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This article is about dispersion of waves in optics. For persion is the change in the angle of refraction of differ-
other forms of dispersion, see Dispersion (disambigua- ent colors of light,[2] as seen in the spectrum produced by
tion). a dispersive prism and in chromatic aberration of lenses.
In optics, dispersion is the phenomenon in which the Design of compound achromatic lenses, in which chro-
matic aberration is largely cancelled, uses a quantifica-
tion of a glass’s dispersion given by its Abbe number V,
where lower Abbe numbers correspond to greater dis-
persion over the visible spectrum. In some applications
such as telecommunications, the absolute phase of a wave
is often not important but only the propagation of wave
packets or “pulses"; in that case one is interested only
in variations of group velocity with frequency, so-called
group-velocity dispersion (GVD).
1
2 4 GROUP AND PHASE VELOCITY
3 Material dispersion in optics with respect to the wave’s wavelength n = n(λ). The wave-
length dependence of a material’s refractive index is usu-
ally quantified by its Abbe number or its coefficients in an
empirical formula such as the Cauchy or Sellmeier equa-
tions.
Because of the Kramers–Kronig relations, the wavelength
dependence of the real part of the refractive index is re-
lated to the material absorption, described by the imagi-
nary part of the refractive index (also called the extinction
coefficient). In particular, for non-magnetic materials (μ
= μ0 ), the susceptibility χ that appears in the Kramers–
Kronig relations is the electric susceptibility χₑ = n2 − 1.
The most commonly seen consequence of dispersion in
optics is the separation of white light into a color spec-
trum by a prism. From Snell’s law it can be seen that the
angle of refraction of light in a prism depends on the re-
fractive index of the prism material. Since that refractive
index varies with wavelength, it follows that the angle that
The variation of refractive index vs. vacuum wavelength for var- the light is refracted by will also vary with wavelength,
ious glasses. The wavelengths of visible light are shaded in red. causing an angular separation of the colors known as an-
gular dispersion.
For visible light, refraction indices n of most transpar-
ent materials (e.g., air, glasses) decrease with increasing
wavelength λ:
dn
< 0.
dλ
In this case, the medium is said to have normal disper-
sion. Whereas, if the index increases with increasing
Influences of selected glass component additions on the mean dis- wavelength (which is typically the case for X-rays), the
persion of a specific base glass (nF valid for λ = 486 nm (blue),
medium is said to have anomalous dispersion.
nC valid for λ = 656 nm (red))[3]
At the interface of such a material with air or vacuum
Material dispersion can be a desirable or undesirable (index of ~1), Snell’s law predicts that light incident at an
effect in optical applications. The dispersion of light angle θ to the normal will be refracted at an angle arc-
by glass prisms is used to construct spectrometers and sin(sin θ/n). Thus, blue light, with a higher refractive in-
spectroradiometers. Holographic gratings are also used, dex, will be bent more strongly than red light, resulting in
as they allow more accurate discrimination of wave- the well-known rainbow pattern.
lengths. However, in lenses, dispersion causes chromatic
aberration, an undesired effect that may degrade images
in microscopes, telescopes, and photographic objectives. 4 Group and phase velocity
The phase velocity, v, of a wave in a given uniform
medium is given by Another consequence of dispersion manifests itself as a
temporal effect. The formula v = c/n calculates the phase
velocity of a wave; this is the velocity at which the phase of
c any one frequency component of the wave will propagate.
v=
n This is not the same as the group velocity of the wave, that
is the rate at which changes in amplitude (known as the
where c is the speed of light in a vacuum and n is the envelope of the wave) will propagate. For a homogeneous
refractive index of the medium. medium, the group velocity v is related to the phase ve-
In general, the refractive index is some function of the locity v by (here λ is the wavelength in vacuum, not in the
frequency f of the light, thus n = n(f), or alternatively, medium):
3
λ d2 n
D=− .
