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Metallurgy
1. Fe 2. Al
m
3. Ca 4. Na
co
2. The most abundant element in the earth’s crust (by weight) is
n.
1. Si 2. Al
io
3. O 4. Fe
3.
at
Which of the following metal occurs in native state?
uc
1. Ca 2. Au
ed
3. Zn 4. Al
hi
1. Flux 2. Slag
a
1. Slag 2. Mud
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3. Gangue 4. Flux
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2. Minerals into silicates
7. When a metal is to be extracted from its ore and the gangue associated with
m
the ore is silica, then
co
1. An acidic flux is added
n.
3. Both acidic and basic and basic fluxes are added
io
at
4. Neither of them is needed uc
8. Which of the following is not a basic flux?
1. CaCO3 2. Lime
ed
3. SiO2 4. CaO
hi
ks
1. Galena 2. Bauxite
a
.s
3. Cinnabar 4. Cryolite
w
11. Willemite is a
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3. Carbonate mineral 4. Oxide mineral
1. Both i & iii 2. Both ii & iv 3. Both i & iv 4. Both iii & iv
m
13. Method used for the concentration of tinstone ore is
co
1. Hand picking 2. Froth flotation
n.
3. Magnetic separation 4. Leaching
io
14. The sulphide ores are generally concentrated by
at
1. Gravity separation uc 2. Froth location process
16. In the froth floatation process of concentration of ores, the ore particles float
.s
because they
w
1. Are light
w
2. Are insoluble
w
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17. The oil used in the froth floatation method for the purification of ores is
m
1. Frothing agent 2. Collecting agent
co
3. Conditioning 4. Lubricating agent
n.
19. The collecting agent in froth floatation process is
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1. Sodium ethyl xanthate 3. Pine oil
at
3. Lime uc 4. Water
1. Silica 2. Wolframite
hi
3. SnO2 4. Clay
ks
21. Heating of ore in the absence of air below its melting point is called
a
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24. Heating of metal pyrites to convert them into oxides of metal in the presence
of air is called
m
1. Zinc 2. Iron 3. Aluminium 4. Copper
co
26. The common method of extraction of metals from oxide ores is
n.
3. Reduction with aluminium 4. Electrolytic method
io
at
27. In electro-refining of metal the impure metal is made the anode a strip pure
metal, the cathode, during the electrolysis an aqueous solution of a complex
uc
metal salt. This method can not be used for refining of
ed
28. An ore after levigation is found to contain basic impurities. The flux which
can be used during smelting is
ks
29. The method for the purification of impure metals which is based upon the
w
30. The phenomenon of removing layers of basic oxides form metals before
electroplating is called.
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31. Glauber salt is
32. Galena on heating in limited supply of air gives lead metal. This is known as
m
33. Column-I Column-II
co
(Metals) (Ores)
n.
A) Tin 1) Calamine
B) Zinc 2) Cassiterite
io
C) Titanium 3) Cerrussite
at
D) Lead 4) Rutile
uc
A B C D
ed
1) 1 2 3 4
2) 2 1 4 3
hi
3) 4 3 2 1
ks
4) 2 1 3 4
a
.s
List-I List-II
w
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D) Leaching 4) Oxidation and the product i solid state
5) Reduction and the product (metal or its sulphate) as
liquid
A B C D
1) 5 4 1 2
m
2) 2 3 4 1
co
3) 3 1 5 2
n.
4) 5 2 1 3
io
35. Froth flotation process used for the concentration of sulphide ore
at
a) Is based on the difference in wettability of different minerals
uc
b) Uses sodium ethyl xanthate, C2 H5OCS 2 Na as collector
ed
c) Uses NaCN as depressant in the mixture of ZnS and PbS when ZnS forms
hi
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2. 3. I, III and IV 4. I, II, III and IV
37. In Van arkel method, If I 2 is introduced at 1700K over impure metal, the
product will be
m
38. Match the following.
co
List-I List-II
n.
Dressing methods Principle involved
io
A) Washing with water 1) Fusibility difference
at
B) Forth floatation 2) Density difference
uc
C) Hand picking 3) Wetting difference
D) Liquation 4) Colour, size etc. of ore particulars difference
ed
A B C D
ks
1) 3 1 4 2
a
2) 5 2 1 3
.s
3) 2 3 4 1
w
4) 3 2 5 4
w
w
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40. Match the following.
List-I List-II
m
C) Pyrargyrite III) MgSO4 .H 2O
D) Diaspore IV) KAlSi3O8
co
V) CaMg 3 SiO3 4
n.
The correct answer is
io
A B C D
1) IV V
at II I
uc
2) IV V I II
ed
3) IV I III II
hi
4) II V IV I
ks
41. Which of the following factors is of no significance for roasting sulphide ores
a
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42. Assertion: Ores are generally converted into oxides, prior to reduction.
