Tube Volume (mL)

Blanko 0.2
15 minute 0.4
30 minute 0.8
45 minute 1
60 minute 1.32
120 minute 1.95

(𝑎 − 𝑏)𝑚𝐿 𝑜𝑓 𝑁𝑎2 𝑆2 𝑂3 𝑥 𝑁 𝑁𝑎2 𝑆2 𝑂3 𝑥 1000

𝑃𝑒𝑟𝑜𝑥𝑖𝑑𝑒 𝑁𝑢𝑚𝑏𝑒𝑟 =
𝑆𝑎𝑚𝑝𝑙𝑒 𝑀𝑎𝑠𝑠 (𝑔𝑟𝑎𝑚)
 t = 15 minutes
a = 0,4 ml
b = 0.2 ml
Peroxide number = (0.4-0.2)ml x 0.1 x 100 x 8

1.86 gr
= 8.6
 t = 30 minutes
a = 0.8 ml
b = 0.2 ml
Peroxide number = (0.8 -0.2)ml x 0.1 x 100 x 8

1.86 gr
= 25.808
 t = 45 minutes
a = 1.0 ml
b = 0.2 ml
Peroxide number = (1.0 -0.2)ml x 0.1 x 1000

1.86 gr
= 34.408
  t = 60 minutes
a = 1.32 ml
b = 0.2 ml
Peroxide number = (1.32 -0.2)ml x 0.1 x 100 x 8

1.86 gr
= 48.176
 t = 120 minutes
a = 1.95 ml
b = 0.2 ml
Peroxide number = (1.95 -0.2)ml x 0.1 x 100 x 8

1.86 gr
= 75.272

t (second) Peroxide Number

900 8.6
1800 25.808
2700 34.408
3600 48.176
7200 75.272

Graphic of time vs peroxide number

90
80
70
Peroxide number

y = 0.0101x + 5.6374
60
R² = 0.9637
50
40
30
20
10
0
0 2000 4000 6000 8000
t (second)
Determine order of reaction

First order using integral non graphic method

𝑎
With this equation 𝑘 𝑡 = ln (𝑎−𝑥)

1 𝑎
𝑘= ln
𝑡 (𝑎 − 𝑥)

t (second) x Calculation k
900 0,02 1 7,27 3,05 x 10-6
𝑘= ln
900 (7,27 − 0,02)
1800 0,04 1 7,27 3,048 x 10-6
𝑘= ln
1800 (7,27 − 0,04)
2700 0,05 1 7,27 2,547 x 10-6
𝑘= ln
2700 (7,27 − 0,05)
3600 0,066 1 7,27 2,516 x 10-6
𝑘= ln
3600 (7,27 − 0,066)
7200 0,0975 1 7,27 1,862 x 10-6
𝑘= ln
7200 (7,27 − 0,0975)

Second order using integral non graphic method

𝑥
With this equation 𝑘 𝑡 = 𝑎(𝑎−𝑥)

1 𝑥
𝑘 =
𝑡 𝑎(𝑎 − 𝑥)
t (second) x Calculation k
900 0,02 1 0,02 4,216 x 10-7
𝑘 =
900 7,27(7,27 − 0,02)
1800 0,04 1 0,04 4,228 x 10-7
𝑘 =
1800 7,27(7,27 − 0,04)
2700 0,05 1 0,05 3,528 x 10-7
𝑘 =
2700 7,27(7,27 − 0,05)
3600 0,066 1 0,066 3.500 x 10-7
𝑘 =
3600 7,27(7,27 − 0,066)
 7200 0,0975 1 0,0975 2,597 x 10-7
𝑘 =
7200 7,27(7,27 − 0,0975)

Third order using integral non graphic method

1 1
With this equation 𝑘 𝑡 = 2(𝑎−𝑥)2 − 2𝑎2

1 1 1
𝑘 = 2
− 2
𝑡 2(𝑎 − 𝑥) 2𝑎

t (second) x Calculation k
900 0,02 1 1 1 9,514 x 10-6
𝑘 = −
900 2(7,27 − 0,02)2 2(7,27)2
1800 0,04 1 1 1 4,788 x 10-6
𝑘 = 2
−
1800 2(7,27 − 0,04) 2(7,27)2
2700 0,05 1 1 1 3,202 x 10-6
𝑘 = −
2700 2(7,27 − 0,05)2 2(7,27)2
3600 0,066 1 1 1 2,413 x 10-6
𝑘 = 2
−
3600 2(7,27 − 0,066) 2(7,27)2
7200 0,0975 1 1 1 1,218 x 10-6
𝑘 = 2
−
7200 2(7,27 − 0,0975) 2(7,27)2

Here are table k from non graphic method

t (second) k in order 1 k in order 2 k in order 3

900 3,05 x 10-6 4,216 x 10-7 9,514 x 10-6
1800 3,048 x 10-6 4,228 x 10-7 4,788 x 10-6
2700 2,547 x 10-6 3,528 x 10-7 3,202 x 10-6
3600 2,516 x 10-6 3.500 x 10-7 2,413 x 10-6
7200 1,862 x 10-6 2,597 x 10-7 1,218 x 10-6
Integral grahic method

First order

t (second) a x a-x ln (a-x)

900 7,27 0,02 7,25 1,981001
1800 7,27 0,04 7,23 1,978240
2700 7,27 0,05 7,22 1,976855
3600 7,27 0,066 7,204 1,974636
7200 7,27 0,0975 7,1725 1,970254

Graphic in first order

1.9820000
1.9800000
1.9780000
y = -2E-06x + 1.9815
ln (a-x)

1.9760000 R² = 0.9659
1.9740000
1.9720000
1.9700000
1.9680000
0 2000 4000 6000 8000
t (second)

Second order

t (second) a x a-x 1/(a-x)

900 7,27 0,02 7,25 0,137931
1800 7,27 0,04 7,23 0,138312
2700 7,27 0,05 7,22 0,138504
3600 7,27 0,066 7,204 0,138811
7200 7,27 0,0975 7,1725 0,139421
 Graphic in second order
0.1396
0.1394
0.1392
0.139
y = 2E-07x + 0.1379
1/ (a-x)

0.1388 R² = 0.9648
0.1386
0.1384
0.1382
0.138
0.1378
0 2000 4000 6000 8000
t (second)

Third order

t (s) a x a-x (a-x)2 1/(a-x) 2

900 7,27 0,02 7,25 52,5625 0,019025
1800 7,27 0,04 7,23 52,2729 0,019130
2700 7,27 0,05 7,22 52,1284 0,019183
3600 7,27 0,066 7,204 51,8976 0,019268
7200 7,27 0,0975 7,1725 51,4447 0,019438

0.019500
Graphic of third order
0.019450
0.019400
0.019350
0.019300
1/(a-x)2

0.019250
y = 6E-08x + 0.019
0.019200 R² = 0.9644
0.019150
0.019100
0.019050
0.019000
0 2000 4000 6000 8000
t (second)