Up Physics

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AMIE(I) STUDY CIRCLE, SECOND FLOOR, SULTAN TOWER, ROORKEE - 247667 (UTTARANCHAL) EMAIL: pcourses@hotmail.com Ph: (01332) 266328, 9412903929, 9897394020
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AMIE Study Material & Admission Packages AMIE(I) Study Circle, Roorkee www.amiestudycircle.com
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(iii) Conductivity of a solution is directly

( vii) Lines of Balmer series are emitted by the proportional to
hydrogen atom when the electron jumps ( a ) dilution
from--.
( b ) number of ions
( viii) If the semiconductor temperature is increased,
( c ) current density
its resistance---
( d) volume of the solution.
{ix) If the externally applied magnetic field strength
(iv) The specific conductance of an electrolyte
on superconductor is increased . more
solution on dilution
than - - its superconductivity is lost.
( a ) decreases
(x) In Ruby laser, the active material i s - - and
( b ) increases
its outcoming wavelength is - - .
( c ) remains unchanged
(B) Choose the correct answer for the following : 1 x 10
(d) first increases and then decreases.
( i) The presence of which of the following gases in
( v ) Corrosion in essence is a process of
air checks the ultraviolet light from sunlight
( a ) red1.1ction
(a) S02
( b ) oxidation
{b) C02
( c ) electrolysis
(c) NO (d) extraction of metals.
(d) 03 ( vi) Which of the following produces another air

pollutant by reacting with oxides of nitrogen in
( ii) Crysta!line solids are presence of sunlight?
(a ) supercooled liquids (a) HCl
( b ) isotropic (b) S02

(c) 03
( c ) anisotropic
(d) HCN gas.
(d) not sharp melting.
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S'09: 3 AN: AN 206 ( 1406)
ENGINEERING PHYSICS AND CHEMIS'IRY
Time : Three hours
Maximum Marks : 100
Answer FIVE questions, taking ANY 1WO from Group A,

ANY 1WO from Group B and ALL from Group C.
AD parts of a question (a, b, etc. ) should

be answered at one place.
Answer should be brief and to-the-point and be supplemented

with neat sketches. Unnecessary long answers may
result in Joss ofmarks.
Any missing or wrong data may be assumed suitably giving

proper justification.
Figures on the right-hand side margin indicate full marks.
Group A
(Engineering Physics)
1. (a) What is Rutherford's nuclear atomic model? Explain.

In Rutherford scattering experiment, the number of
particles observed at an angle of 10" is one million
per minute. How many particles per minute will be
observed at 90"? (sin 5" == 0·0872 .) 3+2
(b) What are the assumptions of Bohr's theory

hydrogen atom? Derive expressions for (i) radius of
the orbit, and (ii) velocity of revolving electron.
(TurnOver)
16
Calculate the radius of the Bohr orbit in the ground
3. (a ) Explain on the following : (i) Average velocity,
state and velocity of electron in the ground state
(ii) root mean square velocity, and (m) most
e= 1·6 x 10- 19 coulomb; m = 9·1 x 10-31 kg,
probable velocity of gas molecules. 5
h=6·6x w-34 J-sec; c=3x 108 m/sec
4+1 ( b ) Determine average value of kinetic energy of
molecules of an ideal gas at 273 Kandat 373 K. What
is the kinetic energy per mole of an ideal gas at these
(c) What are shortcomings of Bohr's theory ofhydrogen
atom? 5 temperatures? K = 1· 38 x 10-23 J !K. 5
(d) What is Planck's quantum theory of radiation? (c) Explain how Newton's rings are formed. In Newton's
Explain. 5 rings experiment, the di~meters of 4th and 12th dark
ring are 0-400cm and 0·700cm, respectively. Find
2. (a ) Distinguish between properties of solids with ionic,
the diameter of the 20th dark ring. 5
covalent and metallic bonds. 5
( d) What do you understand by diffraction of light?
(b) Based on band theory and of solids, distinguish
Distinguish clearly between interference and
between conductors, semiconductors and insulators.
diffraction of light. 5
Give examples for ( i) best two metals at room
temperature with lowest resistances, (ii) direct and 4. (a) What is lattice translation operator? Draw the unit cell
indirect band gap semiconductors, and (m) two
figure and indicate a , b , c, a, ~. y and classify seven
insulators. 5
crystal systems. Also, draw the unit cell diagram of
( c ) What are superconductors? Explain. Mention the NaCl and explain its structure. 5
name of superconductor which has critical
( b ) What are Miller indices of crystalline planes?
temperature more than 90°. 5
Explain. Draw ( 100), ( 110).and (111) planes in cubic
(d) Define polarisation? Write about types of crystalline systems. 5
polarisations in solids. A parallel plate capacitor has
circular plates of radius 8 em and plate separation ( c) What is Bragg's law of X-ray diffraction ? Explain how
1 mm. The dielectric medium with relative you will find crystal structure of a cubic system using
permittivity of 4· 5 is inserted between the plates. Find powder method of X-ray diffraction. 5
the capacitance. e 0 =8·86X IQ- 12 coul 2 /nt-m 2 • 5
(d) Calculate the planar density of (fcc) Nickel in (1 00)
plane. The radius of Nickel atom is 1·245 A. 5
S'09: 3AN: AN 206 ( 1406) ( 2 ) (Continued)
S'09: 3AN:AN206(1406) ( 3 ) (Tum Over)
17
GroupB
(d) For the reaction, 2Fe3 + + 21- <:;:::::=;> 2Fe2+ +~,taking
place at 298 K, find out the equilibrium constant.
(Engineering Chemistry)
[Given that : lP (Fe3+ /Fe2 + ) = 0· 771 V;
S. (a ) Distinguish between the properties of BaC12 and lP (12 /l-) = 0·536V.· (Data provided: F= 96,500C
CC14 in terms of (i) melting point, (ii) boiling point, moi-l, R=8·314JK- 1 mol- 1 ). 5
(iii) equivalent conductance at melting point (at room
temperature), (iv) solubility in water (at room 7. (a ) What is corrosion ? Explain the cathodic protection
and galvanization methods used for prevention of the
temperature), and ( v) solubility in ether (at room
corrosion. 5
temperature). 5
( b ) Explain (i) order of a reaction, (ii) resonance,
(b) For N 2 molecule, (i) write its molecular orbital (iii) catalyst, (iv) optical density ( v) photochemical
configuration,~( ii) find out bond order, and reactions, and ( vi) full name of EDTA. 1x6
(iii) comment on its metallic character. 5
(c) How is ozone formed in the atmosphere ? What are
( c ) What are the different methods through which the causes of depletion of ozone layer? What are the
solutions can be prepared? Explain why solutions harmful effects of depletion of the ozone layer ? 5
(not true solutions) exhibit Tyndall effect. 5
(d) A compound is made up of elements A and B
(d) Explain (i) optically active'substances, (ii) Lambert crystallizing in the cubic structure. The atoms A are
located at the corners of a cube, whereas atoms B
Beer's law, (iii) activation energy, (iv) emulsion, and
are present at the centre of each face of the cube.
( v) adsorption isotherm. 5
What is the formula of the compound ?. 4
6. (a ) What are theories which have been forwarded to 8. (a) State Fagan's rule. What is its significance? 5
explain the metallic bonding. 5
(b) Write a note on ion exchange catalysis. 5
( b ) Differentiate between the primary and secondary
(c) Describe schematically the functioning of a galvanic
pollutants. 4
cell. Also, write the cell reaction for this. 5
(c) Define the following terms while illustrating one
(d) The rate constant of a second order 2A ~ Product
example for each type : (i) Optical isomerism,
is 0·05 mol- 1 dm3 min- 1 • What is the half life, if the
(ii) structural isomerism, and (iii) stereo isomerism. 6
initial concentration is 0·005 mol dm-3 . 5
S'09: 3AN: AN206(1406) ( 4 ) (Continued)
S'09: 3AN: AN 206 ( 1406) ( 5 ) (Turn Over)
18
Groupe ( vii) When an electric field, £ 0 , is applied to a