1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
m
2. If both assertion and reason are correct, but reason is not the correct explanation
of the assertion.
co
3. If assertion is correct but reason is incorrect.
n.
4. If assertion is incorrect but reason is correct.
io
43. Assertion: In froth floatation process sodium ethyl xanthate is used as
at
collector.
uc
Reason: Sulphide ores are water soluble.
ed
1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
hi
2. If both assertion and reason are correct, but reason is not the correct explanation
ks
of the assertion.
a
44. Assertion: Lead, tin and bismuth are purified by liquation method.
w
Reason: Lead, tin and bismuth have low m.p. as compared to impurities.
1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
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2. If both assertion and reason are correct, but reason is not the correct explanation
of the assertion.
m
45. Assertion: All the ores are mineral.
co
Reason: Ores contains metals combined state.
1. If both assertion and reason are correct, and reason is the correct explanation of
n.
the assertion.
io
2. If both assertion and reason are correct, but reason is not the correct explanation
at
of the assertion.
uc
3. If assertion is correct but reason is incorrect.
ed
Key
a
1) 2 2) 3 3) 2 4) 3 5) 4 6) 1 7) 2 8) 3 9) 4 10) 2
.s
11) 2 12) 1 13) 3 14) 2 15) 1 16) 3 17) 4 18) 1 19) 1 20) 2
w
21) 4 22) 4 23) 4 24) 4 25) 3 26) 1 27) 2 28) 1 29) 1 30) 3
w
w
31) 2 32) 3 33) 2 34) 1 35) 4 36) 2 37) 2 38) 3 39) 1 40) 2
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Solutions
1. Al 7.28% by weight.
m
3. Au, Pt, Pd are occur is native state.
co
6. Flux is added to convert insoluble impurities to a fusible mass.
n.
9. Cryolite is Na3 AlF6 or 3 NaF : AlF3
io
13. Tinstone is SnO2
18.
at
Olive oil in the froth floatation process act as Frothing agent.
uc
23. MgCO3 MgO CO2
ed
MgO C Mg CO
ks
Cayreterite - SnO2
w
Cerruti - PbCO3
w
Rutile -
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m
1. Liquation 2. Amalgamation 3. Leaching 4. Calcination
co
2. When Baxuite is heated with NaOH solution, the water soluble compound
formed is
n.
1. NaAlO2 2. Na3 AlO3 3. Al OH 3 4. Al2O3
io
3. A mixture of White Bauxite powder and coke is heated in nitrogen gas very
strongly. The products are
at
uc
1. Al2O3 , C2 N 2 2. Al NO3 3 , CO
ed
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3. Pure alumina in molten cryolite with fluorspar
1. Be 2. Mg 2. Ba 4. Ca
m
8. The formula of Dolomite is
co
1. MgCO3 .CaCl2 2. MgCO3 .CaCO3 3. MgCO3 .CaSO4 4. MgCl2 .CaCO4
n.
9. Composition of carnallite is
io
1. CaCO3 .MgCO3 2. MgCl2 .KCl.6 H 2O 3. Al2O3 .2 H 2O 4. MgSO4 .7 H 2O
10.
at
Hydrated magnesium chloride becomes anhydrous salt when is is heated
uc
1. With P4O10 2. With anhydrous CaCl2
ed
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1. To decrease melting point of NaCl
m
15. Goldsmith thermitt process involves in the following reaction
co
1. Cr2O3 2 Al 2Cr Al2O3
n.
2. Fe2O3 3CO 2 Fe 3CO3
io
IR
3. MoO3 3H 2 Mo 3H 2O
at
0
300 C
4. 2 NiO H 2 CO 2 Ni H 2O CO2
uc
16. In the purification of “Al” by Hoop’s process the correct statement is
ed
2. Under layer is pure Al and Carbon rods in it are cathode and the bottom layer
ks
3. Electrolyte is the middle layer with fused mixture of flouri of Na,Al Ba.
.s
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1. I, II and III are correct 2. Only I and II are correct
3. Only I and III are correct 4. Only II and III are correct
Reason (R): Presence of HCl gas checks up the hydrolysis of MgCl2 by its
m
water or crystallization.
co
1. Both A and R are true and R is correct explanation of A.
n.
2. Both A and R are true and R is not correct explanation of A.
3. A is true but R is false.
io
4. A is false but R is true.
at
19. In Down’s process for the extraction of sodium, the melting point of NaCl is
uc
lowered from 8030 C to 6000 C
ed
b) In order to avoid corrosive action of sodium and chlorine on the vessel at the
hi
high temperature.
ks
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21. Ellingham diagram represents
m
4. Change of G T S with temperature
co
22. Select correct statement.
n.
a) The decomposition of an oxide into oxygen and metal vapour entropy
io
increases.
at
b) Decomposition of an oxide is an endothermic change.
uc
c) To make G0 negative, temperature should be high enough so that T S 0
T S 0 H 0 .
ed
List-I List-II
w
potassium chloride
w
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A B C D
1) 2 3 4 1
2) 5 4 1 2
3) 3 2 1 4
m
4) 5 2 3 2
co
24. Calomel Hg 2Cl2 on reaction with ammonium hydroxide gives
n.
