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Hazardous Area Classification

Training Seminar
Instructor: Allan Bozek, P.Eng MBA
EngWorks Inc., Calgary, Alberta

www.EngWorks.ca
www.EngWorks.ca

Calgary - October 10, 2006


Edmonton – October 11, 2006

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 1
Premise for the Course
„ An area classification as designated by a Professional
Engineer is the area classification
„ Done under professional seal
Currently no definition of “competence”
www.EngWorks.ca
„

„
www.EngWorks.ca
The classification of facilities have become more
complex
„ Need for consistency in design approach and in
documentation
„ Decision to communicate these requirements to
industry via a set of Engineering Guidelines in the
appendix of the 2006 “Code for Electrical Installations
at Oil and Gas Facilities”

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 2
Learning Objectives
1. Provide you with the ability to analyze an oil, gas or chemical
processing facility and establish the degree and the extent of
a classified area.
2. Provide you with an overview of the various Codes and
www.EngWorks.ca
Recommended www.EngWorks.ca
Practices developed for area classification
3. Provide guidelines on how to properly document your analysis
and communicate it to third parties; who will rely on this
information for subsequent design, installation and operating
activities.
4. Provide you with an introduction to some of the various
options available to you for classifying a facility and when
they are appropriate for use.

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 3
Course Parameters
1. Will focus on Class I Hazardous Areas –
Class II and Class III areas are not covered

www.EngWorks.ca
2. Focus willwww.EngWorks.ca
be on the Zone method of area
classification
• Division method will be referenced where
differences exist

3. Primary focus will be on North American


Design and Construction Standards as
established by the CEC
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 4
Definition of a Hazardous
Location
“Hazardous location means premises,
buildings, or parts thereof in which
there exists the
www.EngWorks.cahazard
www.EngWorks.ca of fire or
explosion due to…”
„ Flammable gases and liquids
„ Combustible dust or flyings
„ Ignitable fibres and materials
CEC Section 0
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 5
Background History
„ Concept of a “Hazardous Location” was
first developed in the coal mining
www.EngWorks.ca
industry www.EngWorks.ca
„ Methane and coal dust the primary hazards
„ Light and power essential to mining
operations

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 6
The Davy Safety Lamp

www.EngWorks.ca
www.EngWorks.ca

Sir Humphrey Davy

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 7
Background History
„ Development of the motor led to the
introduction of ventilation into coal
mines reducing the hazard
„
www.EngWorks.ca
www.EngWorks.ca
Motors that were totally enclosed
contained the explosion
„ Led to the development of the XP
enclosure
„ Concept of intrinsic safety developed
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 8
Background History

„ 1920 “Extra Hazardous Location” added to the NEC


„ UL labs were certifying equipment for use in hazardous locations
Class I and Class II designations added in 1931
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„

„ Class I Groupwww.EngWorks.ca
designations added in 1935
„ Concept of Division 1 and Division 2 added in 1947
„ Temperature code classification added in 1971
„ Zone Area classification option added in 1996

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 9
Purpose of an Area Classification
Historical
“Identify the possibility of an explosive atmosphere
being present and influencing the design of the plant
or facility to minimize the risk of ignition”

www.EngWorks.ca
www.EngWorks.ca
Based on normal operating conditions - does not deal
with the potential of catastrophic failures

Primarily used for establishing the type of electrical


equipment and wiring methods that can be used
within a hazardous area

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 10
Purpose of an Area Classification
Present and Future
„ ATEX Directive
„ Essential Health and Safety requirements with
respect to:
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„ Potential ignition sources from equipment in hazardous

locations
www.EngWorks.ca
„ Applies to non-electrical equipment
„ Alberta OH&S Requirements
„ Hazardous area classification is used as a basis for
implementation of the OH&S code
„ Regulates the work activities performed within a
classified location

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 11
What is Impacted by a Hazardous
Area Classification?
Cost of Ownership
„ Materials
„
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Overall installation Cost is 50% greater for Division 1
www.EngWorks.ca
locations when compared to Division 2
„ Cost difference is less between Zone 1 and Zone 2
„ Installation
„ Higher standard of care required for Zone 1 areas
„ Inspection requirements are greater
„ Maintenance
„ Ongoing maintenance costs are greater for Zone 1 areas
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 12
Safety
„ Defines the risk associated with the
performance of activities within an area

„
www.EngWorks.ca
www.EngWorks.ca
Defines (by code) the standard of care
required for installing, operating and
maintaining equipment within an area

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 13
Operations
„ Hot Work Permitting Requirements
„ Provides a basis for Restricted access

„
„
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Special procedures
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Requirement for sniffing the area for gas before performing
basic tasks
„ Shutdown of equipment components before inspection or
repair

All this may have an impact on the on-line performance


of a facility

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 14
Defining the Hazard
www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 15
The Fire Triangle

For an explosion or
www.EngWorks.ca

I gn
fire to occur,www.EngWorks.ca
all

itio
el
three elements of

nS
Fu

ou
the fire triangle

rce
must be present
Oxygen

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 16
Probability of Events
Full House 1 in 500
Royal Flush 1 in 650,000
www.EngWorks.ca
Lotto 649 Win
www.EngWorks.ca
1 in 13,984,000
Dying 15 minutes after you bought your 1 in 14,000,000
649 ticket
Probability of an explosion from 1 gallon 1 in 59,000,000
of hydrocarbon
Probability of a simultaneous failure of 1 in 64,000,000
both process and electrical equipment
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 17
Relative risk of explosion within a
process area
100000

Tons of Hydrocarbon Release


10000

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1000

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100

10

1.0

0.1

100%
1.0%
0.01%

0.1%

10%

% Probability of Explosion
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 18
Probability of a Component Leak
(Source API 4615)

Minor Major
Leaks Leaks
Components 10 to 9999 >10,0000
Facility Type Screened No Leaks ppmv ppmv

www.EngWorks.ca
Light Crudewww.EngWorks.ca 48652 97.90% 1.11% 0.90%

Heavy Crude 13756 99.54% 0.43% 0.00%

Gas Production 40178 96.23% 2.15% 1.61%

Gas Plant 57126 96.28% 1.73% 1.97%


Offshore
Platform 45694 98.60% 0.81% 0.77%

Totals 205397 97.41% 1.39% 1.18%


Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 19
Ignition Sources of Major Fires
Source: Factory Mutual Engineering Corp.

Source Percent of Accidents


Electrical 23
Smoking
Friction
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www.EngWorks.ca
10
18

Overheated Materials 8
Hot Surfaces 7
Burner Flames 7
Cutting, Welding, Mech. Sparks 6
Static Sparks 1
All Other 20
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 20
Rew and Spencer Model
Category Examples of Ignition Sources Ignition
(Strength of Potential
Source)

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Pilot Lights, Fired Heaters,Flares
Certain p=1
www.EngWorks.ca
Hot Work, Electrical Faults,
Strong Smoking p > 0.5
Vehicles, Substations, Unclassified
Medium electrical equipment, Engines, Hot 0.5 > p > 0.05
surfaces
Office Equipment, Electrical
Weak Appliances, Mechanical Sparks, p < 0.05
Static electricity
Intrinsically safe equipment,
Negligible Radio Frequency Sources p=0
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 21
Hazardous Area Classification
Risk Assessment
„ Requires an understanding of process,
mechanical and electrical engineering
concepts

„
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www.EngWorks.ca
Requires an understanding of the various
codes and practices and knowing which one
is most suitable for a given situation

„ Must be carried out before the choice of


appropriately certified equipment is made

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 22
Hazardous Area Classification
Risk Assessment
„ Subjective in nature and will be influenced by:
„ Standards and practices within an operating
company
„ www.EngWorks.ca
www.EngWorks.ca
Practices that vary between upstream, downstream
and offshore facilities
„ Size and complexity of a facility
„ Remote, unmanned or inaccessible facilities
„ Cold weather facilities
„ Operations Experience

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 23
Probability that an Explosive
Atmosphere will exist depends on:
„ Flammable Material Present
„ Source of Release

www.EngWorks.ca
„ Gradewww.EngWorks.ca
of Release
„ Continuous (>1000 hrs per year)
„ Primary (10-1000 hrs per year)
„ Secondary (1-10 hrs per year)
„ Rate of Release
„ Degree of Ventilation
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 24
Extent of a Hazardous Area
Classification depends on:
„ Properties of the flammable material
„ Concentration
„ Volatility
„

„
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Liquid temperature
Density
www.EngWorks.ca

„ Release rate
„ Geometry of the Source of Release
„ Release velocity
„ Ventilation
„ Climatic conditions
„ Topography
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 25
“Group Responsible” Concept

“final determinations of the classifications


should involve coordinated efforts between
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www.EngWorks.ca
process engineers, facility design engineers,
fire and safety specialists, instrument and
electrical engineers”

“should also include operations and


maintenance personnel”
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 26
Codes, Standards and
Recommended Practices
www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 27
Canadian Electrical Code
CSA C22.1 Part 1

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 28
Canadian Electrical Code
„ Sets the minimum standards for
electrical installations in hazardous
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areas www.EngWorks.ca
„ All or portions of the code may be
mandated by law by the Authority having
Jurisdiction

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 29
CSA C22.1 (CEC)
„ Section 18 deals with Hazardous Locations
classified using the Zone Method
„ Zone Method of Classification is the required

„ www.EngWorks.ca
method for new installations
www.EngWorks.ca
Appendix B incorporates an extensive commentary
on Section 18 – well worth reading

„ Appendix J refers to locations where the


Division method of classification is used
„ Division method may be employed for existing
installations at the discretion of the Owner/User

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 30
CSA C22.1 (CEC)
CEC Section 20 provides guidance on area
classification for:
„ Commercial Garages
www.EngWorks.ca
www.EngWorks.ca
„ Aircraft Hangers

„ Motor Fuel Dispensing Facilities

„ Bulk Storage Plants

„ Paint Application Facilities

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 31
CSA C22.1 (CEC Section 19)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 32
CSA C22.1 (CEC Section 19)
„ Section 19 provides guidelines for
upstream oil and gas and drilling facilities
Does not apply to
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„
www.EngWorks.ca
„ Petroleum refineries

„ Petrochemical facilities
„ Gas distribution systems operated by a Utility
„ Fuel supply systems for equipment
Deleted from 2006 O&G Code

„ Not Mandated in all jurisdictions

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 33
CSA C22.1 (CEC Section 19)
„ Rule 19-100 (1)
„ Classifications of hazardous locations
established and documented by a
www.EngWorks.ca
www.EngWorks.ca
professional engineer under the engineer’s
seal and signature shall be the area
classification
„ Appendix D19
„ Engineering Guidelines for Determining
Area Classification
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 34
CEC Standata

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 35
CEC Standata
„ Code clarifications and updates
between formal code book updates
„ www.EngWorks.ca
Specific references to Section 18 and 19
www.EngWorks.ca
„ Available online at:
„ www.municipalaffairs.gov.ab.ca/mahome/ss/safety/electrical.cfm
„ On-line e-mail subscription is available

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 36
Alberta OHSA Requirements

www.EngWorks.ca
www.EngWorks.ca

http://www.hre.gov.ab.ca/documents/WHS/WHS-PUB_OHSC-1.pdf
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 37
Alberta OH&S Requirements
Part 10 Fire and Explosion Hazards
„ Section 162 – “Employers must insure that
flammable and combustible substances in the
workplace do not ignite”
„
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“No workerwww.EngWorks.ca
may enter an area where the
atmosphere LEL exceeds 20%”
„ Regulates placement of IC engines, fired
heaters and other equipment in hazardous
locations
„ Requirements for static control and hot work
permitting requirements