parallel plate capacitor and a dielectric
9. (A) Write true or false in respect of the following material is introduced between two plates, the
statements : 1 x 10 electric field within the dielectric is greater
than E 0 .
(i) A fiber communication has large bandwidth, the
system is capable of handling a large number of ( viii) The ionic solids have very high electrical and
thermal conductivities.
channels. Hence, found wide applications in
communication. {ix) The Maxwell-Boltzman's statistics fails to
explain the phenomena like black body
(ii) For re-construction of image from the hologram, radiation, specific heat of solids at low tempera-
a laser beam of lower wavelength {compared to tures, photoelectric effect, etc.
the wavelength of laser used during formation
(x) Amorphous solids have long range order of pe-
of hologram) is used.
riodicity of lattice.
(iii) In double refraction due to biaxial crystals, the (B) Fill-in the blanks: 2x5
ordinary ray and extraordinary rays travel with
(i) The migration of colloidal particles, under the
different speeds along each one of the axis.
electric fields, towards the electrodes is
(iv) One gram of radioactive material, having a half called ........
period of two years, is kept in store for a duration
(ii) The oxidation half reaction involves ...... of
of four years. 0·25 gm of the material remains electron(s).
unchanged.
(iii) IUPAC name of the
( v) Nuclear fusion reactions takes place at high CH3 - CH (CH3 )- CH2 -CH3 is ......
temperature because kinetic energy is high
(iv) A cell, in which an electric current is used to
enough to overcome repulsion between nuclei.
cause the' chemical change, is called ........
electrochemical cell.
( vi) The resistivity of intrinsic semiconductor
increases linearly with increase in temperature. ( v ) In paper chromatography, mobile phase is ......
'09: 3AN: AN 206 (I 406) ( 6 l ( Continued) S'09: 3AN :AN 206(1406) ( 7 J AG-2,000
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AMIE(I) STUDY CIRCLE, SECOND FLOOR, SULTAN TOWER, ROORKEE - 247667 (UTTARANCHAL) EMAIL: pcourses@hotmail.com Ph: (01332) 266328, 9412903929
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W'10: 3AN :AN 206 (1406)
ENGINEERING PHYSICS AND CHEMISTRY

Time : Three hours
Maximum Marks : 100
Answer FIVE questions, taking ANY TWO from Group A,

