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People v. Gonzales, 708 Phil.

121, 130-131, 2013, the Court explained that:

The first stage in the chain of custody rule is the marking of the dangerous drugs
or related items. Marking, which is the affixing on the dangerous drugs or
related items by the apprehending officer or the poseur-buyer of his initials
or signature or other identifying signs, should be made in the presence of
the apprehended violator immediately upon arrest. The importance of the
prompt marking cannot be denied, because succeeding handlers of dangerous
drugs or related items will use the marking as reference. Also, the marking
operates to set apart as evidence the dangerous drugs or related items from
other material from the moment they are confiscated until they are disposed of at
the close of the criminal proceedings, thereby forestalling switching, planting or
contamination of evidence. In short, the marking immediately upon
confiscation or recovery of the dangerous drugs or related items is
indispensable in the preservation of their integrity and evidentiary
value. (Emphasis supplied)

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