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 38
API RP 500 & RP 505

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 39
API RP 500
„ API 500 refers to Division Classified area as
defined in Article 500 of the NEC
Issued in 1955
„

„
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www.EngWorks.ca
Designed for petroleum refineries
„ Companion documents issued in 1966
„ RP500B – Production Facilities
„ RP500C – Gas Pipeline Transportation Facilities
„ Three documents recombined in 1991

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 40
API RP 505
„ API 505 refers to Zone Classified areas
as defined in Article 505 of the NEC
„ www.EngWorks.ca
Issued forwww.EngWorks.ca
general use in 1997
„ Incorporates several appendices not found
in RP 505
„ Current bases for CEC Section 18
„ Zone system adopted to improve safety,
reliability, maintainability and uniformity
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 41
API RP 500 & RP 505
„ Applicable to:
„ Refineries
„
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Drilling and production facilities
www.EngWorks.ca
„ Offshore drilling and production facilities
„ Pipeline facilities

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 42
API RP 500 & RP 505
„ Prescriptive in nature
„ if this is the situation – this is how you should classify the
area.
Does not attempt to describe the properties of
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„
flammable materials
www.EngWorks.ca
„ Makes reference to NFPA 325
„ Concepts are referenced from a variety of North
American and International publications
„ Incorporates more figures and diagrams than all
other API documents
„ The extent of the zones indicated on the figures are
based on experience

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 43
RP 505 Figure 20

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 44
RP 505 Table of Contents
1. Scope
2. References
3.
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Definitions
www.EngWorks.ca
4. Basic Conditions for a Fire or Explosion
5. Flammable and Combustible Liquids, Gases
and Vapors
6. Classification Criteria
7. Extent of a Classified Location
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 45
RP 505 Table of Contents
8. Recommendations for Common Applications
9. Recommendations for Petroleum Refineries
10. Recommendations for Drilling Rigs and Production
www.EngWorks.ca
Platforms www.EngWorks.ca
11. Recommendations for Offshore Drilling Platforms
12. Recommendations for Offshore Production
Platforms
13. Recommendations for Pipeline and Transportation
Facilities

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 46
API 505 Appendices
A. Sample Calculations to achieve adequate
ventilation by natural
B. Calculation of Minimum Air introduction to
www.EngWorks.ca
www.EngWorks.ca
achieve Adequate Ventilation using Fugitive
Emissions
C. Preferred Symbols
D. Alternative method for Area Classification
E. Procedure for classifying areas
F. Alternative Ventilation Criteria
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 47
NFPA 497

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 48
NFPA 497
„ Recommended Practice
„ Developed for the classification of
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chemical process plants
www.EngWorks.ca
„ The classification of chemical plants should
be less strict than for petrochemical
facilities
„ Appropriate for small to mid size chemical
plants
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 49
NFPA 497
„ Makes reference to both the Zone and Division
method of Classification
„ Incorporates an extensive list of Flammable and
www.EngWorks.ca
Combustible www.EngWorks.ca
materials c/w their physical properties
„ Size of a classified area is dependent on the volume,
pressure and flow rate within the process
„ Incorporates a list of point source diagrams to assist
the user in defining the extent of a classified area

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 50
NFPA 497 Figures

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 51
IEC 60079-10

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 52
ISA RP 12.24.01
(IEC 79-10 Mod)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 53
ISA RP 12.24.01
„ Revision of IEC 79-10 to suit North American
standards and definitions
Recommended Practice
„

„
www.EngWorks.ca
www.EngWorks.ca
All revisions to IEC 79-10 are annotated
„ Incorporates the use of gas detection as a
means of classifying indoor areas Class 1
Zone 2

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 54
IP 15
Model Code of Safe Practice

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 55
IP 15
Model Code of Safe Practice
„ Essential reading when dealing with the
really difficult situations
Describeswww.EngWorks.ca
in detail three different
„
www.EngWorks.ca
approaches to area classification
„ Introduces the concept of the risk based
approach to area classification
„ First code to use dispersion modeling as a
basis for defining the extent of classified
areas
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 56
IGE/SR/25
Hazardous Area Classification for
Natural Gas Installations

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 57
IGE/SR/25
„ UK Guideline for establishing the area
classification for:
„
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Gas transmission and distribution facilities
www.EngWorks.ca
„ Gas Storage facilities

„ Complement IEC 60079-10 by providing


a detailed procedure with examples

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 58
Codes vrs Recommended
Practices
„ CEC are mandatory requirements
„ Set the minimum standards
„ Formal Variance is required to deviate from the CEC
„
„
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OH&S rules are mandatory requirements
www.EngWorks.ca
Vary from Province to Province
„ Code for Electrical Installations at Oil and Gas
Facilities are mandatory requirements in Alberta
„ Recommended practices are not mandatory –
Guidelines only
„ RP-505
„ ISA RP 12.24.01 (IEC 79-10 Mod)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 59
NFPA 325

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 60
NFPA 325
„ Not a code, standard or recommended practice
„ Compilation of fire protection properties of

approximately 1500 materials and substances


www.EngWorks.ca
www.EngWorks.ca
„ Not originally intended for classifying facilities
„ Incomplete information

„ Referenced in RP 500, RP 505 and ISA 12.24.01 as


the reference for flammable and combustible
materials properties

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 61
IEC 60079-20

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 62
IEC 60079-20
„ Designed specifically for area
classification purposes
„
www.EngWorks.ca
Complete set of material properties
www.EngWorks.ca

„ Minor discrepancies in data between


IEC 79-20 and NFPA 325
„ Test methods are similar

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 63
WHMIS MSDS
Material Safety Data Sheets
„ Updated every three years
„ Extensive listing of chemicals at the
www.EngWorks.ca
CCOHS Website (Paid Subscription)
www.EngWorks.ca
„ http://www.ccohs.ca/
„ Completely describes the physical data
and the fire and explosion hazards for a
material

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 64
CAS Numbers
CAS No.

NFPA 497 www.EngWorks.ca


www.EngWorks.ca

CEC 2006
Appendix B

ƒ Refer to the Chemical Abstract Service Registry


Database (Subscription Service)
ƒ ~ 30M Chemical Compounds listed
ƒ No info on LFL, UFL, AIT
Calgary Oct 10, 2006
Edmonton Oct 11, 2006
or MESG
Hazardous Area Classification 65
Area Classification
www.EngWorks.ca
www.EngWorks.ca
Definitions

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 66
Class I, Zone 2, Gp. IIA, TCode T2A
Class Definition of the Hazard

Zone
www.EngWorks.ca
Probability that a hazard may exist
www.EngWorks.ca

Group Characteristics of the Hazardous


Substance
Temp Maximum Surface Temperature
Code allowable in the area
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 67
Class – Definition of the Hazard
Class I – Flammable gases

Class II – Combustible Dusts


www.EngWorks.ca
www.EngWorks.ca
Class III – Ignitable Fibres or Flyings

Non-hazardous – Areas where Class I,II or III


substances are not expected to be present in
quantities as to require special precautions

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 68
Class I, Zone 0
(CEC 2006 Definition)

Class I locations shall be further divided into three


zones based on the frequency of occurrence and
duration of an explosive gas atmosphere as
follows:

a)
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www.EngWorks.ca
Zone 0, comprising Class I locations in which explosive gas
atmospheres are present continuously or are present for long
periods;

Greater than 1000 hrs/year


(10% of the time) Table 3 RP505

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 69
Class I Zone 1
(CEC 2006 Definition)

b) Zone 1, comprising Class I locations in which:

i. Explosive gas atmospheres are likely to occur in normal

Delete from 2006 ii. www.EngWorks.ca


operation or;
www.EngWorks.ca
Explosive gas atmospheres may exist frequently because
CEC Definition
of repair or maintenance operations or because of
leakage; or
iii. The location is adjacent to a Class I, Zone 0 location, from
which explosive gas atmospheres could be communicated.

Greater than 10hrs/year and less than 1000hrs/year (0.1% – 10% of the time)
Table 3 RP 505
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 70
Class I Zone 2
(CEC 2006 Definition)

c) Zone 2, comprising Class I locations in which:

i. Explosive gas atmospheres are not likely to occur in


normal operation and, if they do occur, they will exist for
www.EngWorks.ca
a short time only; or
www.EngWorks.ca
ii. Flammable volatile liquids, flammable gases, or vapours
are handled, processed, or used, but in which liquids,
gases, or vapours are normally confined within closed
Delete from 2006 containers or closed systems from which they can escape
CEC Definition
only as a result of accidental rupture or breakdown of the
containers or systems or the abnormal operation of the
equipment by which the liquids or gases are handled,
processed, or used; or

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 71
Class I Zone 2
(CEC Definition)

c) Zone 2, comprising Class I locations in which:

Delete from 2006


iii. Explosive gas atmospheres are normally prevented by
adequate ventilation but may occur as a result of failure or
www.EngWorks.ca
CEC Definition

abnormalwww.EngWorks.ca
operation of the ventilation system; or

iv. The location is adjacent to a Class I, Zone 1 location from


which explosive gas atmospheres could be communicated,
unless such communication is prevented by adequate
positive-pressure ventilation from a source of clean air,
and effectively safeguards against ventilation failure are
provided

Less than 10hrs/year (<0.1% of the time)


Table 3 RP 505
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 72
Unclassified

Areas that are not classified Zone 0, 1 or 2

www.EngWorks.ca
www.EngWorks.ca
(Less than 1 hour per year (0.01% of the time)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 73
Area Classification Shading
Conventions for Drawings

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www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 74
Division Classification System
Division 1

www.EngWorks.ca
www.EngWorks.ca

Risk
Division 2

Not Classified

1 hr/Year 10 Hr/Year 1000 Hr/Year

Duration of Time Gas Is


Present
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 75
Zone Classification System
Zone 0

Zone 1

www.EngWorks.ca
www.EngWorks.ca

Risk
Zone 2

Not Classified

1 Hr/Year 10 Hr/Year 1000 Hr/Year

Duration of Time Gas Is


Present
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 76
Zone vrs Divisions
Source: “Adapting to the Dual Area Classification System” , Paul Babiarz, Danny Liggett, Craig
Wellman, 1996 PCIC Conference Paper

Comparison of Zones and Divisions


Classified Area Time that Hazardous Gases Estimated % of Division Estimate % of Zone Areas
are Present in Ignitable Areas in North America in Europe

www.EngWorks.ca
Concentrations
www.EngWorks.ca
Zone 0 Continuously < 2%

Division 1 Normally Present < 5%


Occasionally in Normal
Zone 1 Operations > 60%

Zone 2 Division 2 Not Normally Present > 95% < 40%

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 77
“Normal” Operation
(ISA RP 12.24.01)

Normal operations is considered the situation when


facility equipment is operating within its design
parameters. Minor releases of flammable material
may be part of normal operations. Minor releases
www.EngWorks.ca
www.EngWorks.ca
include the releases from mechanical packings on
pumps.

Failures that involve repair or shutdown (such as the


breakdown of pump seats and flange gaskets, and
spillage caused by accidents) are not considered
normal operation.