ANY TWO from Group B and AIL from Group C.
All parts ofa question (a, b, etc. ) should

result in Joss o/',marks.
Any missing or wrong data m;ty be assumed suitably giving

proper.f!stification.
•
Figures on the right-ht/ side margin indicatf: full m~rks.
Group A
(Engineering Physics )
1. (a ) What are Bohr's assumptions in connection with the

structure of hydrogen atom '? Explain Balmer series
of hydrogen spectra. .. . :~ 3+2
for hydrogen be
longest wavelength of the
Balmer 5
·'
(c)
...... . . '·":
Write a short n?le on the-properties o{~a, ~ and y
rays. · ~ ·· 5
(d) An electron has a speed of 500 ml s with an accuracy

of 0·005%. Calculate the uncertainty in the position
of the electron. 5
AMIE(I) STUDY CIRCLE, IInd FLOOR, SULTAN TOWER, ROORKEE - 247667 (UTTARANCHAL) EMAIL: pcourses@hotmail.com Ph: (01332) 266328, 9412903929 Web: www.amiestudycircle.com
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2. (a ) Find the relationship between lattice parameter and ( c ) State Meissner effect. Distinguish between type I and
atomic radius for monoatomic SC , BCC and FCC type n superconductor. 2+3
structures. 5
(d) Show that the torque exerted on a dipole p by a
( b ) An atomic plane in a crystal lattice makes intercept
un1·form f.1eId -+ · gtven
£ 1s · b y -+ -+ x -+
t = p £ . 5
of 6 a, 4 b and 6 c with the crystallographic axes ,
where a, b and care the dimensions of the unit cell.
GroupB
Find the Miller indices of the atomic plane. 5
(E11gineering Chemistry)
(c) Find theinterplanar distance of( 11 0) plane and (Ill)
plane of Nickel crystal. The radius of Nickel atom 5. (a) Describe Eajan's rule. Why is HgC12 colourless,
is 1·245 A. The structure of Nickel is FCC. 5 whereas Hgl 2 is red ? What is the hybridization and
geometry ofNHJ? 3 +3+2
(d) In a cubic cell, find the angle between normals to the
planes (Ill) and (1'01). 5 (b) Write the M.O. energy levels for N 2 and calculate the
bond order. 4 +2
3. ( a ) What is the difference between diffraction due to
double slit and interfe~ce pattern due to two (c) Define lattice energy and solvation energy. Write an
sources'? ~ 5 expression of the lattice energy. What is the value
of Madelung constbtt and Born expouent for sodium
( b } ln aN ewton 's ring experiment , the diameter of a dark chloride. 2 +2 +2
ring is 0·32 em when the wavelength of the
monochromatic light is 6000 A. What would be the 6. ( a ) What is rotational axis of symmetry (C n) '? How many
types of rotational axis is/ are present in NH 3 '? 2+2
.
diameter of that ring when the wavelength of light
used is 5000)..? 5
( b ) Convert the flying wedge projection into Fisher
(c) Write the 5 projection: . 3x2
f \
5 (i) OH
v
H,C '"'C ••• COOH
4. (a) State the law of·equipartition of energy. Find the
values of number of degrees of freedom for diatomic A
and polyatomic gases having y = 1-40 and 1· 3 3 , H
respectively. 2+3 (iii) NH 2
H ..... I.
( b ) Distinguish among metal , semiconductor and
conductor with the help of band theory. 5
H c71'-cooH
3
25
(c) Write the difference between Enantiomers and (d) Given . the equivalence conductances of sodium
Diastereo isomers. 2 chloride , sodium butyrate and hydrochloric acid as
( d) Why is potassium permanganate solution used as a 127, 83, and 426ohm- 1 cm2 at 25°C, respectively.
secondary standard'? What is self-indicator'? Give an Calculate th~ ~uivalence conductance of butyric acid
example. 2+2 at infinite ~"on. 4
( e ) Find the symmetry elements present in the following ( e ) Calculate thy ioni~iobility of the cation..in6molar
compounds: ( i) H20, and ( ii) C 2H 2Clz. 2 +2 solutio~'J~.' N.aCl .ar25 °C. Given its tm.rence
number1ls'~e equivalence conductance at
7. (a ) Derive the rate expression for the reaction : infinite dilution as 127. 4
A + B-+ Product and . from this , calculate the
expression of t 112 • 4+2 (f) Give the difference between lyophilic and lyophobic
solution. 3
(b) State Lambert Beer's law and give the unit of molar
extinction coefficient (in S.I. unit). 2+1 .Groupe
(c) What is the significance of activation energy'? Write (Engineering Physics)

the relation between reaction rates and temperature.
• 2+2 9. (A) Fill in the blanks: 5x2
( d) The halflife period of a substance is 50 min at a certain
(i) If a particle of mass 'm' moving with a velocity
concentration. When the concentration is reduced to
'v', the deBroglie wavelength of that particle
one half of the initial concentration t 112 becomes
is---.
25 min. Calculate the order of the reaction. 4
(ii ) Plane of vibration is - - - to the plane of
(e) What is greenhouse effect'? Give an example of
greenhouse gas. 2+1 polarization.
• I
8. (a ) Give the two half" c~ll ~ction for the following (iii ) If the number of molecules per unit volume is
reaction: 3 N au"d if each bas a moment p, then the
Zn + CuS0 4 ~ ZnS04 + Cu pol ··. ·on is equ~ t o - - -
(b) Write the Ncrnst equation for a cell reaction (for one (iv) ·1ti. principle has been used in
electron transfer) 3 statistics.
aA + bB ~ cC + dD.
( v ) The relation between half-life and disintegration
(c) Define specific conductance and give'its unit. 2+1 constant or decay constant is - - -
W'lO: 3AN:AN206 (1406) ( 4 ) (Continued) W'IO: 3AN:AN206 (1406) ( 5 , (TurnOver)
26
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S'll: 3AN: AN206(1406)

