more liquids that are normally immiscible.
PE-406 Petroleum Refinery Engineering (notes by maisam abbas)
Department of Petroleum Engineering- NED University of Engineering and Technology