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 78
“Abnormal” Operation
(API RP 505)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 79
Abnormal Operations
„ Start-up and Shutdown
„ Plant maintenance activities
„ www.EngWorks.ca
www.EngWorks.ca
Reasonable to ignore if the activity is
expected to exist less than 1% of the
time (100hrs per year) and no
continuous or primary grade releases
expected

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 80
Group
Describes the Characteristics of the Hazardous Substance in terms of:

„ MESG – Maximum Experimental Safe Gap


The maximum gap between two parallel metal surfaces under specified test

www.EngWorks.ca
„
conditions that will prevent an explosion from propagating to an adjacent test
chamber www.EngWorks.ca
„ MIE – Minimum Ignition Current
„ The minimum energy required from a capacitive spark discharge to ignite the
gas or vapor

„ MIC – Minimum Ignition Current Ratio


„ The ratio of minimum inductive current required to ignite a gas or vapor as
compared to the minimum inductive current required to ignite methane

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 81
MESG Explained

Hot Gases are forced through


threaded connections and
fittings

www.EngWorks.ca
www.EngWorks.ca

Explosion

Sealing Compound
Gases must be cooled sufficiently to
prevent external atmosphere from being
Calgary Oct 10, 2006
Edmonton Oct 11, 2006
ignited
Hazardous Area Classification 82
MESG Test Apparatus
Westerburg Explosion Test Vessel

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 83
Group – Characteristics of the
Hazardous Substance
Group I Intended for describing atmospheres that contain
“firedamp” (Comprised mostly of methane)

Group IIA
www.EngWorks.ca
Flammable material having a MESG greater than
www.EngWorks.ca
0.90mm or a minimum MIC greater than 0.80

Group IIB Flammable material having a MESG greater than


0.50mm and less than 0.90mm or a minimum MIC
greater than 0.45 and less than 0.80

Group IIC Flammable material having a MESG greater than


0.50mm or a minimum MIC greater than 0.45

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 84
Comparison between Division and Zone
Methods for Group Classification

Division System Zone System


Group MESG MIC Group MESG MIC
www.EngWorks.ca
(mm)www.EngWorks.ca
Ratio (mm) Ratio
A Acetylene
IIC ≤0.50 ≤0.45
B ≤0.45 ≤0.40
>0.45 >0.40 >0.50 >0.45
C IIB
≤0.75 ≤0.80 ≤0.90 ≤0.80
D >0.75 >0.80 IIA >0.90 >0.80
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 85
Examples
Group Material MESG MIE MIC
(mm) (mJ) Ratio
Methane 1.12 0.28 1.0
Propane 0.97 0.28 0.97
www.EngWorks.ca
IIA www.EngWorks.ca
Butane 1.07 0.25 0.94
Heptane 0.91 0.24 0.88
Pentane 0.93 0.28 0.97
H2S 0.89 0.068 0.51
IIB
Ethylene 0.65 0.070 0.53
Hydrogen 0.28 0.019 0.25
IIC
Acetylene 0.25 0.017 0.25
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 86
MIE in Practical Terms
CH4/Air
H2/Air
10
Typical range of
spark discharge
energy from a
human body

www.EngWorks.ca
www.EngWorks.ca
Ignition Energy (mJ)

1.0

Stoichiometric
CH4/Air Mixture
0.1 0.274 mJ

Stoichiometric
Air/H2 Mixture
0.017 mJ

0
20 40 60 80
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Fuel (% Volume)
Hazardous Area Classification 87
Temperature Code
„ Used to indicate the maximum temperature
allowed within a classified location to prevent
the auto-ignition of hazardous materials
www.EngWorks.ca
www.EngWorks.ca
„ Auto-ignition temperature (AIT) is the
temperature in which a material self-ignites
without any outside source of ignition

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 88
Temperature Codes
(NEC and CEC)

T1 - 450ºC T3A - 180ºC


T2 - 300ºC T3B - 165ºC
www.EngWorks.ca
T2A - 280ºC www.EngWorks.ca
T3C - 160ºC
T2B - 260ºC T4 - 135ºC
T2C - 230ºC T4A - 120ºC
T2D - 215ºC T5 - 100ºC
T3 - 200ºC T6 - 85ºC
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 89
Auto-Ignition Temperature
“The lowest temperature of a heat surface at which,
under specified conditions, the ignition of a
flammable substance in the form of a gas or vapor
mixture with air will occur”
www.EngWorks.ca
www.EngWorks.ca
API RP 505, IEC 79-10 - Mod

“The minimum temperature required to initiate or cause


self-sustained combustion of a solid, liquid or gas
independently of a heated or heating element.”
NFPA 497

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 90
ASTM 659 Test Method for AIT

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 91
Variables that affect AIT
„ Molecular structure of the hydrocarbon
mixture
„ % composition of the vapor in air mixture
„
„
www.EngWorks.ca
Hot surfacewww.EngWorks.ca
material
Type and reactivity of other materials present
„ Rate and duration of heating
„ Environmental Conditions
„ Initial temperature
„ Atmospheric pressure

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 92
Autoignition Temperature

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 93
AIT of Selected Materials
Material Auto-Ignition Temperature (ºC)
NFPA 325 NFPA 497 IEC79-20 CEC
Hydrogen 500 520 560 429

www.EngWorks.ca
Methane 537 630 537 537
Propane
www.EngWorks.ca
450 450 470 432
Butane 287 288 372 287
Ethane 452 472 515 472
H2S 260 260 270 260
Pentane 260 243 258 260
Crude Oil - - 560 -
Naphtha 232 288 290 288
Gasoline 280 280 - 280

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 94
Auto-Ignition Temperature
“Experimental studies, testing and practical experience
has shown that surface temperatures must often be
several hundreds of degrees higher than the
published minimum AIT to induce ignition”
www.EngWorks.ca
www.EngWorks.ca
“In general, ignition of hydrocarbons by hot surface
should not be assumed unless the surface
temperature is 360ºF (182ºC) above the accepted
AIT of the hydrocarbon involved”

API RP 2216 - Ignition Risks of Hot Surfaces


Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 95
Area Classification
www.EngWorks.ca
www.EngWorks.ca

Hazardous Materials

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 96
Hazardous Materials
„ NFPA Classification of Hazardous Materials
„ Flammable Gases
Flammable Liquids
www.EngWorks.ca
„

www.EngWorks.ca
„ Class IA, IB, IC
„ Combustible Liquids
„ Class II, Class III
Does not cover
„ Flammable Mists

„ Compressed Liquefied Gases

„ Cryogenic Flammable Liquids

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 97
Highly Volatile Liquids
„ Compressed Liquefied gases
„ Kept in a liquid state by pressure
When released behave like heavier than air gases
www.EngWorks.ca
„
www.EngWorks.ca
„ Example: Propane Storage Tanks
„ Cryogenic Flammable Liquids
„ Kept in a liquids state by temperature
„ Behave like flammable liquids when released
„ Example: LPG Terminals

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 98
Flammable Gases
„ Lighter than air (Vapor density < 1.0)
„ Seldom accumulate to form a hazardous mixture
except in enclosed area

„
www.EngWorks.ca
www.EngWorks.ca
Heavier than air (Vapor density > 1.0)
„ Fall to grade when released and can form an
ignitable mixture for extended periods of time

Gases with a vapor density between 0.8 and 1.2 may


exhibit characteristics of both

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 99
Flammable Vapors
„ Very similar to flammable gases except
that they are in the vapor phase.
„ www.EngWorks.ca
Exist at temperatures below their
www.EngWorks.ca
boiling point
„ Significant variance in persistence time

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 100
Flashpoint vrs Boiling Point
„ Flash Point
„ Lowest temperature at which a flammable liquid
gives off enough vapor to form an ignitable

„
www.EngWorks.ca
mixture with air near the surface of the liquid
www.EngWorks.ca
Not precise physical quantities – particularly in the
case of mixtures

„ Boiling Point
„ Temperature at which the vapor pressure of the
liquid equals the surrounding atmospheric
pressure
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 101
Flashpoint Illustrated
Ignition can only occur when the material
is in the vapour state.
Liquids cannot burn

www.EngWorks.ca
www.EngWorks.ca
Transition area from liquid to vapour

Open Container

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 102
NFPA Definition
Class I Flammable Liquid
Any liquids with a flash point < 37.8°C
(100°F)
www.EngWorks.ca
„ When released at ambient temperature,
www.EngWorks.ca
will readily evaporate and form a gas-
vapor mixture
„ Tend to disperse rapidly to below their

LEL
„ Behave like heavier than air gases
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 103
Flammable Liquids
Classification
Class Flash point Boiling point Examples

IA Below Below Ethyl Ether


22.8°C 37.8°C
www.EngWorks.cawww.EngWorks.ca
(73°F) (100°F)
Pentane

IB Below Greater than Acetone


22.8°C 37.8°C Gasoline
(73°F) (100°F)
IC At or above Below Naphtha
22.8°C 37.8°C Xylene
(73°F) (100°F)
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 104
Combustible Liquids
Classification

Class Flash point Examples

II above 37.8°C Fuel Oil


(100°F) and below Kerosene
www.EngWorks.ca
www.EngWorks.ca
60°C (140°F)
IIIA above 60°C (140°F) Cresol
but below 93°C Ethylene
(200°F) Glycol
IIIB above 93°C (200°F) Asphalt
Transformer
Calgary Oct 10, 2006 Oil
Edmonton Oct 11, 2006 Hazardous Area Classification 105
Flammable / Explosive Limits
„ Range of composition of material in air
which will burn
www.EngWorks.ca
www.EngWorks.ca
„ UFL – Upper Flammable Limit
„ LFL – Lower Flammable Limit

„ UEL – Upper Explosive Limit

„ LEL – Lower Explosive Limit

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 106
Graphical Explanation of LEL and UEL

www.EngWorks.ca
Too Lean Explosive Range
www.EngWorks.ca Too Rich

0 LEL UEL 100%


Saturation
0% LEL 100% LEL

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 107
LEL and UEL Limits for Selected
Gases and Liquids
Flammable Substance LEL% UEL%
Methane 5.3 15
www.EngWorks.ca
Ethane www.EngWorks.ca 3 12.5
Propane 2.3 9.5
Hydrogen 4.0 75
H2S 4.0 46
Gasoline 1.3 6.9
Crude Oil 1 7
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 108
Flammability Relationships

IT
UPPER LIM
CONCENTRATION OF FUEL

AUTO

E
www.EngWorks.caUR
IGNITION
SS
www.EngWorks.ca
FLAMMABLE REGION
RE FLAMMABLE REGION
MIST
RP
PO
VA

LOWER LIM
IT

TEMPERATURE AIT
FLASH POINT AIT

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 109
Area Classification
www.EngWorks.ca
www.EngWorks.ca

Properties of Hazardous Mixtures

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 110
Properties of Hazardous
Mixtures
„ Estimating the density of a mixture
„ Comparison to the density of air
„ MESG
„
www.EngWorks.ca
www.EngWorks.ca
Lead to Group Classification
„ LFL and UFL
„ AIT
„ Difficult to estimate – Must be determined
experimentally
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 111
Heavier than Air or
Lighter than Air?
„ Air has a molar weight of 28.96g/m at
0°C and Sea Level
„ www.EngWorks.ca
Calculate the molar weight of the
www.EngWorks.ca
mixture and divide by the molar weight
of air

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 112
Density Example
Material % by Molar %X
Volume Weight Mole Wt.
Methane 50% 16.04 8.02
www.EngWorks.ca
Ethane www.EngWorks.ca
10% 30.07 3.0
H2S 15% 34.08 5.11
Nitrogen 15% 28.02 4.2
Heptane 5% 100.2 5.0
Octane 5% 114.22 5.71
Total 100% 31.04
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 113
Density Example
Molar Weight of Material 31.04
= = 1.07
Molar Weight of Air 28.96

www.EngWorks.ca
www.EngWorks.ca
Material mixture is heavier than air

“For practical applications, a gas that has a relative


density below 0.8 is regarded as being lighter than air.
If the relative density is above 1.2, it is regarded as
being heavier than air. Between these values, both of
these possibilities should be considered”
RP-505
Calgary Oct 10, 20066.4.2.4
Edmonton Oct 11, 2006 Hazardous Area Classification 114
Buoyancy Considerations
„ Majority of releases are from
pressurized sources
„ www.EngWorks.ca
Shape of www.EngWorks.ca
a hazardous region is not
related to density but to angle of
release and how close the release point
is to the ground.

