Documente Academic
Documente Profesional
Documente Cultură
Kyra Lawson
Intern/Mentor GT
Dr. Melissa Kiehl
Dr. Mohammad Modarres
April 27, 2018
Abstract
Energy demand is expected to increase dramatically during the following decades. The
source of this energy is important when considering the environment, human safety, and
reliability. Nuclear energy can produce large amounts of electricity in small periods of time
without emitting carbon dioxide. Although uranium has been the major nuclear fuel, thorium is a
much safer, cleaner, and more efficient option. Along with the utilization of a new GEN IV
reactor design, thorium may power the world and solve the energy crisis.
The purpose of this research is to discuss the safety, efficiency, and cost aspects of the
thorium molten salt reactor (MSR). The various designs created around the world were analyzed
and used to determine which specific features improve the reactor’s overall performance. The
data will be presented in papers and reports; an example is the summary written for the American
Nuclear Society meeting. The advantages of generating power through the thorium MSR are
contrasted with the flaws of fossil fuels. More research is required to fully understand and
The energy crisis is a critical issue in the present and future world. As the population
grows, energy demand is projected to double by 2050 (Nuttin et al., 2005). Fossil fuels destroy
the environment, and renewable energy sources cannot keep up with demand. The only realistic
source of energy that can provide substantial amounts of power with no adverse climate effect is
nuclear energy. However, nuclear technology has not been majorly innovated since the 1970s;
most reactors in use today are in forms of those created in the 1950s (“Nuclear power reactors,”
2017). The nuclear industry is slowly changing with future, so called GEN IV, nuclear power
plants that have many predicted advancements and advantages. The GEN IV molten salt reactor
(MSR) is one of the safest and most feasible of the newer designs. The utilization of thorium,
rather than uranium, fuel further increases the benefits of the MSR. The purpose of this paper is
to compare the MSR’s safety features to those of the conventional light water reactor (LWR),
analyze its efficiency and cost attributes, describe the MSR’s long-term qualities and
contributions, and define areas that lack sufficient research. The thorium molten salt reactor has
the potential to provide significant power in the future and possibly solve the energy crisis
Review of Literature
Background
Although this paper will focus on thorium as the main nuclear fuel, it is important to note
the differences between thorium and uranium. Although thorium is more abundant than uranium,
as seen in Chart 1, most reactors around the world utilize uranium. Only one natural isotope of
thorium exists. Because uranium is found in multiple isotopic forms, uranium requires much
more enrichment and processing than thorium. Uranium has been used instead of thorium for
many political reasons. Nuclear energy was first used for weapons, not for electricity generation.
Uranium is a great fissile material for weapons whereas thorium is only fertile. Research and
focus initially were placed on uranium because of these qualities. However, emerging evidence
supports that thorium may have a few advantages over uranium, such as its abundance and
proliferative resistance.
The MSR is a design from the 1950s that operated first at the Oak Ridge National
Laboratory during the 1960s. Originally the design was ignored because of the more competitive
light water reactor. The LWR was cheaper and more efficient in the past compared to the MSR,
and it has remained the most commonly used nuclear reactor in the world. However, this
technology has not been updated for decades. The MSR is becoming more appealing as current
reactors reach decommission. LWRs run on solid uranium fuel, are water-cooled, and operate at
high pressures. The MSR is a small modular reactor, can be salt-cooled and/or salt-fueled,
operate at low pressures, and can reach very high operating temperatures. The variations between
the two designs highlight the advantages the MSR has over the LWR.
The following describes the operation of an MSR that is both fueled and cooled by salt.
Fuel-- in this case thorium-- is dissolved in the molten salt, fissions inside the reactor core, and
creates copious amounts of heat. This heat travels through the primary loop (see Figure 1) and
then is transferred to the secondary loop through the heat exchanger. The gas or liquid, typically
water, inside the secondary loop is heated and turns a turbine that generates electricity. At the
bottom of the reactor, beneath the primary loop, a containment vessel is plugged with solid salt,
called the freeze valve. If the reactor were to overheat, the heat would spread throughout the
entire primary loop, causing the salt in the freeze valve to melt. All radioactive material would
drain by the force of gravity through the plug and into the dump tank, stopping fission. Control
rods and a graphite moderator may be placed in the reactor system to control the neutron flux.