Time : Three hours
/ Maximum Marks : 100

ANY TWO from Group Band ALLfrom Group C.
All parts of a question (a, b, etc.) should

result in loss of marks.
Any missing or wrong data may be assumed sui1ably giving
Figures on the right~hand side margin indicate full marks.
Group A
1. (a) What are emission and absorption spectra and how do
you obtain the~e? Write the expressions for Lyman,
Balmer, Paschen spectral series and mention their range
of electromagnetic spectrum. 3+2
(b) In radio astronomy, hydrogen atoms are observed in
which, for .example, radiative transitions from n = 109
to n = 108 occur. What are the frequ'ency and
wavelength of the radiation emitted in this transition? 5
(c) Mention the law of radioactive decay and define
half-life of the radioactive decay. 5
(d) Write in brief on nuclear fission and fusion. 5
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2. (a) Write the basic idea behind Bohr's model of the atom. (c) What is meant by mechanical, thermal, chemical·and
State the assumptions of Bohr's model. 5 thermodynamic equilibrium ? State zeroth law of
(b) State Heisenberg uncertainty principle. Determine the thermodynamics. 5
de Broglie wavelength of a moving golf ball of mass (d) Describe p-type and n-type extrinsic semiconductors
m = 0·05 kg and velocity v = 40 m/s. 2 +3 in detail. 5
(c) What are Cty!italline and non-crystalline (amorphous)
Group B
materials? 5
(d) Iron at 20 oC is BCC 'Yith atoms of atomic radius
0· i 24 nm. Caicuiate the iattice constant,_ a, for the cube 5. (a) What are the causes of environmentai poiiution ?
edge of ~he iron unit cell. 5 Discuss the toxic effects of CO and cyanide
pollutants. What are the sources of sulphur dioxide
3. (a) Calculate the ato_mic packing factor (APF) for the BCC pollutants in air ? How are they controlled ? 6
unit.ceH, assuming the atoms to be hard spheres. 5
(b) A precipitate of 0.11 0 of calcium oxalate was obtained
(b) (i) State the principle of superposition and explain from 250 ml of a water sample. Explain the calcium
the phenomenon of interference. What do you content (in ppm). 4
mean by constructive and interference ? 3
-~) What is slit spacing required to give a separation
(c) Assign E/Z and R/S configuration of the following
molecule and write its IUPAC name. 4
of 2 em between the second and· third-order
OH
maxima for two slits if A,= 550 nm and
D == 1·50 m? 2 ~c
(c) Light of wavelength 580 nm is incident on a slit

having a width of 0· 3 mm. The viewing screen is Cl Br
2·00 m from the slit. Find the positions of the first dark
fringes and the width of the central bright fringe. 5 (d) Mention appropriate reasons for the following: 3x2
(d) Explain the meaning of spontaneous and stimulated (i) Vander Waal's forces of attractions are
emission and mention the features of these emissions. 5 responsible for the condensation of inert gases.
(ii) Chlorine is a diatomic molecule, while helium is

4. (a) What do you mean by total internal reflection ? How
a monoatomic molecule.
is this phenomenon utilized in an optical fiber? 5
5 (iii) At room temperature, HF is a liquid, whereas HCl,

(b) Write the assumption of kinetic theory of gases.
having larger molecular mass, is a gas.
S' II: 3AN: AN206( 1406) ( 2 ) (Continued) S'll: 3AN: AN206(1406) ( 3 ) (Turn Over)
29
6. (a) Explain, on the basis of molecular orbital theory, about (d) A first order reaction is 15% complete in 20 min. How
the following : 3+2 long will it take to be 60% complete ? 5
(i) Br2 molecule is not stable Group C
(ii) N 2 has stronger bond than B 2 •
9. (A) Choose the correct answer for the following: 5x2
, (b) Based on metallic bond, explain why metals are
(i) Which, one of the foUowingis not evidence for
(i) good· conductors of electricity, and (ii) malleable
' ;_- and ductile·?· · 3+2 the wave nature of matter·?
(a) The photoelectric effect
(c) What is meant by the term 'temperature coefficient of
a reaction ? How would you explain, on the basis of (b) The diffraction pattern obtained when
collision theory, the effect of temperature on the rate electrons pass through a'slit
of react.ions ? The half life for the homogeneous
gaseous reaction S0 2Cl 2 ~ S0 2 + Cl2 , which obeys (c) Electron tunneling
first order kinetics, is 8 min. How long will it take for
(d) The validity of the Heisenberg uncertainty
~ the concentration ofS0 2Cl 2 to be reduced to .l% of
principle
the initial value ? 5+5
(ii) A hoie refers to
7. (a) What are chemical cells ? Differentiate between
reversible and irreversible cells. 7 (a) a positively charged electron.
(b) Find the e.m.f. of the following at 25 °C: 7 (b) an electron that has somehow lost its charge.
Ag I Ag+ (O·OIM) llAg+ (0·1 M) I Ag (c) a microscopic defect in a solid.