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 115
Calculating the MESG of
Mixtures
„ Application of Le Chatelier’s Principle

www.EngWorks.ca
www.EngWorks.ca

Where Xi denotes the % volume of the species i and


MESGi is the MESG of the species

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 116
Calculating the MESG of
Mixtures
Material % by Volume MESG (mm)
Ethylene 45 0.65
Propane 12 0.97
Nitrogen
Methane www.EngWorks.ca 20
www.EngWorks.ca
3

1.12
Isopropyl Ether 17.5 0.94
Diethyl Ether 2.5 0.83

The relationship then becomes:


1
MESGmix = = 0.9442mm
0.45 + 0.12 + 0.20 + 0.03 + 0.175 + 0.025
0.65 0.97 ∞ 1.12 0.94 0.83
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 117
Determining the Group Classification

Division System Zone System


Group MESG MIC Group MESG MIC

www.EngWorks.ca
(mm) Ratio (mm) Ratio
A www.EngWorks.ca
Acetylene
IIC ≤0.50 ≤0.45
B ≤0.45 ≤0.40
>0.45 >0.40 >0.50 >0.45
C IIB
≤0.75 ≤0.80 ≤0.90 ≤0.80
D >0.75 >0.80 IIA >0.90 >0.80

Mixture has MESG of 0.9442 and is therefore Group IIA

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 118
Comparison between Le Chateliers
Approximation and Actual Tests
Source – NEC Group Classification of Mixtures, Edward M Briesch, UL Laboratories 1999

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 119
Approximating UFL and LFL of
a Mixture
„ Le Chatelier’s Principle applies again
„ Must use only the flammable limit
www.EngWorks.ca
components
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 120
Approximating UFL and LFL
„ Applies only to mixtures with air
„ LFL is not influenced by pressure
„ www.EngWorks.ca
UFL www.EngWorks.ca
is influenced by pressure

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 121
UFL and LFL Mixture Example
Material % by Vol. % Vol % LFL % UFL
Combustible
Ethylene 48 60 2.3 36
Propane
Nitrogen
www.EngWorks.ca 12 15
www.EngWorks.ca
20 -
1.7
-
10.9
-
Methane 4 5 4.4 17
Isopropyl 16 20 0.4 7.9
Ether

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 122
UFL and LFL Mixture Example

1
UFLmix =
0.60 + 0.15 + 0.05 + 0.2

www.EngWorks.ca
36 10.9 17 7.9
www.EngWorks.ca
UFL = 17%mix

1
LFLmix =
0.60 + 0.15 + 0.05 + 0.2
2.3 1.7 4.4 0.4

LFLmix = 1.16%

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 123
Estimating the flammability of
a process stream
„ Rule of Thumb
„ If the total % combustibles in a mixture
www.EngWorks.ca
exceed the %LFL for the mixture, the
www.EngWorks.ca
mixture can be considered flammable

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 124
Mixture Flammable Test Example

Material % by Vol. Mole % LFL % UFL


Fraction
Ethylene 0.5 0.15 2.3 36
Hexane www.EngWorks.ca
www.EngWorks.ca
0.8 0.24 1.1 7.5
Methane 2 0.61 4.4 17
Total Combustibles 3.3
Air 97.7 2.37%
Total 100

Total Combustibles > %LFL - Mixture is Flammable


Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 125
Estimating the AIT of a
Mixture
Material % Composition Published AIT

IsoButane 1% 460ºC (860ºF)


nButane 1% 287ºC (550ºF)
www.EngWorks.ca
www.EngWorks.ca
IsoPentane 53% 420ºC (788ºF)
nPentane 4% 260ºC (500ºF)
IsoHexane 23% 264ºC (507ºF)
nHexane 1% 225ºC (437ºF)
Cyclohexane 5% 245ºC (473ºF)
DiMethylButanes 11% 405ºC (761ºF)
Gasoline Tipate 280ºC (536ºF)
(88 Octane)
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 126
Estimating the AIT of a
Mixture
„ The only certain method of ascertaining
the AIT of a mixture is by lab testing
www.EngWorks.ca
www.EngWorks.ca
„ My personal ROT
„ Use the lowest AIT whose composition
exceeds 5% of the mixture

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 127
AIT Mixture Example
Material % by Vol. AIT ºC
Ethylene 45 450
Propane www.EngWorks.ca
12
www.EngWorks.ca 450
Nitrogen 20 -
Methane 3 537
Isopropyl Ether 17.5 443 AIT

Diethyl Ether 2.5 180

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 128
Exercise #1
Define the Material Properties
„ Calculate the density relative to air
„ Calculate the LFL
„ www.EngWorks.ca
Calculate www.EngWorks.ca
the MESG
„ Estimate the AIT

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 129
Mixture Rules of Thumb
„ For H2S, Group IIB classification requires
>25% H2S by composition (RP 505)

„
www.EngWorks.ca
www.EngWorks.ca
For Hydrogen, Group IIC requires >30%
Hydrogen by composition (IP15)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 130
Area Classification
www.EngWorks.ca
www.EngWorks.ca

Ventilation

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 131
Ventilation (RP-505)
Adequate Ventilation (RP-505)
„ Ventilation (natural or artificial) that is sufficient to prevent the
accumulation of significant quantities of vapor-air or gas-air
mixtures in concentrations above 25% of their lower flammable

www.EngWorks.ca
(explosive) limit.
www.EngWorks.ca
Inadequate Ventilation (RP-505)
„ Ventilation that is less than adequate

Enclosed areas are considered adequately ventilated if:


“1.0 cubic foot of air volume flow per minute per square foot of
floor area but at least 6 ACPH on a continuous basis”

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 132
Ventilation (IEC 79-10 Mod)
“the likelyhood of an explosive gas atmosphere,
and hence the zone designation depends
mainly on the grade of release and the
www.EngWorks.ca
ventilation”www.EngWorks.ca

„ Degree of Ventilation
„ High, Medium, Low
„ Availability of Ventilation
„ Good, Fair Poor

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 133
Grade of Release
„ Continuous
„ A release that is continuous and is expected to
occur for long periods.
„
„
www.EngWorks.ca
Primary www.EngWorks.ca
A release that can be expected to occur
periodically or occasionally during normal
operation
„ Secondary
„ A release that is not expected to occur in normal
operation and if it does occur, is likely to do so
infrequently and for short periods

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 134
Influence of Ventilation on
Type of Zone
Degree
High Medium Low
Grade of
Release www.EngWorks.ca
Availability
www.EngWorks.ca
Good Fair Poor Good Fair Poor Good,
Fair or
Poor
Non Zone Zone 1 Zone 0 Zone 0 Zone 0 + Zone 0
Continuous
Haz. 2 +Zone 2 Zone 1
Non Zone Zone 2 Zone 1 Zone 1 + Zone 1 or Zone 1 or
Primary
Haz. 2 Zone 2 Zone 0 Zone 0
Non Non Zone 2 Zone 2 Zone 2 Zone 2 Zone 1 or
Secondary Haz. Haz. Zone 0
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 135
Degree of Ventilation
High Ventilation
„ Can reduce the concentration at the source of
www.EngWorks.ca
release, virtually instantaneously, resulting in
www.EngWorks.ca
a concentration below the LEL
„ Examples:
„ Dilution ventilation on acoustic hoods on

gas turbines
„ May be up to 60 ACPH

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 136
Degree of Ventilation
Medium Ventilation
„ Can control the concentration, resulting
in a stablewww.EngWorks.ca
situation in which the
www.EngWorks.ca
concentration beyond the zone is below
the LEL
„ Examples:
„ Building evacuation fans exchanging air at
6 ACPH

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 137
Why 6 ACPH?

www.EngWorks.ca
www.EngWorks.ca

Combustible Build-up Curve, General Ventilation: Continuous Release


Source NFPA 69
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 138
Why 6 ACPH?

www.EngWorks.ca
www.EngWorks.ca

Combustible Decay Curve, General Ventilation: Instantaneous Release


Source NFPA 69
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 139
Degree of Ventilation
Low Ventilation
„ Cannot control the release while the

www.EngWorks.ca
release iswww.EngWorks.ca
in progress and cannot
prevent undue persistence of a
flammable atmosphere after the release
has stopped
„ Anything less than 6 ACPH

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 140
Availability of Ventilation
Good
„ Ventilation is available continuously

Fair
www.EngWorks.ca
„ Ventilation iswww.EngWorks.ca
expected to be present during normal
operation. Discontinuities are permitted provided
they occur infrequently and for short periods.
Poor
„ Ventilation that does not meet the standard of fair or
good, but discontinuities are not expected to occur
for long periods

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 141
Influence of Ventilation on
Type of Zone
Degree
High Medium Low
www.EngWorks.ca
Grade of
Release www.EngWorks.ca
Availability
Good Fair Poor Good Fair Poor Good,
Fair or
Poor
Non Zone Zone 1 Zone 0 Zone 0 Zone 0 + Zone 0
Continuous
Haz. 2 +Zone 2 Zone 1
Non Zone Zone 2 Zone 1 Zone 1 + Zone 1 or Zone 1 or
Primary
Haz. 2 Zone 2 Zone 0 Zone 0
Non Non Zone 2 Zone 2 Zone 2 Zone 2 Zone 1 or
Secondary Haz. Haz. Zone 0
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 142
Buoyancy Considerations
„ Majority of releases are from
pressurized sources
„ www.EngWorks.ca
Shape of www.EngWorks.ca
a hazardous region is not
related to density but to angle of
release and how close the release point
is to the ground.