There are many variations among MSR designs. First, the salt composition may vary from
lithium fluoride salts to chloride salts. The fuel can be thorium, uranium, spent fuel, radioactive
waste, or leftover nuclear weapons material. The fuel cycle may be open or closed, thus
reprocessing fuel is optional. An online and off-site reprocessing are possible; however, these
rediscovered. Multiple companies have made attempts in improving the reactor design:
MOSART, Flibe Energy, Thorcon, and Terrestrial Energy are some examples. The MSR was
named a GEN IV reactor in 2002 because of its “sustainability, economics, safety, reliability and
The thorium MSR may be the safest and cleanest reactor yet. Its inherent safety features
allow the reactor to be virtually meltdown-proof (Kamei, 2012). The dump tanks as described in
Background, automatically stop fission (Oak Ridge National Laboratory, 1969), so the fuel will
not produce any new heat after being drained. This automatic and passive cooling system
prevents a meltdown from occurring. Other than functioning as safety precautions for emergency
shutdowns and overheating, the dump tanks may also serve as storage for extra salt (Siemer,
2015). As temperatures increase, the volume of the salts expands. Expansion in salts may result
in a lower neutron flux, thus stopping the fission chain reaction and energy production. It is
important that this extra salt can be stored somewhere out of the way of the core and loops.
Another inherent safety feature of the MSR is its negative reactivity (Mathieu et al., 2006). The
reactor, the fuel salt expands and slows the rate of fission reactions. The reactor naturally cools
itself when the temperature becomes too hot. Passive cooling is further enforced with gravity and
natural air flow (Serp et al., 2014). As stated in the Background section, the operating pressures
of MSRs are much lower than those of conventional reactors; in fact, the MSR’s pressure is
about equal to that of a garden hose (TEDx Talks, 2016): 4.93 atm (Greaves, 2012). LWRs
operate at around 150 atm (“Nuclear power reactors,” 2018). Salts have much higher boiling
points than water, so less pressure is required to keep the salt in a safe liquid state (Xu, 2017).
However, some added pressure is required to circulate the fuel salt (Greaves et al., 2012).
Operating at high pressures is dangerous because if there were to be a breech in the reactor’s
outer containment structure, the pressure would force radiotoxic material out into the
surrounding environment. Lastly, the spent fuel of thorium MSRs is relatively safer and less
radioactive than conventionally (uranium) fueled LWRs. Thorium rarely produces long-lived
actinides (Katusa, 2012), whereas the fuel used in conventional reactors results in radioactive
waste with half-lives up to hundreds of thousands of years (see Table 1). This waste cannot be
safely stored for this extended period of time; however, the waste from thorium MSRs, which
has half-lives of around 300 years, can be easily stored until the radioactivity becomes low
enough not to be harmful. The waste is also smaller in volume due to the potential unlimited
burnup (Ignatiev, 2016). Because the fuel is in a liquid state rather than solid, the fuel may
remain in the reactor for as long as needed. A longer time in the reactor means more extraction
of energy. Thus, the energy, also known as radioactivity, in the spent fuel is greatly reduced. The
thorium MSR has many characteristics that contribute to its safety and cleanliness, which in turn
Efficiency
The thorium MSR is a very efficient source of energy. Often, the reasons for the MSR’s
safety and cleanliness are also the reasons for its excellent efficiency. The potentially unlimited
burnup mentioned in the Safety portion also allows for improved utilization of fuel. Most liquid
fuel reactors have at least a 90% burnup rate (Energy Process Developments Ltd et al., 2015).