(c) Give appropriate reason· why solution of sodium (d) the absence of an electron in ari otherwise
chloride is a good conduction of electricity, but filled band.
chlorine-water does not conduct electricity. 6
(iii) Polarization experiments provide evidence that
8. (a) What is meant by 'space lattice' of a crystal? Draw a light is
unit cell for space lattices of face-centred cubic. 5
(a) a longitudinal wave.
(b) Mention various air pollutants and describe the effects
of hydrogen sulphide on environment. 5 (b) a stream of particles.
(c) What are the important sources of water pollution? (c) a transverse wave.
Explain the activated sludge process of treatment of (d) some type of wave.
wastewater. 5
S' II: 3AN: AN206( 1406) ( 4 ) ( Continued ) S'l1:3AN·AN206(1406) ( 5 ) (Turn Over)
30
(iv) 1 atomic mass unit is about (iii) During electrochemical corrosion m acidic
environment,
(a) 1·66 X 10-31 kg
(b) 9·11 X 10-31 kg (a) oxygen evolution occurs.
(c) 1·66 X 10-27 kg (b) oxygen absorption occurs.
(d) 9·11 X 10-27 kg (c) hydrogen evolution takes place.
a
(v) Photons in laser beam have the same energy, (d) hydrogen absorption takes place.
wavelength, polarization direction, and phase
(iv) Which one. of the following is not a strong
because
electrolyte ?
(a) each is produced in an emission that is
stimulated by another. (a) AgN0 3
(b) ail come from the same atom. (b) NaCI
(c) the lasing material has only two quantum (c) NH4 0H
states. (d) NaOH.
(d) all photons are alike, irrespective of their
(v) The molecule that has a linear structure is
source;
(a) C02
(B) Choose the correct answer for the following : 10 x 1
(b) N02
(i) Which one of the following does not conduct
electricity ? (c) S02
(d) Si02
(a) Molten NaCl
(b) NaCl crystal (vi) Arrange 0 2
, 0;:, o;-, o;+ in order of increasing
(c) Solution ofNaCl in water bond length.
(d) Solution ofNaCl in alcohol
(vii) Man dies in the atmo_sphere of CO, because it
(ii) For the first order reaction, half life is 14 s, the
(a) dries up the blood.
time required for the initi'al concentration to
reduce to one-eighth of its value is (b) combines with 0 2 present in the body.
(a) 28 s (c) reduces the organic matter of tissues.
(b) 42 s
(d) combines with haemoglobin ofblood, thereby
(c) (14) 3 s
making the latter incapable of absorbing 0 2 •
(d) (14) 2 s
S"ll: 3AN: AN206(1406) ( 7 ) (Turn Over:
S' II: 3AN: AN206(1406) ( 6 ) ( Continued)
31
32
S'12:5AN :AN 206 (1406)

Time : Three hours
Maximum Marks : I 00
ANY TWO from Group Band ALL from Group C.
All parts of a question (a, b, etc.) should

Any missing or wrong data may be assumed suitably giving
Figures on the right-hand side margin indicate full marks.
Group A
1. (a) Find the number of waves made by a Bohr electron in
one complete revolution in its third orbit. 5
(b) An alpha particle travels at right angle to a magnetic
field of flux density ~-2 Wb/m2 with a speed 6 x 1OS m/s.
Find the force acting on it and its acceleration. 5
(c) Calculate the number of photons emitted per second

by a 100 W sodium lamp assuming that the sodium
light has 1.. = 5896 A. 5
(d) In a compton scattering, the incident photons have

A. = 3 A. Calculate the wavelength of the scattered
radiation, if they are viewed at an angle of 60° to the
direction of in~idence. 5
(Turn Over)
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2. (a) In a drop of water having radius 10- m and molecular (c) Calculate the linear atomic density along [I 00], [11 0]
dipoles are pointed in the same direction. If the dipole and [ lllJ direction in BCC iron whose lattice parameter
moment of water molecule is 6 x 10-30 C-m; calculate is 2·85A. 5
the polarization. 5
(d) What do you understand by V symmetry? Describe
(b) A magnetic material has a magnetization of3200 Aim the types of crystal symmetry with examples. 5
and flux density of 0·0045 Wb/m2 • Determine the
magnetic field and the relative permeability of the Group B
material. 5 (Engineering Chemistry)
(c) A superconducting lead has a critical temperature of 5. (a) Discuss the standard method of monitoring of NO,... 5
7·26 K at zero magnetic field at a critical field of
(b) Discuss the non-dispersive IR method for the analysis
8 x 105 Aim at 0 K. Find the critical field at 5K. 5
of CO pollutant., 5
(d) Find the fraction of electrons excited into conduction (c) Differentiate between primary and secondary pollutants.
band in Ge at 100 K, 300 K and 1200 K, if the band Name five primary pollutants and discuss any one
gap is 0·75 eV. Explain the results. 5 ofthem. 7
3. (a) Define the following: (i) Mean velocity, (ii) rrns (d) Show the relationship between CO, NO,. and HC
velocity, and (iiz} most probable velocity. 3x2 (hydrocarbons) with the help of a graph. 3
(b) Calculate the mean translational kinetic energy per 6. (a) What is the condition for metallic bonding? Discuss
molecule ofa gas at 727 °C. Given : R = 8.32 J/mole.K. 4 any three metallic properties with explanation. 5
(b) Discuss different postulates of molecular orbital theory. 5