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 143
CFD Analysis CH4 Release
Geometry of Release

UFL = 17%

www.EngWorks.ca
www.EngWorks.ca
CH4

LFL = 5.3%

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 144
CFD Analysis CH4 Release
Different Release Rates
2 kg/sec 8 kg/sec 32 kg/sec

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 145
CFD Analysis CH4 Release
Different Release Directions

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 146
Area Classification
www.EngWorks.ca
www.EngWorks.ca
Application of the Principles

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 147
Four Approaches to Area
Classification
1. Classification by Direct Example
• NEC/CEC
• API RP 500/505

•www.EngWorks.ca
NFPA 497
IP15 www.EngWorks.ca

2. Source of Hazard Method (Point Source


Concept)
• Appendix D RP 505
• IEC 79-10 Mod
• IP 15

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 148
Four Approaches to Area
Classification

3. Hybrid Approach
• Use direct example where appropriate
• www.EngWorks.ca
Modify classifications
www.EngWorks.cabased on fugitive
emissions studies, use of gas detection, vapor
barriers ect.
4. Risk Based Approach
• IP 15
• Applicable to situations where the release rate
may be an unknown, unspecified and variable
quantity

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 149
Classification by Direct Example
„ Most commonly used method of area classification in
North America

Easiest to use
www.EngWorks.ca
„
www.EngWorks.ca
„ Requires a judgment be made on the basis of what
hazardous materials might be present and the
probability of the containment systems leaking

„ Extent of an area classification is made by


referencing the figures and diagrams published in
established codes and standards
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 150
Classification by Direct Example Work Process
Based on Appendix E API 505

„ Step 1 – Determine the need

„
www.EngWorks.ca
Step 2 – Assignment of the Classification
www.EngWorks.ca
Based on the probability of a hazardous material
being present in ignitable quantities
„ Are the hazardous materials heavier or lighter
than air

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 151
Classification by Example Work Process
Based on Appendix E API 505

„ Step 3 – Determine the extent of the hazardous area


based on the figures provided in CEC, RP505 and the
Code for Electrical Installations at Oil and Gas
Facilities

„
www.EngWorks.ca
www.EngWorks.ca
Step 4 – Assign the Group and the temperature code
based on the materials present
„ Reference NFPA 325

„ Step 5 Document the Hazardous Locations


„ Area Classification Drawing Plan View and cross sections
where applicable

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 152
Gas Station Example

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 153
Gas Station Pump
CEC 20-004

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 154
Gas Station Storage Tank
(CEC 20-004)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 155
Gas Station Garage
(CEC 20-102 )

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 156
NFPA 325 Materials Data

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 157
Group and Temperature Classification

„ Refer to CEC Appendix B Temperature


and Gas Groups Table
„ www.EngWorks.ca
Gasoline www.EngWorks.ca
„ Group IIA
„ AIT of 280°C
„ T2A temperature code

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 158
Resulting Area Classification

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 159
Drilling Rig Example

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 160
Drilling Rig Classification
Challenges
„ Materials vary in composition
„ Crude Oil
„ Gas/Condensate

„
www.EngWorks.ca
www.EngWorks.ca
Large number of potential ignition sources
„ Combustion engines
„ Tools

„ Large variety of configurations


„ Enclosed, partially enclosed and open type derricks

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 161
Drilling Rig Classification
Challenges
„ Unconventional release sources
„ Dissolved gas in under balance drilling operations
Pressure kicks
www.EngWorks.ca
„

„ www.EngWorks.ca
Fugitive emissions from residual mud on drilling equipment
„ Stuffing box emissions
„ Vapours present in oily water drainage systems

„ High risk of personnel being within the classified area

„ Area classification is not typically reviewed by a


Professional Engineer

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 162
Code for Electrical Installation
at Oil and Gas Facilities

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 163
API RP 505 Drilling Rig

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 164
IP 15 Drilling Rig

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 165
Inherent Problems with the Classification by
Example Work Method
„ Subject to abuse and incorrect use
„ User does not have to fully understand the process; Only required
to apply the recommendations stated in the code or practice
„ Application figures are only a guideline and require the application

www.EngWorks.ca
of sound engineering judgment
www.EngWorks.ca
„ Does not dwell on the group or temperature classification
„ The user is required to reference recommended practices for
complete definition

„ Tend to over classify facilities

„ Leads to inconsistencies between users and applications


„ Diagrams are frequently misinterpreted

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 166
Area Classification
www.EngWorks.ca
www.EngWorks.ca
Hybrid Method

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 167
Hybrid Method
„ Uses the guidelines provided by the
Classification by Direct Example publications
where appropriate
www.EngWorks.ca
www.EngWorks.ca

„ Incorporates concepts related to material


properties, ventilation, fugitive emissions and
other methods of determining hazard radii as
referenced by a variety of publications

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 168
Hybrid Method Work Process
1. Review of Government Regulations and
selection of Industry Codes and References
Assemblewww.EngWorks.ca
Project Data
2.

3.
www.EngWorks.ca
List all Hazardous Materials and Material
Properties
4. Identify all Material Release Sources
5. Assign an Area Classification
6. Document the Area Classification
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 169
Classification of an Upstream Facility
by Direct Example

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 170
Typical Process Building
RP 505

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 171
Tank Farm RP 505

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 172
Pig Launcher RP 505

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 173
Pump (RP 505)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 174
Resulting Classification

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 175
Hybrid Approach
Data Requirements
„ Process Descriptions

„ www.EngWorks.ca
PFDs www.EngWorks.ca
„ P&IDs
„ Material Balance Sheets
„ Equipment List
„ Plot Plan
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 176
Overview of the Process

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 177
Flammable Materials Data Sheet

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 178
Mixture Analysis

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 179
Potential Sources of Release
„ Process Equipment
„ Rotating Equipment
Piping Connections
www.EngWorks.ca
„

„ Flanges www.EngWorks.ca
„ Pumps
„ Valves
„ Tank Fugitive Emissions
„ Sample Connections
„ Pig Launchers
„ Analyzer Emissions
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 180
Potential Sources of Release

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 181
Pig Launcher - Tank Farm

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 182
Potential Sources of Release

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 183
Dehy Building
Enclosed areas are considered adequately ventilated if:
“1.0 cubic foot of air volume flow per minute per
square foot of floor area but at least 6 ACPH on a
continuous basis” RP 505
www.EngWorks.ca
www.EngWorks.ca
„ Outside Dimensions
14’W X 24’L X 12’H
Volume 4032 ft3
Area 336 ft2

„ Air flow required for “Adequate Ventilation”


14’ X 24’ = 336 ft3/min
6 ACPH = 6 X 4032/60 = 403 ft3/min
403 ft3/min or 6 ACPH is required by API 505
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 184
Heating Requirements
„ To maintain the interior temperature at a
nominal 50ºF under ambient conditions of
-45ºF would require 15kW of supplemental heat
www.EngWorks.ca
www.EngWorks.ca

„ May be a problem with local freeze-up on


certain lines requiring the addition of heat
trace as a precautionary measure

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 185
API 505 Fugitive Emissions
Calculation
Adequate Ventilation (RP-505)
„ Ventilation (natural or artificial) that is sufficient to
prevent the accumulation of significant quantities of
vapor-air or gas-air mixtures in concentrations above
www.EngWorks.ca
25% of theirwww.EngWorks.ca
lower flammable (explosive) limit.

„ A fugitive emissions calculation estimates the amount


of hazardous material likely to be present in an
enclosed area under normal operating conditions

„ The results are used for to calculating the amount of


air movement required to achieve the definition of
“adequate” ventilation
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 186
www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 187
API 4615 Background
„ Summarizes the results of several studies
conducted by API and published in 1993
„ 185,000 components in 20 different facilities
„ www.EngWorks.ca
A total of 4796
leaking
components were found to be
www.EngWorks.ca

„ Intent was to support the EPA clean air act of


1990
„ Not originally intended for area classification
purposes

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 188
API 4638
„ Explains a variety of
methods for
performing fugitive
www.EngWorks.ca
www.EngWorks.ca
emission calculations
„ Provides background
definitions, step by
step procedures and
working examples

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 189
Aussie Equivalent

www.EngWorks.ca
www.EngWorks.ca

http://www.npi.gov.au/handbooks/approved_handbooks/foilgas.html
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 190
Component Definitions
(as per API 4615)
Connections Open ended devices
„ Threaded connections „ sample connections
„ Tubing fittings „ Drains
„ Valve connections „ Bleed valves

www.EngWorks.ca
Flanges
www.EngWorks.ca
Other
„ compressor seals
„ pressure relief valves
Pumps and pump „ Hatches
seals „ dump lever arms
„ polished rod stuffing
boxes
Valves „ Instruments
„ Excludes check valves „ sight glasses

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 191
Stream Types
„ Gas
„ Heavy Oil
„ www.EngWorks.ca
Light Oil www.EngWorks.ca
„ Water/Oil

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 192
EPA Average Emission Factors
(lb/Component/day)
Heavy Oil Light Oil Water/Oil
Gas (<20 API (≥20 API (Water Content
Gravity) Gravity) 50% - 99%)

www.EngWorks.ca
Valve 2.4E-01 4.4E-04 1.3E-01 5.2E-03
www.EngWorks.ca
Connector 1.1E-02 4.0E-04 1.1E-02 5.8E-03

Flange 2.1E-02 2.1E-05 5.8E-03 1.5E-04

Open-End 1.1E-01 7.4E-03 7.4E-02 1.3E-02

Other 4.7E-01 1.7E-03 4.0E-01 7.4E-01

Pump 1.3E-01 Not 6.9E-01 1.3E-03


Available
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 193
Fugitive Emission Factors
Abnormal Operation (Gas Service)
(lbs/component/day)

Component Normal Abnormal Emissions


Increase
Connections 1.1E-02 1.4 127 X

Flanges
www.EngWorks.ca
www.EngWorks.ca
2.1E-02 4.3 204 X

Pumps and pump seals 1.3E-01 3.9 30 X


Valves 2.4E-01 5.2 21 X
Open ended devices 1.1E-01 2.9 26 X
Other 4.7E-01 4.7 10 X

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 194
Variables effecting Emission
Rates
• Fluid phase • Batch/continuous

• Valve type/ process


packing/configuration • Equipment size

Pressure • Pump seal type

www.EngWorks.ca

www.EngWorks.ca
• Fluid
• Gasket type
• Temperature toxicity/corrosiveness
• Pump rpm
• Flange type
• Service life
• Flange bolting
procedures • Compressor seal type

• Unit type
• Inspection frequency

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 195
Methods for Estimating
Components
1. Physical Count
2. Estimate from P&IDs
3. API 4638 Approximation
„
www.EngWorks.ca
www.EngWorks.ca
Count the number of valves
„ Number of flanges = number of valves
„ Number of connectors = 3 X number of valves
„ Number of open ended devices = 10% of the
number of valves
„ Number of “other” components = 5% of the
number of valves
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 196
Fugitive Emissions Calculation
RP 505 Appendix B
„ Calculation determines what ventilation rate is
required to ensure that the fugitive emissions do not
exceed 25% of the LEL of the hazardous material
present.
www.EngWorks.ca
www.EngWorks.ca
„ Based on perfect mixing

„ Safety factor of 4 is applied

„ All calculations are done using imperial


measurements
„ Use care when converting to metric values

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 197
Fugitive Emissions – Dehy
Building
Component No. HC Emission Total
Type (lbs/Component/day) Emissions
(lbs/day)

www.EngWorks.ca
Valve

Connector
42
www.EngWorks.ca
126 1.1E-02 1.38
2.4E-01 10.08

Flange 42 2.1E-02 0.882


Open-End 6 1.1E-01 0.66

Other 3 4.7E-01 1.41

Pump 0 1.3E-01 0
Total 14.4
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 198
Fugitive Emissions Calculations
Cont’d
„ Convert lbs/day to lbs/hour
„ 14.4 lbs/day / 24 = 0.6 lbs/hour
www.EngWorks.ca
www.EngWorks.ca
„ Calculate the mole weight of the
Hydrocarbon Emission
„ 24.46 (from mixture analysis)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 199
Calculate the cubic feet/pound-mole
weight of the Hydrocarbon mixture
„ Assumption: volume of one pound-mole of
ideal gas = 359 ft3 at standard temperature-
pressure (32ºF at 14.7 psia)