Rather than only using 5% of the fuel, for example, that is extracted in LWRs (Modarres, 2018),
the MSR could potentially use 100% and thus waste no valuable resources. Because of this
burnup rate, the thorium MSR can potentially have a closed fuel cycle. This means that the fuel
continues to cycle through the reactor and reprocessing systems instead of just running once
through and then being stored underground. The MSR’s efficiency is further improved by the
high operating temperatures. Because salt is the coolant, this particular reactor can reach
temperatures up to 800℃ (Ignatiev & Feynberg, 2012). In comparison, LWRs may reach up to
325℃ (“Nuclear power reactors,” 2018). Higher temperatures yield higher fuel efficiency
because more heat is used in energy conversion; the water or gas in the secondary loop heats up
quicker and turns the turbine more times per unit of volume of fuel, producing more electricity
(“LFTR overview,” n.d.). Plus, the MSR can run off many different fuels: thorium, uranium,
transuranic wastes, actinides, weapon stockpiles, and spent fuel (Ignatiev & Feynberg, 2012).
Thus, the reactor may use whichever fuel is more efficient, depending on the market, cost, and
U from natural thorium also increases the efficiency of the reactor by
technology. Breeding 233
creating more fuel. Lastly, the MSR has multiple purposes other than producing energy. The
reactor may also serve as a heat source for industries not limited to cement, steel, oil, and coal
gasification (Serp et al., 2014), hydrogen production (Hylko, 2008), and fissile material
production. Therefore, the thorium MSR uses fuel very efficiently, decreasing the overall cost of
producing energy.
Cost
The thorium MSR may be the least expensive option in nuclear reactors today and may
even be competitive with fossil fuels in the future. One of the few disadvantages of current
nuclear reactors is the upfront cost. In 2009, one nuclear power plant needed on average $9
billion to complete construction (“Nuclear power cost,” n.d.). Because the MSR is a small
modular reactor, individual reactor parts may be mass-produced in the future. In current reactor
manufacturing, each individual part is built and assembled on or near the reactor site. The MSR
may change this time-consuming and expensive process completely since its parts can be
produced anywhere and then transported to the desired location (TEDx Talks, 2016). Not only
does the reactor have smaller parts, it has fewer parts as well. The low operating pressures
require fewer containment structures than reactors that operate with high pressures (Siemer,
2015). Also, as described in Efficiency, the MSR is very flexible in the type of fuel it burns. The
stress of cost of the MSR is reduced since the reactor can potentially run on whatever fuel is
cheapest at that time. Plus, most conventional reactors are cooled by water, so they must be
located near bodies of water. This problem is not encountered with the MSR; it can virtually be
placed anywhere, relieving the costs of competitive land space. Compared to current LWRs, the
MSR is comparably inexpensive mostly due to the reduction in structural materials. Because of
these cost, efficiency, and safety attributes, the thorium MSR has great potential for future
energy production.
The thorium MSR has immense potential of producing large amounts of clean energy in
the future. Currently, it would be very difficult for nuclear power production to exceed that of
fossil fuels because of the differences in costs and technology. However, fossil fuels and carbon
emissions are expected to increase in price due to the lack of resources and excessive harm to the
environment (Modarres, 2018). Thorium on the other hand is currently cheap and widely
available because there is no market for it (TEDx Talks, 2016). Many thorium reserves are
located in developing countries (see Table 1). India has approximately 846,500 tonnes of
thorium, which would produce enormous amounts of energy if the technology existed (IAEA,
2013). Having access to these resources makes nuclear energy much cheaper and feasible. The
unique ability of the MSR to run off multiple types of fuels allows it to be more versatile and
competitive with fossil fuels. Currently there are tons of nuclear weapon stockpiles around the
world, all of which are unused and will most likely remain unused for decades. Instead of letting
these materials radioactively decay underground or in storage facilities, they could be used to
fuel MSRs. Because of the lack of necessity of this material, the cost for this type of fuel might
be extremely competitive with fossil fuels. MSRs are also cheap enough to be used by
developing countries. Other than the fuel, the actual structure of the reactor is also relatively
inexpensive (see Cost section). China, a developing country, is currently in the process of
designing these reactors. If the country with the largest human population utilizes the thorium
MSR in place of fossil fuels, the environment and air quality may rapidly improve all over the
world.
The question that was to be answered is: is the thorium MSR a feasible design, and to
what extent do the safety, efficiency, and cost features compete with current energy sources? It
was hypothesized that thorium-fueled MSRs have many safety and economic risks due to the
lack of research and experimentation. However, as technology advances and more models are
created, the MSR will be proven exceptionally safe and will provide commercial power in a few
years. Thorium may also become a valuable fuel source because of its availability and resistance
to proliferation. The research question and hypothesis are addressed in this paper by first
addressing the individual safety, efficiency, and economic features of the MSR, then considering
other fuel sources, and then noting the areas in need of more research.