(c) Two coherent sources of intensity ratio J3 interfere. Prove
that in the interference pattern 5 (c) Draw the molecular orbital diagram of 0 2 molecule
/max -/min
=--
z..JP and discuss its magnetic properties. 10
/max +/min 1+ fJ 7. (a) Discuss the mechanism of oxidation corrosion. 5
(d) How many order will be visible if a light of wave- (b) Differentiate between electrochemical and galvanic
length 5000 A falls on a grating of line 2620-per inch. 5 series. 5
4. (a) Draw a (111) plane and Wingez-Seitz cell. 5 (c) Discuss about sacrificial anodic protection method. 5
(b) Find the atomic packing factor ofHCP structure. 5 (d) How much rust (Fep3 ·3~0) will be formed when
100 kg of iron have completely rusted away ? 5
S'l2:5AN: AN206(1406) ( 2 ) ( Continued) ~ i'l2:5AN: AN206(1406) ( 3 ) (Turn Over)
34
35
W'12: 5 AN: AN 206 (1406)

lime : Three hours
Maximum Marks : 100
ANYTWOjrom Group Band ALL from Group C.
All parts of a question (a, b, etc. ) should be
answered at one place.
Answer should be brief and to-the-point and be supple-
mented with neat sketches. Unnecessary long answer may
Any missing or wrong data may be assumed suitably
giving proper justification.
Figures on the right-hand side margin indicate full marks
Group A
1. (a) Describe the Rutherford atomic model. What were

its outcomes ? Describe its applications. 10
(b) Describethelawsofradioactivityanditsdecay. 10
2. (a) Explain the concept of wave function? Explain its

physical meaning. Explain de-Broglie hypothesis.
What do you understand by expectation value ? 10
(b) What type of forces exists in solids? Explain with

neat diagrams. What do you understand by iso-
tropic and anisotropic behaviour of solids? 10
(Turn Over)
36
37
S'13: 5 AN: AN 206 (1406)

Time : Three hours
Maximum Marks : I 00
ANYTWOjrom Group Band ALL from Group C.
All parts of a question ( a, b, etc. ) should be
Answer should be brief and to-the-point and be supple-
mented with neat sketches. Unnecessary long answer may
Figures on the right-hand side margin indicate full marks
Group A
1. (a) Explain the formation of a stable bond using the

potential energy vs. interatomic distance curve. 5
(b) Write an expression for the Fermi-Dirac distribution

function and discuss its behaviour with change in
temperature. 5
(c) Describe three categories of dielectrics with

examples. 5
(d) Compare properties of ferromagnetic and ferro-

electric materials. 5
38
2. (a) According to Bohr's theory, the potential energy of

electron in a hydrogen atom is negative and larger (d) Explain what do you mean by polarisation oflight.
in magnitude than kinetic energy. Explain its signi- Distinguish between polarised light and unpolarised
ficance. 5 light 5
(b) Explain how the experiment on o.-particle scattering . GroupB
led to the concept of the nuclear model of the
atom. 5
(c) Write different diffraction methods of determining
5. (a) What are the causes of environmental pollution?
Discuss the toxic effects of CO and cyanide poJlu-
crystal structure and describe any one method in
tants. What are sources of sulphur dioxide poilu-
detail. 5 tants in air? How are they controlled ? 6
F..l\ -~ ...:1 ....... -..: .......! - ....... £'- ....... -.: ........... .C-.----
1""\..-.......... _.:L,... +L-. __ ....._ ___
I._U} UtJ~I,.;llUt;; lilt; HCllUlt;; C:UlU Ull~lll Ul VC:UlUU::S l.Ull,;t::S
(b) A precipitate of 0.110 of calcium oxalate was
existing between the atoms of a crystal. 5 obtained from 250 ml of a water sample. Express
the calcium content (in ppm). 4
3. (a) Write a note on the kinetic interpretation of
temperature. 5
(c) Assign E/Z and RIS configuration ofthe following
(b) Distinguish between isothermal and adiabatic
molecule and write its IUPAC name. 4
processes. Show that the adiabatic is steeper than OH
the isothermal at the point where they cross. 5 ~ I H
~~
H,C)
CH(CH,),
(c) What is a nuclear reactor ? What do you under-
stand by criticality of a nuclear reactor? 5 CI Br
(d) Give suitable reasons for the following : 3x2
(d) Explain the basic principle ofholography. 5
4. (a) What are extrinsic semiconductors ? At high (i) H 20 is a liquid at room temperature while
temperature, an extrinsic semiconductor behaves H 2S is a gas.
like an intrinsic semiconductor- why? 5
(ii) Chlorine is a diatomic molecule while helium
(b) What are HTSC oxides? What are their future is a monoatomic molecule.
prospects from application of superconductivity
viewpoint? 5 (iii) At room temperature HF is a liquid, whereas
HCl, having a larger molecular mass, is a gas.
(c) Distinguish between interference and diffraction.
Explain why gratings with large number oflines are 6. (a) On the basis ofmolecular orbital theory, explain the
preferred. 5 following: 3+2
{i) Br2 molecule is not stable
39
(ii) N 2 has stronger bond than B 2 • potential and standard electrode potential. A cell
is formed by clipping Zn rod in 0.0 l M Zn2+ solution
(b) Basedonmetallicbond,explainwhymetalsare _3 +2 and Ni-rod in 0.5 M Nil+ solution. The standard
electrode potentialsofZn andNiare-0.76 V and
(i) good conductors of electricity. - 0.25 V, respectively. Write the cell representa-
tion, cell reaction and calculate the emf of the cell.
(ii) malleable and ductile. 5+5
(b) State Ostwald's dilution law for a weak electrolytic
(c) What is meant by the teim 'temperature coefficient solution. Derive the mathematical expression for a
of a reaction' ? How would you explain, on the dilute solution and mention its limitations. 6
basis of collision theory, the effect of temperature
on the rates of reactions ? The half life for the (c) Label the following configurations in terms ofE/Z : 4
homogeneous gaseous reaction S0 2Cl2 -7 S02 +
COOH
Cl2, which obeys first order kinetics, is 8.0 min.
How long wilL it take for the concentration of
(i) ~ /H
S02Cl2 to be reduced to 1% of the initial value? + ~CH 3
5 5
HD~
7. (a) Drawstereodiagramsofthefollowing: 3+3
(z) (S) -2- methylbutanoic acid (ii) ~
(il) (R) -2- (ethoxycarbonyl) propanoic acid 0
(b) What is corrosion of metals ? Explain how corro-