„
www.EngWorks.ca
www.EngWorks.ca
Ideal gas law (PV=nRT)

„ Charles’ Gas Law (V1T2 = V2T1)


„ Volume varies proportionately to the

temperature in degrees Rankin (Fº +


460)
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 200
Volume of ideal gas at 90ºF
„ At 90ºF and 14.7 psia, 359 ft3 would
occupy:
www.EngWorks.ca
www.EngWorks.ca
(359)(460 + 90)/(460 +32) = 401ft3

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 201
Calculate the Hydrocarbon Leak
Rate
(E)(V)
G=
60(mw)

www.EngWorks.ca
Where: www.EngWorks.ca

G = Leak rate,cfm
E = Emission rate, lbs/hour
V = Volume, ft3/lb-mole
mw = average mole weight
60 = 60 minutes per hour

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 202
Hydrocarbon Leak Rate
E = 0.6 lbs/hour
V = 401 ft3/lb-mole
mw = 24.46
www.EngWorks.ca
60 = 60 www.EngWorks.ca
minutes per hour

(0.6)(401)
G= = 0.1639 ft3/min
60(24.46)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 203
Hydrocarbon Concentration
(as per NFPA 69)

C = (G/Q) (1-e-kn)
or
C = (G/Q)

www.EngWorks.ca
(1 – e-kn approaches www.EngWorks.ca
1 after steady state conditions)

Where:
C = Concentration of hydrocarbon in air, percent (in decimal
format)
G = Leak rate
Q = Fresh air introduction rate
N = number of air changes
K = quality factor
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 204
Required Fresh Air Introduction
Rate
100% LEL (from mixture analysis = 3.31%)
Required to maintain a 25% LEL

www.EngWorks.ca
www.EngWorks.ca
Required fresh air introduction rate

0.1639 ft3/min
Q= = 21.15 ft3/min
(0.25 X 0.031)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 205
Application of Safety Factor
„ Safety factor of 4 is applied (as per RP 505
6.6.2.4.8)

„ www.EngWorks.ca
www.EngWorks.ca
Required ventilation rate = 4 X 21.15 ft3/min
= 84.61 ft3/min

„ Volume of Dehy building =4032 ft3

„ Equivalent to 84.61 ft3/min X 60 min/hr /


4032ft3 = 1.25 ACPH
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 206
Application of the Results
„ The Dehy building ventilated at 1.25 ACPH is
considered adequately ventilated
„ Typical value for an upstream process building is between

www.EngWorks.ca
0.5 and 2 ACPH
„
www.EngWorks.ca
Industry recommended bathroom fan sizing criteria – 8
ACPH

„ For ventilated areas < 3 ACPH, RP 505 recommends


continuous monitoring by fixed gas detectors to
assure the LEL remains at the 25% level or below
„ Generally tied in with ventilation fans sized at 12 ACPH

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 207
Design of the HVAC System

Degree
High Medium Low
Grade of
Release
www.EngWorks.ca
www.EngWorks.ca
Availability
Good Fair Poor Good Fair Poor Good,
Fair or
Poor
Non Zone Zone 1 Zone 0 Zone 0 Zone 0 + Zone 0
Continuous Haz. 2 +Zone 2 Zone 1
Non Zone Zone 2 Zone 1 Zone 1 + Zone 1 or Zone 1 or
Primary Haz. 2 Zone 2 Zone 0 Zone 0
Non Non Zone 2 Zone 2 Zone 2 Zone 2 Zone 1 or
Secondary Haz. Haz. Zone 0
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 208
Design of the HVAC System
„ Must provide a good quality of ventilation
„ good mixing
„ no stagnant areas
„
„
www.EngWorks.ca
Must be reliable and provide good availability
www.EngWorks.ca
99% availability target
„ Designed to extract fugitive emissions
„ Heavier than air releases
„ Lighter than air releases
„ Must be capable of stabilizing an abnormal release
„ Consistent with the IEC definition of a Medium degree of
ventilation

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 209
Ventilation Strategies
„ Natural Ventilation
„ Artificial Ventilation
„ www.EngWorks.ca
www.EngWorks.ca
Recirculation Ventilation

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 210
Natural Ventilation

www.EngWorks.ca
www.EngWorks.ca

Wind Driven Flow Stack Driven Flow

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 211
Mechanical Extract Ventilation

Gravity
Louvers
www.EngWorks.ca
www.EngWorks.ca Air Movement

XP Fan

Air Movement
Gravity XP Fan
Louvers

Crossflow Ventilation Crossflow Ventilation


Lighter than Air Density Materials Heavier than Air Density Materials

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 212
Mechanical Supply Ventilation

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 213
Turbine Ventilator

www.EngWorks.ca
www.EngWorks.ca

Dehy Building requires 85 CFM

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 214
Dehy Building
HVAC Design Option #1

Turbine Ventilator

Wind (>2mph)

www.EngWorks.ca
www.EngWorks.ca GD GD

I
Gravity
Louvers
Air Movement XP Fan
12 ACPH

Stack
Effect
Fixed Fixed
Louvers Louvers

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 215
„ Fan Affinity Law – Fan output CFM is
directly proportional to fan speed
„ www.EngWorks.ca
Required HP vary with the fan speed
www.EngWorks.ca
cubed

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 216
Dehy Building
HVAC Design #2
Fan Affinity Law – Fan output CFM is directly proportional to fan speed

www.EngWorks.ca
www.EngWorks.ca GD GD I VFD

Gravity
Louvers
XP Fan
Fan sized for 12 ACPH
Air Movement 2 ACPH Normal Conditions
12 ACPH on Gas Detection

Fixed Fixed
Louvers Louvers

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 217
Plan Layout
Insure no Stagnant Air Pockets
Fixed
Louver

www.EngWorks.ca
1 ACPH

U/
www.EngWorks.ca
H

H
U/

Recirculated Air

Gravity
Louver Exhaust Fan
12 ACPH
Air Flow
H

U/
U/

H
Fixed
Louver
1 ACPH

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 218
Fan Recirculation Options
HM Control Soleniod
T Thermostat
Heat Medium Supply

www.EngWorks.ca
www.EngWorks.ca

Air Flow Fan Motor MS Motor Starter Switch

Heat Medium Return

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 219
Classification around Ventilation
Openings

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 220
Naturally Ventilated Enclosed
Areas
„ Method for naturally ventilating enclosed areas by
means of the stack effect is provided in RP-505
6.6.2.4.5with a working example in Appendix B

„
www.EngWorks.ca
www.EngWorks.ca
Provides 12 ACPH of ventilation (one complete air
change each five minutes)

„ Method for calculating adequate ventilation is only


applicable to building with volumes of 1000 ft3 or less

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 221
Natural Ventilation
RP 505 Appendix A

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Stack Effect
Edmonton Oct 11, 2006 Hazardous Area Classification 222
Sizing Ventilation Louvres
V
A=
1200 h( Ti – To )/ Ti
www.EngWorks.ca
www.EngWorks.ca

Where:
A – Free Area of inlet (or outlet) opening(s) (includes a
50% effectiveness factor)
V – Volume of building to be ventilated, in cubic feet
h – height from the center of the louver opening to the Neutral
Pressure Level (in feet)
Ti – temperature of indoor air (degrees Rankin)
To – temperature of outdoor air (degrees Rankin)
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 223
Calculating the Height to the
Neutral Pressure Level
H
h=
1 + [(A1/A2)2(Ti/To)]

Where:
www.EngWorks.ca
www.EngWorks.ca
h – height from the center of the louver opening to the Neutral
Pressure Level (in feet)
A1 – free area of lower opening, in square feet
A2 – free area of upper opening in square feet
H – Vertical distance (center to center) between A1 and A2 in feet
Ti – temperature of indoor air (degrees Rankin)
To – temperature of outdoor air (degrees Rankin)

Note: If Ti < To the ration Ti/To should be inverted

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 224
Application to the Inlet Separator Building
Dimensions of Inlet Separator Building
12’L X 10’W X 8’H
Volume of Building - 960 ft3

www.EngWorks.ca
Ti - 110ºF or (110 + 460 = ) 570ºR
www.EngWorks.ca
To 95ºF or (95 + 460 = ) 555ºR
-

H – (distance between A1 and A2) – 7ft


Assume A1 = A2

7
h=
1 + [(570/555)]

Calgary Oct 10, 2006


h = 3.45 ft
Edmonton Oct 11, 2006 Hazardous Area Classification 225
Sizing Ventilation Louvers for the
Inlet Separator Bldg
V = 960 ft3
h = 3.45 ft
Ti = 110ºF or (110 + 460 = ) 570ºR
www.EngWorks.ca
To = 95ºF orwww.EngWorks.ca
(95 + 460 = ) 555ºR

960
A=
1200 3.45(570 – 555)/ 570

A = 2.65 ft2 for inlet and outlet


Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 226
Sizing Louvers
Outlet Louver consists of a roof vent that
extends along length of building

www.EngWorks.ca
Size of ventwww.EngWorks.ca
opening is 10ft X 0.5ft
Total area = 5ft2

Inlet Louvers
4 – 10” X 10” louvers for an effective area of
2.75ft2
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 227
Ventilation Considerations
„ Beware of Operator intervention
„ Document the air change requirements
onwww.EngWorks.ca
the area classification drawings
www.EngWorks.ca
„ Be careful with the conversions

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 228
Potential Sources of Release

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 229
Analyzer/Custody Transfer
Building
„ Building is inadequately ventilated
„ Sources of release include emissions from the
analyzer and the custody transfer meter run
„
www.EngWorks.ca
Analyzer is certified
locations
for use in Class 1 Zone 2
www.EngWorks.ca

„ Number of small sample lines that may be prone to


freeze-up

Use of gas detection may be an appropriate strategy for


classifying the building

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 230
Use of Combustible Gas Equipment as a
basis for Area Classification
(RP-505)
„ Gas detectors must be of stationary type

„ Adequate number must be installed

„
www.EngWorks.ca
www.EngWorks.ca
Gas detectors must be calibrated a minimum of every
three months or as specified by the equipment
manufacturer

„ The temperature code of electrically operated


equipment does not exceed 80% of the AIT for the
flammable materials present in the building

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 231
Combustible Gas Detection for Use in
Hazardous Locations
(CEC Appendix H)
„ Provides suggestions for use of combustible gas
detectors as supplementary protection for equipment
not approved for the Zone
„
www.EngWorks.ca
Effectively allows you to place non-hazardous
www.EngWorks.ca
equipment in Zone 2 locations and Zone 2 equipment
in Zone 1 locations
„ Does not change the area classification as per RP-
505
„ Recommends that all essential services such as lighting,
process instrumentation and gas detection be approved for
the Class Group and Zone of the area

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 232
Use of Combustible Gas Detection
Analyzer Approved for use in Zone 2 Locations

www.EngWorks.ca
www.EngWorks.ca

CEC Appendix H RP-505

Audible and visible alarm is actuated when LEL reaches 20%


Equipment is disconnected when LEL reaches 40%
Equipment is de-energized in the failure of gas detection equipment