An evaluation design model was used to gather and present original data. This type of
data collection is qualitative and quantitative. Numerical and descriptive information was
examined, compared, and then used to conclude which reactor design is, overall, the most safe,
efficient, and economical. To support the hypothesis, an analysis of multiple MSR designs lists
and compares the features of different MSR designs. Such qualities were examined to determine
the most feasible, safe, and efficient design. Because building/testing a nuclear reactor is not
probable and experiments/tests on reactor designs already exist, a meta-analysis is the best data
collection method. Through data collection, new comparisons and conclusions have been made,
contributing to the overall collection of information about nuclear energy. Hopefully, the data
will help improve public opinion of nuclear reactors and perhaps push for more research in this
field.
Each of the designs compared (see Appendix A), except the MSRE, is a proposed design
based solely on research rather than direct experimentation. Therefore, some data may be
missing or inaccurate. Flibe Energy (not compared in chart) is another prominent nuclear
company that closely follows ORNL’s design and plans on utilizing a breeder reactor fueled by
thorium. Transatomic Power is another company that focuses on improving fuel utilization and
burnup to reduce nuclear waste output. The MSRE operated on highly enriched uranium that is
not legal for use today. The MSBR appears to be a promising design as multiple companies have
ThorCon seems to be the cheapest option above. Its parts are not designed to withstand
decades of neutron bombardment, so they are expected to be replaced every few years, causing
the price of these materials and parts to decline. Also, the company boasts of how no new
research is required to build and operate their reactor successfully. This reassurance reduces the
cost of research and allows for a quicker construction process. It is so inexpensive that ThorCon
expects to have an operating reactor by the early 2020s. Lastly, fuel is not typically a major cost
factor in the nuclear power industry; the overnight cost of the power plant itself usually
determines most of the budget. By comparing the salts of each of the reactors, it is evident that
ThorCon is the only reactor that does not utilize lithium in its salts. The elimination of usage of
Therefore, ThorCon currently is the most feasible molten salt reactor (MSR) design.
MOSART is a very flexible design in which it can breed or burn fuel. One potential issue,
however, is the operation on the fast neutron spectrum. While all other reactors are in the thermal
spectrum, the MOSART attempts higher burnup by using the fast spectrum. Compared the the
thermal spectrum, fast reactors are more difficult to control and prevent accidents. Therefore,
MOSART may obtain a high burnup, but this will be at the cost of safety. Seaborg’s
Wasteburner may be the most efficient design of the five. The reactor burns more nuclear waste
than it creates, increasing its overall efficiency. This reactor also operates at the highest
temperatures seen in the chart. Higher operating temperatures yield more efficient energy
extraction. Plus, the multiple fuels utilized, as seen in the fuel salt section of the chart, allow
flexibility in the reactor. Seaborg has proposed an onsite and online salt processing system that
Overall, all five designs have at least one aspect of inherent safety that will put these
reactors above conventional designs. Like any other nuclear power plant, however, these MSRs
will be expensive and require further research. The common graphite moderator places a limit on
the lifetime of the reactor cores because of its susceptibility to damage. While other parts of the
reactor remain intact, the graphite moderator becomes damage and must be replaced. Salts are
also known to corrode metals. However, the MSRE’s results showed that the hastelloy-N proved
to be resistant to corrosion at high temperatures; this is why multiple designs chose hastelloy-N
as the piping/container material. Fuel salt processing is also an issue because the United States
does not reprocess fuel due to proliferative risks. Many designs plan on having an onsite and
online processing system in order to improve efficiency and burnup. A combination of the
positive attributes of each reactor along with change in regulations would result in the safest
reactor design.
Although there are many appealing features of the thorium MSR, more research and
development are needed until the reactor may be implemented securely on a commercial level.
