Documente Academic
Documente Profesional
Documente Cultură
GT2017
June 26-30, 2017, Charlotte, NC, USA
GT2017-64181
ABSTRACT INTRODUCTION
In light of the potential of butanol as an alternative fuel for Initiatives to replace fossil fuels by fuels derived from
blending with petroleum fuels such as gasoline, diesel or Jet A, biofeedstocks (i.e. biofuels) are recently gaining importance
experimental data regarding the burning characteristics of these due to environmental and sustainability reasons. Even though
blends are required in order to better understand their fossil fuels are likely to remain dominating transportation and
combustion process. In this study, freely-falling droplets of energy systems in the near future [1, 2], renewable biofuels
butanol, Jet A, and their mixtures (10, 20 and 50% butanol by have the potential to reduce their consumption, and therefore
volume) were examined in a combustion chamber which their environmental footprint, especially through usage as
provides representative conditions of real flames, both in terms additives to conventional fuels. In contrast to fossil fuels, the
of temperature and oxygen availability. The combustion biomass used to produce biofuel is renewable, carbon-neutral
characteristics reported here include evolution of droplet sizes, and domestically available [3, 4]. Furthermore, biofuels are
burning rates, soot measurements, and the occurrence of reported to have negligible sulfur content and to inhibit PAH
microexplosions and soot shells. Results show that the and soot formation [4, 5].
evolution of droplet diameter for butanol, Jet A and their blends The most widely used biofuel today is by far bio-ethanol
are very similar, regardless of the obvious compositional [2, 5], which is commonly added to gasoline for its use in
differences. Sooting behaviors are found to be quite different, spark-ignition engines. Ethanol production via fermentation of
with a clear reduction in the sooting propensity as the butanol plants and starches was among the very first developments in
content in the fuel increases. These results are consistent with a biofuels because of the relatively low cost of production due to
previous study in a gas turbine showing similar performance the existence of a well-established alcohol industry and
among Jet A and its blends with butanol, suggesting that such infrastructure [1]. Although ethanol production from edible
mixtures are promising alternative fuels with very similar crops poses serious concerns, such as competition with the food
combustion characteristics to Jet A, but with much less industry or indirect land-use change, it remains nowadays as
propensity to soot. Moreover, this study provides new results the major source for bio-ethanol feedstock [2]. These concerns
on the combustion properties of Jet A/butanol blends, for which over the so-called first generation biofuels have motivated
very scarce data exist in the open literature. efforts to find new feedstocks which do not compete with the
food industry, such as lignocellulosic biomass or residual waste
[1, 2]. Biofuels derived from such feedstocks are called second
[Keywords: Droplet combustion, Butanol, Jet A, Soot] generation biofuels, and although ethanol can also be produced
from cellulosic biomass [6, 7], there has been an important
a) b)
Fig. 2. Images taken by both cameras for the same droplet (Jet A, 10%
O2, 17 mm after injection): a) Double-exposure BW picture showing
the falling droplet surrounded by its soot shell; b) Color picture
displaying the droplet, the soot shell and a faint flame.
Fig. 1. Schematic of the droplet combustion facility.
Jet A
B10
B20
B50
Butanol
Fig. 9. Evolution of droplet and soot shell for the examined fuels (cropped double-exposure BW images). For a better
comparison, pictures are arranged according to their approximate length after injection (L).
Fig. 9 clearly shows that, as the butanol content in the the surrounding soot cloud. At that point, the droplet diameter
blend increases, the formation of soot shells is delayed, with is estimated to be less than 10 µm. Somewhere between L=24.4
the mixture B50 not displaying any soot shell until practically and 24.7 mm, the microexplosion occurs, with the result as
reaching the droplet depletion length. Likewise, the soot shell presented in the last picture of the sequence, where the soot
registered at a certain location after injection becomes agglomerates are dispersed, and their oxidation gives the
progressively thinner as the mixture is enriched in butanol. The luminosity macroscopically observable as a tiny spark. These
soot shell becomes thicker as the droplet combustion proceeds, last two pictures of Fig. 10 display the same droplet (by means
and near the end of the droplet burning the soot particles of the double-exposure method), with a time lapse between
agglomerate into a self-supported crust which completely shots of 500 µs.