sion can be controlled by sacrificial anode and (iil)
impressed emf methods. 3+3
(c) Iron (ll) oxide, FeO, crystal has a cubic structure
and each edge of the unit cell is 5.0 A. Taking
(iv) ~
<X:,.B.r
density of the oxide as 4.0 g.cm-3·, calculate the
number of Fe 2 + and 0 2- ions present in each unit
cell. 4
Group C
(d) Distinguish between covalent and electro valent
bond. Explain the structure ofSF6 molecule. 4 9. (A) Write whether the following statements are true or
false: 5x 1
8. (a) How is electrode potential experimentally deter-
mined ? Distinguish between single electrode (z) Transition elements have higher melting
40
(C) Choose the correct answer for the following : 10 x J
points and higher densities as compared to
light metals. (i) Which one of the following does not conduct
electricity?
(ii) The charge carriers in the discharge tube at very (a) MoltenNaCl
low pressures are electrons and positive ions.
(b) NaCI crystal
(iii) If (3 2 6) are the Miller indices of a plane, the
(c) SolutionofNaC1 in water
intercepts made by the plane on three crystal-
lographic axes are (2a, 3b, c). (d) Solution ofNaCl in alcohol
(iv) Most widely used conducting materials are (ii) For the first order reaction, halflife is 14 s. The
copper and aluminium. time required for the initial concentration to
reduce to one-eighth of its value is
( v) In superconducting state, entropy increases (a) 28 s
and thermal conductivity decreases.
(b) 42s
(tl) Fill in the bianks: 5 X 1
(c) (14) 3 s
(i) The temperature, at which metal becomes (d) (14) 2 s
superconducting, is called---
(iii) During electrochemical corrosion in acidic
(ii) The nature of binding for a crystal with alter- environment,
nate and evenly spaced positive and negative
(a) oxygen evolution occurs.
lOnSlS---.
(b) oxygen absorption occurs.

(iii) In a unit cell, whose lattice constant is a, the
distance between two {hkl} planes i s - - . (c) hydrogen evolution takes place.
(d) hydrogen absorption takes place.

(iv) The lattice constant of a BCC unit cell with
atomic radius of 1.24 A i s - - - (iv) Which one of the following is not a strong
electrolyte?
( v) Ifelements with principal quantum number n >
4 were not allowed in nature, then the number (a) AgN0 3
of oossible elements would be---.
41
42
W'13: 5 AN: AN 206 {1406)

Tzme : Three hours
Maximum Marks : 100

Answer FIVE questions, taking ANYTWO.from Group A,
ANY TWO from Group B and ALL from Group C.
All parts ofa question (a, b, etc. ) should be

Answer should be briefand to-the-point and be supplemented

with neat sketches. Unnecessary long answer may result in
loss ofmarks.
Figures on the right-hand side margin indicate foil marks.
Group A
1. (a) Explain why a material should expand when heated. 5

(b) What are non-ferrous alloys? Give examples and
write their uses. 5
(c) Write the similarities and differences between ferro-
magnetic and f~oelectric materials. 5
(d) Discuss on the important categories of dieleCtrics

with examples. 5
2. (a) Describe the properties exhibited by ionic solids. 5
(b) Explain the important method suitable for the deter-

mination ofccystal structure. 5
43
(c) Find the radius of frrst orbit of electron in hydrogen (c) Explain how the nature ofbond formed between any
a~m(forhydrogenz:::: 1 andn= 1). 5 two atoms could be predicte~ with the help oftheir
electro-negativity values~ · 8
(d) Explain how are insUlating mat~ classified? 5
6. (a) Ex~ how carbon dioxide is reSponsible for enhanced
3. (a) Describe the differences between thermal expansion glo wanning. . 5
and thennal conductivity. 5
(b) List the chemicals depleting ozone layer. Discuss
(b) What are the properties exhibited by covalent them briefly. 5
solids? Discuss in brief. 5
(c) Describe the important characteristics of colloidal
(c) What is electronic conductivity ? Discuss the factors solution. 5
responsible for reducing its value. 5 f.J\
\UJ Justify why is a reaction speeded up in presence ofa
(d) Describe about the behaviour of cohesive force and catalyst? 5
repulsive force. 5
7. (a) What are the factors influencillg corrosion? Explain. 6
4. (a) Give a clear explanation about intrinsic and extrinsic (b) State Ostwald's dilution law for a weak electrolytic
semiconductors. 5 solution. Derive the mathematical expression for a
dilute solution and write its limitations. 6
(b) Write the differences between polarised light and
unpolarised light 5 (c) Explain the mechanism ofelectrochemical corrosion
based on hydrogen evolution ~d by oxygen absorp-
(c) Justify why certain materials are magnetic while tion. 8
others are not. 5
8. (a) What is electroplating ? Write the merits and de-
(d) Mention about interference and di:ffi:action. Why are merits ofthe process of electrQplating. 6
gratings with large number oflines preferred? 5
(b) Write the effects of increase of temperature on the
Group B adsorption ofa gas on a solid surface. 7
(Engineering Chemistry) (c)" Explain the kinetics ofsaponification ofethyl acetate
by.an alkali. 7
5. (a) Distinguish between the properties of ionic bonds and
covaient bonds. 6 Group C
(b) Explain the following on the basis ofmolecular orbital 9. (A) Identify the correct answer for the following: 5x1
theory : (i) N2 bas stronger bond than B2 ; and (ii) Br2 (l) Which one ofthe following Cl)'Sfal structure charac-
molecule is not stable. 3 +3 terises the ferritic stainless steel ?
(a) Bodycentredcubic
44
(b) Facecentredcubic (B) Mention whether the following sentences are true orfalse:
5 X 1
(c) Simplehexagonal · (z) The phenomenon of emf development between two
(d) Cubic ·different metals placed in contact is known as
•Seeback effect'.
(it) The nature ofatomic bond folllld in diamond is
(i1) Cold-worked components are generally subjected to
(a) covalent 'hardening'.
(b) ionic.
(c) metallic. (iiz) The highest perc~ntage of chromium that can be
added to steel is '50'.
(d) hydrogen bond.
(iv) The mass number of an atom is 40 and its atomic
(iizj According to Pauli's exdusion principle, the maximum number is 20. The number of electrons present in that
number ofelectrons with a principal quantum number atom is '40'.
is
(v) The presence of nucleus in an atom was discovered
(a) 2n by 'Rutherford'.
(C) Answer /Choose the correct answer for the folloWing : I0 x 1
(b) n 2
(z) The gas eliminated during decarbonylation of acetic
(c) 2n3 acid is
(d) 2n2 (a) hydrogen.
(b) carbon dioxide.
(iv) Which one of the following metals has face centred
cubic structure ? (c) methane
(a) Magnesium (d) carbon monoxide.
(b) Gold (il) Match the following :
(c) Cadmium .
. (d) Zinc (A) Propanone (1) CHO
(B). Butarial (2) C=O
(a) Ferrite
(C) Ethanol . (3) COOH
(b) Austenite (D) Acetic acid (4) OH
(c} Cementite (a) A-4, B~l, C-3, :b-2
(d) Pearlite (b) A-2, B-4, C-1. D:-3
45
46
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(iii) Conductivity of a solution is directly