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 233
Gas Detection Application
Considerations
„ Density of the gases being detected
„ Location of gas detectors
„ Redundant heads
„
www.EngWorks.ca
www.EngWorks.ca
Effects of ventilation flow
„ Adverse environments
„ Temperature
„ Airborne particles
„ Contaminants
„ Corrosive compounds
„ Vibration
„ Accessibility for calibration and maintenance
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 234
Gas Detection Technology
Catalytic Bead
„ Platinum coil embedded in a
catalyst
„ Flammable gas reacts with
www.EngWorks.ca
the catalyst creating heat
www.EngWorks.ca
which changes the resistance
in the platinum coil which is
monitored
„ Sensitive to contamination
and “poisoning”
„ Halogens
„ Sulphur compounds

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 235
Gas Detection Technology
Infrared
„ Measurement is based
on the absorption of IR
radiation as it passes
through a volume of
gas www.EngWorks.ca
www.EngWorks.ca
„ Immune to all chemical
poisons Open Path IR Gas Detector

„ Does not need oxygen or


air to detect gas
„ Lower maintenance than
catalytic bead
„ Will not detect hydrogen
Point Source IR Gas Detector

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 236
Maintenance of Gas Detection
Equipment
„ “Combustible gas detection instruments should never
be used as a substitute for safe electrical design”
Appendix H H.1.3 CEC
„ Consideration must be given to environmental
„
www.EngWorks.ca
conditions www.EngWorks.ca
Temperature
„ Airborne particles
„ Contaminants
„ Corrosive compounds
„ Gas detectors must be adjusted to detect all gases
that may be encountered
„ State what gases the gas detectors must be calibrated for
on the area class drawings

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 237
Gas Detector Calibration
Combustible Gas Correction factor for Correction factor for
Sensors Calibrated Sensors Calibrated on
on Propane Methane
Methane
Propane
www.EngWorks.ca
1.0
0.55
www.EngWorks.ca
1.82
1.0

Butane 1.0 1.82


Pentane 1.22 2.22
Hexane
Heptane
Gasoline 0.85 1.54

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 238
Gas Detector Location
Guidelines
„ Locate the detector near the hydrocarbon release
source
„ Locate the detector where gas emissions are likely to

„
www.EngWorks.ca
accumulate www.EngWorks.ca
Take into account the density of the gas
„ May need to place detectors in high and low locations
„ Outdoor applications require special consideration
„ Environmental contamination of detector heads
„ Topography and wind direction play a role
„ Open path IR detectors better suited to outdoor applications

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 239
Gas Detector Location
Guidelines
„ Intake or exhaust duct placement in
mechanical ventilation systems requires
special attention
„
www.EngWorks.ca
LEL alarmwww.EngWorks.ca
set point should be set as low as
reasonably practical
„ Locate gas heads with calibration
maintenance activities in mind
„ Incorporate redundancy into the design
„ Document the rational for placement of the
gas heads

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 240
Gas Detection Maintenance
„ CEC Appendix H5 recommends that the
installation be calibrated in accordance
www.EngWorks.ca
with the manufacturer’s
www.EngWorks.ca instructions
Paragraph 4.8.2(f) of RP 500 (1991
or

Editions)
„ Paragraph 6.8.2 (f) in RP 505
„ Gas detectors calibrated at least every
three months
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 241
www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 242
Potential Sources of Release

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 243
Use of Vapour-tight Barriers
„ Effective way of locating non-hazardous
rated equipment adjacent hazardous
www.EngWorks.ca
areas www.EngWorks.ca
„ Benefits include
„ Reduced on-site wiring costs
„ Allows equipment to be pre-commissioned

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 244
Use of Vapour-tight Barrier

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 245
Definition of a
Vapour-tight Barrier

“a barrier that will not allow the passage


of www.EngWorks.ca
significant quantities of gas or vapor
www.EngWorks.ca
at atmospheric pressure”
RP 500/505

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 246
Compressor/Pump Building

www.EngWorks.ca
www.EngWorks.ca

Cable Transit Detail

Location of vapour-tight walls should be specified


on the area class drawings
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 247
Fired Heaters/Flare Stack

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 248
Fired Heater Considerations
Occupational Health and Safety Code Part 10

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 249
Flares

Typical Detail for a Flare

www.EngWorks.ca (Historical)
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 250
Flares

www.EngWorks.ca
www.EngWorks.ca
Typical Detail for a Flarestack
(Makes more Sense)

600mm

15m

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 251
Other Potential Sources of Release

„Generator Buildings
RP505
www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 252
Batteries
„ Certain battery designs liberate hydrogen
during the recharge cycle
Lead Acid
www.EngWorks.ca
„
www.EngWorks.ca
„ Lead Calcium
„ Lead Antimony
„ Battery design that do not liberate hydrogen
„ Nickel cadmium
„ Nickel hydride

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 253
Batteries RP505

www.EngWorks.ca
www.EngWorks.ca

Valve-regulated lead acid (VRLA) batteries are also known as sealed lead acid
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 254
Batteries Continued
„ VRLA Batteries incorporate a catalyst to
recombine oxygen and hydrogen into
water
„
www.EngWorks.ca
www.EngWorks.ca
Overcharging can cause the battery to
liberate hydrogen through a safety vent
„ Typical UPS is designed to prevent
overcharging
„ Equalization charge cycle can cause a battery
to liberate hydrogen

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 255
CEC Appendix B
Notes on Rules

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 256
Battery Rooms
„ Locations surrounding VRLA batteries
are generally unclassified provided:
„
www.EngWorks.ca
Installedwww.EngWorks.ca
in open type racks
„ Ventilation is present > 1 ACPH
„ Battery rooms incorporating open type
lead calcium batteries required special
attention (Refer to RP505 Section 8.2.6)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 257
Vendor Skid Packages
„ Responsibility for the Area Classification
of a skid package building often blurred
„ www.EngWorks.ca
Some contracts require the skid vendor
www.EngWorks.ca
to perform the area class study
„ Client defines the area classification and
then rely on the vendor to sign and stamp
the drawings
„ Most skid vendors subcontract the task
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 258
Vendor Skid Building
Area Classification Problems
„ Skid vendor does not have access to
the process parameters
Documentation by the skid vendor is
„
www.EngWorks.ca
www.EngWorks.ca
often lacking
„ Number of ACPH required
„ Gas detection operating parameters
„ Signing and stamping the drawings are
often an issue.
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 259
Options
„ Specify in detail what is required by the
vendor
Documentation requirements
www.EngWorks.ca
„

„ www.EngWorks.ca
Design details on drawings
„ Performance verifications
„ Have the Client’s Consultant perform the area
class study
„ Ventilation and gas detection requirements are
defined during the vendor drawing review stage
„ Single source of responsibility
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 260
Remote Locations
„ CEC 2006 Appendix B
„ Note on rule 18-006
www.EngWorks.ca
www.EngWorks.ca

Related to the Definition of a Zone 2 location (<10hrs per Year)

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 261
Additional Considerations
„ Open and Closed Drains
„ Natural Barriers and depressions
„ www.EngWorks.ca
“abnormal” www.EngWorks.ca
operation of equipment
„ Manned and Unmanned facilities
„ Locating electrical equipment outside of
classified areas when-ever possible

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 262
Additional Considerations
„ Posting of area classifications on building
entrances or plant areas

„ www.EngWorks.ca
Training ofwww.EngWorks.ca
plant and construction personnel

„ Area classification may change over the life of


the facility based on operating and
maintenance experience
„ Reviews should be carried out throughout the life
of the facility

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 263
Additional Considerations
„ Area classification may change over the life of
the facility based on operating and
maintenance experience
„ www.EngWorks.ca
www.EngWorks.ca
Reviews should
of the facility
be carried out throughout the life

„ New or modified equipment


„ Changes in installation protection
„ Operations experience
„ Changes in operational procedures
„ Actual measurements
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 264
Area Classification Worksheet

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 265
Resulting Area Classification

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 266
Area Classification Study
„ Codes and Recommended Practices Used
„ Conditions where the study is valid
„ Hazardous Materials Worksheet
Source of Release Worksheet
www.EngWorks.ca
„

„ www.EngWorks.ca
List of assumptions
„ Fugitive Emission Calculations
„ Ventilation Calculations
„ List of recommendations
„ Installation and operations
„ Rational for gas detector placement
„ Area Classification Drawings
„ Plan view and cross sections

„ Professional Engineering Stamp

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 267
Drawing requirements
„ Area Classifications Information
„ Class
„ Zone

„
www.EngWorks.ca
„ Provide a legend consistent IEC recommendations
www.EngWorks.ca
Group Classification
„ May be more than one Group for a facility
„ AIT
„ Indicate a Maximum temperature and what material it is
based on rather than a Temperature Code
„ Cross section drawing details where
appropriate

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 268
Notes to the Drawings
„ Assumptions
„ Reference the Area Classification Study
Document www.EngWorks.ca
„
www.EngWorks.ca
Indicate ventilation requirements for each
building
„ Indicate gas detection and equipment
operating requirements
„ Indicate walls are required to be vapour-tite

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 269
Refinery Application

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 270
Refinery Plot Plan

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 271
RP 505 Figure 20

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 272
Area Classification Example 3 -
Upgrader

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 273
Area Classification Worksheet for a Refinery

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 274
Area Classification - Upgrader

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 275
Area Classification Section Details

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 276
Considerations for Refinery
Facilities
„ Natural barriers and the use of elevation as
means to define an area classification
Drains
„

„
www.EngWorks.ca
www.EngWorks.ca
Gas Detection
„ Process areas
„ Unclassified buildings
„ Locating electrical equipment outside of
classified areas when-ever possible

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 277
Considerations for Refinery
Facilities
„ Vehicles – Road and Rail Traffic
„ Fixed combustion engines
„ www.EngWorks.ca
Gas www.EngWorks.ca
turbine drives
„ Hot surfaces

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 278
Area Classification
www.EngWorks.ca
www.EngWorks.ca

Alternate Methods

Calgary Oct 10, 2006


Edmonton Oct 11,
2006 Hazardous Area Classification 279
NFPA 497

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 280
HTA Liquid at Grade
(NFPA 497)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 281
HTA Liquid at Grade
(NFPA 497)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 282
Adequately Ventilated Indoor
Location (NFPA 497)

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 283
API Alternative Method
Appendix D RP 505
„ Incorporates the results of extensive
dispersion modeling
Requires www.EngWorks.ca
additional engineering skill and
„
www.EngWorks.ca
equipment knowledge
„ Suitable for well-ventilated outdoor
locations
„ Loosely based on the methods
described in IP15 - 2002
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 284
RP-505 Appendix D
Point Source Concept
„ Involves determining the “hazard radius” of
all potential release sources
Volatility of release sources
www.EngWorks.ca
„
www.EngWorks.ca
„ Quantity of release materials
„ Nature of the release
„ Velocity of the materials being released
„ Release source boundaries are plotted on an
area diagram which is then simplified to form
the overall area classification
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 285
Example Pump Application
Pump #1 #2
Pump #2
(Pentane)
Product Butane Pentane
Motor

Seal Low Low

www.EngWorks.ca
Vertical
Emission Emission
Pump #1
(Butane) www.EngWorks.ca Type Seal Seal
P-suc 94 110
(psig)
Material Oper Vapor
Temp Pressure P-dis 130 950
(ºF) (psig)
(psia)
P-Pump 150 319
Seal
Butane 110 60
(psig)
Pentane 180 56
Flow 90 350
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification rate gpm gpm 286
RP 505 Figure 20

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 287
15m

15m

Pump #2

www.EngWorks.ca
(Pentane)