c dλ2 5 Dispersion in waveguides
If D is less than zero, the medium is said to have positive
dispersion. If D is greater than zero, the medium has neg- Waveguides are highly dispersive due to their geometry
ative dispersion. If a light pulse is propagated through (rather than just to their material composition). Optical
a normally dispersive medium, the result is the higher fibers are a sort of waveguide for optical frequencies
frequency components travel slower than the lower fre- (light) widely used in modern telecommunications sys-
quency components. The pulse therefore becomes posi- tems. The rate at which data can be transported on a sin-
tively chirped, or up-chirped, increasing in frequency with gle fiber is limited by pulse broadening due to chromatic
time. Conversely, if a pulse travels through an anoma- dispersion among other phenomena.
lously dispersive medium, high frequency components In general, for a waveguide mode with an angular fre-
travel faster than the lower ones, and the pulse becomes quency ω(β) at a propagation constant β (so that the elec-
negatively chirped, or down-chirped, decreasing in fre- tromagnetic fields in the propagation direction z oscillate
quency with time. proportional to ei(βz−ωt) ), the group-velocity dispersion pa-
The result of GVD, whether negative or positive, is ul- rameter D is defined as:[7]
timately temporal spreading of the pulse. This makes
dispersion management extremely important in optical
communications systems based on optical fiber, since if 2πc d2 β 2πc dvg
D=− 2 = 2 2
dispersion is too high, a group of pulses representing a λ dω 2 vg λ dω
bit-stream will spread in time and merge, rendering the
bit-stream unintelligible. This limits the length of fiber where λ = 2πc/ω is the vacuum wavelength and v =
that a signal can be sent down without regeneration. One dω/dβ is the group velocity. This formula generalizes the
possible answer to this problem is to send signals down one in the previous section for homogeneous media, and
4 9 DISPERSION OF PULSAR EMISSIONS
∫
7 Dispersion in gemology d
DM = ne dl
0
In the technical terminology of gemology, dispersion is
with units of parsecs per cubic centimetre (1 pc/cm3 =
the difference in the refractive index of a material at the
30.857 × 1021 m−2 ).[12]
B and G (686.7 nm and 430.8 nm) or C and F (656.3
nm and 486.1 nm) Fraunhofer wavelengths, and is meant Typically for astronomical observations, this delay can-
to express the degree to which a prism cut from the not be measured directly, since the emission time is un-
gemstone demonstrates “fire.” Fire is a colloquial term known. What can be measured is the difference in arrival
used by gemologists to describe a gemstone’s dispersive times at two different frequencies. The delay Δt between
nature or lack thereof. Dispersion is a material property. a high frequency ν ᵢ and a low frequency ν ₒ component
The amount of fire demonstrated by a given gemstone is of a pulse will be
a function the gemstone’s facet angles, the polish quality,
the lighting environment, the material’s refractive index,
( )
the saturation of color, and the orientation of the viewer 1 1
relative to the gemstone.[9][10] ∆t = kDM × DM × − 2
νlo2 νhi
5
Rewriting the above equation in terms of Δt allows one [8] Chromatic Dispersion, Encyclopedia of Laser Physics and
to determine the DM by measuring pulse arrival times at Technology (Wiley, 2008).
multiple frequencies. This in turn can be used to study
[9] Schumann, Walter (2009). Gemstones of the World:
the interstellar medium, as well as allow for observations Newly Revised & Expanded Fourth Edition. Sterling Pub-
of pulsars at different frequencies to be combined. lishing Company, Inc. pp. 41–2. ISBN 978-1-4027-
6829-3. Retrieved 31 December 2011.
• Green–Kubo relations
• Group delay 12 External links
• Intramodal dispersion • Dispersive Wiki – discussing the mathematical as-
pects of dispersion.
• Kramers–Kronig relations
• Dispersion – Encyclopedia of Laser Physics and
• Linear response function
Technology
• Multiple-prism dispersion theory
• Animations demonstrating optical dispersion by
• Sellmeier equation QED
11 References
[1] Born, Max; Wolf, Emil (October 1999). Principles of Op-
tics. Cambridge: Cambridge University Press. pp. 14–24.
ISBN 0-521-64222-1.
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