(d) 03 ( vi) Which of the following produces another air

(a ) supercooled liquids (a) HCl

( b ) isotropic (b) S02

ENGINEERING PHYSICS AND CHEMIS'IRY

Time : Three hours

Maximum Marks : 100

Answer FIVE questions, taking ANY 1WO from Group A,

AD parts of a question (a, b, etc. ) should

Answer should be brief and to-the-point and be supplemented

Any missing or wrong data may be assumed suitably giving

Figures on the right-hand side margin indicate full marks.

1. (a) What is Rutherford's nuclear atomic model? Explain.

(b) What are the assumptions of Bohr's theory

Groupe ( vii) When an electric field, £ 0 , is applied to a

W'10: 3AN :AN 206 (1406)

ENGINEERING PHYSICS AND CHEMISTRY

Answer FIVE questions, taking ANY TWO from Group A,

All parts ofa question (a, b, etc. ) should

Any missing or wrong data m;ty be assumed suitably giving

1. (a ) What are Bohr's assumptions in connection with the

(d) An electron has a speed of 500 ml s with an accuracy

(c) What is the significance of activation energy'? Write (Engineering Physics)

W'lO: 3AN:AN206 (1406) ( 4 ) (Continued) W'IO: 3AN:AN206 (1406) ( 5 , (TurnOver)

S'll: 3AN: AN206(1406)

ENGINEERING PHYSICS AND CHEMISTRY

/ Maximum Marks : 100

All parts of a question (a, b, etc.) should

(c) Light of wavelength 580 nm is incident on a slit

(ii) Chlorine is a diatomic molecule, while helium is

5 (iii) At room temperature, HF is a liquid, whereas HCl,

Ag I Ag+ (O·OIM) llAg+ (0·1 M) I Ag (c) a microscopic defect in a solid.

S' II: 3AN: AN206( 1406) ( 4 ) ( Continued ) S'l1:3AN·AN206(1406) ( 5 ) (Turn Over)

(b) ail come from the same atom. (b) NaCI

S'12:5AN :AN 206 (1406)

ENGINEERING PHYSICS AND CHEMISTRY

All parts of a question (a, b, etc.) should

(c) Calculate the number of photons emitted per second

(d) In a compton scattering, the incident photons have

(b) Discuss different postulates of molecular orbital theory. 5

S'l2:5AN: AN206(1406) ( 2 ) ( Continued) ~ i'l2:5AN: AN206(1406) ( 3 ) (Turn Over)

W'12: 5 AN: AN 206 (1406)

1. (a) Describe the Rutherford atomic model. What were

2. (a) Explain the concept of wave function? Explain its

(b) What type of forces exists in solids? Explain with

S'13: 5 AN: AN 206 (1406)

1. (a) Explain the formation of a stable bond using the

(b) Write an expression for the Fermi-Dirac distribution

(c) Describe three categories of dielectrics with

(d) Compare properties of ferromagnetic and ferro-

2. (a) According to Bohr's theory, the potential energy of

{i) Br2 molecule is not stable

(b) What is corrosion of metals ? Explain how corro-

(b) oxygen absorption occurs.

(d) hydrogen absorption takes place.

W'13: 5 AN: AN 206 {1406)

ENGINEERING PHYSICS AND CHEMISTRY

Maximum Marks : 100

All parts ofa question (a, b, etc. ) should be

Answer should be briefand to-the-point and be supplemented

1. (a) Explain why a material should expand when heated. 5

(d) Discuss on the important categories of dieleCtrics

(b) Explain the important method suitable for the deter-