1. Hg NH 2 Cl 2. NH 2 Hg Hg Cl
io
3. Hg 2O 4. HgO
25.
at
Assertion: Thermite mixture Fe2O3 Al (powder) is used in the welding.
uc
Reason: Al is a good reductant.
ed
1. If both assertion and reason are correct, and reason is the correct explanation of
hi
the assertion.
ks
2. If both assertion and reason are correct, but reason is not the correct explanation
of the assertion.
a
.s
1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
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2. If both assertion and reason are correct, but reason is not the correct explanation
of the assertion.
m
27. Assertion: In the electrolytic reduction of Al2O3 , cryolite is used.
co
Reason: Cryolite is an ore of aluminium.
n.
1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
io
2. If both assertion and reason are correct, but reason is not the correct explanation
at
of the assertion.
uc
3. If assertion is correct but reason is incorrect.
ed
28. Assertion: Al2O3 is converted into Al by reduction with carbon at high temp.
ks
1. If both assertion and reason are correct, and reason is the correct explanation of
.s
the assertion.
w
2. If both assertion and reason are correct, but reason is not the correct explanation
w
of the assertion.
w
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29. Assertion: Reduction of ZnO with carbon is done at 11000C.
1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
m
2. If both assertion and reason are correct, but reason is not the correct explanation
of the assertion.
co
3. If assertion is correct but reason is incorrect.
n.
4. If assertion is incorrect but reason is correct.
io
30. Which of the following metal can be obtained by the electrolysis of the
at
aqueous solutions of their salts?
uc
1. Cu 2. Na 3. Mg 4. K
ed
31. The mass of carbon anode consumed (giving only carbon dioxide) in the
production of 270 kg of aluminium metal from bauxite by the Hall process is
hi
32. Railway wagon axles are made by heating iron rods embedded in charcoal
a
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34. Stainless steel does not rust because
m
4. Iron forms a hard chemical compound with chromium present in it.
co
35. In the electrolysis of alumina, cryolite and CaF2 are added to
n.
1. Increase the emf of cell 2. Decrease the emf of cell
io
3. decrease the melting point 4. Both (b) and (c)
at
36. The method used to prepare steel is
uc
1. Bessemer’s convertor method 2. Siemen’s Martin process
ed
37. Out of the following metals that cannot be obtained by electrolysis of the
aqueous solution of their salts are
ks
1. Ag 2. Cr 3. Cu 4. Mg
a
.s
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3. Roasting 4. All of the above
m
co
Key
n.
1) 3 2) 1 3) 3 4) 2 5) 2 6) 3 7) 2 8) 2 9) 2 10) 3
io
11) 1 12) 2 13) 2 14) 1 15) 1 16) 4 17) 4 18) 1 19) 4 20) 1
at
21) 1 22) 4 23) 2 24) 1 25) 2 26) 1 27) 2 28) 3 29) 1 30) 1
uc
31) 4 32) 4 33) 1 34) 2 35) 3 36) 4 37) 4 38) 2 39) 4 40) 4
ed
41) 2
hi
ks
Solutions
a
SiO2 2C Si 2CO
w
2075 K
Al2O3 3C N 2 2 AlN 3CO
8. Dolomite is MgCO3CaCO3
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9. Carnallite is KClMgCl2 6 H 2O
m
24. HgCl2 2 NH 2OH Hg Hg NH 2 Cl NH 4Cl 2 H 2O
co
31. Copper metal (Cu) is obtained by the electrolysis of the aqueous solution of their
salts.
n.
io
32. In case hardening technique, iron rods embedded in charcoal power are heated
repeatedly and thus, this technique is used in making axles of railway wagon.
33.
at
Annealing is the process of heating steel to redness followed by slow cooling. It
uc
makes steel soft.
ed
34. Chromium is more electropositive metal than iron. In stainless, chromium forms
an oxide layer and thus, it protects steel from corrosion.
hi
35. Cryolite and CaF2 (fluorspar) are added to alumina in its electrolysis to decrease its
ks
37. Magnesium (Mg) cannot be obtained by the electrolysis of their aqueous salt
solution because when it is liberated at cathode, at once reacts with H 2O give
w
38. In the iron silica is present as impurity so far the removal of silica impurity
limestone is used.
CaCO3 CaO CO2
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CaO SiO2 CaSiO3
Slag
40. Tin stone SnO2 has impurities of wolframite FeWO4 .MnWO4 , which are
m
co
S O2 SO2
41. Cast iron or pig contains 2 to 4.5% of carbon. It is the least ductile and least pure
n.
form of iron; it is brittle and cannot be welded.
io
at
uc
ed
hi
a ks
.s
w
w
w
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