U. This isotope of
First, using thorium as a breeder fuel leads to proliferative issues with 233
uranium is a preferred nuclear weapon material because of its weak radioactivity (Greaves et al.,
Pa
a neutron poison; it captures neutrons and slows the fission reaction rate (Xu et al., 2014). 233
has a half-life of 27 days. Removing the isotope for such a brief period of time may seem
arbitrary, but the isotope also decreases the reactor’s efficiency. There are also proliferation risks
associated with online reprocessing. It is possible to operate an MSR without utilizing online
reprocessing; however, fuel efficiency and cost are greatly improved with this on-site process.
Currently, online reprocessing is complex and opens more opportunities for proliferation
(Mathieu et al., 2006). Reprocessing nuclear fuel overlaps with reprocessing of weapons
materials (Bean, 2018). Nuclear weapons cannot be created without reprocessing the fuel.
Therefore, there will always be the threat of proliferation with reprocessing; this is why the U.S.
does not utilize these systems (Modarres, 2018). The design of the MSR-- no matter the fuel--
faces the obstacle of corrosion. Using salt as the coolant and/or fuel is problematic when flowing
through hot metal pipes. New materials will be the answer to this problem. Hastelloy-N was used
in the original MSR at the Oak Ridge National Laboratory, but it can only function in
temperatures up to 704℃ (Muransky, 2016). Some other proposed materials are the ceramics,
Ni-SiC and NiMo-SiC. These materials are resistant to radiation and corrosion and are stable at
high temperatures. However, ceramics have rarely been used in these types of applications. Also,
lithium is used in many fuel and coolant salts for the purpose of decreasing the overall melting
point. For these salts to be utilized safely, the lithium must be enriched to at least 99.99% 7 Li (Xu
et al., 2014). The alternate isotope, 6 Li, will cause neutron loss. Another potential issue is tritium
production. Tritium is harmful to the reactor because it too eventually causes neutron loss when
it decays into 3 He (Forsberg et al., 2016). Overcoming these problems as well as political
Overall, increased funding, research, and development of the MSR is a very important
step in improving the most feasible and safe nuclear reactor design. New and better materials
need to be created in order to maximize efficiency in heat transfer and decrease corrosion. Fossil
fuels are not going to be able to keep up with energy demand without causing serious harm to the
environment and human health. Renewable energy will not be able to produce the necessary
amounts of electricity in short periods of time. As time goes on, new energy sources will be
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f
Appendix A
Burnup 256 4
250 10
(GWd/ton)
Fuel Salt Very basic, Onsite and Offsite. After Onsite and Onsite and
Processing onsite, and during 8 years in during during
during operation 3 reactor and 4 operation 7 operation 9
operation 1 years of decay
cooling 4
Electrical 250 4
270 10
Capacity
(MWe)
Thermal 556 3 557 4
Capacity
(MWth)
Core power 20 3 16 5
12 10
density
(kW/L)
Net Thermal 44.9 3 45 4
42.5 10
Efficiency
(%)
Core Lifetime 8.6 3 4 6
7 10
(years)
Core Volume 29.5 3 34.9 4 17.2 7 18.1 9
(m3)
Generation 140*3 0.024 4
cost ($/kW(e))
Overnight $140.9*3 $643.2 6
cost (millions)
Other Processing Based on Oak Simple reactor Has flexibility No refueling.
system is Ridge meant to be to be burner Produces less
needed for National deployed as or breeder -- waste than it
breeding with Laboratory’s soon as affects consumes.9
single-fluid (ORNL) possible 6 whether one Decommissio
reactor 1 previous stream or two ning is
experiments. stream.8 cheaper than
This project conventional
never received way. 7 Li is
funding nor expensive.
passed the
design phase.
Remaining “salt Graphite Parts are Graphite
issues chemistry, needs to be replaced limits core’s
fission replaced more often. 6 lifetime 9
product often than any
chemistry, other part of
materials and core ->
corrosion shortens
chemistry, lifetime. “The
radiation off-gas, fuel
chemistry, processing,
analytical afterheat
chemistry, removal, and
and fuel maintenance
processing.”1 systems
needed further
Investigation.
”
PWR requires
less
maintenance 3
*in the value of the 1968 dollar
**missing data is due to either the lack of resources or lack of research done by the company.