encloses the droplet, as typically happens in convection-free
droplet combustions experiments such as [12]. Droplet
diameter cannot be measured in the presence of this soot and,
for this reason, some curves in Fig. 6 lack a few points at the
end of the droplets lifetimes. Droplet depletion occurs with a
weak microexplosion, macroscopically visible as a tiny spark at
the end of the flame trace. This feature has been reported in
other free-falling droplet combustion works (e.g. [37]). Here, it
was possible to observe those microexplosions in the close-up
BW images due to the surrounding soot shells, which act as a
‘marker’. Microexplosion sequences have been captured for Jet
A, B10 and B50, as displayed in Fig. 9.
A full droplet extinction sequence for the mixture B50 is
presented in Fig. 10, where the faint soot shell surrounding the Fig. 10. Extinction sequence of B50 droplets with 10% O2 in
the coflow.
droplet appears to shrink, becoming progressively thicker as
the droplet diameter rapidly diminishes. 24.4 mm after
injection, the droplet becomes almost indistinguishable from
Fig. 12. Axial variation of the flame traces’ luminosity for 150
µm droplets of B50 at different oxygen conditions in the coflow.
The vertical dotted lines indicate the droplet consumption
Fig. 11. Long exposure photographs for 150 µm droplets of B50 at lengths for each condition.
different oxygen conditions in the coflow.
As all the flame traces were captured with fixed camera Once the effect of oxygen availability is ascertained, the
settings, a direct comparison of flame brightness can provide a flame traces captured for different fuels for the 3% O2
soot propensity indicator for each fuel and condition. Fig. 12 condition are compared in Fig. 13. As stated above, pure
shows an analysis of the flame traces displayed in Fig. 11 (B50 butanol traces are completely non-sooty, and for the exposure
at 0, 3 and 10% O2). The axial profiles of luminosity shown in time fixed in these images (200 ms) its trace does not appear
Fig. 12 were calculated by adding the values at all pixels across visible in the photograph. By increasing the exposure time to a
a given cross section of the flame trace. Although the few seconds, a faint blue trace corresponding to the actual
quantitative value of this result is unclear (e.g., due to eventual flame boundary appears, but with much less intensity than the
differences in soot temperature), the luminosity curves can be yellowish sooty traces shown for the other fuels. Comparing
interpreted in terms of the differences in the amount of soot for the flame streaks of Jet A and its blends, it is noted that the
the various fuels at fixed experimental conditions. The vertical addition of butanol clearly decreases the yellowish soot
lines indicate the droplet consumption lengths for B50 at each luminosity, especially for the B50 case. The other two blends
oxygen condition (L=31.0, 28.5 and 24.7 mm for 0, 3 and 10% present a more similar appearance to pure Jet A, although with
O2 respectively). It is noteworthy that droplet depletion length a slightly more orangish and less intense traces. Since soot
only corresponds with flame trace extinction for the 10% O2 formation occurs in the fuel side of the envelop diffusion flame,
condition. This is due to the relatively high oxygen availability a thin blue flame layer should be observable surrounding the
in the coflow, which enhances soot oxidation. In the 3% O2 yellowish sooty streak. But, as it was observed for the tests
condition, the oxidation of the already generated soot is much with pure butanol, this blue luminosity due to
slower, and therefore the flame trace reaches slightly longer chemiluminescence presents much less intensity than the black-
axial distances than the droplets themselves. The limit case is body emission from soot particles, and therefore it remains
the pure evaporation condition (0% O2), where the absence of eclipsed by this last one.
oxygen in the coflow prevents soot consumption, and all the
produced soot remains in the combustion chamber. In this case,
Fig. 15. Soot index axial variation for Jet A, B10, B20 and B50 with
0% O2 in the coflow. ACKNOWLEDGMENTS
Fig. 16. Integrated soot index for Jet A, B10, B20, B50 and butanol REFERENCES
with 0% O2 in the coflow.
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