15m 15m
www.EngWorks.ca Motor

15m
Vertical
Pump #1
(Butane)
15m

Transient Vapour Zone 15m

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 288
Classification Procedure
1. Determine the volatility classification based
on Figure D-1
2. Estimate the mass release rate
„
www.EngWorks.ca
www.EngWorks.ca
May be estimated using the guidelines provided:
„ Table D-1 for pumps, D-4 for flanges and valves
3. Determine the hazard radius
„ Figure D-3 for heavier than air
„ Figure D-4 for lighter than air

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 289
Vapor Pressure – Temperature
Volatility Chart
Category 1 – Materials
„

that almost immediately


flash to atmosphere
www.EngWorks.ca
www.EngWorks.ca
„ Category 2 – Class 1A

Flammable Liquids
„ Category 3 – Class 1B

Flammable Liquids
„ Category 4 – Class II

and heavier materials

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 290
1. Determine the Volatility
Classification
Butane
Category 1
Pentane Volatility
Category 2
Volatility
www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Butane Operating TempHazardous
110ºF Pentane Operating Temp 180ºF
Area Classification 291
2. Estimate the mass release
rate

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 292
Guidelines for Predicting Release Rates

www.EngWorks.ca
www.EngWorks.ca

Butane Pump #1
Pentane Pump #2
Category 1 Volatility
Category 2 Volatility
Flow rate = 90 gpm
Flow rate = 350 gpm
Discharge Pressure
Calgary Oct 10, 2006
= 150 psig 293
Edmonton Oct 11, 2006
Discharge Pressure = 319 psig
Hazardous Area Classification
3. Determine the Hazard
Radius

www.EngWorks.ca
www.EngWorks.ca

Pentane Pump #2

Butane Pump #1

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 294
Resulting Area Classification

3.04m

www.EngWorks.ca
www.EngWorks.ca 3.04m
Pump #2
3.04m
(Pentane)
Motor
3.04m 3.04m
Vertical 1.52m
Pump #1
(Butane)

3.04m

Transient Vapour Zone

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 295
Problems with the Point Source
Concept
„ Requires the release rate from various
sources be determined
„ Maywww.EngWorks.ca
reduce the extent of the area
www.EngWorks.ca
classification but the extent may be
difficult to communicate

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 296
Application to a Refinery

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 297
Fuel Gas Manifold Building
As per RP 505

PSV

www.EngWorks.ca
Process
www.EngWorks.ca Vent

MV
Regulator
MV MV

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 298
Fuel Gas Manifold in Large
Building as per RP 505

www.EngWorks.ca
Process
www.EngWorks.ca Vent
Manifold occupies a very small
Area within the building
Does the whole building need to be classified?

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 299
Option 1 - Classify the
building as Non-hazardous

O&G Code 2002 Appendix B19 Note to rule 19-000


Piping systems with a pressure of 700 kPa or less

www.EngWorks.ca
(utility gas distribution, equipment fuel supplies, Process
ect.) are consideredwww.EngWorks.ca
“low risk” and do not generally Vent
require the area around them be classified.

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 300
Building is unclassified therefore,
common sense does not prevail

Disconnect mounted above


fuel gas manifold
Disconnect adjacent
Fuel gas regulator

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 301
CEC Standata

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 302
RP505 Annex F
Alternative Ventilation Criteria
„ Application of the Point Source method
described in IEC 60079-10
„ www.EngWorks.ca
Applicable for use in Indoor Applications
www.EngWorks.ca
„ Allows the hazardous classification of
portions of an interior based on the
grade of release and degree of
ventilation available

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 303
RP505 Annex F
Alternative Ventilation Criteria
„ Illustrates a calculation method that
allows the user to predict
„
www.EngWorks.ca
A hypothetical volume
www.EngWorks.ca
„ The dispersion time of a release
„ Estimate the level of air movement
required to limit the volume

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 304
Example Scenario
„ Fuel gas manifold for a gas fired steam generator
operating within a large building
Building 12H X 15W X 32LFlammable Methane
Dimensions
Volume
www.EngWorks.ca
5760m
www.EngWorks.ca
Molar Weight 16
3
Material

Air Flow 9 m3/sec %LEL 5%


ACPH 5.63 Release Flange
Source
Ambient 20ºC Release Grade Secondary
Temperature
Operating 350 kPA Safety Factor X2
Pressure
Calgary Oct 10, 2006
Hazardous Area Classification 305
Edmonton Oct 11, 2006
Estimation of
Hypothetical Volume Vz

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 306
Minimum Flow Rate Required

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 307
Maximum Rate of Release
(dG/dt)max = 0.006aP(M/t)0.5

(dG/dt)max = mass release in kg/sec


www.EngWorks.ca
www.EngWorks.ca
a = cross-sectional area of the leak in m2
P = upstream pressure in N/m2
M = molecular weight kg/kmole
t = absolute temperature of release ºK

(Multiply kPa X 1000 to get N/m2)


Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 308
Rule of Thumb for Cross
Sectional Areas of Release

„ Use 0.25mm2 for flanges, screwed fittings,


regulator diaphrams and valve glands
www.EngWorks.ca
www.EngWorks.ca

„ Use 2.5mm2 for purge vents, drains, sample


points, relief valve vents, compressor shaft
seals and booster pumps
Source IGE/SR25

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 309
Release rate
(dG/dt)max = 0.006aP(M/t)0.5

www.EngWorks.ca
a = 2.5mm2 = 2.5 X 10-5 m2
www.EngWorks.ca
P = 350kPA = 350000 N/m2
M = 16 kg/kmole
t = 20ºC = 293ºK

(dG/dt)max = 1.23 X 10-4 kg/sec

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 310
Volumetric Flow Rate

www.EngWorks.ca
www.EngWorks.ca
1.23 X 10-4 kg/sec 293 = 0.0074 m3/sec
X
0.5 X 0.03328 293

LEL = 0.416 X 10-3 X 16 X 5 = 0.03328


Calgary Oct 10,m2006
Edmonton Oct 11, 2006 Hazardous Area Classification 311
Hypothetical Volume

www.EngWorks.ca
V =z
5 Xwww.EngWorks.ca
0.0074 m3/sec
= 23.12m 3

0.0016 sec-1

1/3
3Vz r
r= = 1.78m
4¶ V = 4/3¶r3

C = air changes/sec = ACPH/3600 = 5.63/3600 = 0.0016


Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 312
Extent of Area Classification

Classified area within the building is limited to the extent


the hazard exists

www.EngWorks.ca
Process
Rest of building remains unclassified
www.EngWorks.ca Vent

1.78m

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 313
Time of Persistance

www.EngWorks.ca
www.EngWorks.ca

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Edmonton Oct 11, 2006 Hazardous Area Classification 314
For a 100% LEL Release

www.EngWorks.ca
t=
www.EngWorks.ca
-5
0.0016
x Ln 5% x 0.5
100%

t = 11527 seconds = 3.2 hrs

Falls within the criteria of < than 10 hrs for a Zone 2 location
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 315
An interesting thought
What are the minimum number air changes it
takes to reduce a flammable release to below its %LEL
within the <10hr Zone 2 design criteria?

www.EngWorks.ca
www.EngWorks.ca-5 Ln LEL% x 0.5
C=
10hrs 100%
-5 x Ln 5.0% x 0.5 = 1.84 ACPH
Methane C =
10hrs 100%

Naphtha C=
-5 x Ln 0.9% x 0.5 = 2.7 ACPH
10hrs 100%
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 316
Introduction to the Risk Based
Approach to Area Classification
„ Method that defines the extent of an
area classification based on an
www.EngWorks.ca
predefined acceptable level
www.EngWorks.ca of risk
„ Introduced into IP15 in 2002
„ Similar to the approach used in other
fields for making business and technical
decisions

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 317
Risk Matrix

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 318
IP15 Risk Based Process
„ Applicable to situations where the
release rate is unknown, unspecified
www.EngWorks.ca
and of variable quantity
www.EngWorks.ca
„ Abnormal releases

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 319
IP15 Risk Based Process
„ Determine the level of Individual Risk (IR)
associated with facility
„ Use the results to determine the equivalent

„
www.EngWorks.ca
hole size for a given release
www.EngWorks.ca
Use the hole size to determine the release
rate based on the pressure and flammable
material composition
„ Calculate the hazard radii
„ Using charts provided in IP15
„ Calculated using a set of equations provided

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 320
Individual Risk (IR)

IR Ignited Release = Fflam x Pign x POcc x V x Nrange

F
flam = www.EngWorks.ca
Frequency of flammable Atmosphere
www.EngWorks.ca
P
ign = Probability of Ignition
P
Occ = Probability of Occupancy
V = Vulnerability
N Range = Number of release sources in range
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 321
Closing thoughts
„ Area Classification should be carried out before the
plot plan is finalized
„ Specify the Auto-ignition temperature on the
drawings rather than a T-Code

„
www.EngWorks.ca
„ Reduce the www.EngWorks.ca
confusion
Buy some ºC
„ Posting of area classifications on building entrances
or plant areas
„ Training of plant and construction personnel

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 322
Closing thoughts
„ Area classification may change over the
life of the facility based on operating
andwww.EngWorks.ca
maintenance experience
www.EngWorks.ca
„ Reviews should be carried out

throughout the life of the facility


„ Careful about reclassifying Zone 2 to
Unclassified

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 323
Closing thoughts
„ Facilities such as storage pumps,
loading and discharge facilities –
www.EngWorks.ca
classification should be
www.EngWorks.ca based on
most volatile material anticipated
the

„ Not a good idea to denote small


pockets of non hazardous areas within
hazardous areas

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 324
Closing thoughts
„ Adopt physical plant features to denote
area classification boundary lines (roads
paved areas ect.)
„
www.EngWorks.ca
www.EngWorks.ca
Interface with other disciplines on
projects
„ May not be familiar with area classification
concepts
„ Insure vendors are made aware of area
classification requirements
Calgary Oct 10, 2006
Edmonton Oct 11, 2006 Hazardous Area Classification 325
Closing thoughts
„ Beware of Operator Intervention

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 326
Additional References
„ Practical Considerations of Area Classification: How
Far to Classify – John H. Rannells IEEE Industry
Applications Magazine May/June 1996

„
www.EngWorks.ca
www.EngWorks.ca
Industrial Facilities Gain New Area Classification
Guidelines – D.Bishop, D. Jagger, J. Propst, IEEE
Industry Applications Magazine Jan/Feb 2000

„ Volatility and Mists – Electrical Area Classification


Important Variables, J. Propst IEEE Paper PID 99-09

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 327
Additional References
„ Adapting to the Dual Hazardous Area Classification System, P.
Babiarz, D. Liggett, C. Wellman, IEEE Industry Applications
Magazine March/April 1998

„
www.EngWorks.ca
A Risk Based Approach to Hazardous Area Classification – KJ
www.EngWorks.ca
Glynn IEE Conference Publication No. 469, IEE 1999

„ Applying the API Alternate Method for Area Classification –


J.Propst, L. Barrios, B Lobitz, IEEE PCIC Conference
Proceedings Denver 2005

„ More references cited in Appendix D19 – Engineering Guidelines


Code for Electrical Installations at Oil and Gas Facilities

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 328
Questions?

www.EngWorks.ca
www.EngWorks.ca

Calgary Oct 10, 2006


Edmonton Oct 11, 2006 Hazardous Area Classification 329

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